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公开(公告)号:US20120070575A1
公开(公告)日:2012-03-22
申请号:US13302633
申请日:2011-11-22
申请人: Robert O. Hagerty , Kevin B. Stavens , Randall B. Laird , Zerong Lin , Michael E. Muhle , Agapios K. Agapiou , David M. Glowczwski , Fathi D. Hussein , Gary D. Mohr , Ted A. Powell , Michael E. Sieloff , Edward F. Smith , Keith W. Trapp
发明人: Robert O. Hagerty , Kevin B. Stavens , Randall B. Laird , Zerong Lin , Michael E. Muhle , Agapios K. Agapiou , David M. Glowczwski , Fathi D. Hussein , Gary D. Mohr , Ted A. Powell , Michael E. Sieloff , Edward F. Smith , Keith W. Trapp
CPC分类号: C08F10/00 , C08F110/02 , Y02P20/582 , C08F2/005 , C08F2/34 , C08F2/004
摘要: A method for treating at least one interior surface (for example, a bed wall) of a fluidized bed polymerization reactor system, including by applying a solution catalyst (preferably at least substantially uniformly and in liquid form) to each surface, and optionally (where a catalyst component of the solution catalyst comprises at least one chromium containing compound) oxidizing at least some of the applied chromium containing compound in a controlled manner.
摘要翻译: 一种用于处理流化床聚合反应器系统的至少一个内表面(例如床壁)的方法,包括通过将溶液催化剂(优选至少基本上均匀且液体形式)施加到每个表面,以及任选地(其中 溶液催化剂的催化剂组分包含至少一种含铬化合物)以受控的方式氧化至少一些所施加的含铬化合物。
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公开(公告)号:US08088870B2
公开(公告)日:2012-01-03
申请号:US12529580
申请日:2008-02-21
申请人: Robert O. Hagerty , Kevin B. Stavens , Randall B. Laird , Zerong Lin , Michael E. Muhle , Agapios K. Agapiou , David M. Glowczwski , Fathi D. Hussein , Gary D. Mohr , Ted A. Powell , Michael E. Sieloff , Edward F. Smith , Keith W. Trapp
发明人: Robert O. Hagerty , Kevin B. Stavens , Randall B. Laird , Zerong Lin , Michael E. Muhle , Agapios K. Agapiou , David M. Glowczwski , Fathi D. Hussein , Gary D. Mohr , Ted A. Powell , Michael E. Sieloff , Edward F. Smith , Keith W. Trapp
CPC分类号: C08F10/00 , C08F110/02 , Y02P20/582 , C08F2/005 , C08F2/34 , C08F2/004
摘要: A method for treating at least one interior surface (for example, a bed wall) of a fluidized bed polymerization reactor system, including by applying a solution catalyst (preferably at least substantially uniformly and in liquid form) to each surface, and optionally (where a catalyst component of the solution catalyst comprises at least one chromium containing compound) oxidizing at least some of the applied chromium containing compound in a controlled manner.
摘要翻译: 一种用于处理流化床聚合反应器系统的至少一个内表面(例如床壁)的方法,包括通过将溶液催化剂(优选至少基本上均匀且液体形式)施加到每个表面,以及任选地(其中 溶液催化剂的催化剂组分包含至少一种含铬化合物)以受控的方式氧化至少一些所施加的含铬化合物。
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公开(公告)号:US08129481B1
公开(公告)日:2012-03-06
申请号:US13302633
申请日:2011-11-22
申请人: Robert O. Hagerty , Kevin B. Stavens , Randall B. Laird , Zerong Lin , Michael E. Muhle , Agapios K. Agapiou , David M. Glowczwski , Fathi D. Hussein , Gary D. Mohr , Ted A. Powell , Michael E. Sieloff , Edward F. Smith , Keith W. Trapp
发明人: Robert O. Hagerty , Kevin B. Stavens , Randall B. Laird , Zerong Lin , Michael E. Muhle , Agapios K. Agapiou , David M. Glowczwski , Fathi D. Hussein , Gary D. Mohr , Ted A. Powell , Michael E. Sieloff , Edward F. Smith , Keith W. Trapp
IPC分类号: C08F2/00 , C08F4/06 , C08F210/00 , B01J8/18
CPC分类号: C08F10/00 , C08F110/02 , Y02P20/582 , C08F2/005 , C08F2/34 , C08F2/004
摘要: A method for treating at least one interior surface (for example, a bed wall) of a fluidized bed polymerization reactor system, including by applying a solution catalyst (preferably at least substantially uniformly and in liquid form) to each surface, and optionally (where a catalyst component of the solution catalyst comprises at least one chromium containing compound) oxidizing at least some of the applied chromium containing compound in a controlled manner.
