公开(公告)号：US5368691A

公开(公告)日：1994-11-29

申请号：US991006

申请日：1992-12-16

申请人： Lionel Asselineau ,  Paul Mikitenko ,  Jean Charles Viltard ,  Massimo Zuliani

发明人： Lionel Asselineau ,  Paul Mikitenko ,  Jean Charles Viltard ,  Massimo Zuliani

IPC分类号： B01D3/34 ,  B01D3/00 ,  B01J8/02 ,  B01J8/04 ,  B01J8/20 ,  C07C2/66 ,  C07C15/073 ,  C07C15/085 ,  C07C41/06 ,  C07C41/42 ,  C07C43/04 ,  B01D3/26

CPC分类号： C07C41/42 ,  B01D3/009 ,  B01J8/02 ,  B01J8/0469 ,  B01J8/048 ,  C07C2/66 ,  C07C41/06 ,  B01J2208/00548 ,  B01J2208/0061 ,  Y02P20/127 ,  Y10S203/06

摘要： A reactive distillation process which makes it possible, in the same enclosure, to carry out a catalytic reaction and isolate by distillation the sought product, in which the liquid phase containing the reagents passes from bottom to top through at least one catalyst bed, without the vapor phase of the distillation traversing said catalyst beds. These operating characteristics occur in a reactive distillation zone (C) including an alternation of distillation cells (D) having one or more trays (5) and reaction cells (R) containing the catalyst beds and designed in such a way that the liquid phase flowing from a distillation tray (5) flows above an overflow ( 7) through a downpipe (6) and approaches the base of the catalyst bed (8), traverses the latter in a downward flow and is then allowed to flow over a distillation tray (5) of the following distillation cell (D), so that the distillation vapor circulating from bottom to top through the distillation trays (5) does not traverse said reaction cells (R). Each reaction cell (R) is physically separated from the adjacent distillation cell or cells (D). The process can in particular be applied to the synthesis reactions of tertiary alkyl ethers by the addition of aliphatic monoalcohols (methanol, ethanol) on isoolefins (isobutene, isopentene).

摘要翻译： 反应蒸馏方法使得在相同的外壳中可以进行催化反应并通过蒸馏分离所寻求的产物，其中含有试剂的液相从底部至顶部通过至少一个催化剂床，而没有 蒸馏蒸汽穿过所述催化剂床。 这些操作特性发生在包括具有一个或多个塔盘（5）和含有催化剂床的反应池（R）的蒸馏单元（D）的交替的反应蒸馏区（C）中，并且设计成使得液相流动 从蒸馏托盘（5）流过溢流器（7）通过降管（6）流动并接近催化剂床（8）的底部，以向下的流动方式穿过其中，然后允许其流过蒸馏塔盘（ 5），使得从底部到顶部通过蒸馏塔盘（5）循环的蒸馏蒸气不穿过所述反应池（R）。 每个反应池（R）与相邻的蒸馏单元（D）物理分离。 通过在异烯烃（异丁烯，异戊烯）上加入脂族一元醇（甲醇，乙醇），该方法特别适用于叔烷基醚的合成反应。

公开(公告)号：US4366032A

公开(公告)日：1982-12-28

申请号：US298432

申请日：1981-09-01

申请人： Paul Mikitenko ,  Lionel Asselineau

发明人： Paul Mikitenko ,  Lionel Asselineau

IPC分类号： C07C27/00 ,  C07C29/82 ,  C07C29/84 ,  C07C31/02 ,  C07C67/00 ,  B01D3/40

CPC分类号： C07C29/84 ,  C07C29/82 ,  Y10S203/14

摘要： Process for dehydrating aliphatic alcohols admixed with water wherein the alcohols-water mixture is subjected to a first fractionation in the presence of a selective solvent, giving a vapor effluent containing dehydrated light alcohols and a liquid phase containing heavy alcohols, water and the selective solvent, said liquid phase being subjected to a second fractionation giving as vapor effluent an hetero-azeotropic mixture of water and heavy alcohols and, as liquid effluent, the selective solvent, which is fed back, said hetero-azeotropic mixture being condensed and separated into:(a) a light phase of high alcohol content which is subjected to a third fractionation giving a vapor effluent which is fed back and dehydrated heavy alcohols as liquid effluent, and(b) a heavy phase which is subjected to a fourth fractionation giving a vapor effluent which is fed back and water as liquid effluent.

