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    Thermoplastic vulcanizate with defined morphology for optimum elastic recovery
    1.
    发明授权
    Thermoplastic vulcanizate with defined morphology for optimum elastic recovery 失效
    具有规定形态的热塑性硫化橡胶用于最佳弹性回复

    公开(公告)号：US06579944B1

    公开(公告)日：2003-06-17

    申请号：US10069083

    申请日：2002-01-15

    申请人： Sabet Abdou-Sabet ,  Kenneth Emery Kear ,  Mary C. Boyce ,  Karla Drew Shaw

    发明人： Sabet Abdou-Sabet ,  Kenneth Emery Kear ,  Mary C. Boyce ,  Karla Drew Shaw

    IPC分类号： C08J300

    CPC分类号： C08J3/005 ,  C08L101/00

    摘要： A thermoplastic vulcanizate (TPV) is produced by melt blending until the volume fraction of dispersed rubber particles is greater than 0.5 preferably from 0.55 to 0.95, the remaining being the dispersed continuous plastic phase in a manner so as to develop a morphology which generates optimum elastic recovery. The majority (by volume) of large rubber particles are adjacent a small particle which is separated from one or more large particles by a critically thin, less than 0.1 $G(m)m thick, ligament of deformable plastic. When the majority of large particles evidence this morphology, as seen in a transmission electron microscope (TEM) photomicrograph, the TPV exhibits unexpectedly higher elastic recovery than if the ligaments were thicker. The foregoing is simulated in a micromechanical model which confirms, and in retrospect, predicts the observed actual elastic recovery of the TPV.

    摘要翻译： 通过熔融共混制造热塑性硫化橡胶（TPV），直到分散的橡胶颗粒的体积分数大于0.5，优选为0.55至0.95，剩余的是分散的连续塑性相，从而形成产生最佳弹性的形态 复苏。 大的（体积比）的大橡胶颗粒是与一个小的颗粒相邻的，这个小颗粒是通过一个极薄的，小于0.1 $ G（m）m的可变形塑料韧带与一个或多个大颗粒分开的。 当大多数大颗粒证明这种形态时，如在透射电子显微镜（TEM）显微照片中所见，与韧带较厚相比，TPV显示出意想不到的更高的弹性恢复。 前述内容在微机械模型中进行了模拟，该模型确认并回顾了TPV观察到的实际弹性恢复。

    Modification of thermolastic vulcanizates with a thermoplastic random copolymer of ethylene
    2.
    发明授权
    Modification of thermolastic vulcanizates with a thermoplastic random copolymer of ethylene 有权
    用乙烯热塑性无规共聚物改性热弹性硫化胶

    公开(公告)号：US06399710B1

    公开(公告)日：2002-06-04

    申请号：US09554796

    申请日：2000-07-03

    申请人： Terry M. Finerman ,  Maria D. Ellul ,  Sabet Abdou-Sabet

    发明人： Terry M. Finerman ,  Maria D. Ellul ,  Sabet Abdou-Sabet

    IPC分类号： C08L2302

    CPC分类号： C08L23/10 ,  C08L23/0815 ,  C08L2314/06 ,  C08L2666/04

    摘要： Random thermoplastic ethylene copolymers can be used to increase the elongation to break and toughness of thermoplastic vulcanizates. Polypropylene is a preferred thermoplastic phase. The rubber can be olefinic rubbers. Random thermoplastic ethylene copolymers are different from Ziegler-Natta ethylene copolymers as the compositional heterogeneity of the copolymer is greater with Ziegler-Natta copolymers. This difference results in substantial differences in properties (elongation to break and toughness) between thermoplastic vulcanizates modified with random thermoplastic ethylene and those modified with Ziegler-Natta ethylene copolymers. An increase in elongation to break results in greater extensibility in the articles made from a thermoplastic vulcanizate.

    摘要翻译： 随机热塑性乙烯共聚物可用于增加热塑性硫化橡胶的断裂伸长率和韧性。 聚丙烯是优选的热塑性相。 橡胶可以是烯烃橡胶。 无规热塑性乙烯共聚物不同于齐格勒 - 纳塔乙烯共聚物，因为齐格勒 - 纳塔共聚物，共聚物的组成异质性更大。 该差异导致用随机热塑性乙烯改性的热塑性硫化橡胶和用齐格勒 - 纳塔乙烯共聚物改性的热塑性硫化橡胶之间的性能（断裂伸长率和韧性）的实质差异。 增加断裂伸长率导致由热塑性硫化橡胶制成的制品更大的延展性。

    Thermoplastic vulcanizates from isobutylene rubber and either EPDM or a conjugated diene rubber
    7.
    发明授权
    Thermoplastic vulcanizates from isobutylene rubber and either EPDM or a conjugated diene rubber 失效
    来自异丁烯橡胶和EPDM或共轭二烯橡胶的热塑性硫化橡胶

