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公开(公告)号：US4096139A
公开(公告)日：1978-06-20
申请号：US709089
申请日：1976-07-27
申请人： Ruggero Battisti , Camillo Paffoni
发明人： Ruggero Battisti , Camillo Paffoni
IPC分类号： C09B29/085 , C09B29/08 , C09B43/00 , C09B43/128 , C09B57/02 , D06P1/18 , C09B43/12 , D06P3/85
CPC分类号： C09B29/08 , C09B29/0839 , C09B43/00 , C09B43/128 , C09B57/02 , D06P1/18
摘要： There is provided a new azoic dye having the general formula ##STR1## wherein: A is an aromatic radical of the benzene class which has been substituted with at least one group selected from among alkyl, alkoxyl, N-dialkylamine, halogen, cyano and nitro;X is selected from the group consisting of NH and O;R.sub.1 is selected from the group consisting of H, CH.sub.3, OCH.sub.3 and Cl;R.sub.2 is selected from the group consisting of H, CH.sub.3, OCH.sub.3, Cl;R.sub.3 is selected from the group consisting of CH.sub.3 and C.sub.2 H.sub.5 ; andR.sub.4 is the same as R.sub.3, such dye being useful in the printing and dyeing of the textiles, particularly hydrophobic synthetic fibers such as polyester fibers.
摘要翻译： 提供了具有通式
的新的偶氮染料，其中：A是苯类的芳族基团，其被至少一个选自烷基，烷氧基，N-二烷基胺，卤素，氰基和硝基中的基团取代 ; X选自NH和O; R 1选自H，CH 3，OCH 3和Cl; R 2选自H，CH 3，OCH 3，Cl; R3选自CH3和C2H5; 和R4与R3相同，这种染料可用于纺织品，特别是疏水性合成纤维如聚酯纤维的印染。 -
公开(公告)号：US4187218A
公开(公告)日：1980-02-05
申请号：US886943
申请日：1978-03-15
CPC分类号： C09B31/047 , C09B29/08 , C09B29/0803 , C09B31/04 , D06P1/06
摘要： This invention relates to a class of water-soluble acid azo dyes, containing at least a sulphonic group, having formula (I): ##STR1## wherein the symbols have the following meanings: A is a residue of a diazotizable aromatic or heterocyclic amine, optionally substituted;R is selected from the group consisting of H, CH.sub.3, OCH.sub.3 and OC.sub.2 H.sub.5 ;R.sub.1 is selected from the group consisting of CH.sub.3 and C.sub.2 H.sub.5 ;R.sub.2 is selected from the group consisting of CH.sub.3 and C.sub.2 H.sub.5.The dyes which are the object of the present invention exhibit shades varying from yellow to blue and are useful for dyeing and printing natural polyamide fibres (wool and silk) and synthetic fibres (nylon). They possess an excellent affinity in both an acid bath and a neutral bath and an excellent tinting power. The dyes obtained are characterized by a remarkable purity of shade, by an excellent stability to sunlight, to washing and to sweat, as well as by a good equalizing power on nylon.
摘要翻译： 本发明涉及一类含有至少一个具有式（I）的磺酸基的水溶性酸偶氮染料：其中符号具有以下含义：A是可重氮化芳族的残基或 杂环胺，任选取代的; R选自H，CH 3，OCH 3和OC 2 H 5; R1选自CH3和C2H5; R2选自CH3和C2H5。 作为本发明的目的的染料显示从黄色到蓝色的色调，并且可用于染色和印刷天然聚酰胺纤维（羊毛和丝绸）和合成纤维（尼龙）。 它们在酸浴和中性浴中都具有极好的亲和力，并具有优异的着色力。 所得到的染料的特征在于，通过对阳光的良好的稳定性，洗涤和汗水以及通过尼龙的良好的均衡功率，具有显着的阴影纯度。
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公开(公告)号：US4523953A
公开(公告)日：1985-06-18
申请号：US558023
申请日：1983-12-05
CPC分类号： C09B63/00 , C09B67/0041
摘要： There are described organic-inorganic ternary composite pigments consisting of 70%-90% by weight of an inorganic binary titanium dioxide/aluminum hydrate component and, from 10% to 30% by weight, of a co-precipitated organic component consisting of an organic dye, containing in its structure at least one carboxylic and/or sulphonic acid function, having the formula: ##STR1## wherein R.sub.1 is selected from the group consisting of NO.sub.2 --SO.sub.3 H and --COOH; R.sub.2 is selected from the group consisting of NO.sub.2, --SO.sub.3 H, alkyl and alkoxyl; R.sub.3 is selected from the group consisting of H, halogen and alkyl; R.sub.4 and R.sub.5 are each selected from the group consisting of H, halogen, alkyl and alkoxyl; R.sub.6 is selected from the group consisting of H, halogen and alkoxyl; and wherein the --COOH and/or --SO.sub.3 H group of dye (I) is salified with metal cations.The pigments are obtained by co-precipitation acidifying an aqueous solution and/or dispersion of acid dye (I) in sodium aluminate, in the presence of TiO.sub.2, maintained at 40.degree.-80.degree. C. and at pH=9.5-10.5, by then treating it with any aqueous solution of an alkaline-earth (Ca, Ma, Al, Ba, Sr) salt or of Mn or Zn.
