公开(公告)号：US09775241B2

公开(公告)日：2017-09-26

申请号：US14009922

申请日：2012-04-03

申请人： Ryan M. Walczak ,  John R. Reynolds ,  Andrew Gabriel Rinzler ,  Andrew M. Spring ,  Svetlana V. Vasilyeva ,  Pooja Wadhwa

发明人： Ryan M. Walczak ,  John R. Reynolds ,  Andrew Gabriel Rinzler ,  Andrew M. Spring ,  Svetlana V. Vasilyeva ,  Pooja Wadhwa

IPC分类号： C09D147/00 ,  C09D101/02 ,  C09D11/00 ,  H05K1/09 ,  C08J3/02 ,  C09D5/02 ,  C09D7/12 ,  C01B31/02 ,  C01B31/04 ,  C09D11/30 ,  C09D11/52 ,  B82Y30/00 ,  B82Y40/00 ,  B05D1/04 ,  B05D1/18 ,  B05D1/28 ,  B05D3/00 ,  C08K7/24

CPC分类号： H05K1/092 ,  B05D1/04 ,  B05D1/18 ,  B05D1/28 ,  B05D3/007 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/168 ,  C01B32/174 ,  C01B32/194 ,  C08J3/02 ,  C08J2300/10 ,  C08K3/041 ,  C08K7/24 ,  C09D5/027 ,  C09D7/70 ,  C09D11/30 ,  C09D11/52 ,  C09D101/02 ,  C09D147/00 ,  H05K2201/0323 ,  C08L1/284 ,  C08L101/02

摘要： A degradable polymeric nanotube (NT) dispersant comprises a multiplicity of NT associative groups that are connected to a polymer backbone by a linking group where there are cleavable groups within the polymer backbone and/or the linking groups such that on a directed change of conditions, bond breaking of the cleavable groups results in residues from the degradable polymeric NT dispersant in a manner where the associative groups are uncoupled from other associative groups, rendering the associative groups monomelic in nature. The degradable polymeric nanotube (NT) dispersant can be combined with carbon NTs to form a NT dispersion that can be deposited to form a NT film, or other structure, by air brushing, electrostatic spraying, ultrasonic spraying, ink-jet printing, roll-to-roll coating, or dip coating. The deposition can render a NT film that is of a uniform thickness or is patterned with various thicknesses. Upon deposition of the film, the degradable polymeric nanotube (NT) dispersant can be cleaved and the cleavage residues removed from the film to yield a film where contact between NTs is unencumbered by dispersants, resulting in highly conductive NT films.

公开(公告)号：US20140083752A1

公开(公告)日：2014-03-27

申请号：US14009922

申请日：2012-04-03

申请人： Ryan M. Walczak ,  John R. Reynolds ,  Andrew Gabriel Rinzler ,  Andrew M. Spring ,  Svetlana V. Vasilyeva ,  Pooja Wadhwa

发明人： Ryan M. Walczak ,  John R. Reynolds ,  Andrew Gabriel Rinzler ,  Andrew M. Spring ,  Svetlana V. Vasilyeva ,  Pooja Wadhwa

IPC分类号： C09D147/00 ,  C09D101/02 ,  H05K1/09 ,  C09D11/00

CPC分类号： H05K1/092 ,  B05D1/04 ,  B05D1/18 ,  B05D1/28 ,  B05D3/007 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/168 ,  C01B32/174 ,  C01B32/194 ,  C08J3/02 ,  C08J2300/10 ,  C08K3/041 ,  C08K7/24 ,  C09D5/027 ,  C09D7/70 ,  C09D11/30 ,  C09D11/52 ,  C09D101/02 ,  C09D147/00 ,  H05K2201/0323 ,  C08L1/284 ,  C08L101/02

