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公开(公告)号：US07098290B1
公开(公告)日：2006-08-29
申请号：US09695332
申请日：2000-10-25
CPC分类号： C08G18/3876 , C08G18/324 , C08G18/4277 , C08G18/758 , C08G18/7642 , C08G18/765 , Y10S348/902 , Y10T428/31551
摘要： The present invention is directed to a novel method of preparing a polymerizate, which includes the step of polymerizing a two-component composition, which includes: a first component containing at least one polycyanate reactant having at least two functional groups selected from isocyanate, isothiocyanate and combinations thereof, the polycyanate reactant being the reaction product of: a polythiol monomer having at least two thiol groups; and a polycyanate monomer having at least two functional groups selected from isocyanate, isothiocyanate and combinations thereof; and a second component containing at least one polyamine reactant having at least two functional groups selected from primary amine, secondary amine and combinations thereof. The molar equivalent ratio of (NCO+NCS) groups from the first component to (—NH2+—NH—) groups from the second component is from 0.5 to 100. The present invention is also directed to polymerizates prepared according to the method of the present invention. The present invention is further directed to photochromic articles that may be prepared from the polymerizates of the present invention.
摘要翻译： 本发明涉及一种制备聚合物的新方法，其包括聚合双组分组合物的步骤，其包括：含有至少一种具有至少两个选自异氰酸酯，异硫氰酸酯的官能团的聚氰酸酯反应物的第一组分和 聚氰酸酯反应物是以下物质的反应产物：具有至少两个硫醇基团的多硫醇单体; 和具有至少两个选自异氰酸酯，异硫氰酸酯及其组合的官能团的聚氰酸酯单体; 和含有至少一种具有至少两个选自伯胺，仲胺及其组合的官能团的多胺反应物的第二组分。 来自第二组分的来自第一组分的（NCO + NCS）基团与（-NH 2 N + N - NH-）基团的摩尔当量比为0.5至100.本发明还涉及 根据本发明的方法制备的聚合物。 本发明还涉及可由本发明的聚合物制备的光致变色制品。
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公开(公告)号：US06342571B1
公开(公告)日：2002-01-29
申请号：US09377805
申请日：1999-08-20
IPC分类号： C08F22020
CPC分类号： C08F222/24
摘要： Polymerizable compositions comprising: (a) a mixture of thio(meth)acrylate functional monomers comprising, (a)(i) a first thio(meth)acrylate functional monomer, e.g., bis(thiomethacrylate)-1,2-ethylene, and (a)(ii) a second thio(meth)acrylate functional monomer, which is chain extended; (b) an aromatic monomer having at least two vinyl groups, e.g., divinyl benzene; (c) a polythiol monomer having at least two thiol groups, e.g., pentaerythritol tetrakis(3-mercaptopropionate); and (d) a comonomer selected from, (d)(i) an anhydride monomer having at least one ethylenically unsaturated group, e.g., methacrylic anhydride; (d) (ii) a monomer having at least three (meth)acryloyl groups, e.g., pentaerythritol tetrakis(acrylate); and (d)(iii) mixtures of monomers (d)(i) and (d)(ii). A polymerizate of the polymerizable composition has a refractive index of at least 1.57 and an Abbe number of at least 33.
摘要翻译： 可聚合组合物包括：（a）硫代（甲基）丙烯酸酯官能单体的混合物，其包含（a）（i）第一硫代（甲基）丙烯酸酯官能单体，例如双（硫代甲基丙烯酸酯）-1,2-亚乙基和（ a）（ii）链延伸的第二硫代（甲基）丙烯酸酯官能单体; （b）具有至少两个乙烯基的芳族单体，例如二乙烯基苯; （c）具有至少两个硫醇基的多硫醇单体，例如季戊四醇四（3-巯基丙酸酯）; 和（d）选自（d）（i）具有至少一个烯属不饱和基团的酸酐单体的共聚单体，例如甲基丙烯酸酐; （d）（ii）具有至少三个（甲基）丙烯酰基的单体，例如季戊四醇四（丙烯酸酯）; 和（d）（iii）单体（d）（i）和（d）（ii）的混合物。 聚合性组合物的聚合物的折射率为至少1.57，阿贝数为33以上。
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公开(公告)号：US5976422A
公开(公告)日：1999-11-02
申请号：US37108
申请日：1998-03-09
CPC分类号： C08G75/045 , G02B5/23
摘要： Describes a polymerizable organic composition comprising at least one polymerizable monomer having at least two ethylenically unsaturated groups, e.g., divinyl benzene, and a polythiol monomer represented by the following general formula, ##STR1## wherein R.sub.1 and R.sub.2 are each selected from the group consisting of straight or branched chain alkylene, e.g., methylene or ethylene, cyclic alkylene, phenylene and C.sub.1 -C.sub.9 alkyl substituted phenylene. Optionally, a monoethylenically unsaturated monomer, e.g., phenoxyethyl methacrylate, and/or an anhydride monomer, e.g., methacrylic anhydride, may also be present. Polymerizates prepared from polymerizable organic compositions of the present invention have a refractive index of at least 1.57, an Abbe number of at least 33 and an initial Barcol hardness of at least 1. Also described are photochromic articles prepared from such compositions.
