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    Process of use of a catalyst for synthesizing saturated primary aliphatic alcohols
    5.
    发明授权
    Process of use of a catalyst for synthesizing saturated primary aliphatic alcohols 失效
    使用催化剂合成饱和伯脂肪醇的方法

    公开(公告)号：US4675343A

    公开(公告)日：1987-06-23

    申请号：US863283

    申请日：1986-05-15

    申请人： Philippe Courty ,  Daniel Durand ,  Alain Forestiere ,  Pierre Grandvallet

    发明人： Philippe Courty ,  Daniel Durand ,  Alain Forestiere ,  Pierre Grandvallet

    IPC分类号： C07C29/15 ,  B01J23/00 ,  C07B61/00 ,  C07C27/00 ,  C07C29/156 ,  C07C31/02 ,  C07C67/00 ,  C07C27/06

    CPC分类号： C07C29/156 ,  Y02P20/52

    摘要： The present invention concerns a process of use of a copper and cobalt-containing catalyst for synthesizing saturated primary aliphatic alcohols. This process comprises a first step consisting in at least one catalyst prereduction by means of a gas mixture containing a reducing compound, a second step wherein the prereduced catalyst is contacted with a mixture of hydrogen and carbon oxides (CO, CO.sub.2) for at least 10 hours, so as to produce a mixture of alcohols; a third step wherein the catalyst obtained in the second step is subjected to a treatment with a gas mixture containing a single reducing gas, during about 1 to 400 hours and a fourth step of synthesizing saturated primary aliphatic alcohols from a mixture containing hydrogen and carbon oxides.Optionally the process also comprises an additional step consisting of subjecting the catalyst, whose activity and/or selectivity has been partially lost, to a new treatment according to the procedure defined for the third step.The process according to the invention is particularly applicable to catalysts containing copper, cobalt and optionally aluminum and/or zinc and/or sodium.

    摘要翻译： 本发明涉及使用含铜和钴的催化剂合成饱和伯脂肪醇的方法。 该方法包括通过含有还原化合物的气体混合物进行至少一种催化剂预还原的第一步骤，其中将预还原的催化剂与氢和碳氧化物（CO，CO 2）的混合物接触至少10 小时，以产生醇的混合物; 第三步骤，其中将第二步中得到的催化剂在含有单一还原气体的气体混合物中进行约1-4小时的处理，以及从含有氢和碳氧化物的混合物中合成饱和伯脂肪醇的第四步骤 。 任选地，该方法还包括另外的步骤，该方法包括将其活性和/或选择性已被部分丧失的催化剂按照根据第三步所定义的方法进行新的处理。 根据本发明的方法特别适用于含有铜，钴和任选的铝和/或锌和/或钠的催化剂。

    Process for manufacturing a mixture of primary alcohols from a synthesis gas, in the presence of a catalyst containing copper, cobalt, zinc and at least one alkali and/or alkaline earth metal
    6.
    发明授权
    Process for manufacturing a mixture of primary alcohols from a synthesis gas, in the presence of a catalyst containing copper, cobalt, zinc and at least one alkali and/or alkaline earth metal 失效
    在含有铜，钴，锌和至少一种碱金属和/或碱土金属的催化剂存在下，从合成气中制备伯醇混合物的方法

    公开(公告)号：US4780481A

    公开(公告)日：1988-10-25

    申请号：US26493

    申请日：1987-03-16

    申请人： Philippe Courty ,  Patrick Chaumette ,  Daniel Durand ,  Catherine Verdon

    发明人： Philippe Courty ,  Patrick Chaumette ,  Daniel Durand ,  Catherine Verdon

    IPC分类号： C07B61/00 ,  B01J23/00 ,  B01J23/80 ,  B01J23/89 ,  C07C27/00 ,  C07C29/153 ,  C07C29/154 ,  C07C29/156 ,  C07C29/157 ,  C07C29/158 ,  C07C29/16 ,  C07C31/02 ,  C07C67/00 ,  C07C27/06

