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公开(公告)号：US20150322273A1
公开(公告)日：2015-11-12
申请号：US14804182
申请日：2015-07-20
IPC分类号： C09D5/24 , C09D141/00
CPC分类号： C09D5/24 , C08G77/18 , C09D141/00 , C09D183/04 , H01B1/24 , Y10T428/31663 , C08L65/00
摘要： The invention relates to a composition for an antistatic release agent comprising: a release component, a conductive component, an organic solvent, and water, wherein the release component contains a condensation-type organopolysiloxane, the conductive component contains a complex with a π-conjugated electrically conductive polymer and a polyanion having a molecular weight of 20,000 to 900,000, an amount of the conductive component is 1 to 300 parts by mass, relative to 100 parts by mass of the release component, at least one amine compound selected from the group consisting of a secondary amine, a tertiary amine or a quaternary ammonium salt is coordinated to or bonded to portion of anion groups in the polyanion as an ion pair, and the water content is 5% by mass or less, relative to a total amount of the composition for an antistatic release agent. The present invention can provide a composition for an antistatic release agent containing a release component, which can be sufficiently cured, and having superior antistatic properties and release properties.
摘要翻译： 本发明涉及一种用于抗静电脱模剂的组合物，其包含：释放组分，导电组分，有机溶剂和水，其中所述释放组分含有缩合型有机聚硅氧烷，所述导电组分含有具有 - 共轭导电性聚合物和分子量为20,000〜900,000的聚阴离子，相对于100质量份的剥离成分，导电性成分的量为1〜300质量份，至少1种选自 由仲胺，叔胺或季铵盐构成，与作为离子对的聚阴离子中的阴离子基团的一部分配位或结合，水分含量为5质量％以下 抗静电脱模剂的组合物。 本发明可以提供含有能够充分固化并具有优异的抗静电性和脱模性的释放组分的抗静电脱模剂组合物。
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公开(公告)号：US20150225574A1
公开(公告)日：2015-08-13
申请号：US14427212
申请日：2013-09-11
IPC分类号： C09D5/24 , C09D183/04
CPC分类号： C09D5/24 , C08G77/12 , C08G77/16 , C08G77/18 , C08G77/20 , C08G77/80 , C08G2261/1424 , C08G2261/3223 , C08G2261/794 , C08L65/00 , C09D183/04 , C09J7/401 , Y10T428/31663 , C08L25/18 , C08L83/00 , C08K5/56
摘要： An antistatic release agent of the present invention contains: a silicone emulsion including four mutually different types of organopolysiloxanes and an organohydrogenpolysiloxane: and a conductive complex of a π-conjugated electrically conductive a polymer and a polyanion; the content of the conductive complex being 0.5 to 100 parts by mass relative to 100 parts by mass of the total amount of organopolysiloxanes and organohydrogenpolysiloxane.
摘要翻译： 本发明的抗静电脱模剂包含：包含四种相互不同类型的有机聚硅氧烷和有机氢聚硅氧烷的聚硅氧烷乳液：和共轭导电聚合物和聚阴离子的导电络合物; 相对于100质量份的有机聚硅氧烷和有机氢聚硅氧烷的总量，导电络合物的含量为0.5〜100质量份。
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公开(公告)号：US20150218410A1
公开(公告)日：2015-08-06
申请号：US14426107
申请日：2013-09-05
IPC分类号： C09D141/00 , C09D5/24
摘要： The invention relates to an antistatic release agent comprising: a release component that contains a condensation-curing type organopolysiloxane, a conductive component that contains a complex of a π-conjugated electrically conductive polymer and a polyanion and an organic solvent, wherein the amount of the conductive component relative to 100 parts by mass of the release component is 1 to 300 parts by mass, at least one amine-type compound selected from the group consisting of a secondary amine, a tertiary amine or a quaternary ammonium salt is coordinated to or bonded to portion of anion groups in the polyanion as an ion pair, and the amine-type compound has one or more substituent selected from the group consisting of an alkyl group having 4 or more carbon atoms, an aryl group, an aralkyl group, an alkylene group, an arylene group, an aralkylene group and an oxyalkylene group.