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公开(公告)号:US20100184927A1
公开(公告)日:2010-07-22
申请号:US12529580
申请日:2008-02-21
申请人: Robert O. Hagerty , Kevin B. Stavens , Randall B. Laird , Zerong Lin , Michael E. Muhle , Agapios K. Agapiou , David M. Glowczwski , Fathi D. Hussein , Gary D. Mohr , Ted A. Powell , Michael E. Sieloff , Edward F. Smith , Keith W. Trapp
发明人: Robert O. Hagerty , Kevin B. Stavens , Randall B. Laird , Zerong Lin , Michael E. Muhle , Agapios K. Agapiou , David M. Glowczwski , Fathi D. Hussein , Gary D. Mohr , Ted A. Powell , Michael E. Sieloff , Edward F. Smith , Keith W. Trapp
IPC分类号: C08F2/01
CPC分类号: C08F10/00 , C08F110/02 , Y02P20/582 , C08F2/005 , C08F2/34 , C08F2/004
摘要: A method for treating at least one interior surface (for example, a bed wall) of a fluidized bed polymerization reactor system, including by applying a solution catalyst (preferably at least substantially uniformly and in liquid form) to each surface, and optionally (where a catalyst component of the solution catalyst comprises at least one chromium containing compound) oxidizing at least some of the applied chromium containing compound in a controlled manner.
摘要翻译: 一种用于处理流化床聚合反应器系统的至少一个内表面(例如床壁)的方法,包括通过将溶液催化剂(优选至少基本上均匀且液体形式)施加到每个表面,以及任选地(其中 溶液催化剂的催化剂组分包含至少一种含铬化合物)以受控的方式氧化至少一些所施加的含铬化合物。
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公开(公告)号:US07423103B2
公开(公告)日:2008-09-09
申请号:US11629502
申请日:2005-06-20
申请人: Kevin B. Stavens , Robert O. Hagerty , Randall B. Laird , Zerong Lin , Michael A. Risch , Larry L. Iaccino
发明人: Kevin B. Stavens , Robert O. Hagerty , Randall B. Laird , Zerong Lin , Michael A. Risch , Larry L. Iaccino
CPC分类号: C08F210/16 , C07C17/389 , C07C19/08 , C07C19/10 , C07C21/18 , C08F4/65916 , C08F4/65925 , C08F4/65927 , C08F110/02 , C08F2410/01 , C08F2410/02 , Y02P20/127 , Y10S526/912 , C08F4/69 , C08F2/06 , C08F4/6493 , C08F4/6555 , C08F4/651 , C08F4/65912 , C08F2/14 , C08F210/08 , C08F210/14
摘要: This invention is directed to a polymerization process that is carried out at relatively high productivity levels and with relatively low fouling. The process includes mixing together a catalyst system, at least one monomer and a hydrofluorocarbon to produce the polymer. The reaction is carried out such that little to no chlorine containing hydrocarbons are present.
