公开(公告)号：US4289071A

公开(公告)日：1981-09-15

申请号：US74700

申请日：1979-09-12

申请人： Robert W. Hallman ,  Koichi Kimoto ,  Sakuo Okai

发明人： Robert W. Hallman ,  Koichi Kimoto ,  Sakuo Okai

IPC分类号： B41N1/12 ,  G03C1/76 ,  G03F7/115 ,  B41N1/06 ,  B41C1/00

CPC分类号： B41N1/12 ,  G03C1/7614 ,  G03F7/115

摘要： A shallow relief non-bottoming printing plate is disclosed having a polymerized layer of less than about 0.020 inch and which includes a plurality of dispersed particles sufficient to create small protuberances in non-image or background areas to prevent bottoming. Photopolymerizable elements, as well as processing techniques, are also disclosed for making such printing plates.

摘要翻译： 公开了一种浅浮雕非底印版，其具有小于约0.020英寸的聚合层，并且其包括足以在非图像或背景区域中产生小突起以防止底部的多个分散颗粒。 光聚合元件以及加工技术也被公开用于制造这种印版。

公开(公告)号：US4283481A

公开(公告)日：1981-08-11

申请号：US161757

申请日：1980-06-23

申请人： Sakuo Okai ,  Koichi Kimoto

发明人： Sakuo Okai ,  Koichi Kimoto

IPC分类号： G03F7/027 ,  G03C1/78

CPC分类号： G03F7/027 ,  Y10S430/151

摘要： A photopolymerizable composition and photosensitive elements produced therefrom are disclosed. The photopolymerizable composition includes: (a) a monomer component, (b) a polymer component, (c) a photopolymerization initiator, and (d) an activator.The monomer component contains at least one water soluble, monofunctional unsaturated ethylenic monomer or the combination of such a monomer and at least one polyfunctional unsaturated ethylenic monomer.The polymer component includes a partially saponified water soluble, polyvinyl acetate polymer compatible with the monomer components. The polyvinyl acetate polymer contains both acetyl and hydroxyl groups and has a polymerization degree of from 300-2000. The degree of saponification of the polymer is desirably in the range of 65 to 99 percent.The preferred photopolymerizaton initiators are acetophenone derivatives such as 2,2-dimethoxy-2-phenyl acetopheonone, 2,2-diethoxy-2-phenyl acetophenone, 2,-2-diisopropoxy-2-phenyl acetophenone, benzoin alkyl, aryl, allyl or vinyl ethers, or benzophenone derivatives such as benzophenone, 2-methylbenzophenone, 2-methoxybenzophenone or 2,2'-dimethoxybenzophenone, which are compatible with the monomer component and the polyvinyl acetate polymer and are activatable by actinic light.Finally, the activator is a phosphine derivative generally described by the formula: ##STR1## wherein any of X, Y and Z are hydrogen, halogen, alkyl, alkoxy, aryl, vinyl, or allyl, although not more than one of X, Y and Z may be hydrogen. It is especially preferred in the practice of the present invention that at least one of X, Y or Z in the phosphine derivative activator component be an aryl group.

摘要翻译： 公开了可光聚合组合物和由其制备的感光元件。 可光聚合组合物包括：（a）单体组分，（b）聚合物组分，（c）光聚合引发剂和（d）活化剂。 单体组分含有至少一种水溶性单官能不饱和烯属单体或这种单体与至少一种多官能不饱和烯属单体的组合。 聚合物组分包括与单体组分相容的部分皂化的水溶性聚乙酸乙烯酯聚合物。 聚乙酸乙烯酯聚合物含有乙酰基和羟基，聚合度为300-2000。 聚合物的皂化度优选在65-99％的范围内。 优选的光聚合引发剂是苯乙酮衍生物，例如2,2-二甲氧基-2-苯基苯乙酮，2,2-二乙氧基-2-苯基苯乙酮，2,2-二异丙氧基-2-苯基苯乙酮，苯偶姻烷基，芳基，烯丙基或 乙烯基醚或二苯甲酮衍生物，例如二苯甲酮，2-甲基二苯甲酮，2-甲氧基二苯甲酮或2,2'-二甲氧基二苯甲酮，其与单体组分和聚乙酸乙烯酯聚合物相容并且可通过光化光活化。 最后，活化剂是一般通式如下的膦衍生物：其中X，Y和Z中的任何一个是氢，卤素，烷基，烷氧基，芳基，乙烯基或烯丙基，尽管不超过X，Y Z可以是氢。 在本发明的实践中，特别优选的是，膦衍生物活化剂组分中的X，Y或Z中的至少一个为芳基。