摘要翻译： 描述了包含至少一种具有至少两个烯键式不饱和基团的可聚合单体的可聚合有机组合物，例如二乙烯基苯和由以下通式表示的多硫醇单体，其中R 1和R 2各自选自直链或支链 链亚烷基，例如亚甲基或亚乙基，环状亚烷基，亚苯基和C 1 -C 9烷基取代的亚苯基。 任选地，也可以存在单烯属不饱和单体，例如甲基丙烯酸苯氧基乙酯和/或酸酐单体，例如甲基丙烯酸酐。 由本发明的可聚合有机组合物制备的聚合物具有至少1.57的折射率，至少33的阿贝数和至少为1的初始巴醇硬度。还描述了由这些组合物制备的光致变色制品。
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公开(公告)号：US07473754B1
公开(公告)日：2009-01-06
申请号：US09690595
申请日：2000-10-17
IPC分类号： C08G18/10
CPC分类号： C08G18/3876 , C08G18/8116
摘要： The present invention is directed to a novel polymerizable organic composition comprising one or more radically polymerizable monomers with at least one radically polymerizable monomer having at least two (meth)acryloyl groups that have backbone linkages selected from thiourethane linkages, dithiourethane linkages, combinations of thiourethane linkages and dithiourethane linkages. The present invention is also directed to polymerizates prepared from the polymerizable organic composition, shaped articles prepared from the polymerizable compositions, and photochromic articles that may be prepared from the polymerizable organic composition of the present invention.
摘要翻译： 本发明涉及一种新型的可聚合有机组合物，其包含一种或多种可自由基聚合的单体与至少一种具有至少两个（甲基）丙烯酰基的可自由基聚合的单体，其具有选自硫代氨基甲酸酯键，二硫氨基甲酸酯键，硫代氨基甲酸酯键 和二硫氨基甲酸酯键。 本发明还涉及由可聚合有机组合物制备的聚合物，由可聚合组合物制备的成型制品和可由本发明的可聚合有机组合物制备的光致变色制品。
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公开(公告)号：US06669873B1
公开(公告)日：2003-12-30
申请号：US09524619
申请日：2000-03-14
IPC分类号： G02B523
CPC分类号： G02B1/04 , C08G75/045 , C08G75/12 , C08L33/14 , C08L81/02
摘要： Described is a polymerizable organic composition comprising: (a) a radically polymerizable gel-free prepolymer of (i) at least one first polymerizable monomer having at least two radically polymerizable ethylenically unsaturated groups, e.g., divinyl benzene, and (ii) at least one first polythiol monomer having at least two thiol groups, e.g., thioglycerol bis(mercaptoacetate); and (b) at least one second polymerizable monomer having at least two radically polymerizable ethylenically unsaturated groups, e.g., divinyl benzene and/or methacrylic anhydride, the first and second radically polymerizable monomers each being substantially free of norbornene groups. The molar equivalent ratio of ethylenically unsaturated groups of (a)(i) to the thiol groups of (a)(ii) is no greater than 1:1. The described polymerizable composition has reduced shrinkage, and a polymerizate prepared therefrom has a refractive index of at least 1.57 and an Abbe number of at least 33.
