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    Method for the production of highly elastic, cold-curing polyurethane foams
    3.
    发明授权
    Method for the production of highly elastic, cold-curing polyurethane foams 失效
    用于生产高弹性，固化聚氨酯泡沫的方法

    公开(公告)号：US5064870A

    公开(公告)日：1991-11-12

    申请号：US595677

    申请日：1990-10-10

    申请人： Hans-Joachim Kollmeier ,  Georg Burkhart ,  Rolf-Dieter Langenhagen ,  Helmut Lammerting ,  Bernd-Jurgen Klietsch

    发明人： Hans-Joachim Kollmeier ,  Georg Burkhart ,  Rolf-Dieter Langenhagen ,  Helmut Lammerting ,  Bernd-Jurgen Klietsch

    IPC分类号： C08J9/00

    CPC分类号： C08J9/0061 ,  C08J2375/04 ,  C08J2483/00 ,  Y10S521/904

    摘要： In a method for the preparation of highly elastic, cold curing polyurethane foams, equilibrated organofunctional polysiloxanes of the average general formula ##STR1## wherein R.sup.1 is methyl or R.sup.2,R.sup.2 is chloropropyl,n has a value of 0 to 12,m has a value of 1 to 8 when R.sup.1 is methyl and a value of 0 to 6 when R.sup.1 is chloropropyl,are added in amounts of 0.01 to 2.0% by weight, based on the polyols, to the reaction batch.The stabilizing properties of the organofunctional polysiloxanes are superior to those of the known products. The foams, produced pursuant to the invention, have a coarser cell structure and a higher elasticity. The foams are more open-celled as measured by the impression force.

    摘要翻译： 在制备高弹性，冷固化聚氨酯泡沫的方法中，平均通式为“IMAGE”的有机官能聚硅氧烷，其中R 1为甲基或R 2，R 2为氯丙基，n为0至12，m为 当R 1为甲基时为1至8，当R 1为氯丙基时为0至6的值，相对于多元醇为0.01至2.0重量％。 有机官能聚硅氧烷的稳定性优于已知产品。 根据本发明生产的泡沫具有较粗的泡孔结构和较高的弹性。 根据印象力量，泡沫更加开放。

    Process for the production of highly resilient, cold-curing polyurethane foams
    5.
    发明授权
    Process for the production of highly resilient, cold-curing polyurethane foams 失效
    用于生产高弹性，冷固化聚氨酯泡沫的方法

    公开(公告)号：US4478957A

    公开(公告)日：1984-10-23

    申请号：US532579

    申请日：1983-09-15

    申请人： Bernd-Juergen Klietsch ,  Hans-Joachim Kollmeier ,  Helmut Lammerting ,  Rolf-Dieter Langenhagen

    发明人： Bernd-Juergen Klietsch ,  Hans-Joachim Kollmeier ,  Helmut Lammerting ,  Rolf-Dieter Langenhagen

