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    Process for producing 3,5-difluoraniline
    1.
    发明授权
    Process for producing 3,5-difluoraniline 失效
    制备3,5-二氟苯胺的方法

    公开(公告)号：US5399767A

    公开(公告)日：1995-03-21

    申请号：US194625

    申请日：1994-02-08

    申请人： Rikuo Nasu ,  Motohiko Hamaguchi

    发明人： Rikuo Nasu ,  Motohiko Hamaguchi

    IPC分类号： B01J23/44 ,  C07B61/00 ,  C07C209/68 ,  C07C209/74 ,  C07C211/52 ,  C07C255/58

    CPC分类号： C07C209/74 ,  C07C209/68

    摘要： A process for producing 3,5-difluoroaniline, which comprises reacting a benzonitrile compound of the formula (I): ##STR1## wherein each of X.sub.1, X.sub.2 and X.sub.3 is hydrogen, chlorine, bromine or a cyano group, provided that at least one of X.sub.1 to X.sub.3 is a cyano group, with a mineral acid for hydrolysis and decarboxylation to obtain an aniline compound of the formula (II): ##STR2## wherein each of X.sub.4, X.sub.5 and X.sub.6 is hydrogen, chlorine or bromine, provided that at least one of X.sub.4 to X.sub.6 is hydrogen, and in the case of a compound of the formula (II) wherein X.sub.4, X.sub.5 and X.sub.6 are not simultaneously hydrogen, reacting such a compound with hydrogen in a presence of a catalyst for reduction to obtain 3,5 -difluoroaniline.

    摘要翻译： 一种制备3,5-二氟苯胺的方法，其包括使式（I）的苄腈化合物：其中X1，X2和X3各自为氢，氯，溴或氰基，条件是 X1至X3中的至少一个为氰基，与无机酸进行水解和脱羧，得到式（II）的苯胺化合物：其中X 4，X 5和X 6各自为氢，氯 或溴，条件是X 4至X 6中的至少一个为氢，并且在式（II）化合物的情况下，其中X 4，X 5和X 6不同时为氢），使该化合物与氢在 用于还原的催化剂得到3,5-二氟苯胺。

    Method for halogenating an aromatic compound
    2.
    发明授权
    Method for halogenating an aromatic compound 失效
    卤化芳族化合物的方法

    公开(公告)号：US5491239A

    公开(公告)日：1996-02-13

    申请号：US144525

    申请日：1993-11-02

    申请人： Rikuo Nasu ,  Motohiko Hamaguchi ,  Hayato Ariyoshi

    发明人： Rikuo Nasu ,  Motohiko Hamaguchi ,  Hayato Ariyoshi

    IPC分类号： C07C209/74 ,  C07C253/30 ,  C07D213/61 ,  C07D213/73 ,  C07D213/85

    CPC分类号： C07D213/73 ,  C07C209/74 ,  C07C253/30 ,  C07D213/61 ,  C07D213/85 ,  Y02P20/582

    摘要： A method for halogenating an aromatic compound, which comprises reacting the aromatic compound of the formula (I): ##STR1## wherein X is a hydroxyl group, an amino group or an acylamino group, each of Z.sub.1 and Z.sub.2 is a hydrogen atom or a halogen atom, one of R and Y is a hydrogen atom and the other is a nitro group, a cyano group or a trifluoromethyl group, and Q is a nitrogen atom or --C(T).dbd. (wherein T is a hydrogen atom, a halogen atom, a nitro group, a cyano group or a trifluoromethyl group), with a halogenating agent to obtain a 3-halogenoaromatic compound of the formula (II): ##STR2## wherein one of R' and Y' is a halogen atom and the other is a nitro group, a cyano group or a trifluoromethyl group, and X, Z.sub.1, Z.sub.2 and Q are as defined above.