摘要翻译： 与水混合的脂肪醇脱水方法，其中醇 - 水混合物在选择性溶剂存在下进行第一分馏，得到含脱水轻醇的蒸气流出物和含有重醇，水和选择性溶剂的液相， 所述液相经受第二次分馏，作为蒸汽流出物，得到水和重醇的异质共沸混合物，并且作为反馈的选择性溶剂作为液体流出物，所述异质共沸混合物被冷凝并分离成： a）高酒精含量的轻相，其进行第三分馏，得到蒸汽流出物，其被反馈并脱水重醇作为液体流出物，和（b）重相，其进行第四分馏，得到蒸气流出物 其被反馈并且作为液体流出物的水。

公开(公告)号：US4299999A

公开(公告)日：1981-11-10

申请号：US148341

申请日：1980-05-09

申请人： Paul Mikitenko ,  Lionel Asselineau

发明人： Paul Mikitenko ,  Lionel Asselineau

IPC分类号： C07C41/06 ,  C07C41/42 ,  C07C41/05 ,  C07C41/34

CPC分类号： C07C41/42 ,  C07C41/06

摘要： Process for producing and isolating methyl-tert-butyl ether (MTBE) comprising etherifying isobutene, contained in a C.sub.4 hydrocarbons mixture, with methanol in the presence of a recycle stream of C.sub.5 and/or C.sub.6 hydrocarbons, separating from the obtained reaction product, by fractionation, at least the major part of the unconverted C.sub.4 hydrocarbons, and discharging them, and fractionating the remaining product in two fractions, one of which contains an azeotrope of methanol with the C.sub.5 and/or C.sub.6 hydrocarbons and is recycled, the other fraction containing the purified MTBE.

摘要翻译： 在C5烃和/或C6烃循环流的存在下，用甲醇在甲醇中生成和分离甲基叔丁基醚（MTBE）的方法，该方法包括在C4烃混合物中的醚化异丁烯，与所得反应产物分离， 分馏，至少是未转化的C4烃的主要部分，并将其排出，并将剩余的产物分馏成两个馏分，其中一个馏分含有甲醇与C5和/或C6烃的共沸物并被再循环，另一部分含有 纯化的MTBE。

公开(公告)号：US5536887A

公开(公告)日：1996-07-16

申请号：US319691

申请日：1994-10-07

申请人： Ari Minkkinen ,  Paul Mikitenko ,  Lionel Asselineau

发明人： Ari Minkkinen ,  Paul Mikitenko ,  Lionel Asselineau

IPC分类号： C07C41/06 ,  C07B61/00 ,  C07C41/42 ,  C07C43/04 ,  C07C41/00

CPC分类号： C07C41/42

摘要： Process for the production of tertiary ethers (MTBE, ETBE, TAME, ETAE) in which a hydrocarbon cut (1) containing four or five carbon atoms is reacted with methanol or ethanol (2, 3) in a reactor and recovering ethers (11) and a distillate (10) after distillation (C.sub.I). The distillate undergoes a first extractive distillation step in column (C.sub.11) in the presence of a solvent (27) which is selective towards olefinic hydrocarbons. A saturated hydrocarbon-rich overhead fraction (15) is recovered along with a bottom fraction (18) which is rich in olefins, solvent and alcohol. The olefins (20) are separated from the solvent and alcohol (24) in a second extractive distillation step (C.sub.III). The olefins are isomerised in a skeletal isomerisation reactor (5) and the isomerate is recycled (2) to reactor (6). The alcohol and solvent are separated in a stripping column (C.sub.IV). Alcohol (26) is recycled to the synthesis reactor (6) while the solvent (27) is recycled to C.sub.II. The temperature at the bottom of the second column (C.sub.III) can be reduced by addition of fresh (4) or recycled (34) alcohol.

