摘要:
Describes terminally ethylenically unsaturated poly(alkyleneoxy) surfactant compounds of the general formula, R--O--(R'O).sub.m --(EO).sub.n-1 --CH.sub.2 CH.sub.2 --X, wherein R is the ethylenically unsaturated hydrocarbon group, e.g., allyl, R' is the bivalent radical derived from butylene oxide, E is the bivalent ethylene radical, m and n are numbers of from 10 to 15 and 10 to 40 respectively, and X is chloride, tertiaryamino, sulfonate, sulfate, phosphate, isethionate and alkali metal salts of the anionic groups. These surfactant compounds may be used in emulsion polymerization of ethylenically unsaturated, e.g., vinyl, monomers.
摘要:
Describes alpha-beta ethylenically unsaturated poly(alkyleneoxy) compounds that display surfactant activity and that polymerize when used in the emulsion polymerization of ethylenically unsaturated monomers, including vinyl monomers. Certain of the polymer products are useful in imparting improved hand or feel to textile fabrics.
摘要:
A method of forming an optical element which includes an electrochromic apodized aperture having variable light transmittance through a clear aperture area in response to an applied electrical current is disclosed. The apodized aperture includes a body including an area defining the clear aperture area wherein a fluid containment area substantially overlapping the clear aperture area, and includes at least one fill passage extending from the fluid containment area to at least one fill port outside of the clear aperture area; an electrochromic fluid within the fluid containment area substantially overlapping the clear aperture area and having variable light transmittance in response to an applied electrical current; a cover attached with the electrochromic fluid between the cover and body; electrical contacts electrically coupled to the electrochromic fluid for supplying electrical current thereto; and at least one passage seal in each said fill passage positioned outside of the clear aperture area.
摘要:
A method comprising heating to elevated temperature a ceramic substrate having thereon a sequence of coatings of pigmented coating compositions wherein each of said pigmented coating compositions comprises: (a) reactive organic resin which is polyhydroxy-functional, polyepoxy-functional, or both epoxy-functional and hydroxy-functional; (b) reactive wax; (c) color-imparting pigment; and (d) blocked polyisocyanate; wherein: (e) the pigmented coating composition of at least one coating of the sequence is substantially free of amino-functional curing agent; and (f) the pigmented coating composition of at least one other coating of the sequence further comprises amino-functional curing agent; to crosslink all of the pigmented coating compositions of the coatings of the sequence and to adhere the sequence to the ceramic substrate. The preferred ceramic substrates are glass bottles.The outermost coating of the sequence may optionally be overlain with a coating of substantially clear overcoating composition which comprises reactive organic resin which is polyhydroxy-functional, polyepoxy-functional, or both epoxy-functional and hydroxy-functional. Upon heating to the elevated curing temperature, the substantially clear overcoating composition is crosslinked together with the pigmented coating compositions.
摘要:
Describes a method of electrochemically converting .alpha.-halohydrin, e.g., 1-chloro-2-hydroxypropane and 1,3-dichloro-2-hydroxypropane, to epoxide, e.g., propylene oxide and epichlorohydrin. An aqueous solution of .alpha.-halohydrin is charged to the catholyte compartment of an electrolytic cell, which contains a cathode, hydrogen gas is charged to the anode compartment of the cell, which contains an anode assembly comprising a hydrogen consuming gas diffusion anode fixedly held between a current collecting electrode and an anion exchange membrane. The catholyte and anode compartments of the cell are separated by the anion exchange membrane. An aqueous solution containing epoxide is removed from the catholyte compartment.
摘要:
Describes a method of electrochemically converting amine hydrohalide, e.g., ethyleneamine hydrochloride, into free amine, e.g., free ethyleneamine, by charging an aqueous solution of amine hydrohalide to the catholyte compartment of an electrolytic cell, which contains a cathode, charging hydrogen gas to the anode compartment of the cell, which contains an anode assembly comprised of a hydrogen consuming gas diffusion anode fixedly held between a current collecting electrode and an anion exchange membrane. The catholyte and anode compartments of the cell are separated by the anion exchange membrane. An amine hydrohalide solution containing free amine is removed from the catholyte compartment.
摘要:
A composition and method for providing a non-formaldehyde durable press finish to cellulosic fabrics by employing polyphosphinocarboxylic acids are disclosed. The polyphosphinocarboxylic acid is preferably polyphosphinoacrylic acid, and is optimally used in combination with phosphonoalkylpolycarboxylic acid, and, for cost effectiveness, a low-cost polycarboxylic acid such as citric acid. The catalyst for the curing reaction is preferably a phosphorus-containing acid or alkali metal salt thereof such as a mixture of sodium monophosphate and sodium hypophosphite.
摘要:
A printing medium comprising a substrate having at least one surface and a coating on the surface wherein the coating comprises: (a) binder comprising: (1) organic polymer which is substantially free of ammonium groups, (2) first cationic addition polymer consisting essentially of quaternary ammonium-containing mer units derived from addition monomer and ammonium-free mer units derived from addition monomer, and (3) second cationic addition polymer consisting essentially of secondary, tertiary, or both secondary and tertiary ammonium-containing mer units derived from addition monomer and ammonium-free mer units derived from addition monomer, wherein the binder constitutes from 20 to 90 percent by weight of the coating; and (b) finely divided substantially water-insoluble filler particles which have a maximum dimension of less than 500 nanometers, are distributed throughout the binder, and constitute from 10 to 80 percent by weight of coating.
摘要:
Describes a method of electrochemically converting .alpha.-halohydrins, e.g., 1-chloro-2-hydroxypropane and 1,3-dichloro-2-hydroxypropane, to epoxides, e.g., propylene oxide and epichlorohydrin. A three compartment electrolytic cell is provided having (1) a catholyte compartment containing a cathode assembly comprising a cathode and anion exchange membrane, (2) an anolyte compartment containing an anode assembly comprising an anode and a cation exchange membrane, and (3) an intermediate compartment partitioned from the catholyte and anolyte compartments by the anion and cation exchange membranes respectively. An aqueous solution of .alpha.-halohydrin is charged to the catholyte compartment, while hydrogen halide solutions are charged to the intermediate and anolyte compartments. Direct current is passed through the electrolytic cell and an aqueous solution comprising epoxide is removed from the catholyte compartment.
摘要:
A composition and method for providing a non-formaldehyde durable press finish to cellulosic fabrics by employing polyphosphinocarboxylic acids are disclosed. The polyphosphinocarboxylic acid is preferably polyphosphinoacrylic acid, and is optimally used in combination with phosphonoalkylpolycarboxylic acid, and, for cost effectiveness, a low-cost polycarboxylic acid such as citric acid. The catalyst for the curing reaction is preferably a phosphorus-containing acid or alkali metal salt thereof such as a mixture of sodium monophosphate and sodium hypophosphite.