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1.发明授权Method for preparing polyorganosiloxanes (POS) with thiol functions, POS obtainable by this method and their use particularly in rubber materials 失效制备具有硫醇官能团的聚有机硅氧烷（POS）的方法，该方法可通过该方法得到并且特别用于橡胶材料中公开(公告)号：US06372843B1
公开(公告)日：2002-04-16
申请号：US09462565
申请日：2000-04-19
IPC分类号： C08L8308
CPC分类号： C08K3/36 , C08G77/392 , C08L7/00 , C08L9/00 , C08L9/06 , C08L21/00 , C08L83/08 , C08L2205/03 , C08L2666/14
摘要： The present invention relates to a process for preparing multifunctionalized polyorganosiloxanes (POSs) comprising alkoxyl functional siloxyl units and siloxyl units each having an SH functional group, which consists in introducing the SH functional group by the reaction of H2S on a precursor POS of formula: A—(RXSiO)a—(RYSiO)b—B where R is especially a C1-C6 alkyl radical, X is a C1-C15 alkoxyl radical, Y is a C2-C30 hydrocarbon group which includes an ethylenically unsaturated group from which the SH functionality derives, a is a number ranging from 1 to 150, b is a number ranging from 1 to 150, the number a+b ranging from 2 to 300 and A and B are terminal groups which are selected respectively, from, in particular, on the one hand (R)3SiO— radicals taken alone or as mixtures with (R)2XSiO— and/or R(X)2SiO— and/or (X)3SiO— radicals and on the other hand —Si(R)3 radicals taken alone or as mixtures with —SiX(R)2 and/or —Si(X)2R and/or —Si(X)3 radicals.
摘要翻译： 本发明涉及一种制备多官能化聚有机基硅氧烷（POSs）的方法，该多官能化聚有机硅氧烷（POSs）包含烷氧基官能硅氧烷单元和含有SH官能团的甲硅烷氧基单元，其包括通过H 2 S在式A的前体POS上反应引入SH官能团 - （RXSiO）a-（RYSiO）bB其中R特别是C 1 -C 6烷基，X是C 1 -C 15烷氧基，Y是C 2 -C 30烃基，其包括具有SH官能度的烯属不饱和基团 a为1〜150的数，b为1〜150的数，a + b的数量为2〜300，A，B为分别选择的端子组，特别是 单独（R）3SiO-基单独或与（R）2 XSiO-和/或R（X）2SiO-和/或（X）3SiO-基团的混合物，另一方面-Si（R）3基团取代 单独或作为与-SiX（R）2和/或-Si（X）2R和/或-Si（X）3基团的混合物）。
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2.发明申请公开(公告)号：US20090177003A1
公开(公告)日：2009-07-09
申请号：US12320567
申请日：2009-01-29
CPC分类号： C07F7/1892 , C07F7/188
摘要： The invention concerns the preparation of halogenated monoorganoxysilanes, of formula (I), said compounds being useful as synthesis intermediate in organic chemistry. Said method for preparing monoorganoxysilanes consists in: using as starting product halogenoalkylsilanes of the (CH3)2SiCl2 type and in substituting the silicon with a radical bearing a divalent unit bound to an electrophilic reactive group capable of reacting with at least an appropriate nucleophilic agent to form a functionalised monoorganoxysilane of formula (II)
摘要翻译： 本发明涉及式（I）的卤代单有机基硅烷的制备，所述化合物可用作有机化学中的合成中间体。 所述制备单有机基硅烷的方法包括：以（CH 3）2 SiCl 2类型的起始产物卤代烷基硅烷为原料，并用具有与能够与至少适当的亲核试剂反应的亲电反应性基团结合的二价单元的基团取代硅来形成 式（II）的官能化单有机基硅烷
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3.发明申请Method for obtaining halogenated monoorganoxysilanes useful in particular as synthesis intermediates 失效用于获得特别用作合成中间体的卤化单有机氧硅烷的方法公开(公告)号：US20050070731A1
公开(公告)日：2005-03-31
申请号：US10489836
申请日：2002-09-10
CPC分类号： C07F7/1892 , C07F7/188
摘要： The invention concerns the preparation of halogenated monoorganoxysilanes, of formula (I), said compounds being useful as synthesis intermediate in organic chemistry. Said method for preparing monoorganoxysilanes consists in: using as starting product halogenoalkylsilanes of the (CH3)2SiCl2 type and in substituting the silicon with a radical bearing a divalent unit bound to an electrophilic reactive group capable of reacting with at least an appropriate nucleophilic agent to form a functionalised monoorganoxysilane of formula (II) with, for example: R =C1-C4 alkyl; R , R =C1-C6 alkyl; B═C1-C10 alkylene; m=1 or 2; Hal=halogen; W=amino, mercapto, (organosilyl)-organopolythio radical.
