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1.发明授权Method for producing acrolein by heterogeneous catalytic gas-phase partial oxidation of propene 失效通过丙烯的非均相催化气相部分氧化制备丙烯醛的方法公开(公告)号：US06410785B1
公开(公告)日：2002-06-25
申请号：US09869294
申请日：2001-07-18
IPC分类号： C07C5125
CPC分类号： C07C45/35 , C07C51/252 , C07C47/22 , C07C57/04
摘要： In a process for the preparation of acrolein by gas-phase partial oxidation under heterogeneous catalysis, a reaction gas starting mixture which contains propene and molecular oxygen in a molar C3H6:O2 ratio of >1 is reacted in reaction zones connected in series, at elevated temperatures, over solid-state catalysts, further molecular oxygen being added to the reaction gas mixture in the course of the partial oxidation.
摘要翻译： 在异相催化下通过气相部分氧化制备丙烯醛的方法中，含有丙烯和C3H6：O2比大于1的分子氧的反应气体起始混合物在升高的连续串联反应区中反应 温度，超过固态催化剂，在部分氧化过程中向反应气体混合物中加入进一步的分子氧。
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2.发明授权Method for the production of acrolein or acrylic acid or the mixture thereof from propane 有权从丙烷生产丙烯醛或丙烯酸或其混合物的方法公开(公告)号：US06781017B2
公开(公告)日：2004-08-24
申请号：US10297602
申请日：2002-12-13
申请人： Otto Machhammer , Goetz-Peter Schindler , Andreas Tenten , Klaus Harth , Peter Zehner , Klaus Joachim Müller-Engel , Frank Rosowski , Frieder Borgmeier
发明人： Otto Machhammer , Goetz-Peter Schindler , Andreas Tenten , Klaus Harth , Peter Zehner , Klaus Joachim Müller-Engel , Frank Rosowski , Frieder Borgmeier
IPC分类号： C07C4500
CPC分类号： C07C51/215 , C07C5/333 , C07C45/33 , C07C45/35 , C07C51/252 , C07C11/06 , C07C47/22 , C07C57/04
摘要： In a process for the preparation of acrolein or acrylic acid or a mixture thereof from propane, the propane is subjected, in a first reaction stage, to a partial dehydrogenation under heterogeneous catalysis to give propene, of the components contained in the product gas mixture formed in the first reaction stage other than propene and propane at least a portion of the molecular hydrogen present is then separated off from said mixture and the product gas mixture is then used for the preparation of acrolein and/or acrylic acid by gas-phase catalytic propylene oxidation, molecular nitrogen being present for diluting the reaction gas mixture during the propylene oxidation.
摘要翻译： 在从丙烷制备丙烯醛或丙烯酸或其混合物的方法中，丙烷在第一反应阶段中在非均相催化下进行部分脱氢以形成产物气体混合物中所含组分的丙烯 在除丙烯和丙烷之外的第一反应阶段中，存在的分子氢的至少一部分然后从所述混合物中分离出来，然后将产物气体混合物用于通过气相催化丙烯制备丙烯醛和/或丙烯酸 存在氧化，分子氮，用于在丙烯氧化期间稀释反应气体混合物。
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公开(公告)号：US07087802B2
公开(公告)日：2006-08-08
申请号：US10380552
申请日：2001-09-14
申请人： Goetz-Peter Schindler , Otto Machhammer , Klaus Harth , Klaus Joachim Müller-Engel , Peter Zehner
发明人： Goetz-Peter Schindler , Otto Machhammer , Klaus Harth , Klaus Joachim Müller-Engel , Peter Zehner
IPC分类号： C07C5/327
CPC分类号： C07C5/325 , B01J23/58 , B01J23/626 , B01J23/63 , B01J23/96 , B01J38/14 , C07C2521/06 , C07C2521/08 , C07C2523/02 , C07C2523/04 , C07C2523/10 , C07C2523/14 , C07C2523/42 , C07C2523/44 , Y02P20/128 , Y02P20/584
摘要： In a process for the heterogeneously catalyzed dehydrogenation in one or more reaction zones of one or more dehydrogenatable C2-C30-hydrocarbons in a reaction gas mixture comprising them, with at least part of the heat of dehydrogenation required being generated directly in the reaction gas mixture in at least one reaction zone by combustion of hydrogen, the hydrocarbon or hydrocarbons and/or carbon in the presence of an oxygen-containing gas, the reaction gas mixture comprising the dehydrogenatable hydrocarbon or hydrocarbons is brought into contact with a Lewis-acid dehydrogenation catalyst which has essentially no Brönsted acidity.
