公开(公告)号：US20130168290A1

公开(公告)日：2013-07-04

申请号：US13808817

申请日：2011-07-04

申请人： Prabhu K. Mohan ,  A.V. Karthikeyani ,  Manish Agarwal ,  Biswanath Sarkar ,  Balaiah Swamy ,  V. Chidambaram ,  P.S. Choudhury ,  S. Rajagopal

发明人： Prabhu K. Mohan ,  A.V. Karthikeyani ,  Manish Agarwal ,  Biswanath Sarkar ,  Balaiah Swamy ,  V. Chidambaram ,  P.S. Choudhury ,  S. Rajagopal

IPC分类号： B01J29/90 ,  B01J29/08

CPC分类号： B01J29/90 ,  B01J29/084 ,  B01J29/088 ,  B01J38/485 ,  C10G11/02 ,  C10G11/18 ,  C10G11/182 ,  C10G2300/107 ,  C10G2300/1077 ,  C10G2300/701 ,  C10G2300/703 ,  C10G2300/705 ,  C10G2400/02

摘要： A composition of a value added RFCC catalyst and a process of preparation of a composition for a dual function additive catalyst from a spent catalyst are disclosed. The value added spent FCC catalyst offers improved performance, options such as either employing as an additive for passivation of both vanadium and nickel and enhancing catalytic activity, for initial start-up or make-up for attrition losses. The value addition process does not harm any of physical properties of starting material with respect to ABD, attrition index, surface area and particle size distribution. Value added catalyst can be used in a range from 1-99 wt % in fluid catalytic cracking process in which, feeds may have higher metals and carbon.

摘要翻译： 公开了一种增值RFCC催化剂的组合物和从废催化剂制备双功能添加剂催化剂组合物的方法。 增值消耗的FCC催化剂提供了改进的性能，例如采用作为钒和镍钝化的添加剂并增强催化活性的选择，用于初始启动或补偿损耗。 增值过程对ABD，磨损指数，表面积和粒度分布方面的原料物理性质没有任何影响。 增值催化剂可以在流化催化裂化过程中的1-99重量％的范围内使用，其中进料可以具有较高的金属和碳。

公开(公告)号：US09266101B2

公开(公告)日：2016-02-23

申请号：US13808817

申请日：2011-07-04

申请人： Prabhu K. Mohan ,  A. V. Karthikeyani ,  Manish Agarwal ,  Biswanath Sarkar ,  Balaiah Swamy ,  V. Chidambaram ,  P. S. Choudhury ,  S. Rajagopal

发明人： Prabhu K. Mohan ,  A. V. Karthikeyani ,  Manish Agarwal ,  Biswanath Sarkar ,  Balaiah Swamy ,  V. Chidambaram ,  P. S. Choudhury ,  S. Rajagopal

IPC分类号： B01J29/90 ,  B01J29/08 ,  B01J38/48 ,  C10G11/02 ,  C10G11/18

CPC分类号： B01J29/90 ,  B01J29/084 ,  B01J29/088 ,  B01J38/485 ,  C10G11/02 ,  C10G11/18 ,  C10G11/182 ,  C10G2300/107 ,  C10G2300/1077 ,  C10G2300/701 ,  C10G2300/703 ,  C10G2300/705 ,  C10G2400/02

摘要： A composition of a value added RFCC catalyst and a process of preparation of a composition for a dual function additive catalyst from a spent catalyst are disclosed. The value added spent FCC catalyst offers improved performance, options such as either employing as an additive for passivation of both vanadium and nickel and enhancing catalytic activity, for initial start-up or make-up for attrition losses. The value addition process does not harm any of physical properties of starting material with respect to ABD, attrition index, surface area and particle size distribution. Value added catalyst can be used in a range from 1-99 wt % in fluid catalytic cracking process in which, feeds may have higher metals and carbon.

