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    Polyester Compositions, Method Of Manufacture, And Uses Thereof
    1.
    发明申请
    Polyester Compositions, Method Of Manufacture, And Uses Thereof 有权
    聚酯组合物，制造方法及其用途

    公开(公告)号：US20080139711A1

    公开(公告)日：2008-06-12

    申请号：US11870883

    申请日：2007-10-11

    申请人： Pravin Kamlakar Borade ,  Robert Russell Gallucci ,  Rama Konduri ,  Johannes Hubertus G.M. Lohmeijer ,  Subodh Kumar Pal ,  Veeraraghavan Srinivasan ,  Chris van der Weele ,  Gerrit de Wit

    发明人： Pravin Kamlakar Borade ,  Robert Russell Gallucci ,  Rama Konduri ,  Johannes Hubertus G.M. Lohmeijer ,  Subodh Kumar Pal ,  Veeraraghavan Srinivasan ,  Chris van der Weele ,  Gerrit de Wit

    IPC分类号： C08K5/3492 ,  C08K5/5313

    CPC分类号： C08K5/34928 ,  C08K3/22 ,  C08K3/30 ,  C08K5/0066 ,  C08K5/5313 ,  C08K7/14 ,  C08L67/02 ,  C08L79/08 ,  C08L2666/20

    摘要： A composition comprises 20 to 80 wt. % of a polyester component comprising a modified polybutylene terephthalate random copolymer derived from a polyethylene terephthalate component selected from polyethylene terephthalate and polyethylene terephthalate copolymers and having at least one residue derived from the polyethylene terephthalate component; from 5 to 35 wt. % of a flame retardant phosphinate (I) or (II) (R1)(R2)(PO)—O]−mMm+   (I) [(O—POR1)(R3)(POR2—O)]2−nMm+x,   (II) and/or a flame retardant polymer thereof, wherein R1 and R2 are independently are H, C1-C6-alkyl, or C6-C10-aryl; R3 is C1-C10, alkylene, C6-C10-arylene, -alkylarylene or -arylalkylene; M is an alkaline earth metal, alkali metal, Al, Ti, Zn, Fe, or boron; m is 1, 2, 3 or 4; n is 1, 2, or 3; and x is 1 or 2; 1 to 25 wt. % of a melamine polyphosphate, melamine cyanurate, melamine pyrophosphate, and/or melamine phosphate; and more than 0 to 25 wt. % of a polyetherimide.

    摘要翻译： 组合物包含20至80wt。 ％的聚酯组分包含衍生自选自聚对苯二甲酸乙二醇酯和聚对苯二甲酸乙二醇酯共聚物的聚对苯二甲酸乙二醇酯组分的改性聚对苯二甲酸丁二醇酯无规共聚物，并且具有至少一种衍生自聚对苯二甲酸乙二醇酯组分的残基; 5至35wt。 阻燃次膦酸盐（I）或（II）的％％线内公式描述=“在线公式”末端=“铅”→（R 1 SUP） （PO）-O] - （M）（I）在线公式描述= “In-line Formulas”end =“tail”？> <？in-line-formula description =“In-line Formulas”end =“lead”？> [（O-POR 1 ） （POR 2 -O）] 2 - - - - - - - - - - - - - - - - - - - - - - 和/或其阻燃性聚合物，其中R 1，R 2，R 2， R 2和R 2独立地是H，C 1 -C 6 - 烷基或C 6 -C 10 - 芳基; R 3是C 1 -C 10，亚烷基，C 6 -C 10 - 亚芳基， - 烷基亚芳基或 - 芳基亚烷基; M是碱土金属，碱金属，Al，Ti，Zn，Fe或硼; m为1,2,3或4; n为1,2或3; x为1或2; 1至25wt。 三聚氰胺多磷酸盐，三聚氰胺氰脲酸盐，三聚氰胺焦磷酸盐和/或磷酸三聚氰胺的百分比; 和大于0至25wt。 ％的聚醚酰亚胺。

    Polyester compositions, method of manufacture, and uses thereof
    3.
    发明授权
    Polyester compositions, method of manufacture, and uses thereof 有权
    聚酯组合物，制造方法及其用途

    公开(公告)号：US08188172B2

    公开(公告)日：2012-05-29

    申请号：US11870896

    申请日：2007-10-11

    申请人： Somasundaram Elango ,  Rama Konduri ,  Subodh Kumar Pal ,  Reema Sinha ,  Veeraraghavan Srinivasan ,  Chris van der Weele ,  Gerrit de Wit

    发明人： Somasundaram Elango ,  Rama Konduri ,  Subodh Kumar Pal ,  Reema Sinha ,  Veeraraghavan Srinivasan ,  Chris van der Weele ,  Gerrit de Wit

