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公开(公告)号：US4183406A
公开(公告)日：1980-01-15
申请号：US930121
申请日：1978-08-01
IPC分类号： C09K8/035 , C09K8/24 , C09K8/502 , E21B33/138
摘要： Improvements in the treatment of wells that penetrate subterranean formations are accomplished through the use of a polymer solution which includes a neutralized ionomeric polymer dissolved in an organic solvent and a polar cosolvent. The polymer has a backbone that is substantially soluble in the organic solvent and pendant ionomeric groups that are substantially insoluble in the organic solvent. The polar cosolvent solubilizes the pendant ionomeric groups such that the polymer solution upon introduction into the well has a viscosity less than about 20,000 centipoises and upon mixing with water the polar cosolvent is taken up by the water causing the polymer to aggregate and increase in viscosity sufficient to form a plug. The polymer solution may be used in well drilling operations, well completion operations, and secondary recovery operations.
摘要翻译： 通过使用包含溶解在有机溶剂中的中和的离聚物聚合物和极性助溶剂的聚合物溶液来实现渗透地下地层的井的处理的改进。 聚合物具有基本上可溶于有机溶剂的主链和基本上不溶于有机溶剂的侧基离聚物基团。 极性助溶剂溶解侧基离聚物基团，使得聚合物溶液在引入孔中的粘度小于约20,000厘泊，并且在与水混合时，极性助溶剂被水吸收，导致聚合物聚集并增加粘度足够 形成一个插头。 聚合物溶液可用于钻井操作，完井操作和二次回收操作。
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公开(公告)号：US4282130A
公开(公告)日：1981-08-04
申请号：US106027
申请日：1979-12-21
CPC分类号： C08J3/11 , B01J19/06 , C09K8/035 , C08J2323/32 , Y10S524/916
摘要： The present invention relates to a process for forming a polymeric solution or gel having a viscosity of at least about 50,000 cps which includes the steps forming a solvent system of an organic liquid and a polar cosolvent, the polar cosolvent being less than about 15 wt. % of the solvent system, a viscosity of the solvent system being less than about 1000 cps; dissolving a neutralized sulfonated polymer in the solvent system to form a solution, a concentration of the neutralized sulfonated polymer in the solution being about 0.1 to about 20 wt. %, a viscosity of the solution being less than about 20,000 cps; and adding about 5 to about 500 vol. % water to the solution having viscosity less than about 20,000 cps, the water being immiscible with the solution and the polar cosolvent transferring from the solution phase to the water phase thereby causing the viscosity of said solution to increase from less than 20,000 cps to greater than 50,000 cps.
摘要翻译： 本发明涉及形成具有至少约50,000cps的粘度的聚合物溶液或凝胶的方法，其包括形成有机液体和极性助溶剂的溶剂体系的步骤，极性助溶剂小于约15wt。 ％的溶剂体系，溶剂系统的粘度小于约1000cps; 将中和的磺化聚合物溶解在溶剂体系中以形成溶液，溶液中中和的磺化聚合物的浓度为约0.1至约20wt。 ％，溶液的粘度小于约20,000cps; 并加入约5至约500vol。 ％的水溶于粘度小于约20,000cps的溶液中，水与溶液不混溶，极性助溶剂从溶液相转移到水相，从而使所述溶液的粘度从小于20,000cps增加到大于 50,000 cps。
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公开(公告)号：US4222914A
公开(公告)日：1980-09-16
申请号：US22951
申请日：1979-03-23
CPC分类号： C08F8/44
摘要： This invention relates to a process for the formation of a neutralized sulfonated polymer having about 10 to about 60 meq. sulfonate groups, wherein the sulfonate groups are neutralized with a zinc counterion. A cement of a polymer having olefinic functional groups and a non-reactive solvent is contacted with a sulfonated agent such as an acyl sulfate. The sulfonated polymer is then neutralized with a solution of zinc acetate dissolved in a solvent system of methanol alone or methanol and water, wherein the volume percent of methanol based on non-reactive solvent is less than about 10. A carboxylic acid can be then added to the cement of the neutralized sulfonated polymer thereby forming a zinc salt of the carboxylic acid in situ, wherein the zinc salt of the carboxylic acid is a preferential plasticizer for the zinc sulfonate groups. The Brookfield viscosity at 0.6 rpm at room temperature of the cement of the zinc neutralized sulfonated polymer is less than about 50,000 cps.
