摘要:
Agglomerated polymer particles of finely divided, water-soluble or water-swellable polymers are prepared by azeotropic dewatering of water-in-oil emulsions of water-soluble or water-swellable polymers in the presence of from 1 to 40% by weight, based on the polymers, of polyalkylene glycols which(a) are obtainable by an addition reaction of C.sub.2 -C.sub.4 -alkylene oxides with alcohols, phenols, amines or carboxylic acids and(b) contain not less than 2 polymerized alkylene oxide unitsand isolation of the agglomerated polymer particles. The water-soluble agglomerated polymer particles are used as flocculants and retention and drainage aids, while the water-swellable polymer powders are employed as thickeners for aqueous systems, in particular as thickeners for textile print pastes.
摘要:
Abstract of the Disclosure: Crosslinked acrylic or methacrylic acid copolymers with crosslinkable groups that are useful as thickeners for textile print pastes are obtainable by copolymerization of(a) from 50 to 99 parts by weight of acrylic acid and/or methacrylic acid,(b) from 1 to 50 parts by weight of at least one N-methylol (meth)acrylamide or derivatives thereof,(c) from 50 to 10,000 ppm, based on the monomers (a) and (b), of an at least bifunctional crosslinker, and(d) from 0 to 49 parts by weight of other monoethylenically unsaturated monomersin the presence of a free radical polymerization initiator in the aqueous phase of a water-in-oil emulsion.
摘要:
Agglomerated polymer particles of finely divided, water-soluble or water-swellable polymers are prepared by azeotropic dewatering of water-in-oil emulsions of water-soluble or water-swellable polymers in the presence of from 1 to 40% by weight, based on the polymers, of polyalkylene glycols which (a) are obtainable by an addition reaction of C.sub.2 -C.sub.4 -alkylene oxides with alcohols, phenols, amines or carboxylic acids and (b) contain not less than 2 polymerized alkylene oxide units and isolation of the agglomerated polymer particles. The water-soluble agglomerated polymer particles are used as flocculants and retention and drainage aids, while the water-swellable polymer powders are employed as thickeners for aqueous systems, in particular as thickeners for textile print pastes.
摘要:
Agglomerated polymer particles of finely divided, water-soluble or water-swellable polymers containing ammonium carboxylate groups are prepared by azeotropic removal of water from water-in-oil emulsions of the water-soluble or water-swellable polymers which contain ammonium carboxylate groups in the presence of from 0.1 to 40% by weight, based on the polymers, of polyalkylene glycols which have an agglomerating effect and which are obtainable by an addition reaction of C2-C4-alkylene oxides with alcohols, phenols, amines or carboxylic acids and contain at least two polymerized alkylene oxide units and additionally of from 0.1 to 20% by weight, based on the polymers, of protective colloids which are obtainable by free radical copolymerization of C8-C40-monoolefins with monoethylenically unsaturated C4-C6-dicarboxylic anhydrides by a mass polymerization method at from 80 to 300° C. to give copolymers having molecular weights of from 500 to 20,000 g/mol, and said agglomerated polymer particles are used as thickeners for textile pigment print pastes.
摘要:
Agglomerated particles of water-swellable addition polymers, the agglomerated particles having an average particle diameter of from 20 to 5000 &mgr;m and consisting of primary particles having an average particle diameter of from 0.1 to 15 &mgr;m, being preparable by polymerization of water-soluble monomers in the presence of from 1′ to 10% by weight of a regulator and at least 2000 ppm, each based on the monomers, of a crosslinking agent in the manner of a water-in-oil polymerization and subsequent azeotropic removal of water from the water-in-oil polymer emulsions, containing the primary particles, in the presence of agglomerating polyalkylene glycols which (a) are obtainable by an addition reaction of C2-C4-alkylene oxides with alcohols, phenols, amines or carboxylic acids, and (b) contain at least 2 polymerized alkylene oxide units, and disintegrating into the primary particles on introduction into an aqueous medium, processes for preparing the agglomerated polymer particles and use of the agglomerated particles as thickeners for print pastes.
摘要:
A parking lock gear (1) for a parking lock arrangement for locking an output shaft of a transmission of a vehicle has teeth (5). An annular element (2) is fixed to the parking lock gear (1) and has outer teeth (3) which engage an actuated locking pawl.
摘要:
A problem during electrolytic treatment of printed circuit boards having a very thin basic metallization is that the treatment yields irregular results in various regions on the surface of the printed circuit board. In overcoming this problem the invention provides a device for electrolytically treating an at least superficially electrically conducting work piece having at least two substantially opposing side edges. The device comprises current supply devices for the work piece, said current supply devices each comprising contact strips located on the opposing side edges which are capable of electrically contacting the work piece at the substantially opposing side edges.
摘要:
The invention relates to a device and a method for evening out the thickness of metal layers on electrical contact points on flat items to be treated 7, such as conductor foil and printed circuit boards, during the electrolytic treatment of the items to be treated, guided in a horizontal plane of conveyance in a continuous electroplating plant. The device has counter-electrodes 2, 3 located opposite the plane of conveyance and clamps 4, secured to a continuously revolving means of conveyance 5, for contacting the items to be treated 7. The clamps 4 have a lower portion 14 and an upper portion 13 which are electrically conductive, have a surface consisting of metal, are moveable in relation to one another and respectively have at least one contact point 6 for the items to be treated 7. In addition, at least one current source is provided to produce a flow of current between the counter-electrodes and the items to be treated. To avoid the pirate cathode effect of the contact clamps 4 during electrolytic metallisation, there are disposed between the anodes 2, 3 and the clamps 4 upper and lower shields 15, 16 for the electrical field, which extend so close to the plane of conveyance that the items to be treated, guided in the plane of conveyance, and the clamp portions 13, 14 do not quite come into contact with the shields.
摘要:
A method of treatment of printed circuit boards or conductor films with a chemical, electrolytic, or rinsing treatment liquid, and to a device for carrying out the method, where the printed circuit boards or conductor films are transported in a horizontal direction by transport means, In order to accelerate these processes, the surfaces of the printed circuit boards or conductor films must be exposed to a macroflow in order to apply active treatment liquid. Furthermore, the micromaterial exchange into the diffusion layer must be reinforced. This exchange is brought about by the use of hydrodynamically acting cavitation generators, which form cavitation bubbles in the liquid jets. The treatment liquid is set into an eddy current movement in the generators because the treatment liquid is applied at high pressure in a circuit through the nozzles generating the cavitation bubbles, and is conveyed to the surface in a large quantity. The use of the method is particularly effective in processing fine conductor printed circuit boards with fine bores and blind holes.
摘要:
The invention relates to a process for the preparation of sodium dithionite, comprising the steps (a) provision of a synthesis batch comprising sodium formate, sulfur dioxide and an alkaline sodium compound in aqueous methanolic solution with formation of a sodium dithionite mother liquor, (b) isolation of sodium dithionite from the sodium dithionite mother liquor, a residual mother liquor being obtained, (c) separation of methanol from the residual mother liquor, (d) separation of the residual mother liquor into a thiosulfate-rich first part-stream and a thiosulfate-poor, formate-containing second part-stream by means of nanofiltration, (e) concentration of sodium formate in the second part-stream and (f) recycling of the concentrated second part-stream to process step (a).