摘要翻译： 公开了一种增值RFCC催化剂的组合物和从废催化剂制备双功能添加剂催化剂组合物的方法。 增值消耗的FCC催化剂提供了改进的性能，例如采用作为钒和镍钝化的添加剂并增强催化活性的选择，用于初始启动或补偿损耗。 增值过程对ABD，磨损指数，表面积和粒度分布方面的原料物理性质没有任何影响。 增值催化剂可以在流化催化裂化过程中的1-99重量％的范围内使用，其中进料可以具有较高的金属和碳。

公开(公告)号：US08932712B2

公开(公告)日：2015-01-13

申请号：US13702545

申请日：2011-06-01

申请人： Mohan Prabhu Kuvettu ,  Manish Agarwal ,  Arumugam Velayutham Karthikeyani ,  Balaiah Swamy ,  Biswanath Sarkar ,  Mitra Bhanu Patel ,  Santanam Rajagopal

发明人： Mohan Prabhu Kuvettu ,  Manish Agarwal ,  Arumugam Velayutham Karthikeyani ,  Balaiah Swamy ,  Biswanath Sarkar ,  Mitra Bhanu Patel ,  Santanam Rajagopal

IPC分类号： B32B5/16

CPC分类号： C09K15/02 ,  B01J23/10 ,  B01J29/061 ,  B01J29/088 ,  B01J29/185 ,  B01J29/405 ,  B01J29/7057 ,  B01J35/0006 ,  B01J35/0026 ,  B01J35/023 ,  B01J37/0045 ,  B01J2229/20 ,  B01J2229/42 ,  B82Y30/00 ,  C10G11/02 ,  C10G11/05 ,  C10G75/02 ,  C10G2300/4075 ,  C10G2300/705 ,  Y10S977/773 ,  Y10T428/2982

摘要： The present invention relates a metal passivator additive comprising: a rare earth component; alumina; clay; colloidal silica; and a zeolite having high silica to alumina ratio. The present invention also relates to a process for preparing a metal passivator additive, said process comprising: preparing a rare earth slurry by mixing rare earth component with water; obtaining an alumina gel by treating alumina slurry with an acid, wherein the alumina slurry is prepared by mixing alumina and water; mixing the alumina gel and the rare earth slurry to obtain a slurry mixture; adding a colloidal silica to the slurry mixture; preparing a clay slurry by mixing clay and a dispersant; combining the clay slurry and the slurry mixture to obtain a rare earth-binder-filler slurry; obtaining an additive precursor slurry by mixing a zeolite having high silica to alumina ratio to the rare earth-binder-filler slurry; spray-drying the additive precursor slurry to obtain a spray-dried product; and calcining the spray-dried product to obtain the metal passivator additive.

摘要翻译： 本发明涉及一种金属钝化剂添加剂，其包括：稀土元素; 氧化铝 粘土; 胶体二氧化硅; 和具有高二氧化硅与氧化铝比的沸石。 本发明还涉及一种制备金属钝化剂添加剂的方法，所述方法包括：通过将稀土组分与水混合来制备稀土浆料; 通过用酸处理氧化铝浆料获得氧化铝凝胶，其中通过混合氧化铝和水制备氧化铝浆料; 混合氧化铝凝胶和稀土浆料以获得浆料混合物; 向浆料混合物中加入胶体二氧化硅; 通过混合粘土和分散剂制备粘土浆料; 将粘土浆料和浆料混合物混合，得到稀土 - 粘合剂 - 填料浆料; 通过将具有高二氧化硅与氧化铝比的沸石与稀土 - 粘合剂 - 填料浆料混合来获得添加剂前体浆料; 喷雾干燥添加剂前体浆料以获得喷雾干燥产物; 并煅烧喷雾干燥的产品以获得金属钝化剂添加剂。

公开(公告)号：US20130078468A1

公开(公告)日：2013-03-28

申请号：US13702545

申请日：2011-06-01

申请人： Mohan Prabhu Kuvettu ,  Manish Agarwal ,  Arumugam Velayutham Karthikeyani ,  Balaiah Swamy ,  Biswanath Sarkar ,  Mitra Bhanu Patel ,  Santanam Rajagopal

发明人： Mohan Prabhu Kuvettu ,  Manish Agarwal ,  Arumugam Velayutham Karthikeyani ,  Balaiah Swamy ,  Biswanath Sarkar ,  Mitra Bhanu Patel ,  Santanam Rajagopal

IPC分类号： C09K15/02

CPC分类号： C09K15/02 ,  B01J23/10 ,  B01J29/061 ,  B01J29/088 ,  B01J29/185 ,  B01J29/405 ,  B01J29/7057 ,  B01J35/0006 ,  B01J35/0026 ,  B01J35/023 ,  B01J37/0045 ,  B01J2229/20 ,  B01J2229/42 ,  B82Y30/00 ,  C10G11/02 ,  C10G11/05 ,  C10G75/02 ,  C10G2300/4075 ,  C10G2300/705 ,  Y10S977/773 ,  Y10T428/2982

