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    PRODUCTION OF ETHANOL AND ENHANCED CO-PRODUCTS USING CO-PRODUCTS AS FEEDSTOCK
    1.
    发明申请
    PRODUCTION OF ETHANOL AND ENHANCED CO-PRODUCTS USING CO-PRODUCTS AS FEEDSTOCK 有权

    公开(公告)号：US20220002762A1

    公开(公告)日：2022-01-06

    申请号：US17297225

    申请日：2019-11-26

    Applicant: SHELL OIL COMPANY

    Inventor： Carolina BOTELLA-FRANCO ,  Sivakumar SADASIVAN VIJAYAKUMARI ,  Robert Lawrence BLACKBOURN ,  Paul Richard WEIDER ,  Ye-Mon CHEN ,  Yi LIANG ,  Daniel GAGNE ,  Ashley Villarreal BAUGH

    IPC: C12P7/10

    Abstract: Methods for production of ethanol, distiller's corn oil, and enhanced co-products are disclosed. Methods include obtaining a mixture of one or more co-products of an alcohol production process, which may include wet cake, performing hydrolysis of polysaccharides in the mixture to generate fermentable sugars, fermenting the fermentable sugars in the mixture to produce alcohol, distilling the mixture to remove alcohol from the mixture thereby producing alcohol-containing distillate and enhanced whole stillage, removing released oil from the fermented mixture before distillation and/or from the enhanced whole stillage after distillation, and recovering enhanced wet distiller's grains, enhanced thin stillage, and/or enhanced dried distiller's grains. Compositions disclosed herein include enhanced dried distiller's grains having a cmde protein content of at least 45% on a dry weight basis and having a total fat content of less than 10% on a dry weight basis.

    PROCESSES FOR THE PREPARATION OF AN OLEFINIC PRODUCT
    5.
    发明申请
    PROCESSES FOR THE PREPARATION OF AN OLEFINIC PRODUCT 有权
    制备烯烃产品的方法

    公开(公告)号：US20160355448A1

    公开(公告)日：2016-12-08

    申请号：US15103006

    申请日：2013-12-13

    Applicant: SHELL OIL COMPANY

    Inventor： Antonius Gijsbertus Johannes KLOTH ,  Sivakumar SADASIVAN VIJAYAKUMARI ,  Jeroen VAN WESTRENEN

    IPC: C07C1/20

    CPC classification number: C07C1/20 ,  B01D17/045 ,  C07C2529/00 ,  C07C2529/40 ,  C07C2529/70 ,  C10G3/42 ,  Y02P30/42 ,  C07C11/04 ,  C07C11/02 ,  C07C11/06

    Abstract: The invention provides a process for the preparation of an olefinic product, the process comprising the steps of: (a) reacting an oxygenate feedstock, comprising oxygenate, in an oxygenate reaction zone in the presence of a catalyst comprising a molecular sieve, at a temperature in the range of from 350 to 1000° C., to produce a reaction effluent stream, comprising at least oxygenate, olefin, water and acidic by-products; (b) cooling the reaction effluent stream by means of an indirect heat exchange to provide a cooled reaction effluent stream at a temperature greater than the dew point temperature of reaction effluent stream; (c) passing the cooled reaction effluent stream into a quench tower and contacting the cooled reaction effluent stream with a first aqueous liquid in the presence of at least one set of quench tower internals, to produce a quench tower gaseous stream comprising the olefinic product and a quench tower liquid stream comprising condensed material; and (d) separating the quench tower liquid stream into a hydrocarbon quench tower liquid stream and an aqueous quench tower liquid stream in the presence of one or more coalescers.

    Abstract translation: 本发明提供了一种制备烯烃产物的方法，该方法包括以下步骤：（a）在包含分子筛的催化剂存在下，在含氧化合物反应区中使含氧化合物的含氧化合物原料在温度 在350至1000℃的范围内，以产生至少包含含氧化合物，烯烃，水和酸性副产物的反应流出物流; （b）通过间接热交换冷却反应流出物流，以在高于反应流出物流的露点温度的温度下提供冷却的反应流出物流; （c）将冷却的反应流出物流送入骤冷塔并在至少一组骤冷塔内部存在下将冷却的反应流出物流与第一含水液体接触，以产生包含烯烃产物的骤冷塔气流，和 包括冷凝材料的骤冷塔液流; 和（d）在一种或多种聚结器的存在下将骤冷塔液流分离成烃淬火塔液流和水淬火塔液流。