    摘要翻译： 一种卤化芳族化合物的方法，其包括使式（I）的芳族化合物：其中X为羟基，氨基或酰氨基，其中Z 1和Z 2各自为氢 原子或卤素原子，R和Y中的一个是氢原子，另一个是硝基，氰基或三氟甲基，Q是氮原子或-C（T）=（其中T是氢 原子，卤素原子，硝基，氰基或三氟甲基）与卤化剂反应，得到式（II）的3-卤代芳香族化合物：其中R'和Y '是卤素原子，另一个是硝基，氰基或三氟甲基，X，Z 1，Z 2和Q如上所定义。

    Imidazole compounds and biocidal composition comprising the same for controlling harmful organisms
    3.
    发明授权
    Imidazole compounds and biocidal composition comprising the same for controlling harmful organisms 失效
    咪唑化合物和杀生物组合物，其组成物包含用于控制有害生物体的化合物

    公开(公告)号：US4995898A

    公开(公告)日：1991-02-26

    申请号：US168070

    申请日：1988-03-14

    申请人： Rikuo Nasu ,  Terumasa Komyoji ,  Toshio Nakajima ,  Kazumi Suzuki ,  Keiichiro Ito ,  Takeshi Oshima ,  Hideshi Yoshimura

    发明人： Rikuo Nasu ,  Terumasa Komyoji ,  Toshio Nakajima ,  Kazumi Suzuki ,  Keiichiro Ito ,  Takeshi Oshima ,  Hideshi Yoshimura

    IPC分类号： A01N43/50 ,  A01N31/14 ,  A01N33/00 ,  A01N37/34 ,  A01N43/08 ,  A01N43/84 ,  A01N55/00 ,  A01P3/00 ,  C07D233/84 ,  C07D233/90 ,  C07D233/92 ,  C07D401/04 ,  C07D401/12 ,  C07D405/04 ,  C07D405/14 ,  C07D409/04 ,  C07D409/12 ,  C07F7/08

    CPC分类号： C07D401/04 ,  A01N43/50 ,  A01N55/00 ,  C07D233/90 ,  C07D401/12 ,  C07D405/04 ,  C07D405/14 ,  C07D409/04 ,  C07F7/0814

    摘要： Novel imidazole compounds are disclosed, which are represented by the following general formula: ##STR1## wherein: R.sub.1 represents a cyano group or a --CSNHR.sub.5 group, wherein R.sub.5 represents a hydrogen atom, a C.sub.1-4 alkyl group, or a --COR.sub.6 group, wherein R.sub.6 represents a C.sub.1-4 alkyl group, a halogenated C.sub.1-4 alkyl group, or a phenyl group;R.sub.2 and R.sub.3 each represents a hydrogen atom; a halogen atom; a nitro group; a cyano group; a trimethylsilyl group; a C.sub.3-6 cycloalkyl group; a naphthyl group; a C.sub.1-12 alkyl group which is optionally substituted with one or more halogen atoms, hydroxyl groups, acetoxy groups, C.sub.1-4 alkoxy groups, halogenated C.sub.1-4 alkoxy groups, phenyl groups, halogenated phenyl groups, or C.sub.1-4 alkylated phenyl groups; a C.sub.2-10 alkenyl group which is optionally substituted with one or more halogen atoms; a C.sub.1-6 alkoxy group which is optionally substituted with one or more halogen atoms; a phenyl group which is optionally substituted with one or more halogen atoms, C.sub.1-4 alkyl groups, halogenated C.sub.1-4 alkyl groups, C.sub.1-4 alkoxy groups, halogenated C.sub.1-4 alkoxy groups, C.sub.1-4 alkylthio groups, halogenated C.sub.1-4 alkylthio groups, nitro groups, cyano groups, or 3,4-methylenedioxy groups; a furyl group which is optionally substituted with one or more halogen atoms or C.sub.1-4 alkyl groups; a thienyl group which is optionally substituted with one or more halogen atoms or C.sub.1-4 alkyl groups; a pyridyl group which is optionally substituted with one or more halogen atoms or C.sub.1-4 alkyl groups; an --SO.sub.n R.sub.7 group, wherein R.sub.7 represents a C.sub.1-6 alkyl group, a C.sub.2-6 alkenyl group, a phenyl group which is optionally substituted with one or more halogen atoms, a benzyl group, a pyridyl group which is optionally substituted with one or more halogen atoms, C.sub.1-4 alkyl groups, or halogenated C.sub.1-4 alkyl groups; or an --NR.sub.8 R.sub.9 group, wherein R.sub.8 and R.sub.9 each represents a C.sub.1-4 alkyl group, and n is 0, 1, or 2; or a --CO(NH).sub.m R.sub.10 group, wherein R.sub.10 represents a C.sub.1-4 alkyl group which is optionally substituted with one or more halogen atoms, a C.sub.1-4 alkoxy group which is optionally substituted with one or more halogen atoms, or a phenyl group which is optionally substituted with one or more halogen atoms; and m is 0 or 1; andR.sub.4 represents a C.sub.1-6 alkyl group which is optionally substituted with one or more halogen atoms; a C.sub.3-6 cycloalkyl group; a phenyl group; a thienyl group; or an --NR.sub.11 R.sub.12 group, wherein R.sub.11 and R.sub.12 each represents a hydrogen atom, a C.sub.1-4 alkyl group which is optionally substituted with one or more halogen atoms, a C.sub.2-4 alkenyl group, or R.sub.11 and R.sub.12 are combined with each other together with a nitrogen atoms adjacent thereto to form a pyrrolidinyl group, a piperidinyl group, a morpholino group, or a thiomorpholino group, provided that R.sub.11 and R.sub.12 are not simultaneously a hydrogen atom;provided that R.sub.2 and R.sub.3 are not simultaneously a halogen atom. The compounds are effective as biocides.

