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    Process for the production of fatty acid alkyl esters
    3.
    发明授权
    Process for the production of fatty acid alkyl esters 失效
    生产脂肪酸烷基酯的方法

    公开(公告)号：US08580986B2

    公开(公告)日：2013-11-12

    申请号：US12304078

    申请日：2007-05-16

    申请人： Eric Dubreucq ,  Albrecht Weiss ,  Bernhard Gutsche ,  Bernd Fabry ,  Guy Moulin

    发明人： Eric Dubreucq ,  Albrecht Weiss ,  Bernhard Gutsche ,  Bernd Fabry ,  Guy Moulin

    IPC分类号： C11C3/00 ,  C12P7/64

    CPC分类号： C12P7/649 ,  A23K10/10 ,  C10L1/026 ,  C11C3/003 ,  Y02E50/13 ,  Y02E50/17

    摘要： Disclosed is an improved process for the production of fatty acid lower alkyl esters according to formula (I) R1CO—OR2  (I) in which R1CO represents a linear or branched acyl moiety having from about 6 to about 22 carbon atoms and 0 to 6 double bonds and wherein R2 is a linear or branched alkyl moiety having 1 to 6 carbon atoms, by transesterification of triglycerides or fatty acid esters using C1-C6 aliphatic alcohols, which includes the steps of (a) providing an aqueous mixture of aliphatic C1-C6 alcohol by fermenting in a first reactor a carbon source comprising carbohydrates and/or glycerol produce a fermentation broth comprising said aliphatic C1-C6 alcohol, (b) providing in a second reactor a triglyceride and/or an ester of a fatty acid, together with a biocatalyst capable of effecting a transesterification reaction, (c) transferring said aqueous aliphatic C1-C6 alcohol mixture obtained from said first reactor into said second reactor to provide a two-phase system, and (d) effecting the transesterification reaction to produce said fatty acid lower alkyl ester and a glycerol- or alcohol-containing aqueous phase. The products thus obtained are particularly useful as components of the fuel known as biodiesel.

    摘要翻译： 公开了一种改进的式（I）R1CO-OR2（I）的脂肪酸低级烷基酯的制备方法，其中R 1 CO表示具有约6至约22个碳原子且0至6个双键的直链或支链酰基部分 并且其中R 2是具有1至6个碳原子的直链或支链烷基部分，通过使用C 1 -C 6脂族醇进行甘油三酯或脂肪酸酯的酯交换反应，其包括以下步骤：（a）提供脂族C 1 -C 6 醇通过在第一反应器中发酵包含碳水化合物和/或甘油的碳源产生包含所述脂族C 1 -C 6醇的发酵液，（b）在第二反应器中提供甘油三酯和/或脂肪酸酯，以及 能够进行酯交换反应的生物催化剂，（c）将从所述第一反应器获得的脂族C 1 -C 6醇混合物混合物转移到所述第二反应器中以提供两相体系，和（d） g的酯交换反应以产生所述脂肪酸低级烷基酯和含甘油或醇的水相。 这样得到的产物特别适用于称为生物柴油的燃料的组分。

    Lipophilic Preparations
    4.
    发明申请
    Lipophilic Preparations 审中-公开
    亲脂性制剂

    公开(公告)号：US20110089370A1

    公开(公告)日：2011-04-21

    申请号：US12672705

    申请日：2008-08-01

    申请人： Bernhard Gutsche ,  Ulrich Schörken ,  Albrecht Weiss ,  Bernd Fabry

    发明人： Bernhard Gutsche ,  Ulrich Schörken ,  Albrecht Weiss ,  Bernd Fabry

    IPC分类号： C12P7/64 ,  C09K3/00

    CPC分类号： C12P7/6463 ,  C11C3/003

    摘要： Disclosed are novel lipophilic preparations comprising (a) from 20 to 40% by weight of myristic acid or esters thereof, (b) from 20 to 40% by weight of palmitic acid or esters thereof, (c) from 0.1 to 5% by weight of aliphatic and/or cycloaliphatic hydrocarbons and (d) less than 20% by weight of carboxylic acids or esters thereof having 12 and fewer carbons in the acyl moiety and (e) less than 20% by weight of carboxylic acids or esters thereof having 16 and more carbons in the acyl moiety, with the proviso that all percentages add up to 100% by weight.

    摘要翻译： 公开了新的亲脂性制剂，其包含（a）20至40重量％的肉豆蔻酸或其酯，（b）20至40重量％的棕榈酸或其酯，（c）0.1至5重量％ 的脂族和/或脂环族烃和（d）少于20重量％的在酰基部分中具有12个或更少碳原子的羧酸或其酯，和（e）少于20重量％的具有16个碳原子的羧酸或其酯 和酰基部分中的更多碳，条件是所有百分比加起来为100重量％。

    Method for producing linear or branched fatty acid esters by means of heterogeneously catalysed reactive rectification with an upstream reactor
    9.
    发明申请
    Method for producing linear or branched fatty acid esters by means of heterogeneously catalysed reactive rectification with an upstream reactor 有权
    通过用上游反应器进行非均相催化的反应性精馏生产直链或支链脂肪酸酯的方法

