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公开(公告)号：US5420359A
公开(公告)日：1995-05-30
申请号：US132787
申请日：1993-10-07
CPC分类号： A61K9/0026 , C07C43/123 , C07C43/126
摘要： Normally liquid chlorofluoroether compositions consisting or consisting essentially of one or a selected mixture of perhalogenated chlorofluoroether compounds are provided by direct fluorination of the corresponding chloroether or chlorofluoroether precursors. The compositions are useful, for example, as heat transfer agents, blood substitutes, and solvents.
摘要翻译： 通过直接氟化相应的氯醚或氯氟醚前体提供由基本上由一种或选择的全卤代氯氟醚化合物混合物组成或组成的常规氯氟氯醚组合物。 组合物可用作例如作为热传递剂，血液代用品和溶剂。
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2.发明授权Highly fluorinated, chloro-substituted organic compound-containing emulsions and methods of making and using them 失效高度氟化的含氯取代的含有机化合物的乳液及其制备和使用方法
公开(公告)号：US5785950A
公开(公告)日：1998-07-28
申请号：US244804
申请日：1994-10-12
IPC分类号： A61K47/06 , A01N1/02 , A61B5/055 , A61K9/00 , A61K31/02 , A61K31/08 , A61K49/00 , A61K49/18 , A61N5/00 , B01J13/00 , C07C43/12 , C07C43/313 , A61K49/04 , A61K51/00
CPC分类号： A61K9/0026 , A01N1/02 , A01N1/0205 , A01N1/0221 , A61K31/02 , A61K31/08 , A61K49/0002 , A61K49/1806 , C07C43/123 , C07C43/126 , C07C43/313 , Y10S514/832 , Y10S514/833 , Y10S514/942 , Y10S514/943
摘要： This invention relates to compositions comprising highly fluorinated, chloro-substituted, non-cyclic organic compounds having 7 to 9 carbon atoms and to processes of making and using them. More particularly, this invention relates to emulsions comprising those highly fluorinated, chloro-substituted organic compounds. This invention also related to emulsion comprising noncyclic perfluorochlorethers having 7 to 10 carbon atoms, preferably 7 to 9 carbon atoms. These novel emulsions have various medical and oxygen transport applications. They are especially useful medically as contrast media, for various biological imaging modalities such as nuclear magnetic resonance, ultrasound, x-ray, computed tomography, .sup.19 F-magnetic resonance imaging, and position emission tomography, as oxygen transport agents or "artificial bloods," in the treatment of heart attack, stroke, and other vascular obstructions, as adjuvants to coronary angioplasty and in cancer radiation treatment and chemotherapy.
摘要翻译： PCT No.PCT / US92 / 10736 Sec。 371日期：1994年10月12日 102（e）日期1994年10月12日PCT 1992年12月11日PCT公布。 出版物WO93 / 11868 日期：1993年6月24日本发明涉及包含具有7至9个碳原子的高度氟化的氯取代的非环状有机化合物的组合物及其制备和使用方法。 更具体地说，本发明涉及包含那些高度氟化的氯代取代的有机化合物的乳液。 本发明还涉及包含具有7至10个碳原子，优选7至9个碳原子的非环状全氟聚醚的乳液。 这些新型乳液具有各种医疗和氧气运输应用。 它们在医学上特别用作造影剂，用于诸如核磁共振，超声，X射线，计算机断层扫描，19F-磁共振成像和位置发射断层扫描的各种生物成像模式，作为氧运输剂或“人造血” 用于治疗心脏病发作，中风等血管阻塞，作为冠状动脉血管成形术和癌症放射治疗和化学疗法的佐剂。
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3.发明授权Fluorinated silylethynyl pentacene compounds and compositions and methods of making and using the same 有权氟化甲硅烷基乙炔并五苯化合物及其制备和使用方法公开(公告)号：US08920679B2
公开(公告)日：2014-12-30
申请号：US13318617
申请日：2010-05-28
申请人： Robert Steven Clough , Richard M. Flynn , George G. I. Moore , John E. Anthony , Marcia M. Payne
发明人： Robert Steven Clough , Richard M. Flynn , George G. I. Moore , John E. Anthony , Marcia M. Payne
CPC分类号： C07F7/081
摘要： Fluorinated silylethynyl pentacenes and compositions containing fluorinated silylethynyl pentacenes are disclosed. Methods of making and using fluorinated silylethynyl pentacenes and compositions containing fluorinated silylethynyl pentacenes are also disclosed.