摘要翻译: 本发明涉及一种聚合方法,其以较高的生产率和较低的结垢进行。 该方法包括将催化剂体系,至少一种单体和氢氟烃混合在一起以产生聚合物。 进行反应,使得存在少至不含氯的烃。
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公开(公告)号:US07985811B2
公开(公告)日:2011-07-26
申请号:US12217945
申请日:2008-07-10
申请人: Robert O. Hagerty , Michael E. Muhle , Agapios K. Agapiou , Chi-I Kuo , Mark G. Goode , F. David Hussein , Richard B. Pannell , John F. Szul
发明人: Robert O. Hagerty , Michael E. Muhle , Agapios K. Agapiou , Chi-I Kuo , Mark G. Goode , F. David Hussein , Richard B. Pannell , John F. Szul
CPC分类号: B01J8/1809 , B01J19/002 , B01J2208/00256 , B01J2208/00274 , B01J2208/00734 , B01J2208/00761 , B01J2219/00254 , C08F10/00 , C08F210/16 , C08F2400/02 , C08F2/00 , C08F2/002 , C08F2/34 , C08F210/14
摘要: Embodiments of the present invention relate to measuring and controlling static in a gas phase reactor polymerization. In particular, embodiments relate to monitoring carryover static in an entrainment zone during gas phase polymerization to determine the onset of reactor discontinuity events such as chunking and sheeting. Embodiments also relate to monitoring carryover static to determine the need for effective additions of continuity additives that minimize reactor static activity and thereby preventing discontinuity events.
摘要翻译: 本发明的实施例涉及测量和控制气相反应器聚合中的静电。 特别地,实施方案涉及在气相聚合期间监测夹带区域中的静态滞留,以确定反应器不连续事件(例如分块和片材)的开始。 实施例还涉及监测携带静电以确定需要有效添加连续性添加剂,其使反应堆静态活性最小化,从而防止不连续事件。
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公开(公告)号:US20090018279A1
公开(公告)日:2009-01-15
申请号:US12217945
申请日:2008-07-10
申请人: Robert O. Hagerty , Michael E. Muhle , Agapios K. Agapiou , Chi-I Kuo , Mark G. Goode , F. David Hussein , Richard B. Pannell , John F. Szul
发明人: Robert O. Hagerty , Michael E. Muhle , Agapios K. Agapiou , Chi-I Kuo , Mark G. Goode , F. David Hussein , Richard B. Pannell , John F. Szul
CPC分类号: B01J8/1809 , B01J19/002 , B01J2208/00256 , B01J2208/00274 , B01J2208/00734 , B01J2208/00761 , B01J2219/00254 , C08F10/00 , C08F210/16 , C08F2400/02 , C08F2/00 , C08F2/002 , C08F2/34 , C08F210/14
摘要: Embodiments of the present invention relate to measuring and controlling static in a gas phase reactor polymerization. In particular, embodiments relate to monitoring carryover static in an entrainment zone during gas phase polymerization to determine the onset of reactor discontinuity events such as chunking and sheeting. Embodiments also relate to monitoring carryover static to determine the need for effective additions of continuity additives that minimize reactor static activity and thereby preventing discontinuity events.
摘要翻译: 本发明的实施例涉及测量和控制气相反应器聚合中的静电。 特别地,实施方案涉及在气相聚合期间监测夹带区域中的静态滞留,以确定反应器不连续事件(例如分块和片材)的开始。 实施例还涉及监测携带静电以确定需要有效添加连续性添加剂,其使反应堆静态活性最小化,从而防止不连续事件。
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公开(公告)号:US07342079B2
公开(公告)日:2008-03-11
申请号:US11629413
申请日:2005-06-20
CPC分类号: C08F6/003 , C08F10/00 , C08F110/06 , C08L23/00 , C08F2/06 , C08F2/00 , C08F4/6493 , C08F2500/12 , C08F2500/05 , C08F2500/15
摘要: This invention is directed to processes for making polymer in the presence of a hydrofluorocarbon, and for the recovery of polymer substantially free of dissolved hydrocarbons and hydrofluorocarbons. The processes provided enables polymerization processes to be practiced with minimal fouling in the reaction system, and with the recovery of the hydrofluorocarbon and monomers for reuse in the reactor. The process of the invention utilizes a reactor system, a recovery system and a flare system that minimize environmental emissions of hydrocarbons, hydrofluorocarbons and associated decomposition products.