摘要翻译： 生产叔胺（MTBE，ETBE，TAME，ETAE）的方法，其中将含有4或5个碳原子的烃馏分（1）与甲醇或乙醇（2,3）在反应器中反应并回收醚（11） 和蒸馏后的馏出物（10）（CI）。 馏出液在（C11）塔中，在对烯烃具有选择性的溶剂（27）的存在下进行第一萃取蒸馏步骤。 饱和富含烃的塔顶馏分（15）与富含烯烃，溶剂和醇的塔底馏分（18）一起回收。 在第二萃取蒸馏步骤（CIII）中将烯烃（20）与溶剂和醇（24）分离。 烯烃在骨架异构化反应器（5）中异构化，异构体再循环（2）至反应器（6）。 醇和溶剂在汽提塔（CIV）中分离。 将醇（26）再循环到合成反应器（6）中，同时将溶剂（27）再循环至CII。 通过添加新鲜（4）或再循环（34）酒精可以减少第二塔（CIII）底部的温度。

公开(公告)号：US4302298A

公开(公告)日：1981-11-24

申请号：US123539

申请日：1980-02-22

申请人： Paul Mikitenko ,  Lionel Asselineau

发明人： Paul Mikitenko ,  Lionel Asselineau

IPC分类号： C07C41/06 ,  C07C41/34 ,  B01D3/14

CPC分类号： C07C41/06 ,  C07C41/36 ,  C07C41/42

摘要： Process for isolating methyl tert-butyl ether contained in the reaction product of methanol with a C.sub.4 hydrocarbon cut containing isobutene, comprising fractionating said reaction product by introducing it at an intermediate point of a distillation zone, recovering methyl tert-butyl ether at the bottom thereof and, at the top thereof, a mixture of C.sub.4 hydrocarbons with methanol which is washed with water and condensed and wherefrom is separated a condensed C.sub.4 hydrocarbon fraction, a portion of which is fed back as reflux to the top of the distillation zone and another portion discharged, and separating the remaining water-methanol mixture by distillation.

摘要翻译： 将甲醇的反应产物中含有的甲基叔丁基醚与含有异丁烯的C 4烃馏分分离出来的方法，该方法包括在蒸馏区的中间点将所述反应产物分馏出来，在其底部回收甲基叔丁基醚 并且其顶部是C4烃与甲醇的混合物，其用水洗涤并冷凝，从中分离出冷凝的C4烃馏分，其中一部分作为回流反馈回蒸馏区的顶部，另一部分 排出，并通过蒸馏分离剩余的水 - 甲醇混合物。

公开(公告)号：US4168209A

公开(公告)日：1979-09-18

申请号：US884512

申请日：1978-03-08

申请人： Paul Mikitenko ,  Lionel Asselineau

发明人： Paul Mikitenko ,  Lionel Asselineau

IPC分类号： C07C7/08 ,  B01D3/36 ,  C07C7/06

CPC分类号： C07C7/08

摘要： Process for separating benzene and/or toluene from mixtures thereof with saturated hydrocarbons, by extractive distillation using an aliphatic N-alkylamide as extraction solvent, comprising introducing in the distillation column, above the level of introduction of the extraction solvent, liquid water in an amount and under such conditions that said water is completely vaporized without substantially diluting the solvent, condensing the vapors discharged from the top of the column and dividing the resulting condensate into a phase of liquid saturated hydrocarbons, and a phase of water.