    IPC分类号： C08K5/5313

    CPC分类号： C08K5/34928 ,  C08K3/016 ,  C08K5/0066 ,  C08K5/5313 ,  C08K2201/014 ,  C08L61/06 ,  C08L67/02 ,  C08L71/12 ,  C08L79/08 ,  C08L81/04 ,  C08L81/06 ,  C08L85/02 ,  C08L2666/20

    摘要： A composition is described, comprising: (a) from 20 to 80 wt % of a polyester; (b) from 5 to 35 wt % of a flame retardant phosphinate of the formula (I) [(R1)(R2)(PO)—O]−mMm+  (I), a flame retardant diphosphinate of the formula (II) [(O—POR1)(R3)(POR2—O)]2−nMxm+  (II), and/or a flame retardant polymer derived from the flame retardant phosphinate of the formula (I) or the flame retardant diphosphinate of the formula (II), wherein R1 and R2 are identical or different and are H, C1-C6-alkyl, linear or branched, or C6-C10-aryl; R3 is C1-C10-alkylene, linear or branched, C6-C10-arylene, -alkylarylene or -arylalkylene; M is an alkaline earth metal, alkali metal, Al, Ti, Zn, Fe, or boron; m is 1, 2, 3 or 4; n is 1, 2, or 3; and x is 1 or 2; (c) from 1 to 25 wt % of a melamine polyphosphate, melamine cyanurate, melamine pyrophosphate, and/or melamine phosphate; (d) from more than 0 to 25 wt % of a polyetherimide; and (e) optionally, an additive.

    摘要翻译： 描述了一种组合物，其包含：（a）20至80重量％的聚酯; （b）5至35重量％的式（I）[（R1）（R2）（PO）-O] -mMm +（I）的阻燃二膦酸盐，式（II）的阻燃二磷酸盐[ （O-POR1）（R3）（POR2-O）] 2-nMxm +（II），和/或衍生自式（I）的阻燃次膦酸酯的阻燃聚合物或式（II）的阻燃二磷酸 ），其中R1和R2相同或不同，为H，C1-C6-烷基，直链或支链或C6-C10-芳基; R 3是C 1 -C 10亚烷基，直链或支链的C 6 -C 10亚芳基， - 亚烷基亚芳基或 - 芳基亚烷基; M是碱土金属，碱金属，Al，Ti，Zn，Fe或硼; m为1,2,3或4; n为1,2或3; x为1或2; （c）1〜25重量％的多聚磷酸三聚氰胺，氰尿酸三聚氰胺，焦磷酸三聚氰胺和/或磷酸三聚氰胺; （d）大于0至25重量％的聚醚酰亚胺; 和（e）任选的添加剂。

    Polyester Compositions, Method Of Manufacture, And Uses Thereof
    4.
    发明申请
    Polyester Compositions, Method Of Manufacture, And Uses Thereof 有权
    聚酯组合物，制造方法及其用途

    公开(公告)号：US20090036578A1

    公开(公告)日：2009-02-05

    申请号：US11870896

    申请日：2007-10-11

    申请人： Somasundaram Elango ,  Rama Konduri ,  Subodh Kumar Pal ,  Reema Sinha ,  Veeraraghavan Srinivasan ,  Chris van der Weele ,  Gerrit de Wit

    发明人： Somasundaram Elango ,  Rama Konduri ,  Subodh Kumar Pal ,  Reema Sinha ,  Veeraraghavan Srinivasan ,  Chris van der Weele ,  Gerrit de Wit

    IPC分类号： C08K5/3492 ,  C08K5/5317

    CPC分类号： C08K5/34928 ,  C08K3/016 ,  C08K5/0066 ,  C08K5/5313 ,  C08K2201/014 ,  C08L61/06 ,  C08L67/02 ,  C08L71/12 ,  C08L79/08 ,  C08L81/04 ,  C08L81/06 ,  C08L85/02 ,  C08L2666/20

    摘要： A composition is described, comprising: (a) from 20 to 80 wt % of a polyester; (b) from 5 to 35 wt % of a flame retardant phosphinate of the formula (I) [(R1)(R2)(PO)—O]−mMm+  (I), a flame retardant diphosphinate of the formula (II) [(O—POR1)(R3)(POR2—O)]2−nMxm+  (II), and/or a flame retardant polymer derived from the flame retardant phosphinate of the formula (I) or the flame retardant diphosphinate of the formula (II), wherein R1 and R2 are identical or different and are H, C1-C6-alkyl, linear or branched, or C6-C10-aryl; R3 is C1-C10-alkylene, linear or branched, C6-C10-arylene, -alkylarylene or -arylalkylene; M is an alkaline earth metal, alkali metal, Al, Ti, Zn, Fe, or boron; m is 1, 2, 3 or 4; n is 1, 2, or 3; and x is 1 or 2; (c) from 1 to 25 wt % of a melamine polyphosphate, melamine cyanurate, melamine pyrophosphate, and/or melamine phosphate; (d) from more than 0 to 25 wt % of a polyetherimide; and (e) optionally, an additive.