公开(公告)号：US4164422A

公开(公告)日：1979-08-14

申请号：US834086

申请日：1977-09-19

申请人： Sakuo Okai ,  Koichi Kimoto

发明人： Sakuo Okai ,  Koichi Kimoto

IPC分类号： B41N1/00 ,  G03F7/075 ,  G03C1/76 ,  G03C1/94 ,  G03F7/02

CPC分类号： B41N1/003 ,  G03F7/0752

摘要： Letterpress and offset photopolymer printing plates are disclosed having relatively thin water developable photopolymer layers, which, after being developed, have ink-repulsive, non-image areas. Adhesive layers are provided in the disclosed printing plates that are interposed between an ink-repulsive coating contained in the printing plate substrate and the water-developable photopolymer, and provide a balance between satisfactory adhesive and ink-repulsive properties in the resulting plate.

摘要翻译： 公开了具有相对薄的水显影性光聚合物层的PG，1凸版印刷版和偏移光聚合物印刷版，其在显影之后具有墨排斥性非图像区域。 在所公开的印刷板中设置粘合剂层，该印刷板介于包含在印刷版印刷基板中的墨水排斥涂层和水显影性光聚合物之间，并且在所得到的印版中提供令人满意的粘合剂和墨水排斥性能之间的平衡。

公开(公告)号：US4233391A

公开(公告)日：1980-11-11

申请号：US70190

申请日：1979-08-27

申请人： Sakuo Okai ,  Koichi Kimoto

发明人： Sakuo Okai ,  Koichi Kimoto

IPC分类号： G03F7/029 ,  G03C1/68

CPC分类号： G03F7/029 ,  Y10S430/106 ,  Y10S430/11 ,  Y10S430/118

摘要： A photopolymerizable composition and photosensitive elements produced therefrom are disclosed. The photopolymerizable composition includes: (a) a monomer component, (b) a polymer component, (c) a photopolymerization initiator, and (d) an activator.The monomer component contains at least one water soluble, monofunctional unsaturated ethylenic monomer or the combination of such a monomer and at least one polyfunctional unsaturated ethylenic monomer.The polymer component includes a partially saponified water soluble, polyvinyl acetate polymer compatible with the monomer components. The polyvinyl acetate polymer contains both acetyl and hydroxyl groups and has a polymerization degree of from 300-2000. The degree of saponification of the polymer is desirably in the range of 65 to 99 percent.The preferred photopolymerization initiators are acetophenone derivatives such as 2,2-dimethoxy-2-phenyl acetophenone, 2,2-diethoxy-2-phenyl acetophenone, 2,-2-diisopropoxy-2-phenyl acetophenone, benzoin alkyl, aryl, allyl or vinyl ethers, or benzophenone derivatives such as benzophenone, 2-methylbenzophenone, 2-methoxybenzophenone or 2,2'-dimethoxybenzophenone, which are compatible with the monomer component and the polyvinyl acetate polymer and are activatable by actinic light.Finally, the activator is a phosphine derivative generally described by the formula: ##STR1## wherein any of X, Y and Z are hydrogen, halogen, alkyl, alkoxy, aryl, vinyl, or allyl, although not more than one or X, Y and Z may be hydrogen. It is especially preferred in the practice of the present invention that at least one of X, Y and Z in the phosphine derivative activator component be an aryl group.

摘要翻译： 公开了可光聚合组合物和由其制备的感光元件。 可光聚合组合物包括：（a）单体组分，（b）聚合物组分，（c）光聚合引发剂和（d）活化剂。 单体组分含有至少一种水溶性单官能不饱和烯属单体或这种单体与至少一种多官能不饱和烯属单体的组合。 聚合物组分包括与单体组分相容的部分皂化的水溶性聚乙酸乙烯酯聚合物。 聚乙酸乙烯酯聚合物含有乙酰基和羟基，聚合度为300-2000。 聚合物的皂化度优选在65-99％的范围内。 优选的光聚合引发剂是苯乙酮衍生物，例如2,2-二甲氧基-2-苯基苯乙酮，2,2-二乙氧基-2-苯基苯乙酮，2,2-二异丙氧基-2-苯基苯乙酮，苯偶姻烷基，芳基，烯丙基或 乙烯基醚或二苯甲酮衍生物，例如二苯甲酮，2-甲基二苯甲酮，2-甲氧基二苯甲酮或2,2'-二甲氧基二苯甲酮，其与单体组分和聚乙酸乙烯酯聚合物相容并且可通过光化光活化。 最后，活化剂是一般通式如下的膦衍生物：其中X，Y和Z中的任一个是氢，卤素，烷基，烷氧基，芳基，乙烯基或烯丙基，尽管不大于1或X，Y Z可以是氢。 在本发明的实践中，特别优选的是，膦衍生物活化剂组分中的X，Y和Z中的至少一个是芳基。

