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    HDI residue in reaction injection molding
    3.
    发明授权
    HDI residue in reaction injection molding 失效
    HDI残留物在反应注射成型

    公开(公告)号：US5473044A

    公开(公告)日：1995-12-05

    申请号：US426359

    申请日：1995-04-21

    申请人： Robson Mafoti ,  David D. Steppan

    发明人： Robson Mafoti ,  David D. Steppan

    IPC分类号： C08G18/16 ,  C08G18/72 ,  C08G18/79 ,  C08G18/02 ,  C08G18/06

    CPC分类号： C08G18/161 ,  C08G18/727 ,  C08G18/79 ,  C08G2120/00

    摘要： This invention relates to a process for the production of a polyurethane molded part from a reaction injection molding process. The reaction mixture comprises:A) an isocyanate distillation residue resulting from the production of 1,6-hexamethylenediisocyanate by phosgenation of the corresponding amine, followed by the distillation of the pure 1,6-hexamethylenediisocyanate to yield said residue, wherein said residue has an NCO content of from 20 to 27%, a viscosity of from 1500 to 5000 cps at 25.degree. C., and from 0.1 to 3% by weight of hydrolyzable chlorides; withB) an isocyanate-reactive component comprising at least one organic compound having a molecular weight of from 500 to 10,000 and containing at least two isocyanate-reactive hydroxyl groups, and at least one organic diol having a molecular weight of from about 62 to 500,in the presence ofC) a specific catalyst mixture.The catalyst comprises at least one tertiary amine catalyst in combination with another catalyst selected from the group consisting of metal carboxylates, metal halides, ammonium carboxylates, and mixtures thereof.

    摘要翻译： 本发明涉及从反应注射成型工艺生产聚氨酯模制件的方法。 反应混合物包括：A）通过相应的胺的光气化产生1,6-己二异氰酸酯得到的异氰酸酯蒸馏残余物，然后蒸馏出纯的1,6-己二异氰酸酯以产生所述残余物，其中所述残余物具有 NCO含量为20〜27％，25℃粘度为1500〜5000cps，可水解氯化物为0.1〜3重量％。 B）异氰酸酯反应性组分，其包含至少一种分子量为500至10,000的有机化合物，并含有至少两个异氰酸酯反应性羟基，以及至少一种分子量为约62至500的有机二醇 在C）具体的催化剂混合物的存在下。 催化剂包含至少一种叔胺催化剂与选自金属羧酸盐，金属卤化物，羧酸铵及其混合物的另一种催化剂组合。

    Adhesive for bonding decorative melamine treated paper to particle board
    4.
    发明授权
    Adhesive for bonding decorative melamine treated paper to particle board 失效
    将装饰性三聚氰胺处理纸粘合到刨花板的粘合剂

    公开(公告)号：US5804618A

    公开(公告)日：1998-09-08

    申请号：US739399

    申请日：1996-10-31

    申请人： Robson Mafoti ,  Tien-Chieh Chao

    发明人： Robson Mafoti ,  Tien-Chieh Chao

    IPC分类号： B32B29/04 ,  C08L3/02 ,  C08L29/04 ,  C09J131/04

    CPC分类号： B32B29/04 ,  C09J131/04 ,  C08L29/04 ,  C08L3/02

    摘要： Polyvinyl acetate emulsion based adhesives can be made effective for bonding melamine formaldehyde resin treated decorative solid color and print paper to particle board. This polyvinyl acetate emulsion based adhesive is formulated with tackified polyvinyl alcohol, starch, a tackifier and a coupling agent. Stress cracking is substantially eliminated. Additionally, wrinkling and edge and corner peel resulting during the movement of sheets of melamine resin treated paper on the top and bottom surfaces of sheets of particle board through a heating and pressing zone is substantially eliminated.

    摘要翻译： 聚乙酸乙烯酯乳液基粘合剂可用于将三聚氰胺甲醛树脂处理的装饰性固色和印刷纸粘合到刨花板上。 该聚乙酸乙烯酯乳液基粘合剂用增粘的聚乙烯醇，淀粉，增粘剂和偶联剂配制。 基本消除了应力开裂。 此外，基本上消除了在通过加热和挤压区域在刨花板的顶表面和底表面上移动三聚氰胺树脂处理的纸张期间产生的褶皱和边缘和拐角剥离。

    Rigid polyurethanes based on allophanate-modified aliphatic and/or cycloaliphatic polyisocyanurates
    5.
    发明授权
    Rigid polyurethanes based on allophanate-modified aliphatic and/or cycloaliphatic polyisocyanurates 失效
    基于脲基甲酸酯改性的脂族和/或脂环族聚异氰脲酸酯的刚性聚氨酯

    公开(公告)号：US5614605A

    公开(公告)日：1997-03-25

    申请号：US359213

    申请日：1994-12-19

    申请人： Robson Mafoti ,  William E. Slack

    发明人： Robson Mafoti ,  William E. Slack

    IPC分类号： C08G18/42 ,  C08G18/48 ,  C08G18/78 ,  C08G18/79 ,  C08G18/00

    CPC分类号： C08G18/482 ,  C08G18/4202 ,  C08G18/7837 ,  C08G18/792

    摘要： This invention relates to rigid polyurethanes prepared by reaction, at an isocyanate index of 95 to 110, of(a) an allophanate-modified aliphatic and/or cycloaliphatic polyisocyanurate;(b) 20 to 100% by weight, relative to the total of components (b) and (c), of(i) one or more polyether and/or polyester polyols containing three or more isocyanate-reactive hydroxyl groups and having a molecular weight of 200 to 6000, and(ii) 0 to 30% by weight, relative to component (b)(i), of one or more isocyanate-reactive compounds other than a polyether or polyester of component (b)(i) and containing two or more isocyanate-reactive hydroxyl groups and having a molecular weight of about 400 to about 10,000,(c) 0 to 30% by weight, relative to the total of components (b) and (c), of a chain extender and/or crosslinker other than a polyether or polyester and having a molecular weight of from 32 to 399, wherein the amounts of components (b) and (c) total 100% by weight.