摘要翻译： 本发明涉及式（I）的卤代单有机基硅烷的制备，所述化合物可用作有机化学中的合成中间体。 所述制备单有机基硅烷的方法包括：以（CH 3）2 SiCl 2类型的起始产物卤代烷基硅烷为原料，并用具有与能够与至少适当的亲核试剂反应的亲电反应性基团结合的二价单元的基团取代硅来形成 式（II）的官能化单有机基硅烷与例如：R 1 = C 1 -C 4烷基; R 2，R 3 = C 1 -C 6烷基; B = C1-C10亚烷基; m = 1或2; Hal =卤素; W =氨基，巯基，（有机甲硅烷基） - 有机硫基。
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4.发明申请公开(公告)号：US20070282088A1
公开(公告)日：2007-12-06
申请号：US10584396
申请日：2004-12-21
申请人： Marc Chaussade , Nathalie Guennouni
发明人： Marc Chaussade , Nathalie Guennouni
CPC分类号： C09K3/1018 , C08K3/26 , C08K5/54 , C08K5/57 , C08L83/04
摘要： The invention relates to polyorganosiloxane monocomponent compounds (POS) which are stable when stored without humidity and crosslinking into elastomer in the presence of water. The inventive compounds comprise at least one type of crosslinkable linear polyorganosiloxane (POS), a mineral filler and a crosslinking catalyst of formula (I) which provides said compound with an excellent compromise between cross linking kinetics and a storage stability (i.e. more than 6 months).
摘要翻译： 本发明涉及聚有机硅氧烷单组分化合物（POS），其在没有湿度下储存时稳定，并在水存在下交联成弹性体。 本发明的化合物包括至少一种类型的可交联线性聚有机硅氧烷（POS），矿物填料和式（I）的交联催化剂，其提供所述化合物在交联动力学和储存稳定性之间具有极好的折中（即超过6个月 ）。
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公开(公告)号：US20070032674A1
公开(公告)日：2007-02-08
申请号：US11499585
申请日：2006-08-04
申请人： Kamel Ramdani , Bernard Vogin , Nathalie Guennouni
发明人： Kamel Ramdani , Bernard Vogin , Nathalie Guennouni
IPC分类号： C07F7/00
CPC分类号： C07F7/14 , C07F7/1892
摘要： The invention relates to the preparation of organodialkylalkoxysilane using a continuous method consisting in bringing an alkanol into continuous contact with an omega-haloalkyl dialkylhalosilane in a countercurrent reactor, such as a plate column or a packed column. The reaction is performed in the aforementioned countercurrent reactor in the presence or absence of a non-reactive solvent with scavenging of the hydrochloric acid formed. The omega-haloalkyl dialkylalkoxysilane thus formed is particularly suitable for use as a starting material for the preparation of organosilicon compounds containing sulphur having general formula (I) by means of sulphidisation reaction on an alkaline metal polysulphide.
摘要翻译： 本发明涉及使用连续方法制备有机二烷基烷氧基硅烷，所述连续方法包括使链烷醇与逆流反应器如板式塔或填充塔中的ω-卤代烷基二烷基卤代硅烷连续接触。 反应在上述逆流反应器中，在存在或不存在非反应性溶剂的情况下进行，同时清除形成的盐酸。 由此形成的ω-卤代烷基二烷基烷氧基硅烷特别适合用作通过在碱金属多硫化物上的硫化反应制备含有通式（I）的硫的有机硅化合物的起始原料。
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6.发明授权Cross-linkable compositions containing functionalized silicon fluids and use of these compositions for preparing polyurethane films 失效含有官能化硅液的可交联组合物和这些组合物用于制备聚氨酯膜的用途公开(公告)号：US06369186B1
公开(公告)日：2002-04-09
申请号：US09297856
申请日：1999-07-19
IPC分类号： C08G7704
CPC分类号： C08J5/18 , C08G18/10 , C08G18/4063 , C08G18/61 , C08J2375/04 , C09D175/04
摘要： The invention concerns a novel cross-linkable composition and its use for preparing novel polyurethane films. The cross-linkable composition comprises (a) 20 to 50 wt. % of polyisocyanate, (b) 50 to 80 wt. % of acrylic oligomer containing hydroxyl groupings whose content in weight relative to the acrylic oligomer is between 2.5 and 4.5% and (c) 1 to 10 wt. % of a silicon fluid of formula (1).