摘要翻译： 描述了由70重量％-90重量％的无机二元二氧化钛/铝水合物组分和10重量％至30重量％的由有机物组成的共沉淀有机组分组成的有机 - 无机三元复合颜料 在其结构中含有至少一种具有下式的羧酸和/或磺酸官能团的化合物：其中R 1选自NO 2 -SO 3 H和-COOH; R2选自NO2，-SO3H，烷基和烷氧基; R3选自H，卤素和烷基; R4和R5各自选自H，卤素，烷基和烷氧基; R6选自H，卤素和烷氧基; 并且其中染料（I）的-COOH和/或-SO 3 H基团用金属阳离子盐化。 颜料是通过在保持在40℃-80℃和pH = 9.5-10.5的TiO 2存在下，将酸性染料（I）在铝酸钠中的水溶液和/或分散体共沉淀酸化而获得的， 然后用碱土（Ca，Ma，Al，Ba，Sr）盐或Mn或Zn的任何水溶液处理。
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公开(公告)号：US4486237A
公开(公告)日：1984-12-04
申请号：US468121
申请日：1983-02-22
IPC分类号： C09B25/00 , C09B29/00 , C09B29/01 , C09B29/15 , C09B29/36 , C09B63/00 , C09B67/08 , C09B67/22 , C09C1/00 , C09C1/40 , C04B31/40
CPC分类号： C09B63/00 , C09B25/00 , C09B29/00 , C09B29/0007 , C09B29/103 , C09B29/36 , C09B67/0033 , C09C1/0084 , C01P2004/80 , C01P2006/12 , C01P2006/60
摘要： Novel composite pigments containing both organic and inorganic portions have been produced.These pigments consist of an inorganic binary titanium dioxide/aluminum hydrate component, in a percent quantity comprised between 70% and 95% by weight, the remaining organic component amounting to between 5% and 30% by weight, consisting of an organic dye selected from the group consisting of azoic and quinophtalonic compounds, containing in their structure at least one carboxylic and/or sulphonic, substantially salified, acid function.The pigments are obtained according to a co-precipitation process, under substantially alkaline controlled pH conditions, of the acid organic dye together with the aluminum hydroxide (hydrated aluminum), by acidification of a solution and/or an aqueous dispersion of the acid organic dye in sodium aluminate, in the presence of titanium dioxide, at from 40.degree. C. to about 80.degree. C., and by a subsequent lacquering by treatment with an aqueous solution of an alkaline-earth metal salt (Ca, Mg, Ba, Sr) or of a Mn, Zn salt.The above-mentioned pigments are insoluble in water and in common organic solvents. They possess, moreover, a good dyeing power, an excellent stability under heat, a good fastness to light, a good fastness to bases and acids, to migration in plastic materials and stability to over varnishing in the stove, etc. Lastly, they may be obtained with different degrees of covering power.Thus, the pigments find a preferential application in varnishing products, air-drying and stove-baked enamels, in the pigmentation of plastic materials, in inks and in the beprinting of fabrics, etc., by means of conventional applicational methods.
摘要翻译： 已经制备了含有有机部分和无机部分的新型复合颜料。 这些颜料由无机二元二氧化钛/铝水合物成分组成，其含量为70％至95％（重量），剩余有机成分为5％至30％（重量），由选自 该组由偶氮和喹啉酮化合物组成，其结构含有至少一种羧酸和/或磺酸，基本上盐化的酸功能。 根据酸性有机染料与氢氧化铝（水合铝）一起的共沉淀法，在碱性控制的pH条件下，通过酸性有机染料的水溶液和/ 在铝酸钠存在下，在二氧化钛的存在下，在40℃至约80℃，然后通过用碱土金属盐（Ca，Mg，Ba，Sr ）或Mn，Zn盐。 上述颜料不溶于水和普通的有机溶剂。 此外，它们具有良好的染色力，在热下具有优异的稳定性，良好的耐光牢度，良好的碱和酸牢度，在塑料材料中的迁移以及在炉子上过度的稳定性等。最后，它们可以 获得不同程度的覆盖力。 因此，通过常规应用方法，颜料可以在上漆产品，空气干燥和炉烘烤的搪瓷，塑料材料着色，油墨和织物的印刷等方面得到优先应用。
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公开(公告)号：US4062645A
公开(公告)日：1977-12-13
申请号：US678911
申请日：1976-04-21
CPC分类号： D06P3/241 , C09B29/366 , Y10S8/924
摘要： The known compounds of the formula: ##STR1## wherein X is hydrogen or bromine, Y is hydrogen, chlorine, bromine or methyl and the -COOH group is meta or para to the azo group have been found to be useful in uniformly dyeing polyamide fibers to a yellow shade.
