摘要:
A combined process for the conversion of solid starting particles into solid intermediate particles and reducing the median diameter of the intermediate particles to obtain product particles. This process involves flowing a suspension of starting particles through a series of at least two conversion vessels, thereby converting at least part of the starting particles into intermediate particles, adding a supercritical fluid to one or more of the conversion vessels, thereby forming a supercritical suspension, and releasing pressure from the supercritical suspension, thereby expanding the suspension and converting the intermediate particles into product particles.
摘要:
The present invention is directed to a process for preparing a catalyst which comprises combining catalyst components or precursors thereof in an aqueous medium to form a catalyst precursor mixture, feeding the mixture to a shaping apparatus, and shaping the mixture to form particles wherein just before the shaping step the mixture is destabilized. It was found that with this process catalysts can be prepared which have both a good attrition resistance and a high accessibility. The invention further relates to catalysts obtainable by this process.
摘要:
The present invention pertains to A cyclic process for testing FCC catalysts with resid feedstock on a small scale wherein in a first cycle: a) the feed to be cracked is heated to a temperature between 50 and 500° C., b) the heated feed is injected into a riser reactor containing the FCC catalyst to be tested having a temperature between 500 and 800° C., the injection time being less than 2 seconds, c) an inert gas is injected into the lower end of said reactor riser together in the vicinity of the feed injection in a volume ratio of inert gas to vaporized feed of about 0.03 and 10, the mixing of feed and inert gas occurring in said riser reactor; d) the feed is contacted with the FCC catalyst under fluidized conditions for a contact time of less than 8 seconds; e) the feed is stripped from the FCC catalyst and the properties of the product are analyzed; and in a second cycle a quench liquid is injected into said riser reactor in an amount of up to about 20 wt. % of said feed so as to reduce the temperature in said riser reactor and minimize undesirable secondary reactions. The invention also comprises the apparatus employed to carry out the process. With the process of the invention the mass transfer and diffusion limitations of commercial FCC units are properly simulated.
摘要:
A process is described for reducing the oxygen content of a high-oxygen feedstock. The process is particularly suitable for biomass-based feedstocks. The process comprises contacting the feedstock with carbon monoxide and/or coke in the presence of a catalyst. Conveniently, the coke may be present in the form of a deposit on the catalyst. Carbon monoxide may be generated in a regeneration step of the catalyst. The process may be carried out in conventional refinery equipment.
摘要:
Disclosed is a process for storing solar energy in organic compounds. The process comprises providing a water source and a carbon source. Water present in the water source is activated using solar energy. Activated water is reacted with the carbon source to form an organic compound comprising hydrogen and carbon. The organic compound has higher energy content than the carbon source.In a specific embodiment the organic compound is used as a fuel in an electricity-generating device, such as a fuel cell. In this embodiment the preferred organic compound is methanol.
摘要:
A method for reducing the mechanical strength of solid biomass material, in particular lignocellulosic biomass, comprises mixing the solid biomass material with an inorganic material and heating the solid biomass material mixture to a toasting temperature in the range of 105° C. to 140° C. during an exposure time of from 1 minute to 12 hours. Before or after the heat treatment, which is referred to as “toasting”, the biomass material mixture is subject to flash heating. The treatment significantly reduces the mechanical energy required for reducing the particle size of the solid biomass material and is suitable as a pretreatment prior to a conversion reaction of the solid biomass material.
摘要:
Disclosed is a new composition of matter comprising a polymeric material of photosynthetic origin having embedded therein small particles of an inorganic material. The composition of matter is particularly suitable for use in processes whereby the polymeric material is converted to fuels in liquid or gas form, and/or to the valuable specialty chemicals. The polymeric material comprises biomass. More specifically, the polymeric material comprises cellulose and at least one of hemicellulose and lignin.
摘要:
A process is disclosed for converting a particulate solid biomass material to a high quality bio-oil in high yield. The process comprises a pretreatment step and a pyrolysis step. The pretreatment comprises a step of at least partially demineralizing the solid biomass, and improving the accessibility of the solid biomass by opening the texture of the particles of the solid biomass. In a preferred embodiment the liquid pyrolysis product is separated into the bio-oil and an aqueous phase, and the aqueous phase is used as a solvent in the demineralization step and/or in the step of improving the accessibility of the solid biomass by opening the texture of the particles of the solid biomass.
摘要:
A method for converting solid biomass into hydrocarbons includes contacting the solid biomass with a catalyst in a first riser operated at a temperature in the range of from about 50° C. to about 200° C. to thereby produce a first biomass-catalyst mixture and a first product comprising hydrocarbons; a) separating the first product from the first biomass-catalyst mixture; c) charging the first biomass-catalyst mixture to a second riser operated at a temperature in the range of from about 200° C. to about 400° C. to thereby produce a second biomass-catalyst mixture and a second product comprising hydrocarbons; d) separating the second product from the second biomass-catalyst mixture; e) charging the second biomass-catalyst mixture to a third riser operated at a temperature greater than about 450° C. to thereby produce a spent catalyst and a third product comprising hydrocarbons; and f) separating the third effluent from the spent catalyst.
摘要:
A process is disclosed for pretreating lignocellulosic biomass. The process comprises swelling the lignocellulosic biomass with an aqueous liquid. The pretreated lignocellulosic biomass may be used as a feedstock for the enzymatic conversion to ethanol, or in a thermal conversion process to produce bio-oil. The pretreatment results in a greater yield and, in the case of a thermal conversion process, a better quality of the bio-oil.The pretreatment process may be used to adjust the composition and amount of inorganic material present in the lignocellulosic biomass material.