摘要翻译： 本发明涉及形成约10至约60meq的中和磺化聚合物的方法。 磺酸盐基团，其中磺酸盐基团用锌抗衡离子中和。 具有烯属官能团和非反应性溶剂的聚合物的水泥与磺化剂如酰基硫酸盐接触。 然后将磺化聚合物用溶于仅甲醇溶剂体系的乙酸锌溶液或甲醇和水中和，其中基于非反应性溶剂的甲醇的体积百分比小于约10.然后可以加入羧酸 到中和的磺化聚合物的水泥上，由此原位形成羧酸的锌盐，其中羧酸的锌盐是磺酸锌基团的优选增塑剂。 锌中和磺化聚合物的水泥在室温下在0.6rpm下的Brookfield粘度小于约50,000cps。
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4.发明授权Plasticization of neutralized sulfonated elastomeric polymer with organic carbamates 失效中和磺化弹性体聚合物与有机氨基甲酸酯的增塑
公开(公告)号：US4210568A
公开(公告)日：1980-07-01
申请号：US898465
申请日：1978-04-20
IPC分类号： C08L23/00 , C07C67/00 , C07C239/00 , C07C269/02 , C08K5/16 , C08K5/20 , C08K5/205 , C08L7/00 , C08L21/00 , C08L101/00
摘要： This invention relates to improved polymeric compositions of metal, amine and ammonium neutralized sulfonated polymers which are preferentially plasticized with an N-substituted organic carbamate at a minimum critical concentration level of at least 1 part by weight based on 100 parts by weight of the neutralized polymer, wherein N-substituted organic carbamate has the general formula selected from the group of: ##STR1## wherein R.sub.1, and R.sub.2 are normal or branched chain alkyl, cycloalkyl, aryl, alkaryl, or arylalkyl groups such as ethyl, butyl, octadecyl, behenyl, phenyl, benzyl, and dodecylphenyl and R.sub.4 and R.sub.6 and either R.sub.1 or R.sub.2 must be a long chain, preferably linear, saturated group containing from about 10 to about 50 carbon atoms and R.sub.3 and R.sub.5 are di, tri, or tetrafunctional aliphatic, cycloaliphatic, aryl or alkaryl groups and m is 2, 3, or 4 and n is 2, 3 or 4.
摘要翻译： 本发明涉及金属，胺和铵中和的磺化聚合物的改进的聚合物组合物，其以至少1重量份的最小临界浓度水平优选用N-取代的有机氨基甲酸酯增塑，基于100重量份的中和聚合物 其中N-取代的有机氨基甲酸酯具有选自以下的通式：其中R 1和R 2是正或支链的烷基，环烷基，芳基，烷芳基或芳烷基，例如乙基，丁基，十八烷基，山嵛基 ，苯基，苄基和十二烷基苯基，R 4和R 6以及R 1或R 2必须是含有约10至约50个碳原子的长链，优选直链饱和基团，并且R 3和R 5是二，三或四官能脂族，脂环族 ，芳基或烷芳基，m为2,3或4，n为2,3或4。
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5.发明授权
公开(公告)号：US4153588A
公开(公告)日：1979-05-08
申请号：US855724
申请日：1977-11-29
CPC分类号： C08L23/32 , Y10S260/31
摘要： This invention relates to plasticized metal neutralized sulfonated EPDM terpolymers having at least 65 wt. % of ethylene in the backbone of the EPDM terpolymer and extended compositions of these metal neutralized sulfonated EPDM terpolymers having 100 parts of a neutralized sulfonated EPDM terpolymer; less than about 100 parts per hundred of a non-polar process oil; less than about 300 parts per hundred of a filler; and a preferential plasticizer at about less than 60 parts per hundred based on 100 parts of the sulfonated elastomeric polymer. These compositions can be readily processed due to their superior rheological properties on conventional plastic fabrication equipment, especially on low pressure injection molding and extrusion equipment into elastomeric articles having improved physical properties.
