公开(公告)号：US20140325896A1

公开(公告)日：2014-11-06

申请号：US14265428

申请日：2014-04-30

Applicant: SHELL OIL COMPANY

Inventor： Johannes Pieter HAAN ,  Carolus Matthias Anna Maria MESTERS ,  Ivo Johannes DIJS ,  Arjen NIEUWHOF

IPC: C10G1/00 ,  C10L1/10 ,  C10G1/04

CPC classification number: C10G1/002 ,  C10B53/02 ,  C10G1/045 ,  C10G7/04 ,  C10G9/00 ,  C10G11/00 ,  C10G33/00 ,  C10G47/00 ,  C10G55/04 ,  C10G55/06 ,  C10G67/02 ,  C10G2300/1011 ,  C10G2300/1014 ,  C10G2300/203 ,  C10G2300/302 ,  C10G2300/308 ,  C10L1/02 ,  C10L1/023 ,  C10L1/10 ,  Y02E50/14 ,  Y02P30/20

Abstract: A process for converting a biomass material comprising a) pyrolyzing a biomass material to produce a biomass-derived pyrolysis product; b) providing a petroleum-derived hydrocarbon composition having a C7-asphaltenes content of equal to or more than 0.2 wt %, based on the total weight of the petroleum-derived hydrocarbon composition, which petroleum-derived hydrocarbon composition has a total acid number of equal to or more than 0.5 mg KOH/g and/or a density at 15.5° C. of equal to or more than 0.8 grams/ml and/or a viscosity at 37.8° C. of equal to or more than 500 centiStokes (cSt); c) mixing at least part of the biomass-derived pyrolysis product and at least part of the petroleum-derived hydrocarbon composition to produce a hydrocarbon-containing mixture; and d) dewatering the hydrocarbon-containing mixture to produce a dewatered hydrocarbon-containing mixture.

Abstract translation: 一种用于转化生物质材料的方法，包括a）热解生物质材料以产生生物质衍生的热解产物; b）基于石油衍生的烃组合物的总重量，提供具有等于或大于0.2重量％的C7-沥青质含量的石油衍生的烃组合物，该石油衍生烃组合物的总酸值为 等于或大于0.5mg KOH / g和/或15.5℃下的密度等于或大于0.8克/毫升和/或在37.8℃下的粘度等于或大于500厘沲（cSt ）; c）将至少部分生物质衍生的热解产物和至少部分来自石油的烃组合物混合以产生含烃混合物; 和d）使含烃混合物脱水以产生脱水的含烃混合物。

公开(公告)号：US20180208525A1

公开(公告)日：2018-07-26

申请号：US15745149

申请日：2016-07-15

Applicant: SHELL OIL COMPANY

Inventor： Ronald Van SCHOONEBEEK ,  Andrew David HORTON ,  Andrzej Aleksander PEKALSKI ,  Alouisius Nicolaas Renée BOS ,  Hendrik DATHE ,  Carolus Matthias Anna Maria MESTERS

IPC: C07C2/84 ,  B01J21/08 ,  B01J23/34 ,  B01J23/30 ,  B01J23/04 ,  B01J35/04 ,  B01J19/24

CPC classification number: C07C2/84 ,  B01J19/2415 ,  B01J21/08 ,  B01J23/04 ,  B01J23/30 ,  B01J23/34 ,  B01J35/04 ,  B01J2219/00051 ,  B01J2219/30475 ,  C07C2521/08 ,  C07C2523/04 ,  C07C2523/30 ,  C07C2523/34 ,  Y02P20/52 ,  C07C11/04 ,  C07C11/06 ,  C07C11/02

Abstract: The invention relates to a process for the oxidative coupling of methane comprising converting methane to one or more C2+ hydrocarbons in a reactor, wherein said process comprises contacting a reactor feed comprising methane and oxygen with a catalyst composition and wherein the linear gas velocity of said reactor feed in the region above the catalyst bed is at least 0.6 m/s, the linear gas velocity through the catalyst bed is at least 0.6 m/s and the partial pressure of oxygen in the reactor is greater than 0.08 MPa.

公开(公告)号：US20210147228A1

公开(公告)日：2021-05-20

申请号：US17045949

申请日：2019-04-04

Applicant: SHELL OIL COMPANY

Inventor： Jacobus Johannes Cornelis GEERLINGS ,  Carolus Matthias Anna Maria MESTERS ,  Leonardo SPANU

IPC: C01B3/00 ,  C01B32/162 ,  C01B3/26

Abstract: A process comprising passing methane through a reaction zone comprising a molten salt/metal bed under reaction conditions to produce a gas stream comprising hydrogen and a solid carbon product wherein the reaction zone comprises a hydrogen acceptor.

