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1.发明授权Method for forming a sequence of crosslinked pigmented coatings on ceramic substrates 有权在陶瓷基板上形成交联着色涂层序列的方法公开(公告)号：US06214414B1
公开(公告)日：2001-04-10
申请号：US09359471
申请日：1999-07-22
申请人： Robert H. Tang , Yingchao Zhang , Louis J. Nehmsmann , Alan E. Wang , George D. Morris , Robert A. Montague
发明人： Robert H. Tang , Yingchao Zhang , Louis J. Nehmsmann , Alan E. Wang , George D. Morris , Robert A. Montague
IPC分类号： B05D136
CPC分类号： C03C17/3405 , C03C2217/445 , C03C2217/485
摘要： A method comprising heating to elevated temperature a ceramic substrate having thereon a sequence of coatings of pigmented coating compositions wherein each of said pigmented coating compositions comprises: (a) reactive organic resin which is polyhydroxy-functional, polyepoxy-functional, or both epoxy-functional and hydroxy-functional; (b) reactive wax; (c) color-imparting pigment; and (d) blocked polyisocyanate; wherein: (e) the pigmented coating composition of at least one coating of the sequence is substantially free of amino-functional curing agent; and (f) the pigmented coating composition of at least one other coating of the sequence further comprises amino-functional curing agent; to crosslink all of the pigmented coating compositions of the coatings of the sequence and to adhere the sequence to the ceramic substrate. The preferred ceramic substrates are glass bottles.The outermost coating of the sequence may optionally be overlain with a coating of substantially clear overcoating composition which comprises reactive organic resin which is polyhydroxy-functional, polyepoxy-functional, or both epoxy-functional and hydroxy-functional. Upon heating to the elevated curing temperature, the substantially clear overcoating composition is crosslinked together with the pigmented coating compositions.
摘要翻译： 一种方法，包括将具有着色涂料组合物涂层序列的陶瓷基材加热到高温，其中每种所述着色涂料组合物包含：（a）反应性有机树脂，其为多羟基官能团，聚环氧官能团或环氧官能团 和羟基官能团; （b）活性蜡; （c）赋颜色剂; 和（d）封端的多异氰酸酯; 其中：（e）所述序列的至少一种涂层的着色涂料组合物基本上不含氨基官能的固化剂; 和（f）该序列的至少一种其它涂层的着色涂料组合物还包含氨基官能的固化剂; 以使所述序列的涂层的所有着色涂料组合物交联并将该序列粘附到陶瓷基材上。 优选的陶瓷基材是玻璃瓶。该顺序的最外涂层可以任选地与基本上透明的涂层组合物的涂层重叠，该涂层组合物包含反应性有机树脂，其是多羟基官能的，聚环氧官能的或环氧官能的和羟基官能的 。 加热至升高的固化温度后，基本上透明的外涂层组合物与着色涂料组合物一起交联。
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公开(公告)号：US06340725B1
公开(公告)日：2002-01-22
申请号：US09416154
申请日：1999-10-11
IPC分类号： C08L3326
CPC分类号： B41M5/52 , B41M5/506 , B41M5/5218 , B41M5/5236 , B41M5/5245 , B41M5/5254 , Y10T428/31895
摘要： A printing medium comprising a substrate having at least one surface and a coating on the surface wherein the coating comprises: (a) binder comprising: (1) organic polymer which is substantially free of ammonium groups, (2) first cationic addition polymer consisting essentially of quaternary ammonium-containing mer units derived from addition monomer and ammonium-free mer units derived from addition monomer, and (3) second cationic addition polymer consisting essentially of secondary, tertiary, or both secondary and tertiary ammonium-containing mer units derived from addition monomer and ammonium-free mer units derived from addition monomer, wherein the binder constitutes from 20 to 90 percent by weight of the coating; and (b) finely divided substantially water-insoluble filler particles which have a maximum dimension of less than 500 nanometers, are distributed throughout the binder, and constitute from 10 to 80 percent by weight of coating.