    IPC分类号： C08J9/00 ,  C08G18/14 ,  C08G18/32 ,  C08G18/48 ,  C08G18/72

    CPC分类号： C08J9/0061 ,  C08J2375/04 ,  C08J2483/00 ,  Y10S521/904

    摘要： The invention relates to a process for the manufacture of highly resilient, cold-curing polyurethane foams with the distinctive feature that polysiloxane-polyoxyalkylene block copolymers with the following characteristics are used as foam stabilizers:(a) the polysiloxane block is linear or branched and contains an average of 4 to 25 silicon atoms, wherein the organic radicals linked to the silicon atoms are polyoxyalkylene or methyl radicals and up to 30% of the methyl radicals can be replaced by substituted alkyl radicals with 1 to 4 carbon atoms, and/or phenyl radicals, and mixtures thereof;(b) the polyoxyalkylene portion consists of at least two polyoxyalkylene blocks, A.sub.1 and A.sub.2, which are formed from oxyethylene and oxypropylene units, wherein block A.sub.1 is formed from 45 to 100 mole percent of oxyethylene units and 55 to 0 mole percent of oxypropylene units and block A.sub.2 is formed from 0 to 50 mole percent of oxyethylene units and 100 to 50 mole percent of oxypropylene units, the molecular weight of the polyoxyalkylene blocks A.sub.1 and A.sub.2 in each case being 150 to 1,200 and the molar ratio of blocks A.sub.1 :A.sub.2 falling in the range of 20:80 to 80:20; and(c) the polysiloxane block is linked to the polyoxyalkylene blocks by SiOC or SiC bridges, 1.5 to 10 polyoxyalkylene blocks being linked to each polysiloxane block on the average.The stabilizers have improved stabilizing properties and form open-cell foams at a relatively wide processing latitude.

    摘要翻译： 本发明涉及用于制造具有以下特征的聚硅氧烷 - 聚氧化烯嵌段共聚物作为泡沫稳定剂的独特特征的高弹性，冷固化聚氨酯泡沫的方法：（a）聚硅氧烷嵌段是直链或支链的并含有 平均4至25个硅原子，其中与硅原子连接的有机基团是聚氧化烯或甲基，并且高达30％的甲基可以被具有1至4个碳原子的取代的烷基取代，和/或苯基 自由基及其混合物; （b）聚氧化烯部分由氧化乙烯和氧化丙烯单元形成的至少两个聚氧化烯嵌段A1和A2组成，其中嵌段A1由45-100摩尔％的氧化乙烯单元和55至0摩尔％的氧化丙烯单元形成 并且块A2由0至50摩尔％的氧化乙烯单元和100至50摩尔％的氧化丙烯单元形成，聚氧化烯嵌段A1和A2的分子量在每种情况下为150至1,200，并且嵌段A1：A2的摩尔比 落在20:80至80:20的范围内; 和（c）聚硅氧烷嵌段通过SiOC或SiC桥连接到聚氧化烯嵌段上，1.5至10个聚氧化烯嵌段平均连接到每个聚硅氧烷嵌段。 稳定剂具有改善的稳定性能并且在相对宽的加工范围内形成开孔泡沫。

    Release agent and process for the preparation of molded polyurethane or polyurea articles in the presence of the release agent
    7.
    发明授权
    Release agent and process for the preparation of molded polyurethane or polyurea articles in the presence of the release agent 失效
    在脱模剂存在下制备模塑聚氨酯或聚脲制品的脱模剂和方法

    公开(公告)号：US5043409A

    公开(公告)日：1991-08-27

    申请号：US439267

    申请日：1989-11-20

    申请人： Helmut Lammerting ,  Hans-Joachim Kollmeier ,  Rolf-Dieter Langenhagen

    发明人： Helmut Lammerting ,  Hans-Joachim Kollmeier ,  Rolf-Dieter Langenhagen

    IPC分类号： B29C33/64 ,  B29C67/24 ,  C08G18/61 ,  C08K5/5419 ,  C08L75/04

    CPC分类号： C08K5/5419 ,  B29C33/64 ,  C08G18/61 ,  C08L75/04 ,  B29C67/246 ,  B29K2075/00 ,  C08G2120/00 ,  C08G2125/00

    摘要： In a process for the preparation of molded polyurethane or polyurea articles, especially by the RIM process, internal release agents of the general formula ##STR1## are used. In this formula R.sup.1 =is alkyl with 20 to 40 carbon atoms,R.sup.2 =is R.sup.1 or methyl,R.sup.3 =is --(CH.sub.2).sub.s -- or --[(CH.sub.2).sub.t --].sub.r (OC.sub.2 H.sub.4).sub.x --(OC.sub.3 H.sub.6).sub.y --whereins=3 to 12,t=3 to 12,r=0 or 1,x=0 to 10,y=0 to 10,and the sum of x+y is not less than 1,n=0 to 50,m=2 to 100, m being greater than n,p=0 to 5,with the proviso that the siloxane has a melting point of not less than 38.degree. C.The compounds are finely dispersed with an average particle size of not less than 5 to 100.mu. in amounts of 0.5 to 5 weight percent, based on the reaction formulation. The release agents are preferably suspended in a portion of the polyol or polyolamine that is to be foamed.The release agents exhibit outstanding release properties and, in the event that molded polyurethane or polyurea articles with a cellular core are prepared, do not prevent the development and/or the maintenance of the cellular structure.