    摘要翻译： 由通式I表示的咪唑化合物：其中：R1表示氰基或-CSNHR5基团，其中R5表示氢原子，C1-4烷基或-COR6基团，其中R6表示C1- 4烷基，卤代C 1-4烷基或苯基; R2和R3各自表示氢原子; 卤素原子; 硝基; 氰基; 三甲基甲硅烷基 C 3-6环烷基; 萘基; 任选取代的C 1-12烷基，C 2-10烯基，C 1-6烷氧基，苯基，呋喃基，亚硫酰基或吡啶基; a-SO n R 7基，其中R 7表示C 1-6烷基，C 2-6烯基，苄基，任选取代的苯基或吡啶基; NR8R9基团，其中R8和R9各自表示C1-4烷基，n为0,1或2; 或-CO（NH）m R 10 gorup，其中R 10表示任选取代的C 1-4烷基，C 1-4烷氧基或苯基，m为0或1; 并且R 4表示任选被一个或多个卤素原子取代的C 1-6烷基; C 3-6环烷基; 苯基; 噻吩基; 或-NR 11 R 12基团，其中R 11和R 12各自表示氢原子，任选被一个或多个卤素原子取代的C 1-4烷基，C 2-4链烯基或R 11和R 12一起彼此结合 与其相邻的氮原子形成吡咯烷基，哌啶基，吗啉代基或硫代吗啉基，条件是R 11和R 12不同时为氢原子; 条件是R2和R3不同时为卤素原子。 这些化合物作为杀生物剂是有效的。

    Pyridine-2-thio, -2-sulfinyl, and -2-sulfonyl sulfonanilide compounds useful as a herbicidal component
    5.
    发明授权
    Pyridine-2-thio, -2-sulfinyl, and -2-sulfonyl sulfonanilide compounds useful as a herbicidal component 失效
    可用作除草成分的吡啶-2-硫基，-2-亚磺酰基和-2-磺酰基磺酰苯胺化合物

    公开(公告)号：US4218237A

    公开(公告)日：1980-08-19

    申请号：US961518

    申请日：1978-11-17

    申请人： Ryuzo Nishiyama ,  Kanichi Fujikawa ,  Fumio Kimura ,  Rikuo Nasu ,  Nobuyuki Sakashita ,  Shigeyuki Nishimura

    发明人： Ryuzo Nishiyama ,  Kanichi Fujikawa ,  Fumio Kimura ,  Rikuo Nasu ,  Nobuyuki Sakashita ,  Shigeyuki Nishimura