摘要翻译： 通过使用脂族N-烷基酰胺作为提取溶剂的萃取蒸馏将苯和/或甲苯与其饱和烃的混合物分离的方法，包括在蒸馏塔中引入高于萃取溶剂的引入水平的量， 并且在所述水完全蒸发而基本上不稀释溶剂的条件下，将从塔顶排出的蒸汽冷凝并将所得冷凝物分成液相饱和烃相和水相。

公开(公告)号：US06278029B1

公开(公告)日：2001-08-21

申请号：US09212267

申请日：1998-12-16

申请人： Alain Forestiere ,  Quentin Debuisschert ,  Pierre Marache ,  Paul Mikitenko

发明人： Alain Forestiere ,  Quentin Debuisschert ,  Pierre Marache ,  Paul Mikitenko

IPC分类号： C07C4134

CPC分类号： B01D3/143

摘要： A process for eliminating at least pollutants including polar compounds present in a first fluid, with said first fluid sent to a subsequent treatment, e.g., an etherification process: a) the first fluid containing pollutants is contacted with an auxiliary fluid such as a vapor phase, under operating conditions that are selected so as to obtain, at the end of this first stage, said first fluid that is purified and freed of, for the most part, pollutants, and a vapor phase that is loaded with pollutants, said vapor phase being produced during one phase of the process, and b) at least a portion of said first purified fluid is recycled to a subsequent treatment stage.

摘要翻译： 一种用于消除至少包含存在于第一流体中的极性化合物的污染物的方法，其中所述第一流体被输送到随后的处理，例如醚化过程：a）含有污染物的第一流体与辅助流体例如气相 在选择的操作条件下，在第一阶段结束时获得被净化并且大部分被污染物排出的第一流体和装载有污染物的气相，所述气相 在该过程的一个阶段期间产生，以及b）将所述第一纯化流体的至少一部分再循环到随后的处理阶段。

公开(公告)号：US5925234A

公开(公告)日：1999-07-20

申请号：US747739

申请日：1996-11-12

申请人： Frederic Morel ,  Massimo Zuliani ,  Paul Mikitenko ,  Marc Boulet ,  Roben Loutaty ,  Jean Claude Company

发明人： Frederic Morel ,  Massimo Zuliani ,  Paul Mikitenko ,  Marc Boulet ,  Roben Loutaty ,  Jean Claude Company

IPC分类号： C10G67/00 ,  C10G67/04

CPC分类号： C10G67/0418 ,  C10G67/00 ,  C10G67/04 ,  C10G2400/04

摘要： The invention concerns a petroleum product and a process for the production of a petroleum product which can form part of a blend for an internal combustion engine fuel, the process comprisinga) hydrotreating a hydrocarbon feedstock at a partial pressure of hydrogen at the reactor outlet of about 0.5 MPa to about 6 MPa,b) separating a product (P) from step a) into a product (P1) with a final boiling point of about 300.degree. C. and a product (P2) with an initial boiling point greater than the final boiling point of product (P1),c) performing a liquid-liquid extraction with a solvent (S1), to produce an extract (E1) and a raffinate (R1) from product (P2),d) recovering solvent (S1) from raffinate (R1) to produce a product (Q1), depleted in solvent (S1), which has improved qualities and contains less than 500 ppm by weight of sulphur.

摘要翻译： 本发明涉及石油产品和石油产品的生产方法，该石油产品可以形成内燃机燃料的共混物的一部分，该方法包括：a）在氢的分压下在烃的反应器出口的氢气的加压处理 约0.5MPa至约6MPa，b）将步骤a）中的产物（P）分离成终沸点约300℃的产物（P1）和初始沸点大于 产物（P1）的最终沸点，c）用溶剂（S1）进行液 - 液萃取，从产物（P2）产生萃取物（E1）和萃余液（R1），d）回收溶剂（S1 ）从残液（R1）生产产生（Q1）的产物（Q1），其消耗溶剂（S1），其具有改善的质量并且含有少于500重量ppm的硫。

公开(公告)号：US06336334B1

公开(公告)日：2002-01-08

申请号：US09466980

申请日：1999-12-17

申请人： Ari Minkkinen ,  Paul Mikitenko

发明人： Ari Minkkinen ,  Paul Mikitenko

IPC分类号： C02F122

CPC分类号： C07C15/067 ,  B01D9/0009 ,  B01D9/0059 ,  C07C7/14

摘要： A device for crystallization of a component from a liquid mixture comprising a chamber, a first conduit connected to said chamber for supplying said mixture, a second conduit connected to and in connection with said chamber for introducing cold gas, a third conduit for withdrawing warmed gas from said crystallizer, a turbo-expander for cooling gas withdrawn from said chamber, and a fourth conduit Icading from the turbo-expander to said chamber. The device has particular application for the crystallization of paraxylene.

