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    Process for the preparation of pesticides
    5.
    发明授权
    Process for the preparation of pesticides 失效
    农药制备工艺

    公开(公告)号：US6156923A

    公开(公告)日：2000-12-05

    申请号：US762217

    申请日：1996-12-06

    申请人： Saleem Farooq ,  Stephan Trah ,  Hugo Ziegler ,  Rene Zurfluh

    发明人： Saleem Farooq ,  Stephan Trah ,  Hugo Ziegler ,  Rene Zurfluh

    IPC分类号： C07C249/04 ,  C07C249/12 ,  C07C251/48 ,  C07C251/60

    CPC分类号： C07C249/12 ,  C07C251/48 ,  C07C251/60

    摘要： The invention relates to a process for the preparation of compounds of the formula ##STR1## or, if appropriate, a tautomer thereof, in each case in the free form or in salt form, in whichA, X, Y, Z, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.7, R.sub.9 and n are as defined in claim 1 and the C.dbd.N double bond marked with E has the E configuration, which comprisesa1) reacting either a compound of the formula (II) mentioned above with a compound of the formula (III) mentioned above, in which X.sub.1 is a leaving group, ora2) a compound of the formula (IV) mentioned above, if appropriate in the presence of a base, with a compound of the formula (V) mentioned above, orb1) reacting a compound of the formula (VI) mentioned above with a compound of the formula R.sub.7 --A--X.sub.2 (VII), in which X.sub.2 is a leaving group, and either further reacting the compound thus obtainable, of the formula (IV), for example according to method a2), orb2) reacting it with hydroxylamine or a salt thereof, if appropriate in the presence of a basic or acid catalyst, and further reacting the compound thus obtainable, of the formula (II), for example according to method a1), orc) reacting a compound of the formula (VII), mentioned above with a C.sub.1 -C.sub.6 alkyl nitrite and further reacting the compound thus obtainable, of the formula (VI), for example according to method b), the E isomers of the compounds of the formulae (II), (IV) and (VI), a process for their preparation and their use for the preparation of compounds of the formula (I).

    摘要翻译： 本发明涉及一种制备下式的化合物或其合适的互变异构体的方法，其各自为游离形式或盐形式，其中A，X，Y，Z，R 2，R 3，R 4 ，R 5，R 7，R 9和n如权利要求1中所定义，并且用E标记的C = N双键具有E构型，其包括a1）使上述式（II）的化合物与 上述式（III），其中X1是离去基团，或a2）上述式（Ⅳ）化合物，如果合适，在碱的存在下，与上述式（Ⅴ）化合物， 或b1）使上述式（Ⅵ）化合物与式R7-A-X2（Ⅶ）化合物反应，其中X 2为离去基团，并进一步使由此得到的化合物（式（Ⅴ） IV），例如根据方法a2），或b2）如果合适，在碱性或酸性催化剂存在下，使其与羟胺或其盐反应， 进一步使由式（II）得到的化合物，例如按照方法a1）进行反应，或c）使上述式（Ⅶ）化合物与亚硝酸C 1 -C 6烷基酯反应，然后进一步使化合物 式（Ⅵ）化合物的E异构体，其制备方法及其制备方法（Ⅵ）的制备方法及其制备方法 式（I）的化合物。

    Process for the preparation of pesticides
    6.
    发明授权
    Process for the preparation of pesticides 失效
    农药制备工艺