摘要翻译： 一种印刷介质，包括具有至少一个表面的基材和在所述表面上的涂层，其中所述涂层包含：（a）粘合剂，其包含：（1）基本上不含铵基团的有机聚合物，（2）基本上组成的第一阳离子加成聚合物 由加成单体衍生的含季铵的mer单元和衍生自加成单体的无铵的单体单元，和（3）基本上由二级，三级或两级衍生的仲二级，三级或二级仲铵基的单体组成的第二阳离子加成聚合物 衍生自加成单体的单体和无铵的共聚单体，其中粘合剂占涂料的20至90重量％; 和（b）具有最大尺寸小于500纳米的基本上非水不溶性的填料颗粒分布在整个粘合剂中，并且构成涂层的10至80重量％。
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公开(公告)号：US6074761A
公开(公告)日：2000-06-13
申请号：US876070
申请日：1997-06-13
IPC分类号： B41J2/01 , B41M5/00 , B41M5/50 , B41M5/52 , C09D7/12 , C09D201/00 , C08L33/26 , B32B23/06 , B32B27/20 , C08K5/19 , C08L29/04 , C08L33/08 , C08L33/10 , C08L39/00
CPC分类号： B41M5/52 , B41M5/506 , B41M5/5218 , B41M5/5236 , B41M5/5245 , B41M5/5254
摘要： A printing medium comprising a substrate having at least one surface and a coating on the surface wherein the coating comprises: (a) binder comprising: (1) organic polymer which is substantially free of ammonium groups, (2) first cationic addition polymer consisting essentially of quaternary ammonium-containing mer units derived from addition monomer and ammonium-free mer units derived from addition monomer, and (3) second cationic addition polymer consisting essentially of secondary, tertiary, or both secondary and tertiary ammonium-containing mer units derived from addition monomer and ammonium-free mer units derived from addition monomer, wherein the binder constitutes from 20 to 90 percent by weight of the coating; and (b) finely divided substantially water-insoluble filler particles which have a maximum dimension of less than 500 nanometers, are distributed throughout the binder, and constitute from 10 to 80 percent by weight of coating.
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公开(公告)号：US5880196A
公开(公告)日：1999-03-09
申请号：US874898
申请日：1997-06-13
CPC分类号： B41M5/52 , B41M5/506 , B41M5/5218 , B41M5/5236 , B41M5/5245 , B41M5/5254
摘要： A printing medium comprising a substrate having at least one surface and a coating on the surface wherein the coating comprises: (a) binder comprising: (1) organic polymer which is substantially free of onium groups, and (2) onium addition polymer consisting essentially of onium-containing mer units derived from addition monomer and onium-free mer units derived from addition monomer of which from 20 to 100 percent by weight is hydrophobic addition monomer, wherein the binder constitutes from 20 to 90 percent by weight of the coating; and (b) finely divided substantially water-insoluble pseudoboehmite particles which have a maximum dimension of less than 500 nanometers, are distributed throughout the binder, and constitute from 10 to 80 percent by weight of the coating.
摘要翻译： 一种印刷介质，包括具有至少一个表面和表面上的涂层的基材，其中所述涂层包含：（a）粘合剂，其包含：（1）基本上不含鎓基的有机聚合物，和（2）基本上由 的衍生自加成单体的含鎓mer单元和衍生自其加入单体的无鎓单体单元为20〜100重量％的疏水性加成单体，其中粘合剂占涂料重量的20〜90重量％ 和（b）具有最大尺寸小于500纳米的基本上非水不溶性假勃姆石颗粒分布在整个粘合剂中，并且构成涂层的10至80重量％。
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5.发明授权
公开(公告)号：US5739365A
公开(公告)日：1998-04-14
申请号：US509018
申请日：1995-07-28
IPC分类号： C07C303/02 , C07C53/00
CPC分类号： C07C303/02
摘要： A method is disclosed for preparing ammonium hydroxyalkyl sulfonate by a process of reacting ammonium bisulfite and alkylene oxide wherein the pH is maintained at a relatively low value throughout most of the time of reaction of ammonium bisulfite and alkylene oxide in order to minimize the quantity of impurities, e.g. alkylene glycol and alkanolamine, in the ammonium hydroxyalkyl sulfonate. Ammonium alkanoyl alkyl sulfonates prepared by reacting such ammonium hydroxyalkyl sulfonates with fatty acids form aqueous solutions which are clear at ambient temperatures, and thus are useful as surfactants in clear liquid products.