摘要翻译： 本发明涉及一种新的可交联组合物及其用于制备新型聚氨酯膜的用途。 可交联组合物包含（a）20至50wt。 ％的多异氰酸酯，（b）50〜80重量％ 含有羟基的丙烯酸低聚物的含量相对于丙烯酸低聚物的重量比为2.5〜4.5％，（c）为1〜10重量％ ％的式（1）的硅液。
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公开(公告)号：US20070185344A1
公开(公告)日：2007-08-09
申请号：US10561223
申请日：2004-06-16
IPC分类号： C07F7/14
CPC分类号： C07F7/14
摘要： 3-Chloropropyldimethylchlorosilane is prepared by hydrosilylation reaction in a reaction medium comprising dimethylhydrochlorosilane and allyl chloride, in the presence of a catalytically effective amount of di-p-chlorobis(η-1,5-cyclooctadiene)diiridium and wherein at least one auxiliary in the free or supported state selected from the group of compounds consisting of: (i) ketones, (ii) ethers, (iii) quinones, (iv) anhydrides, (v) unsaturated hydrocarbon compounds (UHC) whether aromatic and/or comprising at least one C═C double bond and/or at least one C≡C triple bond, it being possible for these unsaturated bonds to be conjugated or nonconjugated, the said UHCs being linear or cyclic (mono- or polycyclic), having from 4 to 30 carbon atoms, having from 1 to 8 ethylenic and/or acetylenic sites of unsaturation and optionally comprising one or more heteroatoms, and (vi) mixtures thereof, is added to the reaction medium, with the proviso that, when the auxiliary comprises one or more UHCs as defined above, then this (these) UHC(s) is (are) mixed with at least one other auxiliary other than a UHC.
摘要翻译： 在催化有效量的二 - 对 - 氯双（η-1,5-环辛二烯）二铱的存在下，在包含二甲基氢氯硅烷和烯丙基氯的反应介质中通过氢化硅烷化反应制备3-氯丙基二甲基氯硅烷，其中至少一种在 （i）酮，（ii）醚，（iii）醌，（iv）酸酐，（v）不饱和烃化合物（UHC）和/或至少包含至少 一个CC双键和/或至少一个C≡C三键，这些不饱和键可能是共轭或非共轭的，所述UHC是具有4-30个碳原子的直链或环状（单环或多环） 具有1至8个不饱和键和/或炔属不饱和位点并且任选地包含一个或多个杂原子的化合物，和（vi）其混合物，加入到反应介质中，条件是当辅助剂包含一个或多个U 如上定义的HC，则（这些）UHC与至少一种除UHC之外的其它辅助剂混合。
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8.发明授权Rubber composition for a tire comprising a multifunctional polyorganosiloxane as coupling agent 有权一种用于轮胎的橡胶组合物，其包含多官能聚有机硅氧烷作为偶联剂公开(公告)号：US07186776B2
公开(公告)日：2007-03-06
申请号：US10946188
申请日：2004-09-22
IPC分类号： C08K5/5425
CPC分类号： C08K5/5425 , B60C1/00 , C08K5/544 , C08L7/00 , C08L9/06 , C08L21/00 , C08L83/04 , C08L2666/14
摘要： The present invention relates to a sulfur-cross-linkable elastomeric composition that is useful for the manufacture of tires. This elastomeric composition is based on at least one isoprene elastomer (in particular natural rubber), a reinforcing inorganic filler (in particular, silica), and an (inorganic filler/isoprene elastomer) coupling agent. The coupling agent is a multifunctional polyorganosiloxane (POS), which comprises functions denoted as “Y” and “X”, wherein the Y function is at least one hydroxyl or hydrolyzable function grafted to the silicon atoms of the coupling agent and the X function is a group bearing at least one activated ethylene double bond and is grafted to the silicon atoms of the coupling agent. This POS is, in particular, a POS having an imide, acid or ester function, the ethylene double bond of which is activated by at least one adjacent carbonyl group (—C═O). The present invention further relates to a tire comprising the composition described above as well as semi-finished products for tires, in particular, treads, where the tires comprise a rubber composition according to the present invention.