    摘要翻译： 在制备模塑聚氨酯或聚脲制品的方法中，特别是通过RIM方法，使用通式为＆lt; IMAGE＆gt; + TR＆lt; IMAGE＆gt;的内部脱模剂。 在该式中R1 =是具有20至40个碳原子的烷基，R2 = R1或甲基，R3 =是 - （CH2）s-或 - [（CH2）t-] r（OC2H4）x-（OC3H6） 其中s = 3至12，t = 3至12，r = 0或1，x = 0至10，y = 0至10，x + y之和不小于1，n = 0至50， m = 2〜100，m大于n，p = 0〜5，条件是硅氧烷的熔点不低于38℃。化合物细分散，平均粒径不小于 基于反应制剂，其量为0.5至5重量％的5至100微摩尔。 脱模剂优选悬浮在待发泡的多元醇或多元胺胺的一部分中。 脱模剂具有突出的脱模性能，并且在制备具有多孔芯的模制聚氨酯或聚脲制品的情况下，不妨碍细胞结构的显影和/或维持。

    Process for the preparation of flexible polyurethane foams
    8.
    发明授权
    Process for the preparation of flexible polyurethane foams 失效
    制备柔性聚氨酯泡沫的方法

    公开(公告)号：US4687786A

    公开(公告)日：1987-08-18

    申请号：US833957

    申请日：1986-02-27

    申请人： Hans-Joachim Kollmeier ,  Rolf-Dieter Langenhagen

    发明人： Hans-Joachim Kollmeier ,  Rolf-Dieter Langenhagen

    IPC分类号： C08G77/46 ,  C08J9/00 ,  C08J9/08

    CPC分类号： C08J9/0061 ,  C08G77/46 ,  C08J2375/04 ,  C08J2483/00

    摘要： Process for the preparation of flexible polyurethane foams using polysiloxane-polyoxyalkylene block copolymers as stabilizers having the general formula: ##STR1## in which A represents A.sup.1 and A.sup.2 polyoxyalkylene blocks, as defined hereinafter, which are linked to silicon over carbon and which have the general formula --R.sup.2 --O--(C.sub.x H.sub.2x O--).sub.y R.sup.3, R.sup.2 being a divalent hydrocarbon radical with 2 to 4 carbon atoms and R.sup.3, x and y are as defined hereinafter,B is a methyl radical, the A or R.sup.1 radical,R.sup.1 is an alkyl radical with 1 to 12 carbon atoms, a substituted alkyl radical with 1 to 12 carbon atoms, an aryl or an alkaryl radical,n has a value of 30 to 200,m has a value of 3 to 20 when B is a methyl radical or corresponds to the R.sup.1 radical, and a value of 1 to 18 when B corresponds to the A radical,o has a value of 0 to 40, n being not less than 5 m, and m and o being not greater than 1/3 n,with the proviso that(a) the A.sup.1 blocks consist of 30 to 60 weight percent of oxyethylene units, the remainder being oxypropylene units, the R.sup.3 radical is a hydrogen radical and the average molecular weight of the A.sup.1 Blocks is from 2,500 to 4,500,(b) the A.sup.2 blocks consist of 30 to 80 weight percent of oxyethylene units, the remainder being oxypropylene units, the R.sup.3 radical is an alkyl radical with 1 to 4 carbon atoms or an acyl radical, and the average molecular weight of the A.sup.2 blocks is from 800 to 2,400, and(c) the molar ratio of the A.sup.1 blocks to the A.sup.2 blocks is 20:80 to 60:40, and there is at least one A.sup.1 and one A.sup.2 block in the average molecule.The stabilizers are distinguished by exceptionally high stabilizing properties and, when used in flexible polyurethane foams, surprisingly form open cells in spite of the fact that they contain OH-terminated polyoxyalkylene blocks.

