公开(公告)号：US20200339789A1

公开(公告)日：2020-10-29

申请号：US16764890

申请日：2018-11-29

Applicant: Dow Global Technologies LLC ,  Rohm and Haas Company

Inventor： Liang Chen ,  Robert S. Moglia ,  Carlos A. Cruz ,  Ralph C. Even ,  Jeffrey C. Munro ,  Jeffrey M. Cogen

IPC: C08L23/08 ,  C08L23/06 ,  C08F255/08 ,  C08K5/14

Abstract: Provided is a method of making a polymeric composition comprising (a) providing a dispersion of initial polyolefin particles in an aqueous medium, wherein the initial polyolefin particles comprise (i) one or more hydrocarbon polyolefin, (ii) one or more non-hydrocarbon polyolefin, and (iii) one or more crosslinking agent; (b) contacting the initial polyolefin particles with a peroxide initiator to form crosslinked polyolefin particles.

公开(公告)号：US10316126B2

公开(公告)日：2019-06-11

申请号：US15536145

申请日：2015-12-17

Applicant: Rohm and Haas Company

Inventor： Michael T. Petr ,  Carlos A. Cruz

IPC: C08F265/06 ,  C08L27/06 ,  C08F285/00 ,  C08L51/00

Abstract: An impact modifier composition comprising one or more core/shell polymers which comprise a crosslinked core having from 98 to 99.9 wt % units derived from one or more acrylate monomers and from 0.1 to 2 wt % units derived from a crosslinker containing a vinylically unsaturated moiety with an acrylate free radical reactivity ratio from 0.8 to 1.2 and one or more non-acrylate vinylically unsaturated moiety(ies) with an acrylate free radical reactivity ratio(s) greater than 1, wherein the crosslinked core has a swell ratio in THF between 7 and 15 and a Tg equal to less than 10° C.; and a shell having from 20 to 100 wt % units derived from one or more (meth)acrylate monomers and having a Tg of greater than 20° C. is provided. Also provided is a polymer composition comprising the impact modifier composition and a base structural polymer.

公开(公告)号：US11499040B2

公开(公告)日：2022-11-15

申请号：US16765938

申请日：2018-11-29

Applicant: Dow Global Technologies LLC ,  Rohm and Haas Company

Inventor： Liang Chen ,  Andy Jun Li ,  Matthew Carter ,  Robert S. Moglia ,  Ralph C. Even ,  John F. Kohn ,  Carlos A. Cruz ,  Yannick Saint-Gerard ,  Douglas J. Hasso ,  Miroslav Janco

IPC: C08L23/08

Abstract: Provided is a dispersion of composite particles in an aqueous medium, wherein the composite particles comprise (I) a crosslinked polyolefin core, and (II) a full or partial shell comprising polymerized units of one of more vinyl monomers.

公开(公告)号：US11136452B2

公开(公告)日：2021-10-05

申请号：US16631409

申请日：2018-07-13

Applicant: Rohm and Haas Company

Inventor： Steven Brown ,  Carlos A. Cruz ,  Morris Wills

IPC: C08L33/12 ,  C08F285/00 ,  C08L51/04

Abstract: Provided are poly(methyl methacrylate) resin compositions containing (a) a methyl methacrylate polymer, and (b) a multistage acrylic impact modifier containing (i) a core-shell polymer, and (ii) an overpolymer containing methyl methacrylate monomers and a chain transfer agent.

公开(公告)号：US10851234B2

公开(公告)日：2020-12-01

申请号：US16274570

申请日：2019-02-13

Applicant: ROHM AND HAAS COMPANY

Inventor： Hailan Guo ,  Carlos A. Cruz

IPC: C08L33/12 ,  C08K5/11 ,  C08J5/18 ,  C08L33/08 ,  C08L47/00 ,  C08L51/00 ,  C08K5/00 ,  C08K5/12 ,  C08L71/02

Abstract: Provided is a polymer composition comprising an acrylic resin and a compound (II) wherein R1, R2, R3, and R4 is each independently hydrogen or an organic group having 1 or more carbon atoms, R5 is an alkylene group of 1 to 4 carbon atoms and n is from 1 to 20.

