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1.发明授权公开(公告)号：US07704305B2
公开(公告)日：2010-04-27
申请号：US11665962
申请日：2005-08-22
Applicant: Ryosuke Nishida
Inventor： Ryosuke Nishida
CPC classification number: F28F13/18 , B01D53/261 , B01D53/28 , B01J20/26 , B01J20/261 , B01J20/265 , B01J20/267 , F25B35/04 , F28F2245/02 , Y02A30/276 , Y10T29/49359
Abstract: As conventional heat exchange modules, adsorptive agents of an inorganic type such as silica gel, zeolite, active alumina, active carbon and molecular sieve have been used. While these adsorptive agents have characteristics of high moisture absorptive ability and easy handling, they have problems of durability, regenerating temperature and generation of bacteria or fungi. An object of the present invention is to solve these problems which are noted in the inorganic adsorptive agents and to provide a heat exchanger module of a energy conservation type having a high heat exchange efficiency and a method for the manufacture thereof. The present invention is a heat exchange module of a sorptive type, characterized in that, a moisture absorptive layer in which a sorptive agent of an organic polymer type comprising organic polymer having hydrophilic polar group and cross-linking structure in a molecule is an essential component, saturated moisture absorbing rates at 20° C. and 65% RH and 90% RH are not less than 20% by weight and not less than 40% by weight, respectively and the difference in the saturated moisture absorbing rates under such a condition is not less than 20% by weight is formed on a metal surface having excellent heat conductivity.
Abstract translation: 作为常规的热交换模块，已经使用无机类型的吸附剂如硅胶，沸石，活性氧化铝，活性炭和分子筛。 虽然这些吸附剂具有高吸湿能力和易于处理的特征，但它们具有耐久性，再生温度和细菌或真菌的产生的问题。 本发明的目的是解决无机吸附剂中所记载的这些问题，提供具有高热交换效率的节能型热交换器组件及其制造方法。 本发明是一种吸附型热交换组件，其特征在于，在分子中含有具有亲水极性基团和交联结构的有机聚合物的有机聚合物类型的吸附剂作为必需成分的吸水层 在20℃，65％RH和90％RH下的饱和吸湿率分别不小于20重量％且不低于40重量％，这种条件下的饱和吸湿速率差为 在具有优异导热性的金属表面上形成不少于20重量％。
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2.发明申请公开(公告)号：US20080033113A1
公开(公告)日：2008-02-07
申请号：US11661918
申请日：2005-07-29
Applicant: Masao Ieno , Ryosuke Nishida
Inventor： Masao Ieno , Ryosuke Nishida
IPC: C08F8/30
CPC classification number: D06M11/63 , D06M13/338 , D06M15/263 , D06M2101/28 , D06M2200/00 , D06M2200/30
Abstract: The present invention provides fiber and a fiber structure having a high flame-retarding property and high moisture-absorptive property which do not generate noxious gases such as hydrogen halide gas upon burning, do not elute heavy metal compounds and phosphorus compounds therefrom even when reclaimed upon discarding including a burning treatment and have an excellent processing property. The present invention discloses a highly flame-retarding and moisture-absorptive fiber, characterized in that, it comprises an organic polymer having a cross-linking structure and a salt-type carboxyl group in which at least a part of such a salt-type carboxyl group is a magnesium salt type and a saturated moisture absorption rate at 20° C. and 65% relative humidity and a limiting oxygen index are not less than 35% by weight and not less than 35, respectively, and a flame-retarding fiber structure wherein the highly flame-retarding and moisture-absorptive fiber is used in at least a part of the structure.