摘要翻译： 一种用于从液体混合物中结晶组分的装置，包括室，连接到所述用于供应所述混合物的室的第一导管，连接到所述室并用于引入冷气体的第二导管，用于抽出温热气体的第三导管 来自所述结晶器的用于冷却从所述室抽出的气体的涡轮膨胀机，以及从所述涡轮膨胀机到所述室的第四导管。 该装置特别适用于对二甲苯的结晶。

公开(公告)号：US6054630A

公开(公告)日：2000-04-25

申请号：US158453

申请日：1998-09-22

申请人： Paul Mikitenko ,  Christine Travers ,  Jean Cosyns ,  Charles Cameron ,  Jean-Luc Nocca ,  Francoise Montecot ,  Jean-Charles Viltard ,  Michel Dorbon ,  Blaise Didillon

发明人： Paul Mikitenko ,  Christine Travers ,  Jean Cosyns ,  Charles Cameron ,  Jean-Luc Nocca ,  Francoise Montecot ,  Jean-Charles Viltard ,  Michel Dorbon ,  Blaise Didillon

IPC分类号： B01D3/14 ,  B01D3/00 ,  B01J8/02 ,  B01J8/04 ,  C07B37/02 ,  C07B61/00 ,  C07B63/00 ,  C07C5/02 ,  C07C5/03 ,  C07C5/10 ,  C07C5/13 ,  C07C5/27 ,  C07C7/04 ,  C10G7/00 ,  C10G45/00 ,  C10G45/40 ,  C10G45/44 ,  C10G49/00 ,  C07C5/23

CPC分类号： C10G49/002 ,  B01D3/009 ,  B01J8/0257 ,  B01J8/0278 ,  C07C5/02 ,  C07C5/2767 ,  C10G45/00 ,  C10G45/40 ,  C10G45/44 ,  Y02P20/127 ,  Y10S203/06

摘要： For the treatment of a feed comprising a major portion of olefinic hydrocarbons containing 4 carbon atoms per molecule, including isobutene, 1-butene and 2-butenes in a ratio which substantially corresponds to the thermodynamic equilibrium, in which the feed is treated in a distillation zone comprising a stripping zone and a rectification zone associated with at least one hydroisomerization reaction zone, the hydroisomerization reaction zone being at least partially internal to the distillation zone and comprising at least one catalytic bed, in which hydroisomerization of at least a portion of 1-butene is carried out in the presence of a hydroisomerization catalyst and at least one gas stream comprising hydrogen, such that an effluent rich in isobutene leaves the distillation zone overhead and an effluent rich in 2-butenes leaves the bottom, the process being characterized in that each catalytic bed in the internal portion of the hydroisomerization zone is traversed by an ascending co-current of the gas stream and liquid and is substantially out of contact with the distillation vapor.

摘要翻译： 用于处理包含大部分每分子含有4个碳原子的烯烃的进料，包括基本上对应于热力学平衡的比例的异丁烯，1-丁烯和2-丁烯，其中在蒸馏中处理进料 该区域包括与至少一个加氢异构化反应区相关联的汽提区和精馏区，所述加氢异构化反应区至少部分地位于所述蒸馏区的内部，并且包含至少一个催化床，其中至少部分1- 丁烯在加氢异构化催化剂和至少一种包含氢的气流的存在下进行，使得富含异丁烯的流出物离开蒸馏区顶部，富含2-丁烯的流出物离开底部，该方法的特征在于， 加氢异构化区的内部部分的每个催化床由上升的共混物横穿， 气流和液体的电流并且基本上与蒸馏蒸气不接触。