    公开(公告)号：US06646151B1

    公开(公告)日：2003-11-11

    申请号：US09670147

    申请日：2000-09-26

    申请人： Saleem Farooq ,  Stephan Trah ,  Hugo Ziegler ,  René Zurflüh

    发明人： Saleem Farooq ,  Stephan Trah ,  Hugo Ziegler ,  René Zurflüh

    IPC分类号： C07C24904

    CPC分类号： C07C249/12 ,  C07C251/48 ,  C07C251/60

    摘要： The invention relates to a process for the preparation of compounds of the formula or, if appropriate, a tautomer thereof, in each case in the free form or in salt form, in which A, X, Y, Z, R2, R3, R4, R5, R7, R9 and n are as defined in claim 1 and the C═N double bond marked with E has the E configuration, which comprises a1) reacting either a compound of the formula (II) mentioned above with a compound of the formula (III) mentioned above, in which X1 is a leaving group, or a2) a compound of the formula (IV) mentioned above, if appropriate in the presence of a base, with a compound of the formula (V) mentioned above, or b1) reacting a compound of the formula (VI) mentioned above with a compound of the formula R7—A—X2 (VII), in which X2 is a leaving group, and either further reacting the compound thus obtainable, of the formula (IV), for example according to method a2), or b2) reacting it with hydroxylamine or a salt thereof, if appropriate in the presence of a basic or acid catalyst, and further reacting the compound thus obtainable, of the formula (II), for example according to method a1), or c) reacting a compound of the formula (VIII), mentioned above with a C1-C6alkyl nitrite and further reacting the compound thus obtainable, of the formula (VI), for example according to method b), the E isomers of the compounds of the formulae (II), (IV) and (VI), a process for their preparation and their use for the preparation of compounds of the formula (I).

    摘要翻译： 本发明涉及一种制备式的化合物的方法，如果合适，其合适的是其互变异构体，其各自为游离形式或盐形式，其中A，X，Y，Z，R 2，R 3，R 4， R5，R7，R9和n如权利要求1中所定义，并且用E标记的C = N双键具有E构型，其包括a）使上述式（II）的化合物与式（II） III），其中X1是离去基团，ora2）如果合适的话，在碱的存在下，上述式（Ⅳ）的化合物与上述式（Ⅴ）的化合物相同，反应1）使 上述式（Ⅵ）化合物与式R7-A-X2（Ⅶ）化合物反应，其中X 2为离去基团，并进一步使由此得到的式（Ⅳ）化合物与 根据方法a2）的示例，orb2）如果合适，在碱性或酸性催化剂存在下，使其与羟胺或其盐反应，以及 进一步使由式（II）得到的化合物，例如按照方法a1）进行反应，或者使上述式（Ⅷ）化合物与亚硝酸C 1 -C 6烷基酯反应，并进一步使由此得到的化合物， 式（Ⅵ）化合物的方法，例如根据方法b），式（II），（Ⅳ）和（Ⅵ）化合物的E异构体，其制备方法及其制备方法 式（I）。

    Triazoline and isoxazoline bis-oxime derivatives and their use as pesticides
    9.
    发明授权
    Triazoline and isoxazoline bis-oxime derivatives and their use as pesticides 失效
    三唑啉和异恶唑啉双肟衍生物及其作为农药的用途

    公开(公告)号：US5932583A

    公开(公告)日：1999-08-03

    申请号：US981116

    申请日：1997-12-23

    申请人： Hugo Ziegler ,  Stephan Trah ,  Rene Zurfluh ,  Anthony Cornelius O'Sullivan

    发明人： Hugo Ziegler ,  Stephan Trah ,  Rene Zurfluh ,  Anthony Cornelius O'Sullivan

    IPC分类号： A01N43/647 ,  A01N43/653 ,  A01N43/80 ,  C07C251/52 ,  C07C251/58 ,  C07C251/60 ,  C07C265/12 ,  C07C279/18 ,  C07C281/06 ,  C07C331/28 ,  C07C335/18 ,  C07D249/08 ,  C07D249/12 ,  C07D261/10 ,  C07D261/12 ,  C07D401/12 ,  C07D403/12 ,  C07D413/12 ,  C07D417/12 ,  A61K31/41 ,  A61K31/42 ,  C07C249/08

    CPC分类号： C07D261/10 ,  A01N43/647 ,  A01N43/80 ,  C07C251/52 ,  C07C251/58 ,  C07C251/60 ,  C07C265/12 ,  C07C279/18 ,  C07C331/28 ,  C07C335/18 ,  C07D249/12 ,  C07D261/12 ,  C07D401/12 ,  C07D403/12 ,  C07D413/12 ,  C07D417/12