    摘要翻译： 本发明涉及通过在（a）脲基甲酸酯改性的脂族和/或脂环族聚异氰脲酸酯的异氰酸酯指数为95至110的反应中制备的刚性聚氨酯; （b）相对于组分（b）和（c）的总量为20至100重量％，（i）一种或多种含有三个或更多个异氰酸酯反应性羟基并具有分子量的聚醚和/或聚酯多元醇 相对于组分（b）（i），除了组分（b）（i）的聚醚或聚酯以外的一种或多种异氰酸酯反应性化合物和（ii）0至30重量％ 含有两个或更多个异氰酸酯反应性羟基并且分子量为约400至约10,000，（c）0至30重量％，相对于增链剂组分（b）和（c）的总量，和 /或聚醚或聚酯以外的分子量为32〜399的交联剂，其中组分（b）和（c）的总量为100重量％。

    Preparation of cast elastomers using aminocrotonate-terminated polyether chain extenders
    6.
    发明授权
    Preparation of cast elastomers using aminocrotonate-terminated polyether chain extenders 失效
    使用氨基巴豆酸酯封端的聚醚增链剂制备流延弹性体

    公开(公告)号：US5516872A

    公开(公告)日：1996-05-14

    申请号：US270605

    申请日：1994-07-05

    申请人： Robson Mafoti ,  Alan D. Bushmire

    发明人： Robson Mafoti ,  Alan D. Bushmire

    IPC分类号： C08G18/10 ,  C08G18/67

    CPC分类号： C08G18/6795 ,  C08G18/10

    摘要： This invention relates to a process for preparing polyurethane elastomers comprising reacting in an open mold at an isocyanate index of about 90 to about 110(a) an isocyanate prepolymer having an isocyanate content of about 2 to about 15% by weight and a molecular weight of from about 500 to about 5000 prepared by reaction of(i) at least one organic polyisocyanate with(ii) at least one isocyanate-reactive compound having at least two isocyanate-reactive groups and a molecular weight of from about 250 to about 4000;with(b) certain aminocrotonate-terminated polyethers having a molecular weight of from about 500 to about 1500;(c) optional chain extenders and/or crosslinkers other than aminocrotonate-terminated polyether (b); and(d) optional auxiliaries and/or additives.

    摘要翻译： 本发明涉及一种制备聚氨酯弹性体的方法，包括在开模中以异氰酸酯指数为约90至约110（a）异氰酸酯含量为约2至约15重量％的异氰酸酯预聚物和分子量为 通过（i）至少一种有机多异氰酸酯与（ii）至少一种具有至少两个异氰酸酯反应性基团和分子量为约250至约4000的异氰酸酯反应性化合物的反应制备的约500至约5000; （b）某些氨基巴豆酸酯封端的聚醚，其分子量为约500至约1500; （c）除氨基巴豆酸酯封端的聚醚（b）之外的任选的增链剂和/或交联剂; 和（d）任选的助剂和/或添加剂。

    Polyurea adhesive compositions
    9.
    发明授权
    Polyurea adhesive compositions 失效
    聚脲粘合剂组合物

    公开(公告)号：US5654085A

    公开(公告)日：1997-08-05

    申请号：US604118

    申请日：1996-02-20

    申请人： Peter H. Markusch ,  Jeffrey A. Dodge ,  Robson Mafoti

    发明人： Peter H. Markusch ,  Jeffrey A. Dodge ,  Robson Mafoti

    IPC分类号： C08G18/50 ,  C08G18/66 ,  C09J175/02 ,  B32B3/00 ,  B32B7/10 ,  B32B7/12 ,  C08G18/28

    CPC分类号： C09J175/02 ,  C08G18/5024 ,  C08G18/6685 ,  C08G2190/00 ,  Y10T428/24 ,  Y10T428/249921

    摘要： The present invention relates to a method for adhering two or more substrates by(1) applying to a surface of one of said substrates a non-sagging polyurea adhesive composition comprising the reaction product of:(a) a polyphenyl polymethylene polyisocyanate or a urea-modified prepolymer thereof and(b) an isocyanate-reactive component comprising amines consisting essentially of(i) an aminocrotonate-terminated polyether containing at least two secondary amino groups prepared by reaction of a polyfunctional acetoacetylated polyether polyol with a primary monoamine, and(ii) a low molecular weight aromatic and/or aliphatic diamine, and(2) contacting said substrate with a surface of a second substrate, and(3) curing the polyurea adhesive composition.

    摘要翻译： 本发明涉及一种用于通过（1）向所述基板之一的表面施加非流挂聚脲粘合剂组合物来粘合两种或多种基材的方法，所述非流挂聚脲粘合剂组合物包含以下反应产物：（a）聚苯基多亚甲基多异氰酸酯或脲 - 和（b）包含胺的异氰酸酯反应性组分，其基本上由（i）通过多官能乙酰乙酰化聚醚多元醇与伯单胺反应制备的含有至少两个仲氨基的氨基巴豆酸酯封端的聚醚，和（ii） 低分子量芳族和/或脂族二胺，和（2）使所述基材与第二基材的表面接触，和（3）固化聚脲粘合剂组合物。