摘要： The present invention relates a metal passivator additive comprising: a rare earth component; alumina; clay; colloidal silica; and a zeolite having high silica to alumina ratio. The present invention also relates to a process for preparing a metal passivator additive, said process comprising: preparing a rare earth slurry by mixing rare earth component with water; obtaining an alumina gel by treating alumina slurry with an acid, wherein the alumina slurry is prepared by mixing alumina and water; mixing the alumina gel and the rare earth slurry to obtain a slurry mixture; adding a colloidal silica to the slurry mixture; preparing a clay slurry by mixing clay and a dispersant; combining the clay slurry and the slurry mixture to obtain a rare earth-binder-filler slurry; obtaining an additive precursor slurry by mixing a zeolite having high silica to alumina ratio to the rare earth-binder-filler slurry; spray-drying the additive precursor slurry to obtain a spray-dried product; and calcining the spray-dried product to obtain the metal passivator additive.

摘要翻译： 本发明涉及一种金属钝化剂添加剂，其包括：稀土元素; 氧化铝 粘土; 胶体二氧化硅; 和具有高二氧化硅与氧化铝比的沸石。 本发明还涉及一种制备金属钝化剂添加剂的方法，所述方法包括：通过将稀土组分与水混合来制备稀土浆料; 通过用酸处理氧化铝浆料获得氧化铝凝胶，其中通过混合氧化铝和水制备氧化铝浆料; 混合氧化铝凝胶和稀土浆料以获得浆料混合物; 向浆料混合物中加入胶体二氧化硅; 通过混合粘土和分散剂制备粘土浆料; 将粘土浆料和浆料混合物混合，得到稀土 - 粘合剂 - 填料浆料; 通过将具有高二氧化硅与氧化铝比的沸石与稀土 - 粘合剂 - 填料浆料混合来获得添加剂前体浆料; 喷雾干燥添加剂前体浆料以获得喷雾干燥产物; 并煅烧喷雾干燥的产品以获得金属钝化剂添加剂。

公开(公告)号：US07968079B2

公开(公告)日：2011-06-28

申请号：US11970780

申请日：2008-01-08

申请人： Biswanath Sarkar ,  Kapil Arya ,  Gopal Ravichandran ,  Mohan Prabhu Kuvettu ,  Shiba Prasad Choudhury ,  Venkatachalam Krishnan ,  Sanjay Kumar Ray ,  Jayaraj Christopher ,  Satish Makhija

发明人： Biswanath Sarkar ,  Kapil Arya ,  Gopal Ravichandran ,  Mohan Prabhu Kuvettu ,  Shiba Prasad Choudhury ,  Venkatachalam Krishnan ,  Sanjay Kumar Ray ,  Jayaraj Christopher ,  Satish Makhija

IPC分类号： C01B39/20

CPC分类号： B01J29/084 ,  C01B33/20 ,  C01B39/20

摘要： The present disclosure provides a ready-to-use seed composition water, a source of silica, a source of alumina, and Na20, wherein the molar ratio of H20:Na20 ranges from 5 to 20, Na20:SiO2 ranges from 0.4 to 5 and SiO2:Al203 ranges from 1.3 to 5 used in the preparation of a synthetic faujasite zeolite which has high thermal stability and higher crystallite size. It further provides a process for preparing the ready-to-use seed composition for preparation of synthetic faujasite zeolite that requires lower crystallization time. The present disclosure provides a seed composition that does not require maturing time and a reaction gel composition that has low water and soda content. The present disclosure further provides a process for the preparation of synthetic faujasite zeolite by blending seed and reaction gel reaction composition to form a seed gel composition and subjecting it to crystallization.

摘要翻译： 本公开提供了即用型种子组合物水，二氧化硅源，氧化铝源和Na 2 O，其中H 2 O:Na 2的摩尔比为5至20，Na 2 O:SiO 2的范围为0.4至5，以及 SiO 2：Al 2 O 3在用于制备具有高热稳定性和较高微晶尺寸的合成八面沸石沸石中使用的范围为1.3至5。 它还提供了一种制备即用型种子组合物的方法，该种子组合物用于制备需要较低结晶时间的合成八面沸石沸石。 本公开提供了不需要熟化时间的种子组合物和具有低水和苏打含量的反应凝胶组合物。 本公开还提供了通过混合种子和反应凝胶反应组合物来制备合成八面沸石沸石以形成种子凝胶组合物并使其结晶的方法。