摘要翻译： 已知已知的下式化合物：其中X为氢或溴，Y为氢，氯，溴或甲基，-COOH基团为偶氮基的间位或对位已被发现可用于均匀染色聚酰胺纤维 到一个黄色的阴影。
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公开(公告)号：US4036733A
公开(公告)日：1977-07-19
申请号：US679029
申请日：1976-04-21
IPC分类号： C08K5/00 , C07D235/28 , C07D277/74 , C08L1/00 , C08L7/00 , C08L21/00 , C08L27/00 , C08L33/00 , C08L33/02 , C08L51/00 , C08L51/02 , C09B3/06 , C10G41/00 , C07D235/04 , C08K5/16 , C10L1/24
CPC分类号： C07D235/28 , C07D277/74 , C09B3/06
摘要： A plastosoluble fluorescent organic dye is disclosed that is derived from benzanthrone, and having the general formula: ##STR1## wherein X = --H or --Br; and Y = --H, --OCH.sub.3 or --OC.sub.2 H.sub.5. A process for the preparation of a dye of the general formula (I) is also disclosed. These dyes are useful in the bulk dyeing of polystyrene, polymethylmethacrylate, rigid PVC, polyethylene, acrylonitrile/butadiene/styrene copolymers, polycarbonates or mineral oils.
摘要翻译： 公开了一种衍生自苯并蒽酮的塑性荧光有机染料，具有以下通式：其中X = -H或-Br; 和Y = -H，-OCH 3或-OC 2 H 5。 还公开了制备通式（I）的染料的方法。 这些染料可用于聚苯乙烯，聚甲基丙烯酸甲酯，刚性PVC，聚乙烯，丙烯腈/丁二烯/苯乙烯共聚物，聚碳酸酯或矿物油的本体染色。
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公开(公告)号：US4098793A
公开(公告)日：1978-07-04
申请号：US836087
申请日：1977-09-23
IPC分类号： C09B1/44 , C09B1/516 , C09B1/54 , D06P1/24 , C07D285/10
摘要： The present invention relates to a new class of compounds belonging to the anthraquinone series, having the general formula: ##STR1## wherein R, R', R", R'", R' are indifferently H or Chlorine, ##STR2## Such compounds exhibit a color varying from yellow to violet depending on the nature and position of substituents R, R', R", R'", R'.sup.v and, in virtue of their excellent stability characteristics, they are particularly useful as pigments and vat dyes.This invention relates furthermore to the preparation of compounds having general formula (I) and to the utilization thereof, particularly in the following applications:Pigmentation of plastic materials, such as polyvinyl chloride, polystyrene, polyolefins, polymethylmethacrylate, polycarbonates and ABS copolymers (acrylonitrile-butadiene-styrene);Pigmentation of varnishes, stoving enamels, inks and pastes for the printing of textiles;Vat dyeing of cellulose fibres such as cotton, flax, rayon.BACKGROUND OF THE INVENTIONAs far as it is known, the anthraquinone derivatives of 1,2,5-thiadiazole-3,4-dicarboxylic acid of formula (I), which are the object of the present invention, are not described in the Art.The prior Art, however not directly pertinent, generically describes dyestuffs of the anthraquinone series deriving from dicarboxylic acids, for example benzenic, pyridinic, aliphatic acids etc.OBJECTS OF THE INVENTIONIt is an object of this invention to provide a new class of anthraquinone compounds of general formula (I), having useful applications in the field of the pigments and of the vat dyes. Another object is to provide a process for preparing same.GENERAL DESCRIPTION OF THE INVENTIONThese and still other objects, that will more clearly appear to those skilled in the Art from the following description, are achieved by compounds having general formula (I), prepared by means of a process characterized in that the dichloride of 1,2,5-thiadiazole-3,4-dicarboxylic acid (II) is reacted with 1-aminoanthraquinone or substituted derivatives (III) thereof according to a substantially stoichiometric molar ratio, in the presence of an inert solvent, at a temperature ranging from 100.degree. to about 170.degree. C.The reaction can be schematically represented by the following equation (1): ##STR3## wherein R', R", R'", R'.sup.v have the meaning already specified; HCl forms and liberates as a gas from the reacting mixture. It is not necessary, therefore, to employ basic substances to neutralize hydrochloric acid. As mentioned hereinbefore, the reaction is conducted in an inert solvent and at a temperature comprised between 100.degree. and about 170.degree. C, preferably between 120.degree. and about 150.degree. C.1-aminoanthraquinones (III) employable in the present invention are