    公开(公告)号：US5621045A

    公开(公告)日：1997-04-15

    申请号：US556673

    申请日：1995-11-13

    申请人： Raman Patel ,  Sabet Abdou-Sabet

    发明人： Raman Patel ,  Sabet Abdou-Sabet

    IPC分类号： C08J3/24 ,  C08K3/00 ,  C08L7/00 ,  C08L9/02 ,  C08L9/06 ,  C08L21/00 ,  C08L23/00 ,  C08L23/02 ,  C08L23/10 ,  C08L23/16 ,  C08L23/18 ,  C08L23/22 ,  C08L23/26 ,  C08L23/28 ,  C08L15/02

    CPC分类号： C08L7/00 ,  C08L23/10 ,  C08L9/02

    摘要： Thermoplastic vulcanizates from semicrystalline polyolefins and blends of crosslinked rubbers are disclosed. The blends are a mixture of at least two rubbers. One rubber is a copolymer predominantly of C.sub.4 to C.sub.7 isomonoolefins (e.g. isobutylene), along with optional monomers of conjugated dienes and/or p-alkylstyrene. This copolymer is optionally halogenated. The second rubber is ethylene/propylene rubber, natural rubber or a rubber polymerized predominantly from a conjugated diene. Such rubbers include polybutadiene, nitrile rubber, butadiene-styrene copolymers or combinations thereof.

    摘要翻译： 公开了来自半结晶聚烯烃的热塑性硫化橡胶和交联橡胶的共混物。 混合物是至少两种橡胶的混合物。 一种橡胶是主要由C4至C7异单烯烃（例如异丁烯）共聚的共聚物，以及共轭二烯和/或对 - 烷基苯乙烯的任选单体。 该共聚物任选卤化。 第二橡胶是乙烯/丙烯橡胶，天然橡胶或主要由共轭二烯聚合的橡胶。 这种橡胶包括聚丁二烯，丁腈橡胶，丁二烯 - 苯乙烯共聚物或其组合。

    Acrylate-modified ethylene-vinyl acetate polymer
    9.
    发明授权
    Acrylate-modified ethylene-vinyl acetate polymer 失效
    丙烯酸酯改性乙烯 - 乙酸乙烯酯聚合物

    公开(公告)号：US4104329A

    公开(公告)日：1978-08-01

    申请号：US805535

    申请日：1977-06-10

    申请人： Sabet Abdou-Sabet ,  J. Paul Ferrin

    发明人： Sabet Abdou-Sabet ,  J. Paul Ferrin

    IPC分类号： C08F218/00 ,  C08F218/02 ,  C08F255/02 ,  C08F263/04

    CPC分类号： C08F255/026 ,  C08F263/04

    摘要： Ethylene-vinyl acetate polymer is modified by reaction with a polyfunctional acrylate which improves the processing characteristics of the polymer. The cured modified polymers exhibit improved properties including lower hardness and greater dimensional stability.

    摘要翻译： 通过与改善聚合物的加工特性的多官能丙烯酸酯反应来改性乙烯 - 乙酸乙烯酯聚合物。 固化的改性聚合物表现出改善的性能，包括较低的硬度和更大的尺寸稳定性。

    Use of a silane grafted polyolefin in EPDM/polyolefin thermoplastic vulcanizates to improve compression set
    10.
    发明授权
    Use of a silane grafted polyolefin in EPDM/polyolefin thermoplastic vulcanizates to improve compression set 有权
    在EPDM /聚烯烃热塑性硫化胶中使用硅烷接枝聚烯烃，以改善压缩永久变形

    公开(公告)号：US06476132B1

    公开(公告)日：2002-11-05

    申请号：US09360014

    申请日：1999-07-23

    申请人： Sabet Abdou-Sabet ,  Robert E. Medsker ,  Raman Patel

    发明人： Sabet Abdou-Sabet ,  Robert E. Medsker ,  Raman Patel

    IPC分类号： C06L8300

    CPC分类号： C08L23/10 ,  C08L23/16 ,  C08L51/06 ,  C08L83/04 ,  C08L2666/04 ,  C08L2666/24

    摘要： A thermoplastic vulcanizate (TPV) from a blend of a first thermoplastic polyolefin, a second thermoplastic olefin and a rubber is described. The rubber is crosslinked with a hydrosilylation crosslinking agent. The second polyolefin includes at least one OR group pendant to a Si atom chemically attached via one or more intermediate molecules to said second polyolefin. R can be hydrogen or an alkyl of 1 to 8 carbon atoms. The OR groups can react with the hydrosilylation catalyst to reduce the compression set of the TPV.

    摘要翻译： 描述了来自第一热塑性聚烯烃，第二热塑性烯烃和橡胶的共混物的热塑性硫化橡胶（TPV）。 橡胶与氢化硅烷化交联剂交联。 第二聚烯烃包括通过一个或多个中间分子与所述第二聚烯烃化学连接的Si原子的至少一个OR基团。 R可以是氢或1至8个碳原子的烷基。 OR基团可以与氢化硅烷化催化剂反应以降低TPV的压缩永久变形。