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15 条记录 (耗时 0.022 秒)

    Photographic element containing pyrazoloazole magenta coupler and a specific anti-fading agent
    1.
    发明授权
    Photographic element containing pyrazoloazole magenta coupler and a specific anti-fading agent 失效
    含有吡唑并噻唑品红成色剂的摄影元件和特定的抗褪色剂

    公开(公告)号：US5998122A

    公开(公告)日：1999-12-07

    申请号：US134567

    申请日：1998-08-14

    申请人： Paul P. Spara ,  Stanley W. Cowan

    发明人： Paul P. Spara ,  Stanley W. Cowan

    IPC分类号： G03C7/38 ,  G03C7/30 ,  G03C7/392 ,  G03C1/08 ,  G03C7/26 ,  G03C7/32

    CPC分类号： G03C7/39296 ,  G03C7/301 ,  G03C7/39216 ,  G03C7/3835 ,  G03C7/39236 ,  G03C7/39276

    摘要： The disclosure describes a photographic element comprising a light sensitive silver halide emulsion layer having associated therewith a magenta dye forming coupler containing an azole nucleus and a ballasted compound having Formula I, ##STR1## wherein each R.sub.1 is independently selected from the group consisting of hydrogen and an alkyl, aryl, acyl and acylamino group;L represents a linking atom or group bonded to the phenyl ring by a heteroatom;each "a" independently represents a substituent group at least one of which is linked to the phenyl ring by an N, S, C or O atom and q is 1 to 5;provided that the selection of L and the "a" groups results in no more than one oxygen bond to the phenyl ring.

    摘要翻译： 本公开描述了一种照相元件，其包含感光卤化银乳剂层，其具有与其相关的品红色染料形成成色剂含有唑类核心和具有式I的压载化合物，其中每个R 1独立地选自氢和烷基， 芳基，酰基和酰氨基; L表示通过杂原子与苯环键合的连接原子或基团; 每个“a”独立地表示取代基，其中至少一个通过N，S，C或O原子与苯环连接，q为1至5; 条件是L和“a”基团的选择导致与苯环不超过一个氧键。

    Compositions of iodophenoxy alkanes and iodophenyl ethers in film-forming materials for visualization of the gastrointestinal tract
    2.
    发明授权
    Compositions of iodophenoxy alkanes and iodophenyl ethers in film-forming materials for visualization of the gastrointestinal tract 失效
    用于可视化胃肠道的成膜材料中碘苯氧基烷烃和碘苯基醚的组成

    公开(公告)号：US5326553A

    公开(公告)日：1994-07-05

    申请号：US12171

    申请日：1993-02-02

    申请人： Carl R. Illig ,  Eugene R. Cooper ,  John L. Toner ,  Donald A. Upson ,  Brent D. Douty ,  Thomas J. Caulfield ,  Bacon, Edward R. ,  Kimberly G. Estep ,  Kurt A. Josef ,  Shaughnessy Robinson ,  Paul P. Spara

    发明人： Carl R. Illig ,  Eugene R. Cooper ,  John L. Toner ,  Donald A. Upson ,  Brent D. Douty ,  Thomas J. Caulfield ,  Bacon, Edward R. ,  Kimberly G. Estep ,  Kurt A. Josef ,  Shaughnessy Robinson ,  Paul P. Spara

    IPC分类号： A61K49/04 ,  A61K31/075

    CPC分类号： A61K49/0433 ,  Y10S514/941 ,  Y10S514/942

    摘要： Disclosed are x-ray contrast compositions for oral or retrograde examination of the gastrointestinal tract comprising a polymeric material capable of forming a coating on the gastrointestinal tract and an x-ray producing agent of the formula ##STR1## and methods for their use in diagnostic radiology of the gastrointestinal tract whereinZ=H, halo, C.sub.1 -C.sub.20 alkyl, cycloalkyl, lower alkoxy, cyano, where the alkyl and cycloalkyl groups can be substituted with halogen or halo-lower-alkyl groups;R=C.sub.1 -C.sub.25 alkyl, cycloalkyl, or halo-lower-alkyl, optionally substituted with halo, fluoro-lower-alkyl, aryl, lower-alkoxy, hydroxy, carboxy, lower-alkoxy carbonyl or lower-alkoxycarbonyloxy, (CR.sub.1 R.sub.2).sub.p-- (CR.sub.3 .dbd.CR.sub.4).sub.m Q, or (CR.sub.1 R.sub.2).sub.p --C.tbd.C--Q;R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are independently lower-alkyl, optionally substituted with halo;x is 1-4;n is 1-5;m is 1-15;p is 1-10; andQ is H, lower-alkyl, lower-alkenyl, lower-alkynyl, lower-alkylene, aryl, or aryl-lower alkylin a pharmaceutically acceptable carrier.