公开(公告)号：US20170081593A1

公开(公告)日：2017-03-23

申请号：US15126364

申请日：2015-03-16

Applicant: SHELL OIL COMPANY

Inventor： Gerrit Leendert BEZEMER ,  Carolus Matthias Anna Maria MESTERS ,  Johan Peter DEN BREEJEN

IPC: C10G2/00 ,  B01J23/75 ,  B01J23/94

CPC classification number: C10G2/332 ,  B01J8/001 ,  B01J8/02 ,  B01J8/065 ,  B01J8/067 ,  B01J23/75 ,  B01J23/94 ,  B01J37/18 ,  B01J2208/00061 ,  B01J2208/00628 ,  B01J2208/00646 ,  B01J2208/00716 ,  B01J2219/002 ,  B01J2219/00213 ,  B01J2219/00231 ,  C07C1/04 ,  C07C1/045 ,  C07C1/0455 ,  C07C1/047 ,  C07C1/048 ,  C10G2/341

Abstract: The invention relates to a method for start-up and operation of a Fischer-Tropsch reactor comprising the steps of: (a) providing a reactor with a fixed bed of reduced Fischer-Tropsch catalyst that comprises cobalt as catalytically active metal; (b) supplying a gaseous feed stream comprising carbon monoxide and hydrogen to the reactor, wherein the gaseous feed stream initially comprises a nitrogen-containing compound other than molecular nitrogen in an initial concentration in the range of from 0.1 to 50 ppmv based on the volume of the gaseous feed stream; (c) converting carbon monoxide and hydrogen supplied with the gaseous feed stream to the reactor into hydrocarbons at an initial reaction temperature, wherein the initial reaction temperature is set at a value of at least 200° C. and hydrocarbons are produced at a first yield; (d) maintaining the initial reaction temperature at the set value and maintaining the first yield by decreasing the concentration of the nitrogen-containing compound in the gaseous feed stream supplied to the reactor; (e) optionally increasing the reaction temperature after the concentration of the nitrogen-containing compound in the gaseous feed stream has decreased to a value below 100 ppbv.

公开(公告)号：US20210363013A1

公开(公告)日：2021-11-25

申请号：US17045970

申请日：2019-04-04

Applicant: SHELL OIL COMPANY

Inventor： Leonardo SPANU ,  Carolus Matthias Anna Maria MESTERS

IPC: C01B32/05 ,  B01J35/12 ,  B01J35/02 ,  B01J27/138 ,  B01J27/135 ,  B01J27/128 ,  B01J27/122 ,  B01J27/08 ,  B01J23/34 ,  B01J23/28 ,  B01J23/72 ,  B01J23/755 ,  B01J23/75 ,  B01J23/745 ,  B01J23/06 ,  B01J21/06 ,  B01J27/22 ,  B01J35/00 ,  C01B3/26

Abstract: A catalyst system, which is active in pyrolyzing methane at reaction temperatures above 700° C., comprising a molten salt selected from the group consisting of the halides of alkali metals; the halides of alkaline earth metals; the halides of zinc, copper, manganese, cadmium, tin and iron; and mixtures thereof, the molten salt having dispersed therein one or more catalytically active forms of iron, molybdenum, manganese, nickel, cobalt, zinc, titanium, and copper in the form of finely divided elemental metals, metal oxides, metal carbides or mixtures thereof.

公开(公告)号：US20150008159A1

公开(公告)日：2015-01-08

申请号：US14319483

申请日：2014-06-30

Applicant: SHELL OIL COMPANY

Inventor： Jeramie Joseph ADAMS ,  Franciscus Gondulfus Antonius VAN DEN BERG ,  Carolus Matthias Anna Maria MESTERS ,  Joseph FRANK ROVANI ,  John Francis SCHABRON

IPC: C10G25/00

CPC classification number: C10G25/003 ,  C10G2300/206 ,  C10G2300/302

Abstract: Toluene-insoluble hydrocarbon-containing compounds are selectively separated from a hydrocarbon-containing feedstock containing at least 5 wt. % n-heptane insoluble hydrocarbon-containing materials, wherein at least 10 wt. % of the n-heptane insoluble hydrocarbon-containing materials are toluene insoluble hydrocarbon-containing materials, by contacting the hydrocarbon-containing feedstock with a porous silica adsorbent having a median pore size diameter of less than 180 Å at a temperature of from 120° C. to 300° C.

Abstract translation: 甲苯不溶性含烃化合物与含有至少5wt。 ％正庚烷不溶性烃类材料，其中至少10重量％ 通过使含烃原料与中值孔径直径小于180的多孔二氧化硅吸附剂在120℃的温度下接触，使含有正庚烷不溶性烃的材料的％为不溶于甲苯的含烃材料 至300℃