    摘要： Bis-oxime derivatives of the formula I ##STR1## W is oxygen or sulfur, and the other substituents defined as follows: R.sub.1 =hydrogen, C.sub.1 -C.sub.4 alkyl; cyclopropyl;R.sub.2 =hydrogen, C.sub.1 -C.sub.6 alkyl; halo(C.sub.1 -C.sub.6) alkyl; C.sub.2 -C.sub.6 alkoxyalkyl; C.sub.3 -C.sub.6 cycloalkyl; substituted or unsubstituted aryl; substituted or unsubstituted heteroaryl; cyano; C.sub.1 -C.sub.6 alkoxycarbonyl; C.sub.1 -C.sub.6 alkyl-S(O).sub.n ; substituted or unsubstituted aryl-S(O).sub.n ; C.sub.1 -C.sub.6 alkoxy; substituted or unsubstituted aryloxy; substituted or unsubstituted heteroaryloxy; unsubstituted or mono- to trimethyl-substituted heterocyclyl; substituted or unsubstituted aryl-C.sub.1 -C.sub.6 alkyl; substituted or unsubstituted heteroaryl-C.sub.1 -C.sub.6 alkyl;R.sub.3 =hydrogen; C.sub.1 -C.sub.6 alkyl; C.sub.1 -C.sub.6 haloalkyl having 1 to 5 halogen atoms; C.sub.1 -C.sub.4 alkoxy-C.sub.1 -C.sub.2 -alkyl; unsubstituted or mono- to trihalo-substituted C.sub.1 -C.sub.6 alkenyl; C.sub.2 -C.sub.6 alkynyl; unsubstituted or mono- to tetrahalo-substituted C.sub.3 -C.sub.6 cycloalkyl-C.sub.1 -C.sub.4 alkyl;n=0 to 2;R.sub.8 =H, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.3 -C.sub.6 cycloalkyl;X=OR.sub.5, SR.sub.5, NR.sub.6 R.sub.7, halogen (especially Cl);R.sub.6, R.sub.7 =independently of one another H, C.sub.1 -C.sub.4 alkyl, C.sub.3 -C.sub.4 alkenyl, C.sub.3 -C.sub.4 alkynyl;R.sub.5 =C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.3 haloalkyl, are fungicidal, acaricidal and insecticidal active ingredients for agriculture. They can be employed as formulated crop protection compositions.

    摘要翻译： PCT No.PCT / EP96 / 02695 Sec。 371 1997年12月23日第 102（e）1997年12月23日PCT PCT 1996年6月21日PCT公布。 出版物WO97 / 02255 日期1997年1月23日式I W的双肟衍生物是氧或硫，其它取代基定义如下：R1 =氢，C1-C4烷基; 环丙基 R2 =氢，C1-C6烷基; 卤代（C 1 -C 6）烷基; C2-C6烷氧基烷基; C 3 -C 6环烷基; 取代或未取代的芳基; 取代或未取代的杂芳基; 氰基; C1-C6烷氧基羰基; C 1 -C 6烷基-S（O）n; 取代或未取代的芳基-S（O）n; C1-C6烷氧基; 取代或未取代的芳氧基; 取代或未取代的杂芳氧基; 未取代或单 - 三甲基取代的杂环基; 取代或未取代的芳基-C 1 -C 6烷基; 取代或未取代的杂芳基-C 1 -C 6烷基; R3 =氢; C1-C6烷基; 具有1至5个卤素原子的C 1 -C 6卤代烷基; C 1 -C 4烷氧基-C 1 -C 2 - 烷基; 未取代或单 - 三卤代取代的C 1 -C 6烯基; C2-C6炔基; 未取代或单 - 四卤代取代的C 3 -C 6环烷基-C 1 -C 4烷基; n = 0〜2; R8 = H，C1-C4烷基，C1-C4卤代烷基，C3-C6环烷基; X = OR5，SR5，NR6R7，卤素（特别是Cl）; R6，R7 =彼此独立地为H，C1-C4烷基，C3-C4链烯基，C3-C4炔基; R5 = C1-C4烷基，C1-C3卤代烷基，是农业的杀真菌，杀螨和杀虫活性成分。 它们可以用作配制的作物保护组合物。