摘要翻译： 公开了通过使亚硫酸氢铵和烯化氧反应制备铵羟烷基磺酸铵的方法，其中在亚硫酸氢铵和环氧烷反应的大部分时间内将pH保持在相对较低的值，以使杂质的量最小化 ，例如 烷基二醇和链烷醇胺，在羟烷基磺酸铵中。 通过使这种羟基烷基磺酸铵与脂肪酸反应制备的烷基磺酸烷基磺酸盐形成在环境温度下是透明的水溶液，因此可用作透明液体产物中的表面活性剂。
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6.发明授权Surfactant blend containing an alkyl poly(ethyleneoxy)sulfonate to reduce dermal irritation 失效含有聚（乙烯氧基）磺酸烷基酯的表面活性剂共混物以减少皮肤刺激
公开(公告)号：US5075042A
公开(公告)日：1991-12-24
申请号：US610714
申请日：1990-11-06
CPC分类号： A61K8/466 , A61K8/463 , C11D1/143 , C11D1/37 , A61K2800/596 , A61K2800/75 , C11D1/14 , C11D1/29
摘要： Described are detergent compositions that exhibit reduced skin irritation properties while providing excellent cleaning and detergent characteristics. The detergent composition contains anionic and/or nonionic surface active materials that are at least mildly irritating to the skin and an amount of alkyl poly(ethyleneoxy)sulfonate sufficient to reduce the primary skin irritation potential of the detergent composition. The aliphatic poly(ethyleneoxy)sulfonate typically has a hydrophobe containing from 12 to about 22 carbon atoms and an average of from about 10 to about 30 ethyleneoxy groups, and is present in the detergent composition in amounts of from about 5 to about 50 percent of the total amount of surface active material in the detergent composition.
摘要翻译： 描述了具有降低的皮肤刺激性能同时提供优异的清洁和洗涤剂特性的洗涤剂组合物。 洗涤剂组合物含有对皮肤至少轻度刺激的阴离子和/或非离子表面活性物质，以及足以降低洗涤剂组合物初级皮肤刺激潜力的烷基聚（乙烯氧基）磺酸盐。 脂族聚（乙烯氧基）磺酸盐通常具有含有12至约22个碳原子和平均约10至约30个乙烯氧基的疏水物，并且以约5至约50％的量存在于洗涤剂组合物中 洗涤剂组合物中表面活性物质的总量。
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公开(公告)号：US5804293A
公开(公告)日：1998-09-08
申请号：US569619
申请日：1995-12-08
CPC分类号： B41M5/5218 , C09C1/30 , D21H19/40 , B41M5/5236 , B41M5/5254 , C01P2002/02 , C01P2004/52 , C01P2004/53 , C01P2004/61 , C01P2006/12 , C01P2006/14 , C01P2006/16 , C01P2006/17 , C01P2006/22 , C01P2006/82 , Y10T428/249956 , Y10T428/249978 , Y10T428/249991 , Y10T428/259 , Y10T428/269 , Y10T428/277
摘要： Printed matter of high optical density may be obtained by ink-jet printing techniques when the coating contains composite particulate amorphous precipitated silica having a calculated multimodal particle size distribution wherein the particle sizes at the modes are less than 10 micrometers.
摘要翻译： 当涂层含有具有计算的多峰粒度分布的复合颗粒无定形沉淀二氧化硅时，可以通过喷墨印刷技术获得高光密度的印刷物，其中模式下的粒径小于10微米。
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8.发明授权High foaming, low eye irritation cleaning compositions containing ethoxylated anionic (C13-C30) sulphates 失效含有乙氧基化阴离子（C13-C30）硫酸盐的高发泡，低眼睛刺激清洁组合物
公开(公告)号：US4412944A
公开(公告)日：1983-11-01
申请号：US280369
申请日：1981-07-06
IPC分类号： C11D1/29
摘要： A high foaming, low eye irritation cleaning composition. The composition contains an alkyl ether sulfate having the following structural formulae:R(A).sub.n OSO.sub.3 M or R.sub.1 (A).sub.n SO.sub.3 Mwherein R is an alkyl, alkylaryl, acyl or alkenyl group having at least 13, preferably 13 to 30, most preferably 14 to 24, carbon atoms in the alkyl chain; R.sub.1 is an acylamide group having at least 13, preferably 13 to 30, most preferably 14 to 24, carbon atoms, A is an alkyl ether group derived from ethylene oxide, propylene oxide, butylene oxide, glycidol and substituted epoxides, the preferred group being ethoxy; n is about 6 to about 100, preferably about 6 to about 20, more preferably about 10 to about 20; and M is a cation such as an alkali metal, an alkaline earth metal, a transition metal, ammonium, an alkylamine, or an alkanolamine. These compositions are particularly useful as cosmetic cleaning compositions, such as shampoos and bubble baths.