    公开(公告)号：US20060052619A1

    公开(公告)日：2006-03-09

    申请号：US10537973

    申请日：2003-12-02

    申请人： Bernhard Gutsche ,  Magnus Topphoff ,  Harald Robler ,  Erich Reuter

    发明人： Bernhard Gutsche ,  Magnus Topphoff ,  Harald Robler ,  Erich Reuter

    IPC分类号： C07C69/02

    CPC分类号： C07C67/08 ,  C07C67/54 ,  Y02P20/127 ,  C07C69/003 ,  C07C69/22 ,  C07C69/18

    摘要： The disclosed invention relates to a countercurrent process for the continuous esterification of C1-22 (fatty) acids with C1-10 monoalkanols, C2-5 di- or trialkanols or mixtures thereof in the liquid phase in the presence of heterogeneous catalysts in a preliminary reactor (1) and in a reaction column (3), characterized in that the reaction column (3) is preceded by the preliminary reactor (1) and a separation unit (2) for the purpose of reducing the viscosity of the reaction mixture and removing the water of reaction from the system via a separation unit (2) to displace the reaction equilibrium before the reaction column (3). A further aspect of the invention concerns feeding nitrogen in at the lowermost plate of the reaction column (3) in order to increase the vapour load in the lower part of the reaction column.

    摘要翻译： 所公开的本发明涉及用C 1〜12个单烷醇（C 2-5）连续酯化C 1-22（脂肪酸）的逆流方法， 在反应器（1）和反应塔（3）中的非均相催化剂存在下，液相中的二 - 或三烷醇或其混合物或其混合物，其特征在于反应塔（3）之前是预备 反应器（1）和分离单元（2），用于降低反应混合物的粘度并通过分离单元（2）从体系中除去反应水以置换反应塔（3）之前的反应平衡， 。 本发明的另一方面涉及在反应塔（3）的最下面的塔板上加入氮气，以增加反应塔下部的蒸气负荷。

    Discontinuous process for conducting a heterogeneously catalyzed reaction and installation for heterogeneously catalyzed manufacture of products
    10.
    发明授权
    Discontinuous process for conducting a heterogeneously catalyzed reaction and installation for heterogeneously catalyzed manufacture of products 失效
    用于进行非均相催化反应和非均匀催化产物制造的不连续方法

    公开(公告)号：US06245727B1

    公开(公告)日：2001-06-12

    申请号：US08259362

    申请日：1994-06-14

    申请人： Bernhard Gutsche ,  Lutz Jeromin ,  Eberhard Peukert ,  Levent Yueksel ,  Kurt Adrian ,  Heinz Bollweg

    发明人： Bernhard Gutsche ,  Lutz Jeromin ,  Eberhard Peukert ,  Levent Yueksel ,  Kurt Adrian ,  Heinz Bollweg

    IPC分类号： C07C4330

    CPC分类号： B01J19/1881 ,  B01D3/009 ,  B01J8/025 ,  B01J8/0285 ,  B01J2208/00256 ,  B01J2208/00283 ,  B01J2208/00557 ,  B01J2208/00663 ,  B01J2219/00006 ,  C07C67/08 ,  Y02P20/127 ,  Y02P20/582 ,  C07C69/26

    摘要： The invention relates firstly to a discontinuous process for conducting a heterogeneously catalyzed reaction taking place at elevated temperature, in which heat-sensitive products are formed, a heat transfer unit (4) different from the reactor (1) being used for heating and a fixed-bed catalyst (3) being used as the catalyst and the reaction mixture being continuously circulated in succession through the catalyst (3) and then through the heat transfer unit (4). The problem to be solved in this process is to avoid losses of catalyst and product and to shorten the batch time and, optionally, the reaction time in accordance with German patent applications P 38 13 612.0 and P 38 26 320.3. The invention also relates to a plant for the discontinuous heterogeneously catalyzed production of heat-sensitive products at elevated temperature comprising a reactor (1), characterized by a heat transfer unit (4) arranged outside and connected to the reactor (1), a catalyst container (3) containing a fixed-bed catalyst preceding the heat transfer unit and a pump (2) for continuously circulating the reaction mixture in succession through the catalyst (3) and then through the heat transfer unit (4).

    摘要翻译： 本发明首先涉及一种用于进行非均相催化反应的不连续过程，该反应发生在形成热敏产物的高温下，不同于用于加热的反应器（1）的传热单元（4）和固定 用作催化剂的催化剂（3），反应混合物连续循环通过催化剂（3），然后通过传热单元（4）循环。 在该过程中要解决的问题是避免催化剂和产物的损失，并缩短批料时间，以及根据德国专利申请P 38 13 612.0和P 38 26 3203的任选的反应时间。本发明还涉及 用于在升高的温度下不连续地非均相催化生产热敏产物的设备，包括反应器（1），其特征在于布置在反应器（1）外部并连接到反应器（1）的传热单元（4），催化剂容器（3） 在传热单元之前的固定床催化剂和用于使反应混合物连续循环通过催化剂（3）然后通过传热单元（4）的泵（2）。