摘要翻译： 在包含它们的反应气体混合物中的一种或多种可脱氢C 2 -C 30 - 烃的一个或多个反应区中的非均相催化脱氢的方法中， 需要的至少一部分脱氢热量通过在含氧气体存在下通过氢气，烃或烃和/或碳的燃烧直接在至少一个反应区中的反应气体混合物中产生，反应气体混合物包含 使可脱氢的烃或烃与基本上没有布朗斯台德酸性的路易斯酸脱氢催化剂接触。
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4.发明授权Preparation of at least one partial oxidation and/or ammoxidation product of propylene 有权制备丙烯的至少一种部分氧化和/或氨氧化产物公开(公告)号：US07326802B2
公开(公告)日：2008-02-05
申请号：US10465656
申请日：2003-06-20
申请人： Claus Hechler , Götz-Peter Schindler , Jochen Petzoldt , Christoph Adami , Otto Machhammer , Klaus Joachim Müller-Engel , Hans Martan
发明人： Claus Hechler , Götz-Peter Schindler , Jochen Petzoldt , Christoph Adami , Otto Machhammer , Klaus Joachim Müller-Engel , Hans Martan
IPC分类号： C07C253/00 , C07C491/00
CPC分类号： C07C51/215 , B01J23/002 , B01J23/8877 , C07C51/252 , C07C253/24 , Y02P20/52 , C07C57/04 , C07C255/08
摘要： In a process for preparing at least one partial oxidation and/or ammoxidation product of propylene, the propylene is obtained from crude propane by dehydrogenating and subjected in the presence of unconverted propane as a constituent of a gas mixture 2 which comprises a total C4-hydrocarbon content of ≦3% by volume to a heterogeneously catalyzed gas phase partial oxidation and/or partial gas phase ammoxidation.
摘要翻译： 在制备丙烯的至少一种部分氧化和/或氨氧化产物的方法中，丙烯通过脱氢从粗丙烷获得，并在未转化的丙烷作为气体混合物2的组分存在下进行，所述气体混合物2包含总C
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5.发明授权Preparation of at least one partial oxidation and/or ammoxidation product of propylene 有权制备丙烯的至少一种部分氧化和/或氨氧化产物公开(公告)号：US07238827B2
公开(公告)日：2007-07-03
申请号：US10465659
申请日：2003-06-20
申请人： Claus Hechler , Götz-Peter Schindler , Jochen Petzoldt , Christoph Adami , Otto Machhammer , Klaus Joachim Müller-Engel , Hans Martan
发明人： Claus Hechler , Götz-Peter Schindler , Jochen Petzoldt , Christoph Adami , Otto Machhammer , Klaus Joachim Müller-Engel , Hans Martan
IPC分类号： C07C253/24 , C07C27/10 , C07C51/215
CPC分类号： C07C51/215 , B01J23/002 , B01J23/8877 , C07C51/252 , C07C253/24 , Y02P20/52 , C07C57/04 , C07C255/08
摘要： Process for preparing at least one partial oxidation and/or ammoxidation product of propylene, in which the propylene is produced from crude propane by dehydrogenation and is subjected to a heterogeneously catalyzed gas-phase partial oxidation and/or partial gas-phase ammoxidation in the presence of unreacted propane as constituent of a gas mixture 2 containing
摘要翻译： 制备丙烯的至少一种部分氧化和/或氨氧化产物的方法，其中丙烯由粗丙烷通过脱氢制备，并在存在下进行非均相催化的气相部分氧化和/或部分气相氨氧化 的未反应丙烷作为含有1体积％1-丁烯的气体混合物2的组分。
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6.发明授权Process for preparing acrolein or acrylic acid or a mixture thereof from propane 有权从丙烷制备丙烯醛或丙烯酸或其混合物的方法公开(公告)号：US07524987B2
公开(公告)日：2009-04-28
申请号：US11505800
申请日：2006-08-18
IPC分类号： C07C51/235 , C07C51/16 , C07C45/00
CPC分类号： C07C45/35 , C07C45/33 , C07C51/215 , C07C51/252 , C07C47/22 , C07C57/04
摘要： A process for preparing acrolein, or acrylic acid or a mixture thereof as a target product from propane, in which propane is partially dehydrogenated under heterogeneous catalysis in a reaction zone A, molecular hydrogen thus formed is incinerated partly to water and the product gas A thus formed in reaction zone A is used without secondary component removal to charge a reaction zone B in which propylene present in product gas A is partially oxidized to the target product. From the product gas B formed in reaction zone B, the target product is removed and the residual gas I remaining after an aftertreatment comprising a CO2 scrubbing and a partial discharge thereof is recycled into reaction zone A.
摘要翻译： 制备丙烯醛或丙烯酸或其混合物作为丙烷的目标产物的方法，其中丙烷在反应区A中在非均相催化下部分脱氢，因此形成的分子氢部分地被焚烧成水，产物气A因此 在反应区A中形成的反应区A被使用，而不需要除去二次分量，从而向产物气体A中存在的丙烯部分氧化成目标产物的反应区B进行充电。 从反应区B中形成的产物气体B中，除去目标产物，并且在包括CO 2洗涤和部分排放的后处理之后残留的残留气体I再循环到反应区域A.
