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    Sprayed on superoleophobic surface formulations
    1.
    发明授权
    Sprayed on superoleophobic surface formulations 有权
    喷涂在超疏油表面配方上

    公开(公告)号：US08580027B1

    公开(公告)日：2013-11-12

    申请号：US13207562

    申请日：2011-08-11

    申请人： Raymond Campos ,  Andrew J. Guenthner ,  Timothy S. Haddad ,  Joseph M. Mabry

    发明人： Raymond Campos ,  Andrew J. Guenthner ,  Timothy S. Haddad ,  Joseph M. Mabry

    IPC分类号： C08K9/08 ,  C08K9/06

    CPC分类号： C08K9/08 ,  C09D127/18 ,  C08K9/06 ,  C08L27/18

    摘要： Fluoroalkylsilane-treated metal oxide particles and a fluoroelastomeric binder are dispersed in a fluorinated solvent with a low boiling point and applied to a substrate via spray deposition. The spray deposition process rapidly produces a conformal coating that features low surface energy and surface topography with a large range of characteristic length scales and re-entrant curvature, thereby imparting superoleophobicity. The degree of superoleophobicity is readily adjusted by means of altering the ratio of particles to binder. The choice of particle and binder result in coatings with thermal stability for thousands of hours at temperatures up to 200 degrees Celsius as well as desirable mechanical characteristics.

    摘要翻译： 将氟烷基硅烷处理的金属氧化物颗粒和含氟弹性体粘合剂分散在具有低沸点的氟化溶剂中，并通过喷雾沉积施加到基材上。 喷涂沉积过程快速产生具有低表面能和表面形貌的共形涂层，其具有大范围的特征长度尺度和重入曲率，从而赋予超疏水性。 通过改变颗粒与粘合剂的比例容易地调节超亲水性的程度。 颗粒和粘合剂的选择导致在高达200摄氏度的温度下具有热稳定性数千小时的涂层以及期望的机械特性。

    Fluoroalkylsilanated mesoporous metal oxide particles and methods of preparation thereof
    2.
    发明授权
    Fluoroalkylsilanated mesoporous metal oxide particles and methods of preparation thereof 有权
    氟烷基硅烷化介孔金属氧化物颗粒及其制备方法

    公开(公告)号：US08741432B1

    公开(公告)日：2014-06-03

    申请号：US13206994

    申请日：2011-08-10

    申请人： Raymond Campos ,  Timothy Haddad ,  Joseph M. Mabry ,  Andrew J. Guenthner

    发明人： Raymond Campos ,  Timothy Haddad ,  Joseph M. Mabry ,  Andrew J. Guenthner

    IPC分类号： B32B5/16 ,  B05D7/00 ,  B05D3/02

    CPC分类号： C09C3/12 ,  C01P2006/10 ,  C01P2006/11 ,  C01P2006/12 ,  Y10T428/2991 ,  Y10T428/2995

    摘要： Coated particles comprise a core of fumed or precipitated inorganic metal oxide having a surface area of about 50 to about 500 square meters per gram and a shell consisting of an array of fluoroalkyl molecular chains at a density of at least 1 chain per square nanometer, joined to the core by covalent chemical bonds and with a total organic content of at least 9.9 percent by weight. These particles are formed by the chemical attachment of fluoroalkyl-alkylsilanes after exposure to an alkylamine and followed by an extraction to remove any organic material not covalently bound. The dense packing of molecular chains in the fluoroalkyl shell combined with a mesoporous structure imparts a very low surface energy, a very high specific surface area, and surface texture over a wide range of length scales. Such features are highly desirable for the creation of, for example, superhydrophobic and superoleophobic surfaces, separation media, and release films.