    摘要翻译： 公开了用于口腔或逆行检查胃肠道的x射线造影剂组合物，其包含能够在胃肠道上形成涂层的聚合物材料和具有式“IMAGE”的X射线产生剂及其用于诊断放射学的方法 的胃肠道，其中Z = H，卤素，C 1 -C 20烷基，环烷基，低级烷氧基，氰基，其中烷基和环烷基可被卤素或卤代低级烷基取代; 任选被卤素，氟 - 低级 - 烷基，芳基，低级 - 烷氧基，羟基，羧基，低级 - 烷氧基羰基或低级 - 烷氧基羰基氧基取代的C 1 -C 25烷基，环烷基或卤代低级烷基，（CR 1 R 2）p - （CR3 = CR4）mQ，或（CR1R2）pC 3BOND CQ; R 1，R 2，R 3和R 4独立地为低级烷基，任选被卤素取代; x为1-4; n为1-5; m为1-15; p为1-10; Q为药学上可接受的载体中的H，低级烷基，低级烯基，低级炔基，低级亚烷基，芳基或芳基 - 低级烷基。

    Low melting point ionizable epoxy scavengers for residual magenta couplers
    4.
    发明授权
    Low melting point ionizable epoxy scavengers for residual magenta couplers 失效
    用于残留品红色成色剂的低熔点电离环氧清除剂

    公开(公告)号：US5627017A

    公开(公告)日：1997-05-06

    申请号：US427764

    申请日：1995-04-25

    申请人： Krishnan Chari ,  Paul P. Spara ,  Sundaram Krishnamurthy

    发明人： Krishnan Chari ,  Paul P. Spara ,  Sundaram Krishnamurthy

    IPC分类号： C07D303/16 ,  C07D303/22 ,  C07D303/34 ,  C07D303/42 ,  C07D303/46 ,  C07D405/12 ,  C07F5/02 ,  C07F9/655 ,  G03C1/005 ,  G03C7/392 ,  G03C7/388

    CPC分类号： C07D303/22 ,  C07D303/16 ,  C07D303/34 ,  C07D303/42 ,  C07D303/46 ,  C07D405/12 ,  C07F5/025 ,  C07F9/65502 ,  G03C1/005 ,  G03C7/39268 ,  G03C7/39296 ,  Y10S430/136

    摘要： Low melting point epoxy scavenger compounds are disclosed which contain a pH dependent ionizable group to facilitate migration of the scavenger from an adjacent scavenger layer (that does not contain any coupler) to an imaging layer (containing coupler and emulsion) of a photographic element at the pH of development. One aspect of the invention comprises a process of forming an aqueous dispersion of an epoxy compound of the structural formula SI: ##STR1## wherein: R is H, an alkyl group, or an aryl group; L.sub.1 is an alkyl group or an aryl group; L.sub.2 is --O--, --CO--, --S--, --SO.sub.2 --, --PO.sub.2 --, --CO.sub.2 --, --NHCO-- or --NHSO.sub.2 --, wherein L.sub.2 may be orientated in either direction; L.sub.3 is an alkyl group; m is 0 or 1; p is 0 or 1; and X is ##STR2## wherein R' is H or an alkyl or aryl group, with the proviso that where L.sub.2 comprises an ionizable group, X may also be an alkyl group or an aryl group; wherein the compound has a melting point of less than about 50.degree. C. and the process comprises adding the compound in a liquid state to an aqueous solution, and directly dispersing the compound in the aqueous solution. Thermal and photochemical yellowing of a color photographic element, such as a color print, is inhibited by incorporating such compounds into the photographic element.

    摘要翻译： 公开了低熔点环氧清除剂化合物，其含有pH依赖性可电离基团，以促进清除剂从相邻的清除剂层（不含任何偶合剂）迁移至摄影元件的成像层（含有偶联剂和乳液） 发展pH。 本发明的一个方面包括形成结构式为SI：n芳基的环氧化合物的水分散体的方法; L1是烷基或芳基; L 2是-O-，-CO-，-S-，-SO 2 - ， - O 2 - ， - CO 2 - ， - NHCO-或-NHSO 2 - ，其中L2可以沿任一方向取向; L3是烷基; m为0或1; p为0或1; 并且X是，其中R'是H或烷基或芳基，条件是其中L2包含可离子化基团，X也可以是烷基或芳基; 其中所述化合物具有小于约50℃的熔点，并且所述方法包括将液体中的化合物加入到水溶液中，并将化合物直接分散在水溶液中。 通过将这样的化合物并入照相元件中，可以抑制彩色照相元件如彩色印刷的热和光化学变黄。