摘要翻译： 公开了含氟化的甲硅烷基乙炔戊烯和含有氟化的甲硅烷基乙炔基并五苯的组合物。 还公开了制备和使用氟化甲硅烷基乙炔基并五苯的方法和含有氟化的甲硅烷基乙炔戊腈的组合物。
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公开(公告)号：US08222322B2
公开(公告)日：2012-07-17
申请号：US12684239
申请日：2010-01-08
申请人： Klaus Hintzer , Michael Jürgens , Harald Kaspar , Herbert Koenigsmann , Kai Helmut Lochhaas , Andreas R. Maurer , Werner Schwertfeger , Tilman Zipplies , Ludwig Mayer , Michael C Dadalas , George G. I. Moore , Jay F. Schulz , Richard M. Flynn
发明人： Klaus Hintzer , Michael Jürgens , Harald Kaspar , Herbert Koenigsmann , Kai Helmut Lochhaas , Andreas R. Maurer , Werner Schwertfeger , Tilman Zipplies , Ludwig Mayer , Michael C Dadalas , George G. I. Moore , Jay F. Schulz , Richard M. Flynn
IPC分类号： C08L1/00
CPC分类号： C08L27/12 , C08L71/02 , Y02C20/30 , C08L2666/22
摘要： A method of making a fluoropolymer dispersion by first providing a fluoropolymer dispersion comprising fluoropolymer particles and one or more fluorinated surfactants selected from fluorinated carboxylic acids or salts thereof having the general formula: [Rf—O-L-COO−]iXi+ (I) wherein L represents a linear fully fluorinated alkylene group, Rf represents a linear partially or fully fluorinated aliphatic group or a linear partially or fully fluorinated aliphatic group interrupted with one oxygen atom, Xi+ represents a cation having the valence i and i is 1, 2 or 3; then adding one or more non-fluorinated surfactants selected from anionic and non-ionic surfactants followed by reducing the total amount of the one or more fluorinated surfactants to an amount of not more than 500 ppm, for example not more than 250 ppm based on the total weight of the dispersion while maintaining or increasing the amount of solids in the dispersion.
摘要翻译： 首先提供含氟聚合物颗粒和一种或多种选自氟化羧酸或其盐的含氟表面活性剂的含氟聚合物分散体的制备方法，所述含氟聚合物分散体具有以下通式：[Rf-OL-COO-] iXi +（I）其中L表示 线性全氟化亚烷基，Rf表示直链部分或完全氟化的脂族基团或被一个氧原子间隔的直链部分或全氟化的脂族基团，X i +表示i为i且i为1,2或3的阳离子; 然后加入一种或多种选自阴离子和非离子表面活性剂的非氟化表面活性剂，然后将一种或多种氟化表面活性剂的总量减少至不超过500ppm，例如不超过250ppm，基于 分散体的总重量，同时保持或增加分散体中固体的量。
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公开(公告)号：US07754795B2
公开(公告)日：2010-07-13
申请号：US11420431
申请日：2006-05-25
申请人： Klaus Hintzer , Michael Jürgens , Harald Kaspar , Herbert Koenigsmann , Kai Helmut Lochhaas , Andreas R. Maurer , Werner Schwertfeger , Tilman Zipplies , Ludwig Mayer , Michael C. Dadalas , George G. I. Moore , Jay F. Schulz , Richard M. Flynn
发明人： Klaus Hintzer , Michael Jürgens , Harald Kaspar , Herbert Koenigsmann , Kai Helmut Lochhaas , Andreas R. Maurer , Werner Schwertfeger , Tilman Zipplies , Ludwig Mayer , Michael C. Dadalas , George G. I. Moore , Jay F. Schulz , Richard M. Flynn
IPC分类号： C08K5/00
CPC分类号： C09D127/18 , C08K5/06 , C08K5/09 , C08L27/12 , C08L71/02 , C08L2205/02 , C08L2205/03 , C08L2205/035 , C08L2666/02 , C08L2666/14
摘要： A coating composition having (i) an aqueous dispersion of fluoropolymer particles comprising a non-melt processible polymer of tetrafluoroethylene, (ii) a fluorinated surfactant, (iii) a non-ionic non-fluorinated surfactant and (iv) a non-fluorinated polymer, wherein the fluorinated surfactant is selected from fluorinated carboxylic acids or salts thereof of the general formula (I): [Rf—O-L-COO−]iXi+ (I) wherein L represents a linear partially or fully fluorinated alkylene group or an aliphatic hydrocarbon group, Rf represents a linear partially or fully fluorinated aliphatic group or a linear partially or fully fluorinated aliphatic group interrupted with one or more oxygen atoms, Xi+ represents a cation having the valence i and i is 1, 2 or 3.