    摘要翻译： 涂覆的颗粒包括表面积为约50至约500平方米/克的热解或沉淀的无机金属氧化物的核心和由至少1个链每平方毫米的密度的氟代烷基分子链阵列组成的壳， 通过共价化学键到达核心，总有机含量为至少9.9重量％。 这些颗粒是在暴露于烷基胺之后通过氟代烷基 - 烷基硅烷的化学连接形成的，然后进行萃取以去除未共价结合的任何有机材料。 结合中孔结构的氟烷基壳中的分子链的密集填料在宽范围的长度尺度上赋予非常低的表面能，非常高的比表面积和表面纹理。 这种特征对于产生例如超疏水和超疏油表面，分离介质和脱模膜是非常需要的。

    Fluorinated POSS as alloying agents in nonfluorinated polymers
    6.
    发明申请
    Fluorinated POSS as alloying agents in nonfluorinated polymers 有权
    氟化POSS作为非氟化聚合物中的合金剂

    公开(公告)号：US20080221262A1

    公开(公告)日：2008-09-11

    申请号：US11725994

    申请日：2007-03-19

    申请人： Joseph M. Mabry ,  Timothy S. Haddad ,  Sarah Anne Mazzella ,  Sukhendu B. Hait ,  Joseph J. Schwab ,  Joseph D. Lichtenhan

    发明人： Joseph M. Mabry ,  Timothy S. Haddad ,  Sarah Anne Mazzella ,  Sukhendu B. Hait ,  Joseph J. Schwab ,  Joseph D. Lichtenhan

    IPC分类号： C08L83/06

    CPC分类号： B82Y30/00 ,  C08F8/42 ,  C08F120/14

    摘要： A method of using fluorinated-nanostructured POSS chemicals as alloying agents for the reinforcement of polymer microstructures, including polymer coils, domains, chains, and segments, at the molecular level. Because of their tailorable compatibility with nonfluorinated polymers, nanostructured chemicals can be readily and selectively incorporated into polymers by direct blending processes. The incorporation of a nanostructured chemical into a polymer favorably impacts a multitude of polymer physical properties. Properties most favorably improved are surface properties, such as lubricity, contact angle, water repellency, deicing, surface tension, and abrasion resistance. Improved surface properties may be useful for applications such as anti-icing surfaces, non-wetting surfaces, low friction surfaces, self cleaning. Other properties improved include time dependent mechanical and thermal properties such as heat distortion, creep, compression set, shrinkage, modulus, hardness and biological compatibility. In addition to mechanical properties, other physical properties are favorably improved, including lower thermal conductivity, dielectric properties, fire resistance, gas permeability and separation. These improved properties may be useful in a number of applications, including space-survivable materials and seals, gaskets, cosmetics, and personal care.

    摘要翻译： 使用氟化纳米结构化POSS化学品作为合金剂的方法，用于在分子水平上增强聚合物微结构，包括聚合物线圈，结构域，链和链段。 由于其与非氟化聚合物的可定制的相容性，纳米结构化学物质​​可以通过直接共混方法容易且有选择地并入聚合物中。 将纳米结构化学物质​​掺入聚合物有利地影响了许多聚合物的物理性质。 最有利地改善的性能是表面性质，例如润滑性，接触角，防水性，除冰，表面张力和耐磨性。 改进的表面性质可用于诸如防冰表面，非润湿表面，低摩擦表面，自清洁等应用。 改进的其它性能包括时间相关的机械和热性能，如热变形，蠕变，压缩永久变形，收缩，模量，硬度和生物相容性。 除机械性能外，其他物理性能得到有利改善，包括较低的导热性，介电性能，耐火性，透气性和分离性。 这些改进的性质可用于许多应用，包括空间存活材料和密封件，垫圈，化妆品和个人护理。

    Fluorinated POSS as alloying agents in nonfluorinated polymers
    7.
    发明授权
    Fluorinated POSS as alloying agents in nonfluorinated polymers 有权
    氟化POSS作为非氟化聚合物中的合金剂

