公开(公告)号：US3929859A

公开(公告)日：1975-12-30

申请号：US52472974

申请日：1974-11-18

Applicant: STANDARD OIL CO OHIO

Inventor： CALLAHAN JAMES L

IPC: C07B61/00 ,  B01J21/00 ,  B01J23/00 ,  B01J23/72 ,  B01J23/76 ,  B01J27/00 ,  C07C67/00 ,  C07C253/00 ,  C07C255/04 ,  C07C255/33 ,  C07C120/00 ,  C07C121/20 ,  C07C121/26 ,  C07C121/64

CPC classification number: B01J23/72 ,  B01J23/76 ,  C07C253/30 ,  C07C255/04

Abstract: The invention is the extrusion of sulfur from thiodinitriles to obtain the corresponding dinitrile by heating the thiodinitrile at a temperature of 200* to 700*C. For example, sulfur is extruded from thiodipropionitrile to obtain adiponitrile. This extrusion reaction can be either a strictly thermal reaction employing no other reactant or a reaction conducted in the presence of other gases, liquids or solids.

Abstract translation: 本发明是通过在200℃至700℃的温度下加热硫代腈来从硫代腈中挤出硫以获得相应的二腈。例如，硫从硫代二丙腈中挤出以获得己二腈。 该挤出反应可以是不使用其它反应物的严格热反应或在其它气体，液体或固体存在下进行的反应。

公开(公告)号：US3658877A

公开(公告)日：1972-04-25

申请号：US3658877D

申请日：1970-07-13

Applicant: STANDARD OIL CO OHIO

Inventor： CALLAHAN JAMES L ,  PRESSON ROBERT D ,  MILLER ARTHUR F

IPC: B01J8/00 ,  C07C121/02 ,  C07C121/32

CPC classification number: C07C253/26 ,  B01J8/005 ,  Y10S585/921 ,  Y10S585/922 ,  Y10S585/926 ,  Y10S585/95 ,  C07C255/08

Abstract: STEAM IS USED KEEP THE QUIESCENT ZONE ABOUT 200*F. COOLER THAN THE TURBULENT ZONE OF A FLUID-BED REACTOR UTILIZED IN THE AMMOXIDATION OF MONOOLEFINS TO UNSATURATED NITRIELS. STEAM ESCAPING FROM THE QUIESCENT ZONE INTO THE TURBULEN ZONE PREVENTS FUSION OF POWDERY CATALYST IN THE PRESENCE OF OXYGEN AND THE ADHESION OF FUSED CATALYST TO INTERNALS IN THE TOP PORTION OF THE REACTOR.