摘要翻译： 描述了一种可聚合的有机组合物，其包含：（a）可自由基聚合的无凝胶预聚物，其包含（i）至少一种具有至少两个可自由基聚合的烯属不饱和基团的第一可聚合单体，例如二乙烯基苯，和（ii）至少一种 具有至少两个硫醇基的第一多硫醇单体，例如硫代甘油双（巯基乙酸酯）; 和（b）至少一种具有至少两个可自由基聚合的烯键式不饱和基团的第二可聚合单体，例如二乙烯基苯和/或甲基丙烯酸酐，第一和第二可自由基聚合单体各自基本上不含降冰片烯基团。 （a）（i）的烯属不饱和基团与（a）（ii）的硫醇基团的摩尔当量比不大于1:1。 所述可聚合组合物的收缩率降低，由其制备的聚合物的折射率至少为1.57，阿贝数为33。
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6.发明授权Partially polymerized mixture of diethylene glycol (allyl carbonate) compounds 失效二甘醇（碳酸烯丙酯）化合物的部分聚合混合物
公开(公告)号：US5952441A
公开(公告)日：1999-09-14
申请号：US661
申请日：1997-12-30
CPC分类号： C08F18/24
摘要： A polymerizable, liquid, substantially gel-free composition comprising a partially polymerized mixture of ethylenically unsaturated compounds wherein: (a) the mixture of ethylenically unsaturated compounds which was partially polymerized comprised a mixture of diethylene glycol (allyl carbonate) compounds each represented by Formula I: ##STR1## in which n is a positive integer, m is a positive integer, and the diethylene glycol (allyl carbonate) compound for which the value of n is 1 constituted from 25 to 75 area percent of the mixture of diethylene glycol (allyl carbonate) compounds; and (b) the ethylenic double bond utilization of the polymerizable, liquid, substantially gel-free composition is at least 3 percent. The polymerizable, liquid, substantially gel-free composition exhibits low shrinkage in the mold when polymerized.
摘要翻译： 一种可聚合的，液体的，基本上不含凝胶的组合物，其包含烯属不饱和化合物的部分聚合的混合物，其中：（a）部分聚合的烯键式不饱和化合物的混合物包括由式I表示的二甘醇（碳酸烯丙酯） ：其中n为正整数，m为正整数，n为1的二甘醇（碳酸烯丙酯）化合物由二甘醇（碳酸烯丙酯）化合物的混合物的25〜75面积％构成 ; 和（b）可聚合的，液体的，基本上不含凝胶的组合物的烯属双键利用率为至少3％。 可聚合的，液体的，基本上不含凝胶的组合物在聚合时在模具中表现出低的收缩率。
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公开(公告)号：US5932681A
公开(公告)日：1999-08-03
申请号：US37106
申请日：1998-03-09
CPC分类号： C08G18/3876
摘要： Describes a method of preparing a polymerizate by polymerizing a two-component organic composition comprising: a first component containing a polyfunctional reactant having two or more functional groups selected from isocyanate, isothiocyanate and combinations of isocyanate and isothiocyanate groups; and a second component containing a polythiol represented by the following general formula I, ##STR1## wherein R.sub.1 and R.sub.2 are each selected from the group consisting of straight or branched chain alkylene, e.g., methylene and ethylene, cyclic alkylene, phenylene and C.sub.1 -C.sub.9 alkyl substituted phenylene. The second component may also optionally contain a reactive hydrogen compound that is different than the polythiol of general formula I. Polymerizates prepared according to the present invention are useful as ophthalmic lenses and have a refractive index of at least 1.57, an Abbe number of at least 33 and an initial Barcol hardness of at least 1. Also described are photochromic articles prepared from such polymerizates.
摘要翻译： 描述了通过聚合双组分有机组合物制备聚合物的方法，包括：含有具有两个或多个选自异氰酸酯，异硫氰酸酯和异氰酸酯和异硫氰酸酯基团的组合的多官能反应物的第一组分; 和含有由以下通式I表示的多硫醇的第二组分，其中R 1和R 2各自选自直链或支链亚烷基，例如亚甲基和亚乙基，环状亚烷基，亚苯基和C 1 -C 9烷基取代的亚苯基 。 第二组分还可任选地含有与通式I的多硫醇不同的反应性氢化合物。根据本发明制备的聚合物可用作眼科镜片，折射率至少为1.57，阿贝数至少为 33，初始的Barcol硬度至少为1.还描述了由这种聚合物制备的光致变色制品。
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公开(公告)号：US20100048852A1
公开(公告)日：2010-02-25
申请号：US12590085
申请日：2009-11-02
申请人： Nina V. Bojkova , Robert A. Smith , Robert D. Herold , Chandra B. Rao , William H. McDonald , Vidhu J. Nagpal , Marvin J. Graham , Phillip C. Yu , Suresh G. Sawant , Michael O. Okoroafor
发明人： Nina V. Bojkova , Robert A. Smith , Robert D. Herold , Chandra B. Rao , William H. McDonald , Vidhu J. Nagpal , Marvin J. Graham , Phillip C. Yu , Suresh G. Sawant , Michael O. Okoroafor
IPC分类号： C08G18/00
CPC分类号： C08G18/758 , C08G18/10 , C08G18/12 , C08G18/324 , C08G18/3876 , C08G18/4018 , C08G18/4202 , C08G18/4277 , C08G18/4837 , C08G18/52 , C08G18/6611 , C08G18/6644 , C08G18/722 , C08G18/724 , C08J5/18 , C08J2375/04 , G02B1/041 , C08G18/6685 , C08G18/3874 , C08G18/3237 , C08L75/04 , C08L81/00
摘要： The present invention relates to a sulfur-containing polyureaurethane and a method of preparing the polyureaurethane. The sulfur-containing polyureaurethane has a refractive index of at least 1.57, an Abbe number of at least 32 and a density of less than 1.3 grams/cm3 when cured. The sulfur-containing polyureaurethane is prepared by the reaction of: (a) a sulfur-containing, isocyanate functional polyurethane prepolymer derived from: (i) a polyisocyanate; and (ii) a polythiol oligomer produced by the reaction of at least two or more different dienes with one or more dithiols and in certain embodiments at least one trifunctional or higher-functional polythiol; and (b) an amine-containing curing agent.