摘要翻译： 本发明涉及一种抗静电脱模剂，其包含：含有缩合固化型有机聚硅氧烷的释放组分，含有共轭导电聚合物和聚阴离子与有机溶剂的络合物的导电组分，其中， 导电成分相对于100质量份的脱模成分为1〜300质量份，选自仲胺，叔胺或季铵盐中的至少一种胺型化合物与 与作为离子对的聚阴离子中的阴离子基部分结合，胺型化合物具有一个以上取代基，该取代基选自碳原子数4以上的烷基，芳基，芳烷基，芳烷基 亚烷基，亚芳基，亚芳烷基和氧化烯基。
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公开(公告)号：US09657181B2
公开(公告)日：2017-05-23
申请号：US14804182
申请日：2015-07-20
IPC分类号： H01B1/24 , C09D5/24 , C09D141/00 , C09D183/04 , C08G77/18
CPC分类号： C09D5/24 , C08G77/18 , C09D141/00 , C09D183/04 , H01B1/24 , Y10T428/31663 , C08L65/00
摘要： The invention relates to a composition for an antistatic release agent comprising: a release component, a conductive component, an organic solvent, and water, wherein the release component contains a condensation-type organopolysiloxane, the conductive component contains a complex with a π-conjugated electrically conductive polymer and a polyanion having a molecular weight of 20,000 to 900,000, an amount of the conductive component is 1 to 300 parts by mass, relative to 100 parts by mass of the release component, at least one amine compound selected from the group consisting of a secondary amine, a tertiary amine or a quaternary ammonium salt is coordinated to or bonded to portion of anion groups in the polyanion as an ion pair, and the water content is 5% by mass or less, relative to a total amount of the composition for an antistatic release agent. The present invention can provide a composition for an antistatic release agent containing a release component, which can be sufficiently cured, and having superior antistatic properties and release properties.
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公开(公告)号：US09624398B2
公开(公告)日：2017-04-18
申请号：US14426107
申请日：2013-09-05
摘要： The invention relates to an antistatic release agent comprising: a release component that contains a condensation-curing type organopolysiloxane, a conductive component that contains a complex of a π-conjugated electrically conductive polymer and a polyanion and an organic solvent, wherein the amount of the conductive component relative to 100 parts by mass of the release component is 1 to 300 parts by mass, at least one amine-type compound selected from the group consisting of a secondary amine, a tertiary amine or a quaternary ammonium salt is coordinated to or bonded to portion of anion groups in the polyanion as an ion pair, and the amine-type compound has one or more substituent selected from the group consisting of an alkyl group having 4 or more carbon atoms, an aryl group, an aralkyl group, an alkylene group, an arylene group, an aralkylene group and an oxyalkylene group.
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公开(公告)号：US09640296B2
公开(公告)日：2017-05-02
申请号：US14889407
申请日：2014-05-20
IPC分类号： H01B1/00 , H01B1/12 , C09D4/00 , C08K5/5455 , C08L101/12 , C09D5/24
CPC分类号： H01B1/127 , C08K5/5455 , C08L101/12 , C09D4/00 , C09D5/24 , H01B1/122 , H01B1/128
摘要： The present invention relates to an electroconductive polymer dispersion liquid characterized in containing a π-conjugated electrically conductive polymer, a polyanion, a compound represented by the following chemical formula (1), and a dispersion medium. In accordance with the present invention, an electroconductive polymer dispersion liquid capable of readily forming an electroconductive coating having excellent electrical conductivity, heat resistance, moist-heat resistance, and substrate adhesion property can be provided.[Chemical formula 1] CH2═C(R1)—CO—NH—R2—O—CO—NH—R3—Si(OR4)3 (1) In chemical formula (1), R1 represents a hydrogen atom or a methyl group, R2 and R3 each independently represent an arbitrary substituent group, and R4 represents a methyl group or an ethyl group.
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公开(公告)号：US20160086684A1
公开(公告)日：2016-03-24
申请号：US14889407
申请日：2014-05-20
CPC分类号： H01B1/127 , C08K5/5455 , C08L101/12 , C09D4/00 , C09D5/24 , H01B1/122 , H01B1/128
摘要： The present invention relates to an electroconductive polymer dispersion liquid characterized in containing a π-conjugated electrically conductive polymer, a polyanion, a compound represented by the following chemical formula (1), and a dispersion medium. In accordance with the present invention, an electroconductive polymer dispersion liquid capable of readily forming an electroconductive coating having excellent electrical conductivity, heat resistance, moist-heat resistance, and substrate adhesion property can be provided. [Chemical formula 1] CH2═C(R1)—CO—NH—R2—O—CO—NH—R3—Si(OR4)3 (1) In chemical formula (1), R1 represents a hydrogen atom or a methyl group, R2 and R3 each independently represent an arbitrary substituent group, and R4 represents a methyl group or an ethyl group.