    CPC分类号： C07C29/156 ,  Y02P20/52

    摘要： A process for manufacturing a mixture of saturated primary alcohols by reacting carbon oxides with hydrogen in the presence of a catalyst formed essentially of the following elements: copper, cobalt, zinc, at least one metal A selected from the group consisting of alkali and alkaline earth metals and optionally zirconium and/or at least one metal M selected from the group formed of scandium, yttrium and rare earth metals and/or at least one metal N selected from group VIII noble metals, the proportion by weight of each metal element being: copper: 15-55%, colbalt: 5-25%, zinc: 15-70%, metal A: 0.01-5%, zinconium: 0-55%, metal M: 0-20%, metal N: 0-1%, the total amount by weight of zinc and zirconium in percent by weight of all the metals being from 15 to 70% and the atomic ratios between these metals being: Cu/Co: 0.2:1 to 5:1 and Zn/(Zn+Zr): 0.05:1 to 1:1 and (Zn+Zr)/Co: 0.5:1 to 8:1.The catalyst may be prepared by complexing or by coprecipitating catalytic elements.

    摘要翻译： 一种在主要由以下元素形成的催化剂存在下使碳氧化物与氢气反应来制造饱和伯醇的混合物的方法：铜，钴，锌，至少一种选自碱金属和碱土金属的金属 金属和任选的锆和/或至少一种选自钪，钇和稀土金属的金属和/或至少一种选自VIII族贵金属的金属，金属元素的重量比例为： 铜：15-55％，钴：5-25％，锌：15-70％，金属A：0.01-5％，锌银：0-55％，金属M：0-20％，金属N：0-1 ％，所有金属的重量百分比为15〜70％的锌和锆的总量，这些金属的原子比为Cu / Co:0.2:1〜5:1，Zn /（Zn + Zr）：0.05:1〜1:1，（Zn + Zr）/ Co:0.5:1〜8:1。 催化剂可以通过络合或通过共沉淀催化元素来制备。

    Process for reducing the benzine content of petrols
    9.
    发明授权
    Process for reducing the benzine content of petrols 失效
    降低汽油汽油含量的方法

    公开(公告)号：US5607891A

    公开(公告)日：1997-03-04

    申请号：US638313

    申请日：1996-04-26

    申请人： Christine Travers ,  Philippe Courty ,  Patrick Sarrazin

    发明人： Christine Travers ,  Philippe Courty ,  Patrick Sarrazin

    IPC分类号： B01J27/128 ,  B01J23/40 ,  B01J23/74 ,  B01J27/13 ,  C07C5/22 ,  C10G35/06 ,  C10G35/085 ,  C10G45/60 ,  B01J27/06

    CPC分类号： B01J23/74 ,  B01J23/40 ,  C10G45/60

    摘要： The invention concerns an isomerization catalyst comprising 4 to 15% of at least one halogen and at least one metal from group VIII deposited on a support composed of a mixture of specific proportions of eta alumina and gamma alumina. The invention also concerns a process for reducing the benzene content of gasoline fractions and isomerizing paraffins in the presence of this catalyst, in which isomerization is carried out on a mixture of a) a feed with the following composition by weight: 40% to 80% of paraffins, 0.5% to 7% of cyclic hydrocarbons and 6% to 45% of aromatics, and with a maximum distillation temperature of between 70.degree. C. and 90.degree. C., and b) a C.sub.5 -C.sub.6 cut which is generally a straight run cut.

    摘要翻译： 本发明涉及一种异构化催化剂，其包含4至15％的至少一种卤素和至少一种沉积在由特定比例的氧化铝和γ氧化铝的混合物构成的载体上的来自第VIII族的金属。 本发明还涉及在该催化剂存在下降低汽油馏分的苯含量和异构化烷烃的方法，其中异构化在a）以下重量组成的进料的混合物中进行：40％至80％ 的链烷烃，0.5％至7％的环烃和6％至45％的芳族化合物，最高蒸馏温度在70℃至90℃之间，和b）C5-C6馏分，通常为 直跑