摘要翻译： 本发明涉及可用于制造轮胎的可硫交联的弹性体组合物。 该弹性体组合物基于至少一种异戊二烯弹性体（特别是天然橡胶），增强无机填料（特别是二氧化硅）和（无机填料/异戊二烯弹性体）偶联剂。 偶联剂是多功能聚有机硅氧烷（POS），其包括表示为“Y”和“X”的功能，其中Y官能团是至少一个接枝到偶联剂硅原子上的羟基或可水解的官能团，X官能团是 具有至少一个活化的乙烯双键的基团并且接枝到偶联剂的硅原子上。 该POS特别是具有酰亚胺，酸或酯官能团的POS，其乙烯双键被至少一个相邻的羰基（-C-O）活化。 本发明还涉及包含上述组合物以及用于轮胎，特别是胎面的半成品的轮胎，其中轮胎包括根据本发明的橡胶组合物。
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9.发明授权Method of preparing polyorganosiloxane with functional groups in the presence of lithium silanolate 有权在硅酸铝锂存在下用官能团制备聚有机硅氧烷的方法公开(公告)号：US07973121B2
公开(公告)日：2011-07-05
申请号：US11792375
申请日：2005-12-06
申请人： Marc Chaussade , Nathalie Guennouni
发明人： Marc Chaussade , Nathalie Guennouni
IPC分类号： C08G77/26
CPC分类号： C08G77/08 , C08G77/18 , C08K5/5415 , C08L83/04
摘要： The invention relates to a method of preparing polyorganosiloxanes containing at least one functional group using a lithium silanolate catalyst. A polyorganosiloxane, having at least one hydroxyl group, is reacted with a polyalkoxysilane having the formula (R1)a(R2)bSi(OR3)4-(a+b) (I), where R1 is an alkyl radical, a cycloalkyl radical, or an aryl radical; R2 is —(Z)m-(X)n, wherein m=0 or 1, n=1 or 2; Z is a divalent hydrocarbon residue; X is an unsaturated hydrocarbon radical when m=0 and, when m=1, X is chlorine, bromine, iodine, —O—CO—CR4═CR5R6 (in which R4, R5 and R6 each represent a hydrogen atom, an alkyl radical and/or a phenyl radical), —RF (in which RF is a perfluorinated residue), —NHR7 (in which R7 is a hydrogen atom, an alkyl radical, or a radical-R8—NH2, wherein R8 is Z), or —SH; R3 is an alkyl radical; a=0, 1, 2 or 3; b=0 or 1 and a+b=0, 1, 2 or 3, with the additional condition that the sum a+b=3, symbol b cannot be equal to 0. The method is performed in the presence of an effective quantity of a lithium organosilanolate catalyst having formula (R1)a(R2)b(OR3)3-(a+b)SiO−Li+ (II), wherein R1, R2, R3, a and b have the meanings indicated above. The method is performed without the addition of an aliphatic alcohol having the formula R3OH to the reaction medium.
摘要翻译： 本发明涉及使用硅酸锂催化剂制备含有至少一个官能团的聚有机硅氧烷的方法。 具有至少一个羟基的聚有机硅氧烷与具有式（R1）a（R2）bSi（OR3）4-（a + b）（I）的聚烷氧基硅烷反应，其中R1是烷基，环烷基 ，或芳基; R2是 - （Z）m-（X）n，其中m = 0或1，n = 1或2; Z是二价烃残基; 当m = 0时，X是不饱和烃基，当m = 1时，X是氯，溴，碘，-O-CO-CR 4 = CR 5 R 6（其中R 4，R 5和R 6各自表示氢原子，烷基 和/或苯基），-RF（其中RF是全氟化残基），-NHR7（其中R7是氢原子，烷基或基团R8-NH2，其中R8是Z）或 -SH; R3是烷基; a = 0,1,2或3; b = 0或1，a + b = 0,1,2或3，附加条件是和a + b = 3，符号b不能等于0.该方法在存在有效量 的具有式（R1）a（R2）b（OR3）3-（a + b）SiO-Li +（Ⅱ）的有机硅烷醇酯锂催化剂，其中R1，R2，R3，a和b具有上述含义。 该方法在不向反应介质中加入具有式R3OH的脂族醇的情况下进行。
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10.发明申请TIN-FREE SINGLE-COMPONENT SILICONE COMPOSITIONS CROSSLINKABLE INTO ELASTOMERIC STATE 审中-公开无机单组分硅酮组合物可交联成弹性体状态公开(公告)号：US20100234510A1
公开(公告)日：2010-09-16
申请号：US12514243
申请日：2007-11-09
申请人： Michel Feder , Hervé Parisot , Nathalie Guennouni
发明人： Michel Feder , Hervé Parisot , Nathalie Guennouni
摘要： Tin-free, single-component silicone compositions which are stable with respect to storage in the absence of moisture, and which can be crosslinked into an elastomer by means of polycondensation reactions at ambient temperature and in the presence of water; such elastomers are adherent on various supports and harden rapidly and the silicone compositions contain an alkoxy-functional polyorganosiloxane (POS), a carboxylic acid and/or a carboxylic acid anhydride, and, optionally, a mineral filler of fumed silica type, an alkoxy-functional POS resin and an organometallic compound (containing no tin).
摘要翻译： 无环氧单组分有机硅组合物相对于不存在水分时的储存是稳定的，并且可以在环境温度和水的存在下通过缩聚反应交联成弹性体; 这种弹性体粘附在各种载体上并迅速硬化，硅氧烷组合物含有烷氧基官能的聚有机硅氧烷（POS），羧酸和/或羧酸酐，以及任选的气相法二氧化硅型矿物填料， 功能POS树脂和有机金属化合物（不含锡）。
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