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公开(公告)号：US07612152B2
公开(公告)日：2009-11-03
申请号：US11123859
申请日：2005-05-06
IPC分类号： C08L63/00
CPC分类号： B29C73/163 , B29C73/22 , C08F291/00
摘要： A composite material includes a polymer matrix, a polymerizer, and a plurality of capsules containing a corresponding activator for the polymerizer. The composite material can also include an adhesion promoter, and the polymerizer can be phase separated from the polymer matrix. The composite material can be made by dispersing the polymerizer and capsules into the polymer matrix. These composite materials can exhibit improved environmental stability, and can be used with a wider variety of activators.
摘要翻译： 复合材料包括聚合物基质，聚合反应器和包含用于聚合反应器的相应活化剂的多个胶囊。 复合材料还可以包括粘合促进剂，并且聚合反应器可以与聚合物基质相分离。 复合材料可以通过将聚合反应器和胶囊分散到聚合物基质中来制备。 这些复合材料可以表现出改善的环境稳定性，并且可以与更多种类的活化剂一起使用。
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公开(公告)号：US07723405B2
公开(公告)日：2010-05-25
申请号：US11620276
申请日：2007-01-05
申请人： Paul V. Braun , Soo Hyoun Cho , Scott R. White
发明人： Paul V. Braun , Soo Hyoun Cho , Scott R. White
IPC分类号： C08K9/06
CPC分类号： C08L83/04 , B29C73/163 , B29C73/22 , C08G77/04 , C08G77/60 , C08K5/098 , C08K9/10 , C08L101/00 , C09D5/00 , C09D7/67 , C09D7/68 , C09D7/69 , C09D7/70 , C09D183/04 , Y10T428/2985 , C08L83/00 , C08L2666/28 , C08L2666/52
摘要： A self-healing coating includes a polymer matrix, a polymerizer, and a set of capsules containing a corresponding activator for the polymerizer. The polymerizer may be present in another set of capsules, or the polymerizer may be phase separated from the polymer matrix. The coating may be prepared by depositing a coating composition on a substrate and solidifying the coating composition, where the coating composition includes the polymerizer, the activator capsules and a matrix precursor. A combination of polymerizer capsules and activator capsules may be part of a kit, which may be used to provide self-healing properties to a coating. The polymerizer and the activator may be wet-curable, and coatings containing the polymerizer and activator may be able to self-heal when in contact with water.
摘要翻译： 自修复涂层包括聚合物基质，聚合反应器和一组含有聚合反应器的相应活化剂的胶囊。 聚合反应器可以存在于另一组胶囊中，或聚合反应器可以与聚合物基质相分离。 涂层可以通过将涂料组合物沉积在基材上并固化涂料组合物来制备，其中涂料组合物包括聚合反应器，活化剂胶囊和基质前体。 聚合器胶囊和活化剂胶囊的组合可以是试剂盒的一部分，其可以用于向涂层提供自愈合性质。 聚合反应器和活化剂可以是湿固化的，并且含有聚合反应器和活化剂的涂层当与水接触时可以自愈。
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3.发明申请公开(公告)号：US20120067615A1
公开(公告)日：2012-03-22
申请号：US13164144
申请日：2011-06-20
申请人： Benjamin J. Blaiszik , Susan A. Odom , Mary M. Caruso , Aaron C. Jackson , Marta B. Baginska , Joshua A. Ritchey , Aaron D. Finke , Scott R. White , Jeffrey S. Moore , Nancy R. Sottos , Paul V. Braun , Khalil Amine
发明人： Benjamin J. Blaiszik , Susan A. Odom , Mary M. Caruso , Aaron C. Jackson , Marta B. Baginska , Joshua A. Ritchey , Aaron D. Finke , Scott R. White , Jeffrey S. Moore , Nancy R. Sottos , Paul V. Braun , Khalil Amine
IPC分类号： H01B3/30
CPC分类号： H01B1/02 , Y10T428/249997
摘要： An autonomic conductivity restoration system includes a solid conductor and a plurality of particles. The particles include a conductive fluid, a plurality of conductive microparticles, and/or a conductive material forming agent. The solid conductor has a first end, a second end, and a first conductivity between the first and second ends. When a crack forms between the first and second ends of the conductor, the contents of at least a portion of the particles are released into the crack. The cracked conductor and the released contents of the particles form a restored conductor having a second conductivity, which may be at least 90% of the first conductivity.