Abstract translation: 本发明提供具有高阻燃性和高吸水性的纤维和纤维结构，其在燃烧时不会产生诸如卤化氢气体等有害气体，即使在回收时也不会从其中洗脱重金属化合物和磷化合物 丢弃包括燃烧处理并具有优异的加工性能。 本发明公开了一种高阻燃和吸湿性纤维，其特征在于，它包括具有交联结构和盐型羧基的有机聚合物，其中至少一部分这种盐型羧基 基团为镁盐型，在20℃，65％相对湿度和极限氧指数下的饱和吸湿率分别为35重量％以上且35以上，阻燃性纤维结构体 其中所述高阻燃和吸湿纤维用于所述结构的至少一部分。
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3.发明申请Moisture absorptive and desorptive ultrafine particles and a product using said ultrafine particles 有权吸湿和解吸超细颗粒和使用所述超细颗粒的产品公开(公告)号：US20070185292A1
公开(公告)日：2007-08-09
申请号：US10585318
申请日：2004-11-18
Applicant: Ryosuke Nishida
Inventor： Ryosuke Nishida
IPC: C08F2/00
CPC classification number: B01J20/26 , B01D53/261 , B01D2253/30 , B01J20/261 , B01J20/267 , C08F8/44 , C08F2810/20 , F24F3/1411 , F24F3/1423 , F24F2203/1036 , F24F2203/1068 , Y10S526/909 , Y10T428/31855 , C08F220/44 , C08F220/14 , C08F212/36 , C08F212/14 , C08F8/12 , C08F2220/1825 , C08F220/06 , C08F2220/286
Abstract: To provide moisture absorptive and desorptive ultrafine particles having high moisture absorptive and moisture desorptive properties and particularly having an excellent moisture absorptive rate and also a product using said ultrafine particles. Moisture absorptive and desorptive ultrafine particles, characterized in that, the said particles consist of a cross-linked polymer containing 1.0 to 10.0 meq/g of a salt-type carboxyl group as a polar group where an average primary particle size is not more than 0.2 μm and saturated moisture absorptive ratios at 65% RH and 90% RH at 20° C. are not less than 20% by weight and not less than 40% by weight, respectively.
Abstract translation: 提供具有高吸水性和湿气解吸性能，特别是具有优异的吸湿速率的吸湿和解吸超细颗粒，以及使用所述超细颗粒的产品。 吸水性和解吸性超微粒子，其特征在于，所述粒子由含有1.0〜10.0meq / g的盐型羧基作为极性基团的交联聚合物构成，其中平均一次粒径不大于0.2 在20℃，65％RH和90％RH下的母体和饱和吸湿比分别不小于20重量％且不小于40重量％。
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4.发明申请公开(公告)号：US20080093059A1
公开(公告)日：2008-04-24
申请号：US11665962
申请日：2005-08-22
Applicant: Ryosuke Nishida
Inventor： Ryosuke Nishida
CPC classification number: F28F13/18 , B01D53/261 , B01D53/28 , B01J20/26 , B01J20/261 , B01J20/265 , B01J20/267 , F25B35/04 , F28F2245/02 , Y02A30/276 , Y10T29/49359
Abstract: As conventional heat exchange modules, adsorptive agents of an inorganic type such as silica gel, zeolite, active alumina, active carbon and molecular sieve have been used. While these adsorptive agents have characteristics of high moisture absorptive ability and easy handling, they have problems of durability, regenerating temperature and generation of bacteria or fungi. An object of the present invention is to solve these problems which are noted in the inorganic adsorptive agents and to provide a heat exchanger module of a energy conservation type having a high heat exchange efficiency and a method for the manufacture thereof. The present invention is a heat exchange module of a sorptive type, characterized in that, a moisture absorptive layer in which a sorptive agent of an organic polymer type comprising organic polymer having hydrophilic polar group and cross-linking structure in a molecule is an essential component, saturated moisture absorbing rates at 20° C. and 65% RH and 90% RH are not less than 20% by weight and not less than 40% by weight, respectively and the difference in the saturated moisture absorbing rates under such a condition is not less than 20% by weight is formed on a metal surface having excellent heat conductivity.
Abstract translation: 作为常规的热交换模块，已经使用无机类型的吸附剂如硅胶，沸石，活性氧化铝，活性炭和分子筛。 虽然这些吸附剂具有高吸湿能力和易于处理的特征，但它们具有耐久性，再生温度和细菌或真菌的产生的问题。 本发明的目的是解决无机吸附剂中所记载的这些问题，提供具有高热交换效率的节能型热交换器组件及其制造方法。 本发明是一种吸附型热交换组件，其特征在于，在分子中含有具有亲水极性基团和交联结构的有机聚合物的有机聚合物类型的吸附剂作为必需成分的吸水层 在20℃，65％RH和90％RH下的饱和吸湿率分别不小于20重量％且不低于40重量％，这种条件下的饱和吸湿速率差为 在具有优异导热性的金属表面上形成不少于20重量％。
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公开(公告)号：US06429265B2
公开(公告)日：2002-08-06
申请号：US09547878
申请日：2000-04-12
Applicant: Ryosuke Nishida
Inventor： Ryosuke Nishida
IPC: C08F844
Abstract: Disclosed herein is a moisture-absorbing and desorbing polymer, characterized in that, the said polymer is an organic high-molecular substance containing 1.0-8.0 meq/g of carboxyl group of a potassium type and having a cross-linking structure.