公开(公告)号：US10851233B2

公开(公告)日：2020-12-01

申请号：US15776159

申请日：2016-12-13

Applicant: Rohm and Haas Company

Inventor： Hailan Guo ,  Carlos A. Cruz

IPC: C08L33/12 ,  C08K5/11 ,  C08J5/18 ,  C08L33/08 ,  C08L47/00 ,  C08L51/00 ,  C08K5/00 ,  C08K5/12 ,  C08L71/02

Abstract: Provided is a polymer composition comprising an acrylic resin and a compound (I) wherein R1, R2, R3, and R4 is each independently hydrogen or an organic group having 1 or more carbon atoms, and n is from 1 to 20.

公开(公告)号：US20200332098A1

公开(公告)日：2020-10-22

申请号：US16765938

申请日：2018-11-29

Applicant: Dow Global Technologies LLC ,  Rohm and Haas Company

Inventor： Liang Chen ,  Andy Jun Li ,  Matthew Carter ,  Robert S. Moglia ,  Ralph C. Even ,  John F. Kohn ,  Carlos A. Cruz ,  Yannick Saint-Gerard ,  Douglas J. Hasso ,  Miroslav Janco

IPC: C08L23/08

Abstract: Provided is a dispersion of composite particles in an aqueous medium, wherein the composite particles comprise (I) a crosslinked polyolefin core, and (II) a full or partial shell comprising polymerized units of one of more vinyl monomers.

公开(公告)号：US20170362367A1

公开(公告)日：2017-12-21

申请号：US15536145

申请日：2015-12-17

Applicant: Rohm and Haas Company

Inventor： Michael T. Petr ,  Carlos A. Cruz

IPC: C08F265/06 ,  C08L27/06

CPC classification number: C08F265/06 ,  C08F285/00 ,  C08L27/06 ,  C08L51/003 ,  C08F2/22 ,  C08F220/12

Abstract: An impact modifier composition comprising one or more core/shell polymers which comprise a crosslinked core having from 98 to 99.9 wt % units derived from one or more acrylate monomers and from 0.1 to 2 wt % units derived from a crosslinker containing a vinylically unsaturated moiety with an acrylate free radical reactivity ratio from 0.8 to 1.2 and one or more non-acrylate vinylically unsaturated moiety(ies) with an acrylate free radical reactivity ratio(s) greater than 1, wherein the crosslinked core has a swell ratio in THF between 7 and 15 and a Tg equal to less than 10° C.; and a shell having from 20 to 100 wt % units derived from one or more (meth)acrylate monomers and having a Tg of greater than 20° C. is provided. Also provided is a polymer composition comprising the impact modifier composition and a base structural polymer.

公开(公告)号：US11414540B2

公开(公告)日：2022-08-16

申请号：US16767741

申请日：2018-12-04

Applicant: Dow Global Technologies LLC ,  Rohm and Haas Company

Inventor： Liang Chen ,  Carlos A. Cruz ,  Yannick Saint-Gerard ,  Jessica Ye Huang ,  Matthew J. Crimmins ,  Douglas J. Hasso

IPC: C08L69/00 ,  C08L55/02 ,  C08L51/06 ,  C08F255/02 ,  C08F255/06

Abstract: Provided is a method of modifying a blend of polycarbonate and acrylonitrile/butadiene/styrene copolymer comprising adding composite particles to the blend, wherein the composite particles comprise (I) a partially crosslinked polyolefin core and (II) a full or partial shell comprising polymerized units of one or more vinyl monomer, and the resulting modified blend.

公开(公告)号：US20190211197A1

公开(公告)日：2019-07-11

申请号：US16274570

申请日：2019-02-13

Applicant: ROHM AND HAAS COMPANY

Inventor： Hailan Guo ,  Carlos A. Cruz

IPC: C08L33/12 ,  C08L33/08 ,  C08L47/00 ,  C08L51/00

CPC classification number: C08L33/12 ,  C08J5/18 ,  C08J2333/08 ,  C08J2333/12 ,  C08K5/0016 ,  C08K5/11 ,  C08K5/12 ,  C08L33/08 ,  C08L47/00 ,  C08L51/003 ,  C08L71/02 ,  C08L2203/16 ,  C08L2205/02 ,  C08L2205/03 ,  C08L33/10 ,  C08L51/00

Abstract: Provided is a polymer composition comprising an acrylic resin and a compound (II) wherein R1, R2, R3, and R4 is each independently hydrogen or an organic group having 1 or more carbon atoms, R5 is an alkylene group of 1 to 4 carbon atoms and n is from 1 to 20.