摘要翻译： 自主导电恢复系统包括固体导体和多个颗粒。 颗粒包括导电流体，多个导电微粒和/或导电材料形成剂。 固体导体具有在第一和第二端之间的第一端，第二端和第一导电性。 当在导体的第一和第二端之间形成裂纹时，至少一部分颗粒的内容物被释放到裂纹中。 破裂的导体和释放的颗粒的内容物形成具有第二导电性的恢复的导体，其可以是第一导电率的至少90％。
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4.发明授权公开(公告)号：US08679621B2
公开(公告)日：2014-03-25
申请号：US13164144
申请日：2011-06-20
申请人： Benjamin J. Blaiszik , Susan A. Odom , Mary M. Caruso , Aaron C. Jackson , Marta B. Baginska , Joshua A. Ritchey , Aaron D. Finke , Scott R. White , Jeffrey S. Moore , Nancy R. Sottos , Paul V. Braun , Khalil Amine
发明人： Benjamin J. Blaiszik , Susan A. Odom , Mary M. Caruso , Aaron C. Jackson , Marta B. Baginska , Joshua A. Ritchey , Aaron D. Finke , Scott R. White , Jeffrey S. Moore , Nancy R. Sottos , Paul V. Braun , Khalil Amine
IPC分类号： H01B3/30
CPC分类号： H01B1/02 , Y10T428/249997
摘要： An autonomic conductivity restoration system includes a solid conductor and a plurality of particles. The particles include a conductive fluid, a plurality of conductive microparticles, and/or a conductive material forming agent. The solid conductor has a first end, a second end, and a first conductivity between the first and second ends. When a crack forms between the first and second ends of the conductor, the contents of at least a portion of the particles are released into the crack. The cracked conductor and the released contents of the particles form a restored conductor having a second conductivity, which may be at least 90% of the first conductivity.
摘要翻译： 自主导电恢复系统包括固体导体和多个颗粒。 颗粒包括导电流体，多个导电微粒和/或导电材料形成剂。 固体导体具有在第一和第二端之间的第一端，第二端和第一导电性。 当在导体的第一和第二端之间形成裂纹时，至少一部分颗粒的内容物被释放到裂纹中。 破裂的导体和释放的颗粒的内容物形成具有第二导电性的恢复的导体，其可以是第一导电率的至少90％。
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5.发明授权公开(公告)号：US09517939B2
公开(公告)日：2016-12-13
申请号：US13467419
申请日：2012-05-09
申请人： Paul V. Braun , Hui Gang Zhang
发明人： Paul V. Braun , Hui Gang Zhang
CPC分类号： C01B33/18 , C01P2004/03 , C01P2004/34 , C08G77/04 , H01M4/661 , H01M4/667 , H01M4/801 , Y10T428/249921
摘要： A method of enhancing the connectivity of a colloidal template includes providing a lattice of microparticles, where the microparticles are in contact with adjacent microparticles at contact regions therebetween, and exposing the lattice to a solution comprising a solvent and a precursor material. The solvent is removed from the solution, and the precursor material moves to the contact regions. A ring is formed from the precursor material around each of the contact regions, thereby creating interconnects between adjacent microparticles and enhancing the connectivity of the lattice.
摘要翻译： 提高胶体模板的连接性的方法包括提供微粒的晶格，其中微粒在其间的接触区域处与相邻微粒接触，并将晶格暴露于包含溶剂和前体材料的溶液中。 从溶液中除去溶剂，并且前体材料移动到接触区域。 从每个接触区域周围的前体材料形成环，从而在相邻的微粒之间产生互连并增强晶格的连通性。
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6.发明授权公开(公告)号：US09406938B2
公开(公告)日：2016-08-02
申请号：US14235338
申请日：2012-07-25
申请人： William P. King , Paul V. Braun , James H. Pikul
发明人： William P. King , Paul V. Braun , James H. Pikul
CPC分类号： H01M4/78 , H01M4/0404 , H01M4/08 , H01M6/40
摘要： A three-dimensional porous electrode architecture for a microbattery includes a substrate having first and second conductive patterns disposed thereon where the first and second conductive patterns are electrically isolated from each other, a three-dimensional porous cathode disposed on the first conductive pattern, and a three-dimensional porous anode disposed on the second conductive pattern. The porous cathode includes a first conductive scaffold conformally coated with a layer of a cathode active material and having a porosity defined by a network of interconnected pores, where the first conductive scaffold has a lateral size and shape defined by the first conductive pattern and porous side walls oriented substantially perpendicular to the substrate. The porous anode includes a second conductive scaffold conformally coated with a layer of an anode active material and having a porosity defined by a network of interconnected pores.
摘要翻译： 用于微电池的三维多孔电极结构包括其上布置有第一和第二导电图案的基板，其中第一和第二导电图案彼此电隔离，设置在第一导电图案上的三维多孔阴极，以及 设置在第二导电图案上的三维多孔阳极。 多孔阴极包括第一导电支架，其第一导电支架共形涂覆有阴极活性材料层，并且具有由互连孔的网络限定的孔隙，其中第一导电支架具有由第一导电图案和多孔侧限定的横向尺寸和形状 基本上垂直于衬底取向的壁。 多孔阳极包括第二导电支架，该第二导电支架共形涂覆有阳极活性材料层，并具有由互连孔网络限定的孔隙。
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公开(公告)号：US09601234B2
公开(公告)日：2017-03-21
申请号：US13978453
申请日：2011-01-06
申请人： William P. King , Paul V. Braun , Zhenting Dai , Xindi Yu , Hui Gang Zhang
发明人： William P. King , Paul V. Braun , Zhenting Dai , Xindi Yu , Hui Gang Zhang
CPC分类号： H01B5/14 , B05D5/12 , B81B2203/0353 , B81C1/00031 , C25D5/02 , C25D5/48 , C25D7/00 , Y10T428/249967
摘要： A method of making a three-dimensional porous device entails providing a substrate having a conductive pattern on a surface thereof, and depositing a colloidal solution comprising a plurality of microparticles onto the surface, where the microparticles assemble into a lattice structure. Interstices of the lattice structure are infiltrated with a conductive material, which propagates through the interstices in a direction away from the substrate to reach a predetermined thickness. The conductive material spans an area of the surface overlaid by the conductive pattern. The microparticles are removed to form voids in the conductive material, thereby forming a conductive porous structure having the predetermined thickness and a lateral size and shape defined by the conductive pattern.