摘要翻译： 本发明涉及增塑金属中和的磺化EPDM三元共聚物，其具有至少65wt。 EPDM三元共聚物主链中乙烯的百分比和这些金属中和的磺化EPDM三元共聚物的延伸组合物，其具有100份中和的磺化EPDM三元共聚物; 小于约100份/百份非极性加工油; 每百份填料少于约300份; 和基于100份磺化弹性体聚合物约100份的约100份的优选增塑剂。 这些组合物由于其在常规塑料制造设备上的优异的流变性能而可以容易地加工，特别是在低压注射成型和挤出设备成为具有改进的物理性能的弹性体制品中。
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公开(公告)号：US4313862A
公开(公告)日：1982-02-02
申请号：US136835
申请日：1980-04-03
CPC分类号： C08J3/11 , B01J19/06 , C09K8/035 , C08J2323/32
摘要： The present invention relates to a process for forming a polymeric solution or gel having a viscosity of at least about 50,000 cps which includes the steps of dissolving an unneutralized or neutralized sulfonated polymer in a solvent to form a solution, a concentration of the unneutralized or neutralized sulfonated polymer in the solution being about 0.1 to about 20 wt. %, a viscosity of the solution being less than about 20,000 cps; and adding about 5 to about 500 vol. % water to the solution having a viscosity less than about 20,000 cps, the water being immiscible with the solvent and the solution, the viscosity of said solution increasing rapidly upon the addition of said water from less than 20,000 cps to greater than 50,000 cps.
摘要翻译： 本发明涉及形成粘度至少约50,000cps的聚合物溶液或凝胶的方法，其包括将未中和或中和的磺化聚合物溶解在溶剂中以形成溶液，将未中和或中和的浓度 溶液中的磺化聚合物为约0.1至约20wt。 ％，溶液的粘度小于约20,000cps; 并加入约5至约500vol。 ％的水溶于粘度小于约20,000cps的溶液中，水与溶剂和溶液不混溶，所述溶液的粘度在加入所述水从小于20,000cps至大于50,000cps时迅速增加。
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公开(公告)号：US4208310A
公开(公告)日：1980-06-17
申请号：US19704
申请日：1979-03-12
申请人： Robert D. Lundberg , Jan Bock , Henry S. Makowski
发明人： Robert D. Lundberg , Jan Bock , Henry S. Makowski
CPC分类号： C08L91/06 , C08L23/32 , Y10S260/31
摘要： This invention relates to elastomeric blend compositions of a neutralized sulfonated elastomeric polymer. The compositions include a major portion of a sulfonated elastomeric polymer and a minor proportion of a non-polar wax, wherein the resultant composition has both improved physical and rheological properties.
摘要翻译： 本发明涉及中和磺化弹性体聚合物的弹性共混组合物。 组合物包括磺化弹性体聚合物的主要部分和少部分非极性蜡，其中所得组合物具有改善的物理和流变性质。
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公开(公告)号：US4147677A
公开(公告)日：1979-04-03
申请号：US855764
申请日：1977-11-29
申请人： Robert D. Lundberg , Henry S. Makowski , Jan Bock
发明人： Robert D. Lundberg , Henry S. Makowski , Jan Bock
IPC分类号： C08L23/00 , C08J3/12 , C08K5/09 , C08L7/00 , C08L21/00 , C08L23/26 , C08L23/32 , C08L101/00 , C08L91/00
CPC分类号： C08L23/32 , Y10S260/31
摘要： This invention relates to a process for first preparing a free flowing finely divided powder of a neutralized sulfonated elastomer and subsequently and optionally admixing said formed powder with other agents such as fillers and oils thereby providing free flowing powders capable of being subsequently fabricated into tough elastomeric objects. The neutralized sulfonated elastomeric polymer can be converted into a free flowing finely divided powder which does not agglomerate or cold flow under ambient conditions by a variety of processes, preferably by a grinding process conducted at low temperatures. The formed powder of the neutralized sulfonated elastomeric polymer is blended with at least one chemical additive into a homogeneous mixture, wherein the chemical additive is selected from the group including fillers, polyolefinic thermoplastics, non-polar backbone process oils, lubricants or a metallic oxide and mixtures thereof. The homogeneous mixture is formed into a finished elastomeric article by conventional fabrication.
