Abstract:
The disclosure relates to a process that includes blending a polyimide resin and a primary alky amine organic compound to produce an aryl amine functionalized polyimide, having aryl amine functionality in excess of any anhydride functionality. The polyimide resin can have a weight average molecular weight (Mw) from 5,000 to 100,000 daltons. The organic compound can include at least one primary aliphatic amine without a direct linkage of a nitrogen to an aryl group and without a functionality selected from a halogen functionality, a hydroxyl functionality, a sulfonic acid functionality, a sulfonic acid salt functionality, and combinations thereof. The disclosure also relates to alkyl imide functionalized polyimides also with aryl amine functionalized polyimides, having aryl amine functionality in excess of any anhydride functionality and articles produced therefrom.
Abstract:
The disclosure relates to a process that includes blending a polyimide resin and a primary alky amine organic compound to produce an aryl amine functionalized polyimide, having aryl amine functionality in excess of any anhydride functionality. The polyimide resin can have a weight average molecular weight (Mw) from 5,000 to 100,000 daltons. The organic compound can include at least one primary aliphatic amine without a direct linkage of a nitrogen to an aryl group and without a functionality selected from a halogen functionality, a hydroxyl functionality, a sulfonic acid functionality, a sulfonic acid salt functionality, and combinations thereof. The disclosure also relates to alkyl imide functionalized polyimides also with aryl amine functionalized polyimides, having aryl amine functionality in excess of any anhydride functionality and articles produced therefrom.
Abstract:
A method including the steps of extruding a melt including an amorphous polymer composition through a spinneret under a pressure of from 400 to 1500 psi to produce a spun fiber; collecting the spun fiber on a feeding roll without drawing the spun fiber; producing a solidified fiber from the spun fiber. The solidified fiber can have a dpf within a range of from greater than 0 to 2.5 dpf, and a shrinkage less than or equal to 2%. The method can also include collecting the solidified fiber onto a spool without subjecting the solidified fiber to a drawing step. A spinneret for producing fibers of at most 2.5 dpf from a composition comprising an amorphous polyetherimide polymer, the spinneret comprising a die having a plurality of round melt channels but no distribution plates. Fibers produced by the method and from the spinneret are also disclosed.
Abstract:
Small diameter poly(phenylene ether) fibers can be consistently formed from a composition comprising specific amounts of a poly(phenylene ether), a processing aid, and optionally a poly(alkenyl aromatic). The processing aid can be LLDPE, a petroleum resin, or combinations thereof. The processing aid can optionally further comprise a phosphite or phosphonate. Flame retardants are minimized or excluded from the composition. The fibers can be melt spun without entanglement or breakage, and this improved processability enables small diameter fibers to be formed. The resulting fibers can be used in reinforcing structures for printed circuit boards.