摘要翻译: 本发明涉及在氢氟烃存在下制备聚合物的方法,以及用于回收基本上不含溶解的烃和氢氟烃的聚合物。 所提供的方法使聚合方法能够在反应体系中以最小的结垢进行,并且通过回收氢氟烃和单体以在反应器中重新使用。 本发明的方法利用反应器系统,回收系统和火炬系统,其最小化碳氢化合物,氢氟烃和相关分解产物的环境排放。
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公开(公告)号:US07728084B2
公开(公告)日:2010-06-01
申请号:US11628904
申请日:2005-06-20
申请人: Robert O. Hagerty , Chia S. Chee , Randall B. Laird , Michael A. Risch , Pradeep P. Shirodkar , Zerong Lin , Larry L. Iaccino
发明人: Robert O. Hagerty , Chia S. Chee , Randall B. Laird , Michael A. Risch , Pradeep P. Shirodkar , Zerong Lin , Larry L. Iaccino
IPC分类号: C08F4/44
CPC分类号: C08F10/00 , C08F110/06 , C08F210/16 , C08F2/06 , C08F2/14 , C08F2500/01 , C08F2500/20 , C08F2500/12 , C08F210/08 , C08F2500/03 , C08F2500/24 , C08F210/14
摘要: This invention is directed to processes of making polymer in the presence of a hydrofluorocarbon or perfluorocarbon and recovering the polymer. The processes provided enable polymerization processes to be practiced with minimal fouling in the reaction system, and to the recovery of the hydrofluorocarbon and other hydrocarbons such as hydrocarbons for reuse in the process or hydrocarbon by-products from the polymerization process. The invention is particularly beneficial in the production of ethylene based polymers using Ziegler Natta catalyst systems.
摘要翻译: 本发明涉及在氢氟碳化合物或全氟化碳存在下制备聚合物并回收聚合物的方法。 所提供的方法使聚合方法能够在反应体系中以最小的结垢进行聚合反应,以及回收氢氟烃和其它烃,例如在该方法中重新使用的烃或来自聚合方法的烃副产物。 本发明特别有益于使用齐格勒纳塔催化剂体系生产基于乙烯的聚合物。
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公开(公告)号:US07491776B2
公开(公告)日:2009-02-17
申请号:US11628907
申请日:2005-06-20
申请人: Robert O. Hagerty , Chia S. Chee , Randall B. Laird , Michael A. Risch , Pradeep P. Shirodkar , Zerong Lin , Larry L. Iaccino
发明人: Robert O. Hagerty , Chia S. Chee , Randall B. Laird , Michael A. Risch , Pradeep P. Shirodkar , Zerong Lin , Larry L. Iaccino
CPC分类号: C08F210/16 , C08F110/02 , C08F2410/01 , C08F2/06 , C08F2/14 , C08F4/69 , C08F2/002 , C08F2500/20 , C08F2500/12 , C08F210/14
摘要: This invention is directed to processes of making polymer in the presence of a hydrofluorocarbon or perfluorocarbon and recovering the polymer. The processes provided enable polymerization processes to be practiced with minimal fouling in the reaction system, and provide polymer products that can be manufactured to relatively low densities. The invention is particularly beneficial in the production of ethylene based polymers using chromium catalyst systems.
摘要翻译: 本发明涉及在氢氟碳化合物或全氟化碳存在下制备聚合物并回收聚合物的方法。 所提供的方法使聚合方法能够在反应体系中以最小的结垢进行,并且提供可制成相对较低密度的聚合物产物。 本发明特别有利于使用铬催化剂体系生产基于乙烯的聚合物。
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