摘要翻译： {PG，1]本发明涉及一种首先制备中和的磺化弹性体的自由流动细碎粉末的方法，随后任选地将所形成的粉末与其它试剂如填料和油混合，从而提供能够随后制成的自由流动的粉末 变成坚韧的弹性物体。 中和的磺化弹性体聚合物可以转化成自由流动的细分散的粉末，其在环境条件下通过各种方法，优选通过在低温下进行的研磨过程不凝聚或冷流。 所形成的中和的磺化弹性体聚合物的粉末与至少一种化学添加剂混合成均匀的混合物，其中所述化学添加剂选自填料，聚烯烃热塑性塑料，非极性主链工艺油，润滑剂或金属氧化物，以及 其混合物。 均匀混合物通过常规制造形成成品弹性制品。
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公开(公告)号：US4127546A
公开(公告)日：1978-11-28
申请号：US855755
申请日：1977-11-29
IPC分类号： C08L23/00 , C08L7/00 , C08L21/00 , C08L23/26 , C08L23/32 , C08L33/00 , C08L33/02 , C08L101/00 , C08L93/00
CPC分类号： C08L23/32 , Y10S260/31
摘要： This invention relates to an improved elastomeric composition of metal neutralized sulfonated polymers which are plasticized with a preferential plasticizer at a concentration level of at least 1 part by weight based on 100 parts by weight of the metal neutralized EPDM terpolymer, wherein the preferential plasticizer is a metal rosin salt. The resultant compositions have improved physical properties and can be processed on conventional plastic fabrication equipment.
摘要翻译： 本发明涉及金属中和的磺化聚合物的改进的弹性体组合物，其基于100重量份的金属中和的三元共聚物三元共聚物，以优选的增塑剂增塑至少1重量份，其中， 优选的增塑剂是金属松香盐。 所得组合物具有改善的物理性能并且可以在常规塑料制造设备上加工。
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公开(公告)号：US4053548A
公开(公告)日：1977-10-11
申请号：US199799
申请日：1971-11-17
IPC分类号： B29B9/00 , B29B13/00 , B29B15/00 , B29C61/00 , C08G18/10 , C08J3/18 , C08J5/00 , C08L53/00 , B29B3/02 , B29C25/00
CPC分类号： C08L53/00 , B29C61/003 , C08G18/10 , C08J3/18 , C08J5/00 , B29K2096/005 , B29K2096/02 , B29K2096/04
摘要： A process for fabricating a plastic, which plastic is either a thermoplastic ionomer or a multiphase graft or block copolymer of the ABA, ##STR1## or (AB).sub.n wherein n is greater than 1 and wherein the polymer blocks (A and B) are thermoplastic, incompatible with one another, and have different softening points, both softening points being substantially above room temperature when using the latter class of polymers. The material is first heated to a temperature above both softening points and formed into any desired shape, then cooled and re-formed into a new desired shape at a temperature between that of the softening points of the two blocks and finally cooled to a temperature below both softening points thereby retaining the shape last achieved. When using thermoplastic ionomers the process is similar. The material is heated above the softening point of the thermoplastic backbone and plasticizers are employed to disrupt the ionic domains. The process may be readily employed to prepare containers, bottles, or rigid foams and the like which may be shipped as compact materials and re-formed for actual use by simply reheating, etc.
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