公开(公告)号：US07517827B2

公开(公告)日：2009-04-14

申请号：US11506405

申请日：2006-08-17

申请人： Gopal Ravichandran ,  Biswanath Sarkar ,  Mohan P. Kuvettu ,  Deepa Megavathu ,  Sanjay K Ray ,  Shiba P. Choudhury ,  Sudipta Roy ,  Venkatachalam Krishnan ,  Satish Makhija

发明人： Gopal Ravichandran ,  Biswanath Sarkar ,  Mohan P. Kuvettu ,  Deepa Megavathu ,  Sanjay K Ray ,  Shiba P. Choudhury ,  Sudipta Roy ,  Venkatachalam Krishnan ,  Satish Makhija

IPC分类号： B01J29/06

CPC分类号： C10G11/05 ,  B01J21/16 ,  B01J29/06 ,  B01J29/18 ,  B01J29/40 ,  B01J29/65 ,  B01J29/70 ,  B01J29/7007 ,  B01J35/023 ,  B01J37/0045 ,  B01J2229/20 ,  B01J2229/38 ,  B01J2229/42

摘要： The present invention relates to a cracking catalyst composition for cracking heavy hydrocarbon and processes for preparing the catalyst. The process can include treating zeolite with sodium free basic compound with or without phosphate, treating an alumina with a dilute acid, acidifying a colloidal silica, preparing a fine slurry of clay with a source of phosphate, adding alumina slurry and/or acidified colloidal silica to clay phosphate slurry, adding treated zeolite and spray-drying the slurry and calcining the same to obtain a cracking catalyst having adequate ABD and attrition resistance property.

摘要翻译： 本发明涉及一种用于裂解重质烃的裂化催化剂组合物及其制备方法。 该方法可以包括用含有或不含磷酸盐的无钠碱性化合物处理沸石，用稀酸处理氧化铝，酸化胶体二氧化硅，用磷酸盐源制备粘土的细浆料，加入氧化铝浆料和/或酸化胶体二氧化硅 加入处理过的沸石并喷雾干燥浆料并煅烧，得到具有足够ABD和耐磨性的裂化催化剂。

公开(公告)号：US20050158237A1

公开(公告)日：2005-07-21

申请号：US10758898

申请日：2004-01-16

申请人： Ram Thakur ,  Mohan Kuvettu ,  Biswanath Sarkar ,  Venkatachalam Krishnan ,  Mitra Patel ,  Sanjay Ray ,  Gopal Ravichandran ,  Satish Makhija ,  Sobhan Ghosh

发明人： Ram Thakur ,  Mohan Kuvettu ,  Biswanath Sarkar ,  Venkatachalam Krishnan ,  Mitra Patel ,  Sanjay Ray ,  Gopal Ravichandran ,  Satish Makhija ,  Sobhan Ghosh

IPC分类号： C01B39/02 ,  C01B39/14 ,  C01B39/20 ,  C01B39/26

CPC分类号： C01B39/14 ,  C01B39/02 ,  C01B39/20 ,  C01B39/26

摘要： The present invention relates to a process for enhancing the yield of molecular sieve zeolite during the synthesis from a sodium aluminosilicate reaction mixture, said process comprising the step of adding at an intermediate stage of crystallization a source of aluminum to the sodium aluminosilicate reaction mixture and allowing the mixture to crystallize.

摘要翻译： 本发明涉及一种在由铝硅酸钠反应混合物合成过程中提高分子筛沸石的产率的方法，所述方法包括在中间阶段将铝源加入到硅铝酸钠反应混合物中并允许 混合物结晶。

公开(公告)号：US20070203017A1

公开(公告)日：2007-08-30

申请号：US11506405

申请日：2006-08-17

申请人： Gopal Ravichandran ,  Biswanath Sarkar ,  Mohan P. Kuvettu ,  Deepa Megavathu ,  Sanjay K. Ray ,  Shiba P. Choudhury ,  Sudipta Roy ,  Venkatachalam Krishnan ,  Satish Makhija

发明人： Gopal Ravichandran ,  Biswanath Sarkar ,  Mohan P. Kuvettu ,  Deepa Megavathu ,  Sanjay K. Ray ,  Shiba P. Choudhury ,  Sudipta Roy ,  Venkatachalam Krishnan ,  Satish Makhija