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8.发明申请THREE-DIMENSIONAL (3D) POROUS DEVICE AND METHOD OF MAKING A 3D POROUS DEVICE 有权三维（3D）多孔器件及制造3D多孔器件的方法公开(公告)号：US20140011014A1
公开(公告)日：2014-01-09
申请号：US13978453
申请日：2011-01-06
申请人： William P. King , Paul V. Braun , Zhenting Dai , Xindi Yu , Hui Gang Zhang
发明人： William P. King , Paul V. Braun , Zhenting Dai , Xindi Yu , Hui Gang Zhang
CPC分类号： H01B5/14 , B05D5/12 , B81B2203/0353 , B81C1/00031 , C25D5/02 , C25D5/48 , C25D7/00 , Y10T428/249967
摘要： A method of making a three-dimensional porous device entails providing a substrate having a conductive pattern on a surface thereof, and depositing a colloidal solution comprising a plurality of microparticles onto the surface, where the microparticles assemble into a lattice structure. Interstices of the lattice structure are infiltrated with a conductive material, which propagates through the interstices in a direction away from the substrate to reach a predetermined thickness. The conductive material spans an area of the surface overlaid by the conductive pattern. The microparticles are removed to form voids in the conductive material, thereby forming a conductive porous structure having the predetermined thickness and a lateral size and shape defined by the conductive pattern.
摘要翻译： 制造三维多孔器件的方法需要在其表面上提供具有导电图案的衬底，并将包含多个微粒的胶体溶液沉积到表面上，其中微粒组装成晶格结构。 晶格结构的间隙被导电材料渗透，导电材料在远离基板的方向上传播通过间隙以达到预定厚度。 导电材料跨越由导电图案覆盖的表面的区域。 去除微粒以在导电材料中形成空隙，由此形成具有预定厚度的导电多孔结构和由导电图案限定的横向尺寸和形状。
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9.发明申请公开(公告)号：US20130302669A1
公开(公告)日：2013-11-14
申请号：US13467419
申请日：2012-05-09
申请人： Paul V. Braun , Hui Gang Zhang
发明人： Paul V. Braun , Hui Gang Zhang
CPC分类号： C01B33/18 , C01P2004/03 , C01P2004/34 , C08G77/04 , H01M4/661 , H01M4/667 , H01M4/801 , Y10T428/249921
摘要： A method of enhancing the connectivity of a colloidal template includes providing a lattice of microparticles, where the microparticles are in contact with adjacent microparticles at contact regions therebetween, and exposing the lattice to a solution comprising a solvent and a precursor material. The solvent is removed from the solution, and the precursor material moves to the contact regions. A ring is formed from the precursor material around each of the contact regions, thereby creating interconnects between adjacent microparticles and enhancing the connectivity of the lattice.
摘要翻译： 提高胶体模板的连接性的方法包括提供微粒的晶格，其中微粒在其间的接触区域处与相邻微粒接触，并将晶格暴露于包含溶剂和前体材料的溶液中。 从溶液中除去溶剂，并且前体材料移动到接触区域。 从每个接触区域周围的前体材料形成环，从而在相邻的微粒之间产生互连并增强晶格的连通性。
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10.发明授权Porous battery electrode for a rechargeable battery and method of making the electrode 有权用于可充电电池的多孔电池电极和制造电极的方法公开(公告)号：US08237538B2
公开(公告)日：2012-08-07
申请号：US12575197
申请日：2009-10-07
申请人： Paul V. Braun , Hui Gang Zhang , Xindi Yu
发明人： Paul V. Braun , Hui Gang Zhang , Xindi Yu
IPC分类号： H01C7/10
CPC分类号： C25F3/02 , H01M4/0452 , H01M4/131 , H01M4/32 , H01M4/505 , H01M4/66 , H01M4/80 , H01M10/345
摘要： A porous battery electrode for a rechargeable battery includes a monolithic porous structure having a porosity in the range of from about 74% to about 99% and comprising a conductive material. An active material layer is deposited on the monolithic porous structure. The pores of the monolithic porous structure have a size in the range of from about 0.2 micron to about 10 microns. A method of making the porous battery electrode is also described.
摘要翻译： 用于可再充电电池的多孔电池电极包括具有约74％至约99％范围内的孔隙率并且包括导电材料的整体式多孔结构。 活性材料层沉积在整体式多孔结构上。 整体式多孔结构的孔具有在约0.2微米至约10微米范围内的尺寸。 还描述了制造多孔电池电极的方法。
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