    Photographic element having improved magenta dye light stability and process for its use
    6.
    发明授权
    Photographic element having improved magenta dye light stability and process for its use 失效
    具有改善的品红染料光稳定性的照相元件及其使用方法

    公开(公告)号：US5925503A

    公开(公告)日：1999-07-20

    申请号：US784851

    申请日：1997-01-15

    申请人： John W. Harder ,  Paul A. Burns ,  Paul P. Spara

    发明人： John W. Harder ,  Paul A. Burns ,  Paul P. Spara

    IPC分类号： G03C7/38 ,  G03C7/46

    CPC分类号： G03C7/3835

    摘要： The invention provides a photographic element comprising a silver halide emulsion layer having associated therewith a dye-forming coupler represented by formula I: ##STR1## wherein X is hydrogen or a coupling-off group; andR' is a tertiary alkyl group and R" represents the group ##STR2## in which R.sup.1, R.sup.2, and R.sup.3 are independently selected alkyl groups, provided that any two of R.sup.1, R.sup.2, and R.sup.3 may join to form a ring;R.sup.4 is hydrogen or a substituent, provided that R.sup.3 and R.sup.4 may join to form a ring when R.sup.4 is a substituent; andW is a substituent selected from the group consisting of --C(O)R.sup.5, --SO.sub.2 R.sup.5, and --P(O)(OR.sup.6).sub.2 in which R.sup.5 is selected from the group consisting of alkyl, aryl, alkoxy, aryloxy, alkylamino, and arylamino groups and R.sup.6 is selected from the group consisting of alkyl and aryl groups.The element exhibits improved magenta dye light stability.

    摘要翻译： 本发明提供了一种照相元件，其包含卤化银乳剂层，其具有与式I化合物形成的染料形成成色剂：其中X为氢或偶合离去基团; 并且R'是叔烷基，R“表示其中R 1，R 2和R 3是独立选择的烷基的基团，条件是R 1，R 2和R 3中的任何两个可以连接形成环; R4是氢或取代基，条件是当R 4为取代基时，R 3和R 4可以连接形成环; 并且W是选自-C（O）R 5，-SO 2 R 5和-P（O）（OR 6）2的取代基，其中R 5选自烷基，芳基，烷氧基，芳氧基，烷基氨基 和芳基氨基，R 6选自烷基和芳基。 该元件表现出改善的品红染料光稳定性。

    Polyiodinated aroyloxy esters
    9.
    发明授权
    Polyiodinated aroyloxy esters 失效
    多碘化芳酰基酯

    公开(公告)号：US5466433A

    公开(公告)日：1995-11-14

    申请号：US261794

    申请日：1994-06-20

    申请人： Edward R. Bacon ,  Sol J. Daum ,  Paul P. Spara

    发明人： Edward R. Bacon ,  Sol J. Daum ,  Paul P. Spara

    IPC分类号： C07C69/76 ,  A61K49/04 ,  C07C233/54 ,  C07C233/88 ,  C07C233/91

    CPC分类号： A61K49/0433 ,  C07C233/54 ,  C07C233/88 ,  C07C233/91

    摘要： Compounds having the structure ##STR1## wherein Z--COO).sub.m is the residue of a polyiodinated aromatic acid; m is 1, 2, 3 or 4;n is an integer from 1 to 20;R.sup.1 and R.sup.2 are independently H, alkyl, fluoroalkyl, cycloalkyl, aryl, aralkyl, alkoxy or aryloxy;R.sup.3 and R.sup.4 are independently H, alkyl, fluoroalkyl, cycloalkyl, aryl, aralkyl, alkoxy, aryloxy, halogen, hydroxy or acylamino; andR.sup.5 is H, alkyl, cycloalkyl, aryl, aralkyl, alkoxyalkyl or acetamidoalkyl;are useful as contrast agents in x-ray imaging compositions and methods.

    摘要翻译： 具有结构的化合物，其中Z-COO）m是多元芳族酸的残基; m为1,2,3或4; n为1〜20的整数， R 1和R 2独立地为H，烷基，氟烷基，环烷基，芳基，芳烷基，烷氧基或芳氧基; R 3和R 4独立地为H，烷基，氟代烷基，环烷基，芳基，芳烷基，烷氧基，芳氧基，卤素，羟基或酰基氨基; R5是H，烷基，环烷基，芳基，芳烷基，烷氧基烷基或乙酰氨基烷基; 作为x射线成像组合物和方法中的造影剂是有用的。