摘要： A degradable polymeric nanotube (NT) dispersant comprises a multiplicity of NT associative groups that are connected to a polymer backbone by a linking group where there are cleavable groups within the polymer backbone and/or the linking groups such that on a directed change of conditions, bond breaking of the cleavable groups results in residues from the degradable polymeric NT dispersant in a manner where the associative groups are uncoupled from other associative groups, rendering the associative groups monomelic in nature. The degradable polymeric nanotube (NT) dispersant can be combined with carbon NTs to form a NT dispersion that can be deposited to form a NT film, or other structure, by air brushing, electrostatic spraying, ultrasonic spraying, ink-jet printing, roll-to-roll coating, or dip coating. The deposition can render a NT film that is of a uniform thickness or is patterned with various thicknesses. Upon deposition of the film, the degradable polymeric nanotube (NT) dispersant can be cleaved and the cleavage residues removed from the film to yield a film where contact between NTs is unencumbered by dispersants, resulting in highly conductive NT films.

摘要翻译： 可降解的聚合物纳米管（NT）分散剂包括多个NT缔合基团，其通过连接基团连接到聚合物主链上，其中在聚合物主链和/或连接基团内存在可切割基团，使得在条件的定向改变下， 可切割基团的键断裂导致可降解聚合物NT分散剂的残留物，其中缔合基团与其它缔合基团脱离，使缔合基团本质上单体。 可降解聚合物纳米管（NT）分散剂可与碳NT组合以形成NT分散体，其可以通过空气刷涂，静电喷涂，超声波喷涂，喷墨印刷，辊压沉积法沉积形成NT膜或其它结构， 辊涂或浸涂。 沉积可以使具有均匀厚度的NT膜或者以各种厚度图案化。 在沉积膜时，可以将可降解的聚合物纳米管（NT）分散剂切割，并且从膜中除去的裂解残余物产生膜，其中NTs之间的接触不受分散剂的阻碍，导致高度导电的NT膜。

公开(公告)号：US20140175281A1

公开(公告)日：2014-06-26

申请号：US14127816

申请日：2012-06-28

申请人： John R. Reynolds ,  Ryan M. Walczak ,  Andrew Gabriel Rinzler ,  Svetlana V. Vasilyeva ,  Aubrey Lynn Dyer

发明人： John R. Reynolds ,  Ryan M. Walczak ,  Andrew Gabriel Rinzler ,  Svetlana V. Vasilyeva ,  Aubrey Lynn Dyer

IPC分类号： G02F1/163 ,  G01J1/44 ,  G02F1/157 ,  G01J1/04

CPC分类号： G02F1/163 ,  B82Y20/00 ,  B82Y30/00 ,  B82Y99/00 ,  G01J1/0407 ,  G01J1/44 ,  G02F1/15 ,  G02F1/15165 ,  G02F1/155 ,  G02F1/157 ,  G02F2001/1536 ,  G02F2201/16 ,  G02F2201/58 ,  G02F2202/28 ,  G02F2202/36 ,  G02F2203/11 ,  Y02A30/257 ,  Y02B80/50 ,  Y10S977/742

摘要： An electrochromic device (ECD) includes an electrochromic cell and, optionally, one or more additional electrochromic cells where all cells are parallel, and where at least one of the electrodes of one of the cells comprises a single-walled carbon nanotube (SWNT) film The electrochromic cells allow the control of transmittance of two or more different portions of the electro-magnetic spectrum through the ECD. One cell can control the transmittance of visible radiation while the other cell can control the transmittance of IR radiation. The ECD can be employed as a “smart window” to control the heat and light transmission through the window. The ECD can be in the form of a laminate that can be added to an existing window.

摘要翻译： 电致变色装置（ECD）包括电致变色电池和任选的一个或多个附加的电致变色细胞，其中所有细胞平行，并且其中一个电池的至少一个电极包括单壁碳纳米管（SWNT）膜 电致变色细胞允许通过ECD控制电磁光谱的两个或多个不同部分的透射率。 一个电池可以控制可见光的透射率，而另一个电池可以控制IR辐射的透射率。 ECD可以用作“智能窗口”来控制通过窗户的热和光透射。 ECD可以是可以添加到现有窗口的层压板的形式。