    摘要翻译： 描述了一种组合物，其包含：（a）20至80重量％的聚酯; （b）5至35重量％的式（I）的阻燃次膦酸盐<？in-line-formula description =“In-line Formulas”end =“lead”→> [（R1）（R2） PO）-O] -mMm +（I），<？在线公式描述=“在线配方”end =“tail”？>式（II）的阻燃二磷酸钠< 描述=“在线公式”end =“lead”？> [（O-POR1）（R3）（POR2-O）] 2-nMxm +（II），<？in-line-formula description =“In-line 和/或衍生自式（I）的阻燃次膦酸酯或式（II）的阻燃二膦酸盐的阻燃聚合物，其中R 1和R 2相同或不同，并且是 H，C 1 -C 6 - 烷基，直链或支链或C 6 -C 10 - 芳基; R 3是C 1 -C 10亚烷基，直链或支链的C 6 -C 10亚芳基， - 亚烷基亚芳基或 - 芳基亚烷基; M是碱土金属，碱金属，Al，Ti，Zn，Fe或硼; m为1,2,3或4; n为1,2或3; x为1或2; （c）1〜25重量％的多聚磷酸三聚氰胺，氰尿酸三聚氰胺，焦磷酸三聚氰胺和/或磷酸三聚氰胺; （d）大于0至25重量％的聚醚酰亚胺; 和（e）任选的添加剂。

    Method to make a solid polymeric phosphate and resinous compositions containing it
    5.
    发明授权
    Method to make a solid polymeric phosphate and resinous compositions containing it 有权
    制备固体聚合物磷酸盐和含有它的树脂组合物的方法

    公开(公告)号：US06713598B2

    公开(公告)日：2004-03-30

    申请号：US10229836

    申请日：2002-08-28

    申请人： Immanuel I. Selvaraj ,  Gerrit de Wit ,  Jan Gosens

    发明人： Immanuel I. Selvaraj ,  Gerrit de Wit ,  Jan Gosens

    IPC分类号： C08G7902

    CPC分类号： C08G79/04 ,  C09K21/12

    摘要： Disclosed is a method for the preparation of polymeric phosphate flame retardants with a molecular weight of at least about 1500 and a softening temperature of at least about 10° C. comprising the steps of (a) reacting a phosphorus oxyhalide with a monohydroxyaromatic compound, (b) removing substantially all of any remaining phosphorus oxyhalide; (c) reacting the monoaryldichlorophosphate product with a dihydroxyaromatic compound and (d) reacting the product of step (c) with a monohydroxyaromatic compound. The solid polymeric flame retardant has a linear structure and less than 10 ppm halogen bound to phosphorus. Also disclosed are resinous compositions comprising the solid polymeric phosphate made by the method of the invention and at least one other polymeric resin.

    摘要翻译： 公开了一种制备聚合磷酸酯阻燃剂的方法，其分子量为至少约1500，软化温度为至少约10℃，包括以下步骤：（a）使卤代磷卤化物与单羟基芳族化合物反应， b）基本上除去所有剩余的磷酰卤; （c）使单芳基二氯磷酸盐产物与二羟基芳族化合物反应，和（d）使步骤（c）的产物与单羟基芳族化合物反应。 固体聚合物阻燃剂具有线性结构和小于10ppm的与磷结合的卤素。 还公开了包含通过本发明的方法制备的固体聚合磷酸酯和至少一种其它聚合物树脂的树脂组合物。

    Polycarbonate polyester molding composition
    6.
    发明授权
    Polycarbonate polyester molding composition 失效
    聚碳酸酯聚酯成型组合物

    公开(公告)号：US06949599B2

    公开(公告)日：2005-09-27

    申请号：US10650391

    申请日：2003-08-28

    申请人： Peter H. Th. Vollenberg ,  Gerrit de Wit

    发明人： Peter H. Th. Vollenberg ,  Gerrit de Wit

    IPC分类号： C08G63/199 ,  C08K3/32 ,  C08K5/52 ,  C08L67/00 ,  C08L67/02 ,  C08L69/00

    CPC分类号： C08L67/02 ,  C08L69/00 ,  C08L2205/02 ,  C08L2666/18 ,  C08L2666/02

    摘要： A clear blend of three resin components includes a first polycarbonate resin component; a second resin component of a first polyester copolymer resin derived from a cycloaliphatic diol and a cycloaliphatic dicarboxylic acid, and a third resin component of a second polyester polymer resin derived from the condensation of a cyclohexane diol with a terephthalic acid and an additional condensation reaction component selected from aliphatic or aromatic diacids or diols suitable for enhancing the clarity of said blend wherein the three component blend has a light transmission of seventy percent or greater and an elongation at break after exposure to Fuel C of forty percent or greater.

