Catalytic alkylation of aromatic amines with alkanols
    3.
    发明授权
    Catalytic alkylation of aromatic amines with alkanols 失效
    芳烃与烷醇的催化烷基化

    公开(公告)号:US4599449A

    公开(公告)日:1986-07-08

    申请号:US624522

    申请日:1984-06-25

    Inventor: Duane C. Hargis

    CPC classification number: C07C209/18 B01J23/889

    Abstract: Aromatic amines are alkylated by reaction with an alcohol in the presence of a Group VII-B metal oxide alkylation catalyst, preferably a major proportion of a Group VII-B metal oxide such as MnO.sub.2 in combination with a minor proportion of a Group VIII metal oxide such as Fe.sub.2 O.sub.3, so that alkylation of the aromatic amine occurs. Under most reaction conditions a considerable portion of the alcohol alkylating agent such as ethanol not consumed in the alkylation reaction passes through the reaction zone undecomposed and thus can be readily recovered for recycle or other use.

    Abstract translation: 芳族胺通过在Ⅶ-B族金属氧化物烷基化催化剂存在下与醇反应而烷基化,优选主要比例的Ⅶ-B族金属氧化物如MnO 2与少量VIII族金属氧化物 例如Fe 2 O 3,从而发生芳族胺的烷基化。 在大多数反应条件下,在烷基化反应中未消耗的相当大量的醇烷基化试剂如乙醇通过未分解的反应区,因此可以容易地回收再循环或其它用途。

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