Abstract translation: 本文公开了一种吸湿解吸聚合物，其特征在于，所述聚合物是含有1.0-8.0meq / g钾型羧基并具有交联结构的有机高分子物质。
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Patent Agency Ranking6.发明授权
公开(公告)号：US6080797A
公开(公告)日：2000-06-27
申请号：US322407
申请日：1999-05-28
Applicant: Ryosuke Nishida
Inventor： Ryosuke Nishida
IPC: C08J9/28 , B01D53/26 , B01D53/28 , B01J20/26 , B01J20/28 , C08F2/04 , C08F8/00 , C08F8/30 , C08F20/00 , C08F20/44 , C08L33/20 , C09J9/28
CPC classification number: B01J20/28016 , B01D53/261 , B01D53/28 , B01J20/26 , B01J20/28004 , B01J20/28014 , B01J20/28023 , B01J20/28026 , B01J20/2803 , B01J20/28033 , B01J20/28057 , B01J20/28059 , B01J20/28085 , C08F8/12 , C08L33/20 , C08F2800/20
Abstract: There is disclosed a porous moisture-absorbing and desorbing polymer, characterized in that, said polymer is an organic polymer containing 2.0-12.0 meq/g of carboxyl-groups of a salt type, having a cross-linking structure and having macropores of not less than 1 m.sup.2 /g of specific surface area and 0.005-1.0 .mu.m of average pore size.
Abstract translation: 公开了一种多孔吸湿解吸聚合物，其特征在于，所述聚合物是含有2.0-12.0meq / g盐类羧基的有机聚合物，其具有交联结构并且具有不小于 比表面积为1m 2 / g以上，平均孔径为0.005〜1.0μm。
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7.发明授权Acrylonitrile polymer compositions, method for producing the compositions, and method for producing shaped articles from the compositions 失效丙烯腈聚合物组合物，制备组合物的方法，以及从组合物制备成型制品的方法
公开(公告)号：US5973106A
公开(公告)日：1999-10-26
申请号：US909850
申请日：1997-08-12
Applicant: Hirotaka Shiota , Ryosuke Nishida , Takahisa Kida , Noriyuki Kohara , Yoshihiro Watanabe , Ryuichi Kasahara
Inventor： Hirotaka Shiota , Ryosuke Nishida , Takahisa Kida , Noriyuki Kohara , Yoshihiro Watanabe , Ryuichi Kasahara
CPC classification number: D01F6/18 , Y10S526/935
Abstract: Disclosed are a hot-melting acrylonitrile (AN) polymer composition comprising a non-volatile component modified from AN alone or a AN monomer composition through chemical reaction, an AN polymer and water, a method for producing the composition, and a method for producing a shaped article of AN polymer by melting the composition under heat followed by shaping the melt. The composition and the shaped article do not contain toxic AN and AN monomer mixture.
Abstract translation: 公开了一种热熔丙烯腈（AN）聚合物组合物，其包含由AN单独改性的非挥发性组分或通过化学反应的AN单体组成，AN聚合物和水，该组合物的制备方法及其制备方法 通过在加热下熔化组合物，然后使熔体成形，形成AN聚合物的成型制品。 组合物和成型制品不含有毒的AN和AN单体混合物。
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8.发明授权
公开(公告)号：US5928785A
公开(公告)日：1999-07-27
申请号：US935487
申请日：1997-09-24
Applicant: Ryosuke Nishida , Hiroshi Ono
Inventor： Ryosuke Nishida , Hiroshi Ono
IPC: D06M11/00 , D01F1/02 , D01F1/10 , D01F6/18 , D01F6/54 , D06M11/45 , D06M11/49 , D06M11/74 , D06M11/79 , D06M11/83 , D06M101/00 , D06M101/16 , D06M101/18 , D06M101/28 , D02G3/00
CPC classification number: D01F6/18 , D01F1/10 , Y10T428/2927 , Y10T428/2967
Abstract: Disclosed herein is fine inorganic particles-containing fiber which is characterized in that the fiber contains fine inorganic particles with an average particle size of not larger than 10 .mu.m and the fiber-forming polymer contains not less than 0.01 milliequivalent/gram of any of the polar groups consisting of sulfonic acid group, carboxyl group and phosphoric acid group.