in particular:1-aminoanthraquinone, 1-amino-4-hydroxyanthraquinone, 1-amino-4-benzamidoanthraquinone, 1-amino-5-benzamidoanthraquinone, 1-amino-4-(p-acetamidoanilino)-anthraquinone, 1-amino-4-(p-toluidino)-anthraquinone, 1-amino-5-methoxyanthraquinone, 1-amino-2-phenoxy-4-hydroxyanthraquinone, 1-amino-2,4-dibromoanthraquinone, 1-amino-2-bromo-4-hydroxyanthraquinone, 1-amino-6,7-dichloroanthraquinone etc.As inert solvent it is possible to use chlorobenzene, the various dichlorobenzenes and trichlorobenzenes, and nitrobenzenes.The time required for the reaction varies from 2 to 8 hours, depending on the reaction temperature and on the type of 1-aminoanthraquinones utilized. The molar ratio is practically stoichiometric, that is: 2 moles of anthraquinone compound (III) for 1 mole of dichloride (II).The raw materials necessary for the process according to this invention are easily available, as 1-aminoanthraquinone and the substituted derivatives (III) thereof are commercial products usually employed as intermediates for dyestuffs and pigments.As to the dichloride of 1,2,5-thiadiazole-3,4-dicarboxylic acid (II), such product is known since long and is obtained, according to known techniques, by chlorination with SOCl.sub.2 of the monopotassium salt of 1,2,5-thiadiazole-3,4-dicarboxylic acid, that is, in its turn, a known compound.According to an effective embodiment, the present invention is conducted by operating in practice as follows: the dichloride of 1,2,5-thiadiazole-3,4-dicarboxylic acid (II) and the 1-aminoanthraquinone or its substituted derivatives (III) are heated, after mixing in the inert solvent, to 100.degree.-170.degree. C, preferably to 120.degree.-150.degree. C, until the anthraquinone compound (III) has thoroughly disappeared.The thin layer chromatography is useful for this check.At the end of the reaction the reaction mixture is filtered, preferably in hot conditions, and the pigment cake is then washed with the reaction solvent and successively with methanol until the washings result colourless.The pigments obtained according to this invention are substances exhibiting a colour varying from yellow to violet and characterized by a high insolubility in the common organic solvents and by a high melting point, generally higher than 300.degree. C.To impart the particular desired applicative characteristics to the products so obtained it is impossible to utilize the grinding, for example in a ball mill, or the precipitation from sulphuric acid and in general the techniques already known.Also for the dyeing of plastic materials, of varnishing products and for the vat dyeing the pigments of the present invention are consistent with the conventional techniques.Due to the simple preparation conditions and applicative characteristics of the obtained pigments, the present invention appears particularly advantageous.Preparation and application of the present invention will be now described more in detail in the following examples, which are given, however, by way of example only.
摘要翻译： 本发明涉及一类属于蒽醌系列的化合物，具有以下通式：其中R，R'，R“，R”'，R'为无差异的H或氯，
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公开(公告)号：US4031096A
公开(公告)日：1977-06-21
申请号：US679030
申请日：1976-04-21
IPC分类号： C08K5/00 , C08K5/34 , C08L1/00 , C08L7/00 , C08L21/00 , C08L23/00 , C08L27/00 , C08L33/00 , C08L33/02 , C08L51/00 , C08L51/02 , C08L101/00 , C09B5/14
CPC分类号： C09B5/14
摘要： A fluorescent azabenzanthronic dye is disclosed having the general formula (I): ##STR1## wherein X = --NH-- or --S--; and Y = --OCH.sub.3 or --OC.sub.2 H.sub.5. A process for the preparation of a dye of the general formula (I) is also disclosed. These dyes are useful in the bulk dyeing of polystyrene, polymethylmethacrylate, rigid PVC, polyethylene, acrylonitrile/butadiene/styrene copolymers, polycarbonates or mineral oils.
摘要翻译： 公开了具有通式（I）的荧光偶氮苯并酞染料：其中X = -NH-或-S-; 和Y = -OCH 3或-OC 2 H 5。 还公开了制备通式（I）的染料的方法。 这些染料可用于聚苯乙烯，聚甲基丙烯酸甲酯，刚性PVC，聚乙烯，丙烯腈/丁二烯/苯乙烯共聚物，聚碳酸酯或矿物油的本体染色。
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