    摘要翻译： 使用聚硅氧烷 - 聚氧化烯嵌段共聚物作为稳定剂制备柔性聚氨酯泡沫体的方法，其具有以下通式：其中A表示与下列定义的A1和A2的聚氧化烯嵌段，其与碳相连，并具有一般性 式-R2-O-（CxH2xO-）yR3，R2是具有2至4个碳原子的二价烃基，R3，x和y如下文所定义，B是甲基，A或R1基团，R1是 具有1至12个碳原子的烷基，具有1至12个碳原子的取代烷基，芳基或烷芳基，n具有30至200的值，当B是甲基时，m具有3至20的值 或对应于R1基团，当B对应于A基团时为1〜18，o为0〜40，n为5m以上，m为0以下，1 / n，条件是（a）A1嵌段由30至60重量％的氧化乙烯单元组成， 茚基为氧化丙烯单元，R3基团为氢原子，A1嵌段的平均分子量为2,500至4,500，（b）A2嵌段由30至80重量％的氧化乙烯单元组成，其余为氧化丙烯单元， R3基是碳原子数为1〜4的烷基或酰基，A2嵌段的平均分子量为800〜2400，（c）A1嵌段与A2嵌段的摩尔比为20 ：80〜60:40，平均分子中至少有一个A1和A2嵌段。 稳定剂的特征在于极高的稳定性，并且当用于柔性聚氨酯泡沫时，令人惊奇地形成开孔，尽管它们含有OH封端的聚氧化烯嵌段。

    Siloxanes with betaine groups, their synthesis and use in hair care products
    9.
    发明授权
    Siloxanes with betaine groups, their synthesis and use in hair care products 失效
    具有甜菜碱基团的硅氧烷，它们在护发产品中的合成和用途

    公开(公告)号：US4609750A

    公开(公告)日：1986-09-02

    申请号：US744469

    申请日：1985-06-13

    申请人： Hans-Joachim Kollmeier ,  Rolf-Dieter Langenhagen ,  Klaus Hoffmann

    发明人： Hans-Joachim Kollmeier ,  Rolf-Dieter Langenhagen ,  Klaus Hoffmann

    IPC分类号： A61K8/893 ,  A61K8/898 ,  A61Q5/02 ,  A61Q5/12 ,  C07F7/10 ,  C08G77/26 ,  C08G77/388 ,  C11D3/37

    CPC分类号： A61K8/898 ,  A61Q5/02 ,  A61Q5/12 ,  C08G77/388

    摘要： Organopolysiloxanes that have betaine groups and the following general formula ##STR1## in which R.sup.1 can represent the same or different groups in the molecule and may be an alkyl radical with 1 to 18 carbon atoms, an aryl radical or a polyoxyalkylene radical with the proviso that at least 70% of the R.sup.1 radicals are methyl radicals,R.sup.2 may be the same as R.sup.1, with the proviso that at least one R.sup.2 radical represents ##STR2## in which R.sup.3 is a divalent alkylene radical with 2 to 12 carbon atoms,R.sup.4 is a divalent alkylene radical with 2 to 6 carbon atoms,R.sup.5 and R.sup.6 are the same or different and represent an alkyl radical with 1 to 4 carbon atoms or a benzyl radical, andn=1, 2, or 3,x has a value of 0 to 200, andy has a value of 1 to 50, as well as processes for their synthesis and their use in cosmetic preparations, especially in hair care products.