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7.发明授权Method for carrying out the catalytic gas phase oxidation of propene to form acrylic acid 失效进行催化气相氧化丙烯以形成丙烯酸的方法公开(公告)号：US06740779B1
公开(公告)日：2004-05-25
申请号：US10110227
申请日：2002-04-22
申请人： Andreas Tenten , Hartmut Hibst , Otto Machhammer , Claus Hechler , Klaus Joachim Müller-Engel , Signe Unverricht
发明人： Andreas Tenten , Hartmut Hibst , Otto Machhammer , Claus Hechler , Klaus Joachim Müller-Engel , Signe Unverricht
IPC分类号： C07C5702
摘要： In a process for the two-stage catalytic gas-phase oxidation of propene to acrylic acid, the reaction gas starting mixture is passed, in a tube-bundle reactor, with a propene loading of ≧160 l (S.T.P.) of propene/l·h, first over a fixed catalyst bed 1 present in two successive temperature zones A, B and then over a fixed catalyst bed 2 which is housed either in one further temperature zone C or in two further temperature zones D, E, the temperature of the zone A being kept at a lower temperature than the zone B and the temperature of the zone D at a lower temperature than the zone E.
摘要翻译： 在将丙烯二阶段催化气相氧化成丙烯酸的过程中，将反应气体起始混合物在管束反应器中以丙烯/丙烯的加入量为约160l（STP）/ 1h 首先在存在于两个连续的温度区域A，B中的固定的催化剂床1上，然后在固定的催化剂床2上，该固定的催化剂床2容纳在一个另外的温度区域C或两个另外的温度区域D，E中， A在比区域B低的温度下保持在比区域B低的温度和区域D的温度。
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公开(公告)号：US06596901B1
公开(公告)日：2003-07-22
申请号：US09147484
申请日：1999-01-08
IPC分类号： C07C5142
摘要： A process for preparing acrylic acid or methacrylic acid comprises (a) preparing a gaseous product mixture having essentially the composition of a reaction mixture of the catalytic gas phase oxidation of C3-/C4-alkanes, -alkenes, -alkanols and/or -alkanals and/or precursors thereof to form acrylic acid or methacrylic acid, characterized by (b) condensing said product mixture, (c) crystallizing acrylic acid or methacrylic acid from the solution obtained in step (b), and (d) removing the resulting crystals from the mother liquor.
摘要翻译： 制备丙烯酸或甲基丙烯酸的方法包括（a）制备气态产物混合物，其基本上具有C3- / C4-烷烃， - 烯烃， - 烷醇和/或 - 烷烃的催化气相氧化反应混合物的组成 和/或其前体以形成丙烯酸或甲基丙烯酸，其特征在于（b）冷凝所述产物混合物，（c）从步骤（b）中获得的溶液中结晶丙烯酸或甲基丙烯酸，和（d）除去所得晶体 从母酒。
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9.发明授权Heterogeneously catalyzed partial gas phase oxidation of propene to acrylic acid 有权将丙烯非均相催化部分气相氧化成丙烯酸公开(公告)号：US06888024B2
公开(公告)日：2005-05-03
申请号：US10799754
申请日：2004-03-15
CPC分类号： B01J23/002 , B01J23/8876 , B01J23/8877 , B01J35/0006 , B01J37/0221 , B01J2523/00 , C07C51/252 , C07C57/04 , B01J2523/17 , B01J2523/55 , B01J2523/68 , B01J2523/69 , B01J2523/13 , B01J2523/41 , B01J2523/54 , B01J2523/842 , B01J2523/845
摘要： In a process for heterogeneously catalyzed partial gas phase oxidation of propene to acrylic acid, the starting reaction gas mixture is oxidized at a propene loading of
摘要翻译： 在将丙烯非均相催化的部分气相氧化成丙烯酸的过程中，起始反应气体混合物在第一反应阶段中以<160l（STP）/ 1h的丙烯负载量在被容纳的固定催化剂床1上被氧化 在两个连续的反应区A，B和第一反应阶段的含丙烯醛的产物气体混合物随后在第二反应阶段中在固定的催化剂床2上氧化，固定的催化剂床2容纳在两个连续的反应区C，D中， 反应区A内的反应气体混合物的最高温度高于反应区B内反应气体混合物的最高温度，反应区C内的反应气体混合物的最高温度高于反应气体混合物的最高温度 区D.
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公开(公告)号：US07015354B2
公开(公告)日：2006-03-21
申请号：US10917414
申请日：2004-08-13
申请人： Jochen Petzoldt , Signe Unverricht , Heiko Arnold , Klaus Joachim Müller-Engel , Martin Dieterle
发明人： Jochen Petzoldt , Signe Unverricht , Heiko Arnold , Klaus Joachim Müller-Engel , Martin Dieterle
CPC分类号： C07C45/35 , C07C51/252 , C07C47/22 , C07C57/04
摘要： A process for preparing (meth)acrolein and/or (meth)acrylic acid by heterogeneously catalyzed gas phase partial oxidation of an organic precursor compound over a fresh fixed catalyst bed, in which the process is started up at a reduced hourly space velocity of charging gas mixture on the fixed catalyst bed.
摘要翻译： 通过在新鲜的固定催化剂床上的有机前体化合物的非均相催化气相部分氧化制备（甲基）丙烯醛和/或（甲基）丙烯酸的方法，其中该方法以减小的小时空速充电开始 固定催化剂床上的气体混合物。
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