IPC分类号： B01J29/06

CPC分类号： C10G11/05 ,  B01J21/16 ,  B01J29/06 ,  B01J29/18 ,  B01J29/40 ,  B01J29/65 ,  B01J29/70 ,  B01J29/7007 ,  B01J35/023 ,  B01J37/0045 ,  B01J2229/20 ,  B01J2229/38 ,  B01J2229/42

摘要： The present invention relates to a cracking catalyst composition for cracking heavy hydrocarbon and processes for preparing the catalyst. The process can include treating zeolite with sodium free basic compound with or without phosphate, treating an alumina with a dilute acid, acidifying a colloidal silica, preparing a fine slurry of clay with a source of phosphate, adding alumina slurry and/or acidified colloidal silica to clay phosphate slurry, adding treated zeolite and spray-drying the slurry and calcining the same to obtain a cracking catalyst having adequate ABD and attrition resistance property.

摘要翻译： 本发明涉及一种用于裂解重质烃的裂化催化剂组合物及其制备方法。 该方法可以包括用含有或不含磷酸盐的无钠碱性化合物处理沸石，用稀酸处理氧化铝，酸化胶体二氧化硅，用磷酸盐源制备粘土的细浆料，加入氧化铝浆料和/或酸化胶体二氧化硅 加入处理过的沸石并喷雾干燥浆料并煅烧，得到具有足够ABD和耐磨性的裂化催化剂。

公开(公告)号：US20070059238A1

公开(公告)日：2007-03-15

申请号：US11442871

申请日：2006-05-30

申请人： Ram Thakur ,  Mohan Kuvettu ,  Biswanath Sarkar ,  Venkatachalam Krishnan ,  Mitra Patel ,  Sanjay Ray ,  Gopal Ravichandran ,  Satish Makhija ,  Sobhan Ghosh

发明人： Ram Thakur ,  Mohan Kuvettu ,  Biswanath Sarkar ,  Venkatachalam Krishnan ,  Mitra Patel ,  Sanjay Ray ,  Gopal Ravichandran ,  Satish Makhija ,  Sobhan Ghosh

IPC分类号： C01B39/00

CPC分类号： C01B39/02 ,  C01B39/14 ,  C01B39/20 ,  C01B39/26

摘要： The present invention relates to a process for enhancing the yield of molecular sieve zeolite during the synthesis from a sodium aluminosilicate reaction mixture, said process comprising the step of adding at an intermediate stage of crystallization a source of aluminum to the sodium aluminosilicate reaction mixture and allowing the mixture to crystallize.

摘要翻译： 本发明涉及一种在由铝硅酸钠反应混合物合成过程中提高分子筛沸石的产率的方法，所述方法包括在中间阶段将铝源加入到硅铝酸钠反应混合物中并允许 混合物结晶。

公开(公告)号：US06864202B2

公开(公告)日：2005-03-08

申请号：US10282898

申请日：2002-10-29

申请人： Biswanath Sarkar ,  Ram Mohan Thakur ,  Nagesh Samant ,  Mohan Kuvettu Prabhu ,  Ravichandran Gopal ,  Mitra Bhanu Patel ,  Sanjay Kumar Ray ,  Krishnan Venkatachalam ,  Satish Makhija ,  Sobhan Ghosh

发明人： Biswanath Sarkar ,  Ram Mohan Thakur ,  Nagesh Samant ,  Mohan Kuvettu Prabhu ,  Ravichandran Gopal ,  Mitra Bhanu Patel ,  Sanjay Kumar Ray ,  Krishnan Venkatachalam ,  Satish Makhija ,  Sobhan Ghosh

IPC分类号： B01J29/06 ,  B01J37/00 ,  B01J29/08

CPC分类号： B01J29/06 ,  B01J37/0009 ,  B01J2229/42

摘要： The present invention relates to an improved process for obtaining sodium silicate alkali solution depleted of sodium salt and enriched in silica from a mother liquor recovered after isolation of molecular sieves and more particularly, the present invention relates to a process for recycling mother liquor obtained after the isolation of molecular sieves for the preparation of fresh molecular sieves or as a binder for producing Fluid Catalytic Cracking (FCC) catalyst.

摘要翻译： 本发明涉及一种用于从分离筛分离后回收的母液中获得不含钠盐并富集二氧化硅的硅酸钠碱溶液的改进方法，更具体地说，本发明涉及一种在 隔离用于制备新鲜分子筛的分子筛或用作制备流体催化裂化（FCC）催化剂的粘合剂。