    摘要翻译： 具有甜菜碱基团的有机聚硅氧烷和以下通式“IMAGE”，其中R 1可以在分子中表示相同或不同的基团，并且可以是具有1至18个碳原子的烷基，芳基或聚氧化烯基，条件是 至少70％的R 1基团是甲基，R 2可以与R 1相同，条件是至少一个R 2基团表示其中R 3是具有2至12个碳原子的二价亚烷基，R 4是 具有2至6个碳原子的二价亚烷基，R 5和R 6相同或不同，表示具有1至4个碳原子的烷基或苄基，n = 1,2或3，x具有 0至200，y值为1至50，以及它们的合成方法及其在化妆品制剂中的用途，特别是在护发产品中。

    Process for the production of rigid polyurethane foams
    10.
    发明授权
    Process for the production of rigid polyurethane foams 失效
    生产硬质聚氨酯泡沫的方法

    公开(公告)号：US4529743A

    公开(公告)日：1985-07-16

    申请号：US660497

    申请日：1984-10-12

    申请人： Hans-Joachim Kollmeier ,  Rolf-Dieter Langenhagen

    发明人： Hans-Joachim Kollmeier ,  Rolf-Dieter Langenhagen

    IPC分类号： C08G77/46 ,  C08J9/00 ,  C08G18/14

    CPC分类号： C08J9/0061 ,  C08G77/46 ,  C08J2375/04 ,  C08J2483/00

    摘要： In a process for producing rigid polyurethane foams, polysiloxane-polyoxyalkylene block copolymers having the formula ##STR1## are used, in which A represents polyoxyalkylene blocks A.sup.1 or A.sup.2 having the formula --R.sup.2 --O--(C.sub.m H.sub.2m O).sub.y R.sup.1, which are linked to silicon by an SiC bond and in which R.sup.1 represents a hydrogen atom or an alkyl radical with 1 to 4 carbon atoms, R.sup.2 represents a bridging group, y is a whole number, and m has a value of 2.0 to 2.6, with the proviso that:a. the A.sup.1 blocks comprise 70 to 100 weight percent oxyethylene units, the remainder being oxypropylene units, and have a molecular weight from about 250 to 1,000,b. the A.sup.2 blocks comprise 35 to 65 weight percent oxyethylene units, the remainder being oxypropylene units, and have a molecular weight from about 600 to 1,500,c. the molar ratio of the A.sup.1 block to the A.sup.2 blocks is 85:15 to 15:85 and there is at least one block of A.sup.1 and block of A.sup.2 in the average molecule;B is a methyl radical or an A.sup.1 or A.sup.2 polyoxyalkylene block;a has a value of 15 to 150, andb has a value of 5 to 20, when B is a methyl radical, and a value of 3 to 18, when B represents A.sup.1 or A.sup.2.

    摘要翻译： 在制造刚性聚氨酯泡沫体的方法中，使用具有式（I）的聚硅氧烷 - 聚氧化烯嵌段共聚物，其中A表示具有式-R 2 -O-（C m H 2 m O）y R 1的聚氧化烯嵌段A 1或A 2，其与 硅，其中R1表示氢原子或具有1至4个碳原子的烷基，R2表示桥连基团，y表示整数，m表示2.0至2.6的值，条件是 ： 一个。 所述A1嵌段包含70至100重量％的氧化乙烯单元，其余为氧化丙烯单元，分子量为约250至1,000，b。 A2嵌段包含35至65重量％的氧化乙烯单元，其余为氧化丙烯单元，分子量为约600至1500，c。 A1嵌段与A2嵌段的摩尔比为85:15〜15:85，在平均分子中存在至少一个A1嵌段和A2嵌段; B是甲基或A1或A2聚氧化烯嵌段; a的值为15〜150，当B为甲基时，b为5〜20，B为A1或A2时为3〜18。