    公开(公告)号：US07897667B2

    公开(公告)日：2011-03-01

    申请号：US11725994

    申请日：2007-03-19

    申请人： Joseph M. Mabry ,  Timothy S. Haddad ,  Sarah Anne Mazzella ,  Sukhendu B. Hait ,  Joseph J. Schwab ,  Joseph D. Lichtenhan

    发明人： Joseph M. Mabry ,  Timothy S. Haddad ,  Sarah Anne Mazzella ,  Sukhendu B. Hait ,  Joseph J. Schwab ,  Joseph D. Lichtenhan

    IPC分类号： C08K5/24

    CPC分类号： B82Y30/00 ,  C08F8/42 ,  C08F120/14

    摘要： A method of using fluorinated-nanostructured POSS chemicals as alloying agents for the reinforcement of polymer microstructures, including polymer coils, domains, chains, and segments, at the molecular level. Because of their tailorable compatibility with nonfluorinated polymers, nanostructured chemicals can be readily and selectively incorporated into polymers by direct blending processes. The incorporation of a nanostructured chemical into a polymer favorably impacts a multitude of polymer physical properties. Properties most favorably improved are surface properties, such as lubricity, contact angle, water repellency, deicing, surface tension, and abrasion resistance. Improved surface properties may be useful for applications such as anti-icing surfaces, non-wetting surfaces, low friction surfaces, self cleaning. Other properties improved include time dependent mechanical and thermal properties such as heat distortion, creep, compression set, shrinkage, modulus, hardness and biological compatibility. In addition to mechanical properties, other physical properties are favorably improved, including lower thermal conductivity, dielectric properties, fire resistance, gas permeability and separation. These improved properties may be useful in a number of applications, including space-survivable materials and seals, gaskets, cosmetics, and personal care.

    摘要翻译： 使用氟化纳米结构化POSS化学品作为合金剂的方法，用于在分子水平上增强聚合物微结构，包括聚合物线圈，结构域，链和链段。 由于其与非氟化聚合物的可定制的相容性，纳米结构化学物质​​可以通过直接共混方法容易且有选择地并入聚合物中。 将纳米结构化学物质​​掺入聚合物有利地影响了许多聚合物的物理性质。 最有利地改善的性能是表面性质，例如润滑性，接触角，防水性，除冰，表面张力和耐磨性。 改进的表面性质可用于诸如防冰表面，非润湿表面，低摩擦表面，自清洁等应用。 改进的其它性能包括时间相关的机械和热性能，如热变形，蠕变，压缩永久变形，收缩，模量，硬度和生物相容性。 除机械性能外，其他物理性能得到有利改善，包括较低的导热性，介电性能，耐火性，透气性和分离性。 这些改进的性质可用于许多应用，包括空间存活材料和密封件，垫圈，化妆品和个人护理。

    Nanostructured chemicals as alloying agents in fluorinated polymers
    8.
    发明授权
    Nanostructured chemicals as alloying agents in fluorinated polymers 有权
    纳米结构化学品作为氟化聚合物中的合金剂

    公开(公告)号：US07193015B1

    公开(公告)日：2007-03-20

    申请号：US10815544

    申请日：2004-03-31

    申请人： Joseph M. Mabry ,  Rene I. Gonzalez ,  Rusty L. Blanski ,  Patrick N. Ruth ,  Brent D. Viers ,  Joseph J. Schwab ,  Joseph D. Lichtenhan

    发明人： Joseph M. Mabry ,  Rene I. Gonzalez ,  Rusty L. Blanski ,  Patrick N. Ruth ,  Brent D. Viers ,  Joseph J. Schwab ,  Joseph D. Lichtenhan