    IPC分类号： A01N43/40 ,  C07D213/70 ,  A01N9/22

    CPC分类号： C07D213/70 ,  A01N43/40

    摘要： A sulfonanilide compounds having the formula (I): ##STR1## wherein X.sub.1 is hydrogen atom, a halogen atom, methyl group or trifluoromethyl group, X.sub.2 is hydrogen atom or a halogen atom, R.sub.1 is a (C.sub.1 -C.sub.4) alkyl group or a halo(C.sub.1 -C.sub.4) alkyl group, R.sub.2 is hydrogen atom, a (C.sub.1 -C.sub.4) alkyl group, trifluoromethyl group or nitro group, R.sub.3 is hydrogen atom, --SO.sub.2 R.sub.1 group (R.sub.1 is the same as defined above), a (C.sub.2 -C.sub.4) acyl group, a (C.sub.2 -C.sub.4) acylmethyl group, a (C.sub.1 -C.sub.4) alkyl group, a (C.sub.1 -C.sub.4) alkoxy (C.sub.1 -C.sub.4) alkyl group or a (C.sub.3 -C.sub.4) alkenyl group, R.sub.4 is hydrogen atom or a halogen atom, and n is an integer of 0 to 2; and a salt thereof, which is useful as a herbicidal component.

    摘要翻译： 具有式（I）的磺酰苯胺化合物：其中X 1是氢原子，卤素原子，甲基或三氟甲基，X 2是氢原子或卤素原子，R 1是（C 1 -C 4）烷基 基或卤代（C 1 -C 4）烷基，R 2是氢原子，（C 1 -C 4）烷基，三氟甲基或硝基，R 3是氢原子，-SO 2 R 1基（R 1如上所定义） （C 2 -C 4）酰基，（C 2 -C 4）酰基甲基，（C 1 -C 4）烷基，（C 1 -C 4）烷氧基（C 1 -C 4）烷基或（C 3 -C 4） R4为氢原子或卤原子，n为0〜2的整数。 及其盐，其可用作除草成分。

    Method for producing dichloromethylpyridines
    6.
    发明授权
    Method for producing dichloromethylpyridines 失效
    二氯甲基吡啶的制备方法

    公开(公告)号：US5290944A

    公开(公告)日：1994-03-01

    申请号：US990276

    申请日：1992-12-14

    申请人： Rikuo Nasu ,  Taku Shimura ,  Isamu Katsuyama

    发明人： Rikuo Nasu ,  Taku Shimura ,  Isamu Katsuyama

    IPC分类号： C07B61/00 ,  C07D213/26 ,  C07D213/61 ,  C07D213/62

    CPC分类号： C07D213/26 ,  C07D213/61

    摘要： A method for producing a dichloromethylpyridine of the formula (II): ##STR1## wherein each of R.sup.1, R.sup.2, R.sup.3 and R.sup.4 which are independent of one another, is a hydrogen atom, a halogen atom, an alkoxy group or a phenoxy group which may be substituted, provided that R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are not simultaneously hydrogen atoms, which comprises reacting a trichloromethylpyridine of the formula (I): ##STR2## wherein R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are as defined above, with a reducing agent, wherein:(1) a dialkyl phosphite or a trialkyl phosphite is used as the reducing agent, and the reaction is conducted in the presence of a basic substance and an alcohol solvent, or(2) a trialkyl phosphine or triphenyl phosphine is used as the reducing agent, and the reaction is conducted in the presence of an alcohol solvent.

    摘要翻译： 制备式（II）的二氯甲基吡啶的方法：（*化学结构*）（II）其中R 1，R 2，R 3和R 4彼此独立地为氢原子，卤素原子，烷氧基 基团或可被取代的苯氧基，条件是R 1，R 2，R 3和R 4不同时为氢原子，其包括使式（I）的三氯甲基吡啶：（*化学结构*）（I） ，R3和R4如上定义，与还原剂反应，其中：（1）亚磷酸二烷基酯或亚磷酸三烷基酯用作还原剂，反应在碱性物质和醇溶剂的存在下进行， 或（2）使用三烷基膦或三苯基膦作为还原剂，反应在醇溶剂的存在下进行。