摘要翻译： 一种涂料组合物，其具有（i）含氟聚合物颗粒的水分散体，其包含四氟乙烯的不可熔融加工聚合物，（ii）氟化表面活性剂，（iii）非离子非氟化表面活性剂和（iv）非氟化聚合物 其中氟化表面活性剂选自通式（I）的氟化羧酸或其盐：[Rf-OL-COO-] iXi +（I）其中L表示直链部分或完全氟化的亚烷基或脂族烃基 Rf表示直链部分或完全氟化的脂族基团或被一个或多个氧原子间隔的线性部分或全部氟化的脂肪族基团，Xi +表示i为i且i为1,2或3的阳离子。
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公开(公告)号：US06649719B2
公开(公告)日：2003-11-18
申请号：US09931215
申请日：2001-08-16
IPC分类号： C08F1418
CPC分类号： C09D133/16 , C07C69/63 , C08F20/24 , C08F120/24
摘要： Described is a compound having at least one acrylate monomer, said monomer including at least one pendant group of the structure —O—CH(Rf)(Rf′), wherein Rf is a straight chain or branched perfluoroalkyl group with five or less carbon atoms, and Rf′ is a branched perfluoroalkyl group with three to five carbon atoms; and a method of reducing the surface tension of a liquid by adding a compound of the invention to the liquid. Also described is a composition that includes a compound of the invention in an aqueous solution or dispersion; a method of treating a substrate to render it oil- and/or water-repellent that includes treating a substrate with a composition of the invention; a method of coating an electrical device that includes applying a composition of the invention; a method of coating optical fibers that includes applying a composition of the invention; and an article that includes a substrate treated with a composition of the invention.
摘要翻译： 描述了具有至少一种丙烯酸酯单体的化合物，所述单体包括至少一个-O-CH（Rf）（Rf'）结构的侧基，其中Rf是具有五个或更少碳原子的直链或支链全氟烷基 ，Rf'为3〜5个碳原子的支链全氟烷基; 以及通过将本发明的化合物加入到液体中来降低液体的表面张力的方法。 还描述了在水溶液或分散体中包含本发明化合物的组合物; 处理基材以使其具有油和/或防水性的方法，其包括用本发明的组合物处理基材; 包括施用本发明的组合物的电气装置的涂覆方法; 涂布光纤的方法，其包括施加本发明的组合物; 以及包含用本发明的组合物处理的基材的制品。
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7.发明授权公开(公告)号：US06506459B2
公开(公告)日：2003-01-14
申请号：US10028217
申请日：2001-12-20
IPC分类号： C08J704
CPC分类号： C07C43/12 , C07C43/126 , C07C2601/14 , C07D207/10 , C07D211/38 , C07D265/30 , C11D7/28 , C11D7/3281 , C11D7/34 , C11D7/5009 , C11D7/5013 , C11D7/5018 , C23G5/032 , D06L1/02
摘要： A process for removing contaminants from the surface of a substrate comprises contacting the substrate with a cleaning composition comprising at least one mono-, di-, or trialkoxy-substituted perfluoroalkane, perfluorocycloalkane, perfluorocycloalkyl-containing perfluoroalkane, or perfluorocycloalkylene-containing perfluoroalkane compound, the compound optionally containing additional catenary heteroatoms. The compounds exhibit good solvency properties while being environmentally acceptable.
摘要翻译： 用于从基材表面除去污染物的方法包括使基材与包含至少一种单 - ，二 - 或三 - 烷氧基取代的全氟烷烃，全氟环烷烃，含全氟环烷基的全氟烷烃或含全氟环亚烷基的全氟烷烃化合物的清洁组合物接触， 化合物任选地含有另外的链状杂原子。 该化合物在环境可接受性方面表现出良好的溶解性能。
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公开(公告)号：US06376452B1
公开(公告)日：2002-04-23
申请号：US09282815
申请日：1999-03-31
IPC分类号： C11D324
CPC分类号： C07D265/30 , C07C43/12 , C07C43/126 , C07C2601/14 , C07D207/10 , C07D211/38 , C11D7/28 , C11D7/3281 , C11D7/34 , C11D7/5009 , C11D7/5013 , C11D7/5018 , C23G5/032
摘要： A process for removing contaminants from the surface of a substrate comprises contacting the substrate with a cleaning composition comprising at least one mono-, di-, or trialkoxy-substituted perfluoroalkane, perfluorocycloalkane, perfluorocycloalkyl-containing perfluoroalkane, or perfluorocycloalkylene-containing perfluoroalkane compound, the compound optionally containing additional catenary heteroatoms. The compounds exhibit good solvency properties while being environmentally acceptable.