摘要翻译： 本发明涉及一种含硫聚脲氨酯及其制备方法。 含硫聚脲聚氨酯的固化时的折射率至少为1.57，阿贝数至少为32，密度小于1.3克/厘米3。 通过以下反应制备含硫聚脲氨酯：（a）衍生自以下的含硫异氰酸酯官能化聚氨酯预聚物：（i）多异氰酸酯; 通过至少两种或更多种不同的二烯与一种或多种二硫醇的反应和在某些实施方案中至少一种三官能或更高官能度的多硫醇反应产生的多硫醇低聚物; 和（b）含胺固化剂。
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公开(公告)号：US5942158A
公开(公告)日：1999-08-24
申请号：US37107
申请日：1998-03-09
CPC分类号： G02B5/23 , C08G18/3876 , C08G18/807
摘要： Described is a polymerizable organic composition comprising at least one capped polyisocyanate having nonfugitive capping groups, e.g., a 1H-azole, a polythiol having two or more thiol groups, and optionally a reactive hydrogen compound selected from polyols, compounds having both hydroxy and thiol groups, and mixtures thereof. A polymerizate, having a thickness of at least 0.5 millimeters, e.g., an optical lens, obtained from the composition of the present invention has an initial Barcol hardness of at least 1, a refractive index of at least 1.57 and an Abbe number of at least 33. Also described are photochromic articles prepared from such polymerizates.
摘要翻译： 描述了包含至少一种具有非挥发性封端基团的封端多异氰酸酯的可聚合有机组合物，例如1H-唑，具有两个或更多个硫醇基团的多硫醇，以及任选的选自多元醇的反应性氢化合物，具有羟基和巯基的化合物 ，及其混合物。 具有至少0.5毫米厚度的聚合物，例如由本发明组合物获得的光学透镜，其初始Barcol硬度至少为1，折射率至少为1.57，阿贝数至少为 还描述了由这样的聚合物制备的光致变色制品。
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公开(公告)号：US5917006A
公开(公告)日：1999-06-29
申请号：US8222
申请日：1998-01-16
CPC分类号： C08G75/045 , G02B1/04
摘要： Describes a polymerizable organic composition comprising an aromatic monomer having at least two vinyl groups, e.g., divinyl benzene, a polythiol monomer having at least two thiol groups, e.g., pentaerythritol tetrakis(2-mercaptoacetate), and an anhydride monomer having at least one ethylenically unsaturated group, e.g., methacrylic anhydride. Polymerizable compositions according to the present invention, may optionally further comprise a polymerizable comonomer having at least two (meth)acryloyl groups, e.g., pentaerythritol tetrakis (acrylate). Polymerizates prepared from polymerizable organic compositions of the present invention have a refractive index of at least 1.57 and an Abbe number of at least 33. Also described are photochromic articles prepared from such compositions.
摘要翻译： 描述了包含具有至少两个乙烯基的芳族单体的可聚合有机组合物，例如二乙烯基苯，具有至少两个硫醇基的多硫醇单体，例如季戊四醇四（2-巯基乙酸酯）和具有至少一个烯属的 不饱和基团，例如甲基丙烯酸酐。 根据本发明的可聚合组合物可任选地进一步包含具有至少两个（甲基）丙烯酰基的可聚合共聚单体，例如季戊四醇四（丙烯酸酯）。 由本发明的可聚合有机组合物制备的聚合物具有至少1.57的折射率和至少为33的阿贝数。还描述了由这些组合物制备的光致变色制品。
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