    IPC分类号： C08F8/00

    CPC分类号： C08K5/549 ,  B82Y30/00 ,  C08G77/045 ,  C08K2201/011 ,  C08L27/12 ,  C08L27/16 ,  C08L83/06

    摘要： A method of using nanostructured chemicals as alloying agents for the reinforcement of flouropolymer microstructures, including polymer coils, domains, chains, and segments, at the molecular level. Because of their tailorable compatibility with fluorinated polymers, nanostructured chemicals can be readily and selectively incorporated into polymers by direct blending processes. Properties most favorably improved are time dependent mechanical and thermal properties such as heat distortion, creep, compression set, shrinkage, modulus, hardness and abrasion resistance. In addition to mechanical properties, other physical properties are favorably improved, including lower thermal conductivity, fire resistance, and improved oxygen permeability. These improved properties may be useful in a number of applications, including space-survivable materials and creep resistant seals and gaskets. Improved surface properties may be useful for applications such as anti-icing or non-wetting surfaces or as low friction surfaces.

    摘要翻译： 一种使用纳米结构化学药品作为合成剂的方法，用于在分子水平上加强含氟聚合物微观结构，包括聚合物线圈，结构域，链和链段。 由于其与氟化聚合物的可定制的相容性，纳米结构化学物质​​可以通过直接共混方法容易且选择性地引入到聚合物中。 最有利地改善的性能是时间相关的机械和热性能，如热变形，蠕变，压缩永久变形，收缩率，模量，硬度和耐磨性。 除了机械性能之外，其他物理性能得到有利改善，包括较低的导热性，耐火性和改善的氧气渗透性。 这些改进的性能可用于许多应用，包括空间存活材料和抗蠕变密封件和垫圈。 改进的表面性质可用于诸如防冰或不润湿表面或作为低摩擦表面的应用。

    Increasing the rate of crystallization of engineering thermoplastics
    9.
    发明授权
    Increasing the rate of crystallization of engineering thermoplastics 有权
    提高工程热塑性塑料的结晶率

    公开(公告)号：US07790841B1

    公开(公告)日：2010-09-07

    申请号：US12079089

    申请日：2008-02-06

    申请人： Gregory R. Yandek ,  Darrell Marchant ,  Joseph M. Mabry ,  Mark B. Gruber ,  Mark A. Lamontia

    发明人： Gregory R. Yandek ,  Darrell Marchant ,  Joseph M. Mabry ,  Mark B. Gruber ,  Mark A. Lamontia

    IPC分类号： C08F6/00 ,  C08G64/00

    CPC分类号： B82Y30/00 ,  C08J3/201 ,  C08J3/2056 ,  C08K5/0083 ,  C08K5/5419 ,  Y10T428/2982 ,  Y10T428/2993

    摘要： Method for enhancing the crystallization rates of engineering thermoplastics through the use and incorporation of particulate additives with dimensions on the order of 10-1000 nm is described. The presence of nanoparticles at concentrations of, e.g., less than 10 weight percent of the composition, reduces the viscosity of the thermoplastics as compared to the respective homopolymer, thereby increasing polymer chain transport and diffusion to the crystallizing growth front. The prescription of this technology has been shown to reduce crystallization half times of some engineering thermoplastics by as much as 40 percent at optimal crystallization temperatures, an effect that is magnified as the temperature is reduced towards the glassy state of the amorphous phase. Nano-modified engineering thermoplastics with rapid crystallization kinetics and relatively low viscosities can be utilized in component fabrication processes that require rapid processing times, e.g., for the sake of cost efficiency.

    摘要翻译： 描述了通过使用和结合尺寸在10-1000nm的颗粒添加剂来提高工程热塑性塑料的结晶速率的方法。 相对于各均聚物，存在的纳米颗粒的浓度例如低于组合物的10重量％，降低了热塑性塑料的粘度，从而增加了聚合物链的转运和扩散到结晶生长前沿。 已经表明，该技术的处方已经证明，在最佳结晶温度下，将一些工程热塑性塑料的结晶半结晶减少多达40％，随着温度朝着非晶相的玻璃状态而减小的效应被放大。 具有快速结晶动力学和相对低粘度的纳米改性工程热塑性塑料可用于需要快速加工时间的部件制造工艺中，例如为了成本效率。