摘要翻译： 用于从基材表面除去污染物的方法包括使基材与包含至少一种单 - ，二 - 或三 - 烷氧基取代的全氟烷烃，全氟环烷烃，含全氟环烷基的全氟烷烃或含全氟环亚烷基的全氟烷烃化合物的清洁组合物接触， 化合物任选地含有另外的链状杂原子。 该化合物在环境可接受性方面表现出良好的溶解性能。
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公开(公告)号：US07671112B2
公开(公告)日：2010-03-02
申请号：US11420386
申请日：2006-05-25
申请人： Klaus Hintzer , Michael Jürgens , Harald Kaspar , Herbert Koenigsmann , Kai Helmut Lochhaas , Andreas R. Maurer , Werner Schwertfeger , Tilman Zipplies , Ludwig Mayer , Michael C. Dadalas , George G. I. Moore , Jay F. Schulz , Richard M. Flynn
发明人： Klaus Hintzer , Michael Jürgens , Harald Kaspar , Herbert Koenigsmann , Kai Helmut Lochhaas , Andreas R. Maurer , Werner Schwertfeger , Tilman Zipplies , Ludwig Mayer , Michael C. Dadalas , George G. I. Moore , Jay F. Schulz , Richard M. Flynn
IPC分类号： C08L1/00
CPC分类号： C08L27/12 , C08L71/02 , Y02C20/30 , C08L2666/22
摘要： A method of making a fluoropolymer dispersion by first providing a fluoropolymer dispersion comprising fluoropolymer particles and one or more fluorinated surfactants selected from fluorinated carboxylic acids or salts thereof having the general formula: [Rf—O-L-COO−]iXi+ (I) wherein L represents a linear partially or fully fluorinated alkylene group or an aliphatic hydrocarbon group, Rf represents a linear partially or fully fluorinated aliphatic group or a linear partially or fully fluorinated aliphatic group interrupted with one or more oxygen atoms, Xi+ represents a cation having the valence i and i is 1, 2 or 3; then adding one or more non-fluorinated surfactants selected from anionic and non-ionic surfactants followed by reducing the total amount of the one or more fluorinated surfactants to an amount of not more than 500 ppm, for example not more than 250 ppm based on the total weight of the dispersion while maintaining or increasing the amount of solids in the dispersion.
摘要翻译： 首先提供含氟聚合物颗粒和一种或多种选自氟化羧酸或其盐的含氟表面活性剂的含氟聚合物分散体的制备方法，所述含氟聚合物分散体具有以下通式：[Rf-OL-COO-] iXi +（I）其中L表示 线性部分或完全氟化的亚烷基或脂族烃基，Rf表示直链部分或完全氟化的脂族基团或被一个或多个氧原子间隔的线性部分或全部氟化脂族基，X i +表示具有i价和 我是1,2或3; 然后加入一种或多种选自阴离子和非离子表面活性剂的非氟化表面活性剂，然后将一种或多种氟化表面活性剂的总量减少至不超过500ppm，例如不超过250ppm，基于 分散体的总重量，同时保持或增加分散体中固体的量。
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公开(公告)号：US07385089B2
公开(公告)日：2008-06-10
申请号：US11567398
申请日：2006-12-06
IPC分类号： C07C49/173 , C07C43/00 , C10M107/34 , C09K5/04
CPC分类号： C07C49/175 , C08G65/007
摘要： A fluorochemical ketone compound consists of two terminal, branched, independently fluoroalkylcarbonyl or perfluoroalkylcarbonyl groups and an intervening linear perfluoropolyether segment, each of the terminal groups optionally comprising at least one catenated heteroatom, and the perfluoropolyether segment consisting essentially of at least one tetrafluoroethyleneoxy moiety and, optionally, at least one difluoromethyleneoxy moiety, the moieties being randomly or non-randomly distributed within the perfluoropolyether segment.
摘要翻译： 含氟酮化合物由两个末端，支链，独立的氟代烷基羰基或全氟烷基羰基和插入的直链全氟聚醚链段组成，每个末端基团任选地包含至少一个连接的杂原子，并且全氟聚醚链段主要由至少一个四氟乙烯氧基部分组成， 任选地，至少一个二氟亚甲基氧基部分，所述部分是随机或非随机分布在全氟聚醚部分内。
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