摘要翻译： 本发明涉及一种导电聚合物分散液，其特征在于含有共轭导电聚合物，聚阴离子，由以下化学式（1）表示的化合物和分散介质。 根据本发明，可以提供能够容易地形成具有优异的导电性，耐热性，耐湿热性和基材粘附性的导电涂层的导电聚合物分散液。 [化学式1] CH2 = C（R1）-CO-NH-R2-O-CO-NH-R3-Si（OR4）3（1）在化学式（1）中，R1表示氢原子或甲基 ，R 2和R 3各自独立地表示任意的取代基，R 4表示甲基或乙基。
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公开(公告)号：US09688868B2
公开(公告)日：2017-06-27
申请号：US15108749
申请日：2015-01-09
IPC分类号： H01B1/00 , C09D5/24 , H01B1/12 , C09D7/12 , C09D201/00 , C08L65/00 , C09D133/06 , C09D167/02 , C09D181/02
CPC分类号： C09D5/24 , C08G2261/1424 , C08G2261/3223 , C08G2261/794 , C08L65/00 , C08L2203/206 , C09D7/40 , C09D7/63 , C09D133/068 , C09D167/02 , C09D181/02 , C09D201/00 , H01B1/124 , H01B1/127 , H01B1/128 , C08L25/18 , C08L33/068 , C08L67/04
摘要： A conductive polymer dispersion is provided which is capable of easily forming a conductive coating film having both excellent water resistance and excellent solvent resistance.The conductive polymer dispersion of the present invention includes a π-conjugated conductive polymer, a polyanion, a polyester resin having an alkali metal salt of an acid group, and a glycidyl group-containing acrylic resin. In the conductive polymer dispersion, the ratio (α/β) of total mass α of the polyester resin and the glycidyl group-containing acrylic resin to total mass β of the π-conjugated conductive polymer and the polyanion is in a range of 6.90 to 62.5.
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公开(公告)号：US09546310B2
公开(公告)日：2017-01-17
申请号：US14830454
申请日：2015-08-19
CPC分类号： C09K3/16 , B05D3/007 , B05D3/0254 , B05D3/12 , C08J7/047 , C08J7/08 , C08J2381/06 , C08J2429/02 , C08J2429/04 , H01B1/12 , H01B1/127
摘要： A method of manufacturing an antistatic film includes a preparation step of preparing a mixed liquid by mixing a polyvinyl alcohol with an aqueous conductive polymer dispersion in which a conductive composite containing a π-conjugated conductive polymer and a polyanion is included in a water-based dispersion medium; a coating step of obtaining a coating film by coating at least one surface of a film base with the mixed liquid; and a drying and stretching step of drying and stretching the coating film with heating.
摘要翻译： 制造抗静电膜的方法包括制备步骤，通过将聚乙烯醇与含有π共轭导电聚合物和聚阴离子的导电性复合物的水性导电聚合物分散体混合在水性分散体 中; 涂布步骤，通过用所述混合液体涂布薄膜基材的至少一个表面来获得涂膜; 以及通过加热干燥和拉伸涂膜的干燥和拉伸步骤。
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10.发明授权Antistatic release agent, antistatic release coated film and antistatic release base material 有权抗静电脱模剂，抗静电脱模涂膜及抗静电脱模基材公开(公告)号：US09505935B2
公开(公告)日：2016-11-29
申请号：US14032304
申请日：2013-09-20
摘要： The present invention relates to an antistatic release agent comprising an aqueous solution of an electrically conductive polymer complex composed of a π-conjugated electrically conductive polymer and a polyanion having an anionic group in a molecule thereof, an alkaline compound, a silicone emulsion and a dispersion medium, wherein the alkaline compound is at least one type of compound selected from the group consisting of an inorganic alkali, as amine compound and a nitrogen-containing aromatic cyclic compound, the content of the alkaline compound in the antistatic release agent is 0.7 times or more relative to the number of moles of the neutralization equivalent of the electrically conductive polymer complex, and the pH of the antistatic release agent at 25° C. is 10 or lower. The present invention can provide an antistatic release agent having superior storage stability for forming an antistatic release coated film.
摘要翻译： 本发明涉及一种抗静电脱模剂，其包含由π共轭导电聚合物和分子中具有阴离子基团的聚阴离子组成的导电聚合物络合物的水溶液，碱性化合物，硅氧烷乳液和分散体 介质，其中所述碱性化合物是选自无机碱，作为胺化合物和含氮芳族环状化合物的至少一种化合物，所述抗静电脱模剂中的碱性化合物的含量为0.7倍或 更优选相对于导电性聚合物配合物的中和当量的摩尔数，并且抗静电剂在25℃下的pH为10以下。 本发明可以提供一种具有优异的防静电脱模涂膜形成保存稳定性的抗静电脱模剂。
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