公开(公告)号：US4042386A

公开(公告)日：1977-08-16

申请号：US693306

申请日：1976-06-07

申请人： Sakuo Okai ,  Koichi Kimoto

发明人： Sakuo Okai ,  Koichi Kimoto

IPC分类号： C08F2/50 ,  G03F7/027 ,  G03C1/68

CPC分类号： G03F7/027

摘要： A photopolymerizable composition and photosensitive elements produced therefrom are disclosed which include a monomer component, a polymer component and a polymerization initiator activatable by actinic light. The monomer component includes at least one water soluble monofunctional unsaturated ethylenic monomer, and at least one polyfunctional unsaturated ethylenic monomer. The polymer component includes a partially saponified, water-soluble, polyvinyl acetate which is compatible with said monomer components. The ratio, by weight, of polyfunctional monomer to monofunctional monomer is in the range of about 0.2 to about 0.6, and the ratio, by weight, of said monomer component to said polymer component is in the range of about 0.7 to about 1.2.

摘要翻译： 公开了可光聚合组合物和由其制备的感光元件，其包括单体组分，聚合物组分和可通过光化剂活化的聚合引发剂。 单体组分包括至少一种水溶性单官能不饱和烯属单体和至少一种多官能不饱和烯属单体。 聚合物组分包括与所述单体组分相容的部分皂化的水溶性聚乙酸乙烯酯。 多官能单体与单官能单体的重量比在约0.2至约0.6的范围内，所述单体组分与所述聚合物组分的重量比在约0.7至约1.2的范围内。

公开(公告)号：US4115123A

公开(公告)日：1978-09-19

申请号：US761975

申请日：1977-01-24

申请人： Sakuo Okai ,  Shozo Tsuchida

发明人： Sakuo Okai ,  Shozo Tsuchida

IPC分类号： G03F7/20 ,  G03F7/30 ,  G03C1/68

CPC分类号： G03F7/30 ,  G03F7/2022

摘要： A shallow relief printing plate is disclosed having a polymerized layer of less than about 0.020 inch and which includes an array of small protuberances in non-image or background areas to prevent bottoming. Photopolymerizable elements, as well as processing techniques, are also disclosed for making such printing plates.

公开(公告)号：US4115119A

公开(公告)日：1978-09-19

申请号：US761974

申请日：1977-01-24

申请人： Sakuo Okai ,  Shozo Tsuchida

发明人： Sakuo Okai ,  Shozo Tsuchida

IPC分类号： G03F7/20 ,  G03F7/30 ,  G03C5/00

CPC分类号： G03F7/30 ,  G03F7/2022

摘要： A shallow relief printing plate is disclosed having a polymerized layer of less than about 0.020 inch and which includes an array of small protuberances in non-image or background areas to prevent bottoming. Photopolymerizable elements, as well as processing techniques, are also disclosed for making such printing plates.

摘要翻译： 公开了一种浅浮雕印版，其具有小于约0.020英寸的聚合层，并且包括非图像或背景区域中的小突起阵列以防止底部。 光聚合元件以及加工技术也被公开用于制造这种印版。

公开(公告)号：US3981583A

公开(公告)日：1976-09-21

申请号：US390874

申请日：1973-08-23

申请人： Shozo Tsuchida ,  Sakuo Okai

发明人： Shozo Tsuchida ,  Sakuo Okai

IPC分类号： G03F7/30 ,  G03B27/30

CPC分类号： G03F7/3042

摘要： An apparatus for processing photopolymer plates includes an exposure unit, a washing unit, and a drying unit. The plate, which has a water-developable photopolymer surface, is continuously conveyed through each unit so that the functions therein performed, are done automatically. More particularly, exposure is accomplished by bringing a negative photographic image into alignment with the water-developable photopolymer plate, and then passing light through the negative and onto portions of the plate. Unexposed areas of the plate are then washed away in the washing unit, thus producing a relief surface necessary for letter-press printing. Finally, the photopolymer plate is conveyed to the drying unit where drying and postcuring take place.

摘要翻译： 用于处理光聚合物板的设备包括曝光单元，洗涤单元和干燥单元。 具有水显影性光聚合物表面的板被连续输送通过每个单元，使得其中所执行的功能被自动完成。 更具体地，曝光是通过使负照相图像与水显影性光聚合物板对准，然后使光通过阴极和板的部分来实现的。 然后在洗涤单元中冲洗板的未曝光区域，从而产生用于信纸印刷所需的浮雕表面。 最后，将光聚合物板输送到干燥单元，在其中进行干燥和后固化。