摘要翻译： 高发泡，低眼睛刺激清洁组合物。 该组合物含有具有以下结构式的烷基醚硫酸酯：R（A）nOSO 3 M或R 1（A）n SO 3 M其中R是具有至少13，优选13至30，最优选14至14的烷基，烷基芳基，酰基或烯基 24，烷基链中的碳原子; R1是具有至少13个，优选13-30个，最优选14-24个碳原子的酰胺基，A是衍生自环氧乙烷，环氧丙烷，环氧丁烷，缩水甘油和取代环氧化物的烷基醚基团，优选的基团是 乙氧基 n为约6至约100，优选约6至约20，更优选约10至约20; M是阳离子如碱金属，碱土金属，过渡金属，铵，烷基胺或烷醇胺。 这些组合物特别可用作化妆品清洁组合物，例如洗发剂和泡泡浴。
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公开(公告)号：US5354829A
公开(公告)日：1994-10-11
申请号：US906960
申请日：1992-06-30
IPC分类号： C08G69/42 , C08G73/02 , C08G73/04 , C08G77/26 , C08G77/42 , D06M15/59 , D06M15/61 , D06M15/643 , C08G77/00
CPC分类号： C03C25/26 , C03C25/328 , C08G69/42 , C08G73/0213 , C08G73/0233 , C08G73/028 , D06M15/59 , D06M15/61 , D06M15/6436 , D06M7/00 , D06M2200/40
摘要： A polymeric reaction product is disclosed that is a silylated polyamine-containing polymer having moieties from fatty acid moieties and/or chain extenders as difunctional organo moieties and free amine moieties and hydrolyzed and/or hydrolyzable organofunctional silane moieties and that is at least water dispersible. The reactants that produce this product are a polyamine-containing polymer with fatty acid moieties and free amine moieties and at least one amine-reactable organo functional alkoxysilane or its hydrolysis products. The former reactant results from the reaction of a polyamine-containing polymer with free amine moieties with fatty acids alone or in mixtures with other fatty acids and/or dimer acids. The polymeric reaction product is combined with a predominant amount of water to form a fiber treating formulation that can reside on the surface of one or more treated fibers.
摘要翻译： 公开了一种聚合反应产物，其是具有来自脂肪酸部分和/或扩链剂的部分作为双功能有机部分和游离胺部分以及水解和/或可水解的有机官能硅烷部分并且至少是水分散性的甲硅烷基化的含多胺的聚合物。 产生该产物的反应物是具有脂肪酸部分和游离胺部分的多胺聚合物和至少一种胺可反应的有机官能烷氧基硅烷或其水解产物。 前者反应物是由含多胺聚合物与游离胺部分与单独的脂肪酸或与其它脂肪酸和/或二聚酸的混合物的反应产生的。 将聚合反应产物与主要量的水混合以形成纤维处理制剂，其可以驻留在一种或多种经处理的纤维的表面上。
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公开(公告)号：US4832865A
公开(公告)日：1989-05-23
申请号：US140852
申请日：1988-01-05
摘要： A composition comprises: (A) chlorine-containing organic solvent selected from the group consisting of methylchloroform, trichloroethylene, perchlorethylene, and mixtures thereof, and (B) non-ionic surfactant selected from the group consisting of ##STR1## or mixtures thereof, wherein: (C) each R is independently straight or branched alkyl containing from about 8 to about 24 carbon atoms or ##STR2## (D) each R' is independently straight or branched alkyl containing from about 8 to about 18 carbon atoms, (E) each Z is independently fluoro, chloro, bromo, or alkoxy containing from 1 to about 4 carbon atoms, (F) the average value of a is in the range of from 0 to about 100, (G) the average value of b is in the range of from 0 to about 60, (H) the average value of c is in the range of from 0 to about 50, (I) the sum of the average values of a, b, and c is in the range of from 3 to about 150, (J) the sum of the average values of d and f is in the range of from 2 to about 50, (K) the average value of e is in the range of from 2 to about 60, (L) the average value of g is in the range of from 2 to about 50, (M) the average value of n is in the range of from 0 to about 2, and (N) the composition is essentially free of methylene chloride.
摘要翻译： 组合物包含：（A）选自甲基氯仿，三氯乙烯，全氯乙烯及其混合物的含氯有机溶剂，和（B）选自以下的非离子表面活性剂： （C）每个R独立地为含有约8至约24个碳原子的直链或支链烷基，或者（D），每个R'独立地为含有约8至约24个碳原子的直链或支链烷基， 约18个碳原子，（E）各Z独立地是氟，氯，溴或含有1至约4个碳原子的烷氧基，（F）a的平均值在0至约100的范围内（G ）b的平均值在0至约60的范围内，（H）c的平均值在0至约50的范围内，（I）a，b， 并且c在3至约150的范围内，（J）d和f的平均值之和在范围内 （K），e的平均值在2至约60的范围内，（L）g的平均值在2至约50的范围内，（M）平均值 n的值在0至约2的范围内，和（N）组合物基本上不含二氯甲烷。
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