    METHOD FOR CONVERTING OXYGENATES TO OLEFINS
    6.
    发明申请
    METHOD FOR CONVERTING OXYGENATES TO OLEFINS 审中-公开
    将氧化剂转化为烯烃的方法

    公开(公告)号：US20150119616A1

    公开(公告)日：2015-04-30

    申请号：US14526598

    申请日：2014-10-29

    Applicant: SHELL OIL COMPANY

    Inventor： Richard Addison SANBORN ,  Sivakumar SADASIVAN VIJAYAKUMARI ,  Leslie Andrew CHEWTER ,  Ye-Mon CHEN

    IPC: C07C1/22 ,  C07C4/06

    CPC classification number: C07C1/20 ,  B01J29/90 ,  C07C2529/06 ,  C07C2529/40 ,  Y02P20/52 ,  Y02P20/584 ,  Y02P30/42 ,  C07C11/04 ,  C07C11/06

    Abstract: A method for converting oxygenates to olefins comprising: a) feeding an oxygenate containing stream to a reactor; b) contacting the oxygenate containing stream with a molecular sieve catalyst under oxygenate-to-olefin conversion conditions to form products wherein the catalyst becomes deactivated due to the formation of coke on the catalyst; c) removing the products from the reactor; d) removing at least a portion of the catalyst from the reactor and sending the catalyst to a catalyst regenerator; e) contacting the catalyst with a regeneration medium and a fuel to combust at least a portion of the coke and to heat the catalyst; and f) returning at least a portion of the heated catalyst to the reactor wherein the fuel is a light hydrocarbon gas that has been at least partially diluted with nitrogen and/or air.

    Abstract translation: 一种将含氧化合物转化为烯烃的方法，包括：a）将含氧化合物的料料送入反应器; b）在含氧化合物至烯烃转化条件下使含氧化合物的物流与分子筛催化剂接触以形成其中催化剂由于在催化剂上形成焦炭而失活的产物; c）从反应器中取出产品; d）从反应器中除去至少一部分催化剂并将催化剂送到催化剂再生器; e）使催化剂与再生介质和燃料接触以燃烧至少一部分焦炭并加热催化剂; 和f）将至少一部分加热的催化剂返回到反应器，其中燃料是至少部分用氮气和/或空气稀释的轻质烃气体。

    PROCESS FOR EXTRACTING C4+ OLEFINS AND A PROCESS FOR CONVERTING OXYGENATES TO OLEFINS
    7.
    发明申请
    PROCESS FOR EXTRACTING C4+ OLEFINS AND A PROCESS FOR CONVERTING OXYGENATES TO OLEFINS 审中-公开
    提取C4 +烯烃的方法和将氧化剂转化为烯烃的方法

    公开(公告)号：US20140187834A1

    公开(公告)日：2014-07-03

    申请号：US14136021

    申请日：2013-12-20

    Applicant: Shell Oil Company

    Inventor： Sivakumar SADASIVAN VIJAYAKUMARI ,  Jeroen VAN WESTRENEN

    IPC: C07C1/22 ,  C07C4/02

    CPC classification number: C07C7/08 ,  C07C1/20 ,  Y02P30/42 ,  C07C11/06 ,  C07C11/04

    Abstract: The current invention provides a process for extracting C4+ olefins from a stream comprising C4+ olefins and C4+ paraffins, wherein an oxygenate, preferably methanol (MeOH) is used as extractant, and wherein the resulting extract phase comprising C4+ olefins and extractant is converted into olefins. Also provided is a process for converting oxygenates to olefins, wherein the oxygenate preferably comprises MeOH, wherein the oxygenate is used as extractant and wherein an extract phase comprising C4+ olefins and the extractant are converted into olefins.

    Abstract translation: 本发明提供了一种从包含C4 +烯烃和C4 +链烷烃的流中提取C4 +烯烃的方法，其中使用含氧化合物，优选甲醇（MeOH）作为萃取剂，其中所得到的包含C4 +烯烃和萃取剂的萃取相转化为烯烃。 还提供了将含氧物转化为烯烃的方法，其中含氧化合物优选包含MeOH，其中含氧化合物用作萃取剂，并且其中将包含C4 +烯烃和萃取剂的萃取相转化为烯烃。

    INTEGRATED PROCESS FOR THE PREPARATION OF OLEFINS
    8.
    发明申请
    INTEGRATED PROCESS FOR THE PREPARATION OF OLEFINS 审中-公开
    用于制备油脂的综合方法