Abstract translation: 本发明公开了一种无机微粒纤维，其特征在于，该纤维含有平均粒径不大于10μm的无机微粒，纤维形成性聚合物含有0.01毫当量/ 由磺酸基，羧基和磷酸基组成的极性基团。
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9.发明授权Moisture absorptive and desorptive ultrafine particles and a product using said ultrafine particles 有权吸湿和解吸超细颗粒和使用所述超细颗粒的产品公开(公告)号：US07468414B2
公开(公告)日：2008-12-23
申请号：US10585318
申请日：2004-11-18
Applicant: Ryosuke Nishida
Inventor： Ryosuke Nishida
IPC: C08F8/44 , C08F8/12 , C08F220/02 , B01J20/26 , F24F3/14
CPC classification number: B01J20/26 , B01D53/261 , B01D2253/30 , B01J20/261 , B01J20/267 , C08F8/44 , C08F2810/20 , F24F3/1411 , F24F3/1423 , F24F2203/1036 , F24F2203/1068 , Y10S526/909 , Y10T428/31855 , C08F220/44 , C08F220/14 , C08F212/36 , C08F212/14 , C08F8/12 , C08F2220/1825 , C08F220/06 , C08F2220/286
Abstract: To provide moisture absorptive and desorptive ultrafine particles having high moisture absorptive and moisture desorptive properties and particularly having an excellent moisture absorptive rate and also a product using said ultrafine particles. Moisture absorptive and desorptive ultrafine particles, characterized in that, the said particles consist of a cross-linked polymer containing 1.0 to 10.0 meq/g of a salt-type carboxyl group as a polar group where an average primary particle size is not more than 0.2 μm and saturated moisture absorptive ratios at 65% RH and 90% RH at 20° C. are not less than 20% by weight and not less than 40% by weight, respectively.
Abstract translation: 提供具有高吸水性和湿气解吸性能，特别是具有优异的吸湿速率的吸湿和解吸超细颗粒，以及使用所述超细颗粒的产品。 吸水性和解吸性超微粒子，其特征在于，所述粒子由含有1.0〜10.0meq / g的盐型羧基作为极性基团的交联聚合物构成，其中平均一次粒径不大于0.2 在20℃，65％RH和90％RH下的母体和饱和吸湿比分别不小于20重量％且不小于40重量％。
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10.发明申请公开(公告)号：US20070158043A1
公开(公告)日：2007-07-12
申请号：US10587147
申请日：2004-11-29
Applicant: Ryosuke Nishida , Hideo Naka
Inventor： Ryosuke Nishida , Hideo Naka
IPC: D21H17/38
CPC classification number: D21H21/22 , C08L1/00 , C08L33/04 , C08L2205/22 , D21H13/18 , D21H13/40 , D21H17/38 , Y10T428/249921 , Y10T428/249924 , C08L2666/26
Abstract: Moisture absorptive and desorptive paper having both high moisture absorptive and desorptive properties and high dimensional stability is provided. Moisture absorptive and desorptive paper comprising organic fine particles having cross-linking structure and 1 to 10 mmol/g of acidic group where not less than 1 mmol/g of metal ion of at least one kind of metal selected from the group consisting of Li, Na, K, Mg and Ca is bonded to said acidic group, inorganic fiber and pulp-shaped fiber. By the basic constitution as above, on one hand the moisture absorptive and desorptive properties inherent to the organic fine particles are efficiently utilized by suppressing the use of binder as much as possible, and on the other hand deformation or thermal shrinking of the paper due to swelling in water at the time of absorption etc. is able to be suppressed.
Abstract translation: 提供具有高吸水性和解吸性和高尺寸稳定性的吸水和解吸纸。 包含具有交联结构的有机细颗粒和1至10mmol / g酸性基团的吸水和解吸纸，其中不少于1mmol / g金属离子选自Li， Na，K，Mg和Ca与所述酸性基团，无机纤维和纸浆状纤维结合。 通过上述基本结构，一方面通过尽可能地抑制粘合剂的使用，有效地利用了有机细颗粒所固有的吸湿和解吸性能，另一方面由于纸的变形或热收缩 能够抑制吸收时的水分膨胀等。
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