    摘要翻译： 三种树脂成分的透明混合物包括第一聚碳酸酯树脂组分; 衍生自脂环族二醇和脂环族二羧酸的第一聚酯共聚物树脂的第二树脂组分和衍生自环己烷二醇与对苯二甲酸缩合的第二聚酯聚合物树脂的第三树脂组分和另外的缩合反应组分 选自适于增强所述共混物的透明度的脂族或芳族二酸或二醇，其中三组分共混物具有百分之七十以上的透光率和暴露于燃料C中的断裂伸长率为百分之四十以上。

    Flame-retardant polyester composition, method for the preparation thereof, and articles derived therefrom
    7.
    发明授权
    Flame-retardant polyester composition, method for the preparation thereof, and articles derived therefrom 有权
    阻燃聚酯组合物，其制备方法和由其衍生的制品

    公开(公告)号：US06710108B2

    公开(公告)日：2004-03-23

    申请号：US09682409

    申请日：2001-08-30

    申请人： Luc Govaerts ,  Sapna Halim Talibuddin ,  Gerrit de Wit

    发明人： Luc Govaerts ,  Sapna Halim Talibuddin ,  Gerrit de Wit

    IPC分类号： C08J510

    CPC分类号： C08K5/16 ,  C08K5/49 ,  C08L67/02

    摘要： A polyester composition includes a poly(butylene terephthalate), a nitrogen-containing flame retardant, and a phosphorus-containing flame retardant, such that the weight ratio of the total of the nitrogen-containing flame retardant and the phosphorus-containing flame retardant to poly(butylene terephthalate resin) is at least about 0.70, and the weight ratio of the phosphorus-containing flame retardant to the nitrogen-containing flame retardant is at least about 1.0. The compositions have excellent color stability under ultraviolet light aging, good flame retardance, and high impact strength.

    摘要翻译： 聚酯组合物包括聚（对苯二甲酸丁二醇酯），含氮阻燃剂和含磷阻燃剂，使得含氮阻燃剂和含磷阻燃剂的总量与聚 （对苯二甲酸丁二醇酯树脂）为至少约0.70，含磷阻燃剂与含氮阻燃剂的重量比为至少约1.0。 该组合物在紫外线老化下具有优异的颜色稳定性，良好的阻燃性和高冲击强度。

    Method of manufacture of polyester molding compositions and articles produced therefrom
    9.
    发明授权
    Method of manufacture of polyester molding compositions and articles produced therefrom 有权
    聚酯成型用组合物的制造方法及由其制造的制品

    公开(公告)号：US07253230B2

    公开(公告)日：2007-08-07

    申请号：US10710187

    申请日：2004-06-24

    申请人： Sebastiaan Bernardus Damman ,  Gerrit de Wit

    发明人： Sebastiaan Bernardus Damman ,  Gerrit de Wit

    IPC分类号： C08L51/04

    CPC分类号： C08L67/02 ,  C08K3/013 ,  C08L51/04 ,  C08L79/08 ,  C08L2666/02

    摘要： A thermoplastic molding composition comprises a resin composition having 50 to about 90 weight percent of a polyester, about 8 to about 48 weight percent of a polyetherimide, about 2 to about 25 weight percent of a high rubber graft impact modifier, each based on the total resin composition, and up to about 15 weight percent of a particulate filler. A method of making the composition comprises pre-melt compounding a polyester, a polyetherimide, and a high rubber graft impact modifier to form a pre-compounded blend, wherein the pre-compounded blend has a Tg of greater than or equal to about 110° C.; and dry-blending a crystallized polyester with the pre-compounded blend to form the molding composition. Such molding compositions are particularly useful in blow-molding containers for liquids such as beer.

    摘要翻译： 热塑性模塑组合物包含一种树脂组合物，其具有50至约90重量％的聚酯，约8至约48重量％的聚醚酰亚胺，约2至约25重量％的高橡胶接枝抗冲改性剂，各自基于总量 树脂组合物和至多约15重量％的颗粒填料。 制备组合物的方法包括将聚酯，聚醚酰亚胺和高橡胶接枝抗冲改性剂预熔混合以形成预混合共混物，其中预混合共混物的Tg大于或等于约110℃ C。; 并将结晶的聚酯与预混合的共混物干混以形成模塑组合物。 这种成型组合物特别适用于诸如啤酒的液体吹塑容器。