    公开(公告)号：US20140187833A1

    公开(公告)日：2014-07-03

    申请号：US14135952

    申请日：2013-12-20

    Applicant: Shell Oil Company

    Inventor： Leslie Andrew CHEWTER ,  Sivakumar SADASIVAN VIJAYAKUMARI ,  Jeroen VAN WESTRENEN

    IPC: C07C7/13 ,  C07C4/04

    CPC classification number: C07C1/20 ,  C10G9/36 ,  C10G29/205 ,  C10G29/22 ,  C10G57/005 ,  C10G2300/1088 ,  C10G2400/20 ,  C10G2400/22 ,  Y02P20/125 ,  Y02P30/42 ,  Y02P30/464 ,  C07C11/04 ,  C07C11/06

    Abstract: The invention provides a process for preparing olefins, comprising: (a) reacting an oxygenate and/or olefinic feed in a first reactor in the presence of a molecular sieve catalyst to form a first effluent comprising olefins; (b) fractionating at least part of the first effluent into an olefinic product fraction comprising ethylene and propylene and an olefinic product fraction comprising olefins containing 4 or more carbon atoms; (c) subjecting a paraffin-containing hydrocarbon feedstock in a second reactor to a steam cracking process to form a second effluent comprising olefins including butadiene; (d) fractionating the second effluent into an olefinic product fraction comprising ethylene and/or propylene and an olefinic product fraction comprising mono-olefins containing 4 or more carbon atoms; and (e) recycling the olefinic product fraction comprising at least part of the ethylene and/or propylene as obtained in step (d) to the reactor in step (a).

    Abstract translation: 本发明提供一种制备烯烃的方法，包括：（a）在分子筛催化剂存在下使第一反应器中的含氧化合物和/或烯烃进料反应以形成包含烯烃的第一流出物; （b）将至少部分第一流出物分馏成包含乙烯和丙烯的烯烃产物馏分和含有含有4个或更多个碳原子的烯烃的烯烃产物馏分; （c）使第二反应器中的含链烷烃的原料进行蒸汽裂解处理以形成包含丁二烯的烯烃的第二流出物; （d）将第二流出物分馏成包含乙烯和/或丙烯的烯烃产物馏分和包含含有4个或更多个碳原子的单烯烃的烯烃产物馏分; 和（e）将步骤（d）中获得的至少部分乙烯和/或丙烯的烯烃产物馏分再循环到步骤（a）中的反应器中。

    PROCESS FOR CONVERTING OXYGENATES TO OLEFINS
    10.
    发明申请
    PROCESS FOR CONVERTING OXYGENATES TO OLEFINS 审中-公开
    将氧化剂转化为油脂的方法

    公开(公告)号：US20160257625A1

    公开(公告)日：2016-09-08

    申请号：US15032800

    申请日：2014-10-30

    Applicant: SHELL OIL COMPANY

    Inventor： Jeroen Gerard MARSMAN ,  Leslie Andrew CHEWTER ,  Sivakumar SADASIVAN VIJAYAKUMARI ,  Jeroen VAN WESTRENEN

    IPC: C07C1/20 ,  C07C7/04

    CPC classification number: C07C1/20 ,  C07C7/04 ,  C07C2529/00 ,  C07C2529/40 ,  Y02P30/42 ,  C07C11/04 ,  C07C11/06

    Abstract: A process for converting oxygenates to olefms comprising: a) contacting an oxygenate containing stream with a molecular sieve catalyst under oxygenate to olefms conversion conditions in a reactor to form an effluent comprising olefms; b) separating C3-hydrocarbons from C4+ hydrocarbons in the effluent; c) separating C1 hydrocarbons and other light gases from C2+ hydrocarbons; d) separating C2 hydrocarbons from the C3 hydrocarbons; e) sending the C3 hydrocarbons to a C3 splitter to separate pro pylene from propane; f) removing propylene from the C3 splitter; and g) removing propane from the C3 splitter.

    Abstract translation: 一种将含氧化合物转化为烯烃的方法，包括：a）在含氧化合物下使含氧化合物的物流与分子筛催化剂接触，以在烯烃转化条件下在反应器中形成含烯烃的流出物; b）将C3-烃与流出物中的C4 +烃分离; c）从C2 +烃分离C1烃和其他轻质气体; d）从C3烃中分离C2烃; e）将C3碳氢化合物送入C3分离器以将丙烯与丙烷分离; f）从C3分离器中除去丙烯; 和g）从C3分离器中除去丙烷。

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