公开(公告)号：US20160096924A1

公开(公告)日：2016-04-07

申请号：US14598506

申请日：2015-01-16

申请人： SAMSUNG SDI CO., LTD.

发明人： Jin Kyu KIM ,  So Young KWON ,  Young Sub JIN ,  Joon Sung KIM ,  Su Yeong SON ,  Ki Yon LEE ,  Sang Kyun IM ,  Suk Min JUN

IPC分类号： C08G69/30

CPC分类号： C08G69/30 ,  C08G69/26

摘要： A polyamide resin is a polymer of an adipic acid-containing dicarboxylic acid component and an m-xylenediamine-containing diamine component, wherein the polymer includes about 100 ppm or less of phosphorus and about 100 ppm or less of sodium (Na), and has a gel content of about 0.5% or less as measured on a specimen prepared by melting about 10 g of the polymer at about 260° C., maintaining the molten polymer for about 30 minutes, and then cooling the molten polymer to room temperature. The polyamide resin can exhibit excellent heat resistance and can reduce or prevent gel generation upon polymerization or molding.

摘要翻译： 聚酰胺树脂是含己二酸的二羧酸成分和含有间二甲苯胺的二胺成分的聚合物，其中聚合物包含约100ppm以下的磷和约100ppm以下的钠（Na），并且具有 在通过在约260℃熔化约10g聚合物制备的样品上测量的凝胶含量为约0.5％或更低，保持熔融聚合物约30分钟，然后将熔融聚合物冷却至室温。 聚酰胺树脂可以表现出优异的耐热性，并且可以减少或防止聚合或模塑时的凝胶生成。

公开(公告)号：US20160144337A1

公开(公告)日：2016-05-26

申请号：US14899203

申请日：2013-10-22

申请人： Samsung SDI Co., Ltd..

发明人： Sang Kyun IM ,  Suk Min JUN ,  Shin Hyo BAE ,  So Young KWON ,  Eun Ju LEE ,  Young Sub JIN ,  Kyoung Kyun PARK

IPC分类号： B01J19/28 ,  C08G64/20 ,  C08G63/80 ,  C08G69/06

CPC分类号： B01J19/28 ,  B01F7/00466 ,  B01F9/08 ,  B01F13/06 ,  B01F15/065 ,  B01F2015/061 ,  B01F2015/062 ,  B01F2215/0431 ,  B01J19/0066 ,  B01J19/0073 ,  B01J19/18 ,  B01J2219/00094 ,  B01J2219/00159 ,  B01J2219/00162 ,  B01J2219/00166 ,  B01J2219/00168 ,  B01J2219/00186 ,  B01J2219/00189 ,  B01J2219/0204 ,  B01J2219/182 ,  C08F2/01 ,  C08G63/80 ,  C08G64/205 ,  C08G69/06 ,  C08G69/30 ,  Y02P20/149

摘要： The continuous solid-state polymerisation device of the present invention comprises: a feeder for continuously introducing a prepolymer; a horizontal reactor which is connected via a first connecting part to the feeder and receives the prepolymer from the feeder so as to subject same to solid-state polymerisation, wherein the reactor itself is rotated; a stirring device which comprises a stirring shaft rotating inside the horizontal reactor, in the direction opposite to that of the rotational axis of the horizontal reactor, and comprises stirring blades joined vertically to the stirring shaft; and a chamber which is connected via a second connecting part to the horizontal reactor and, once the solid-state polymerisation has been completed, receives the resulting polymer discharged from the horizontal reactor, and, here, the feeder, the horizontal reactor and the chamber are in a vacuum state. The continuous solid-state polymerisation device prevents the formation of prepolymer stagnation zones, and allows solid-state polymerisation to take place continuously in the vacuum state without any inert gas.

摘要翻译： 本发明的连续固态聚合装置包括：用于连续引入预聚物的进料器; 水平反应器，其经由第一连接部分连接到进料器并且接收来自进料器的预聚物以便同时进行固相聚合，其中反应器本身旋转; 搅拌装置，包括在水平反应器内沿与水平反应器的旋转轴线相反的方向旋转的搅拌轴，并包括垂直于搅拌轴连接的搅拌叶片; 以及经由第二连接部分连接到水平反应器的室，并且一旦固态聚合已经完成，则接收从水平反应器排出的所得聚合物，并且在这里，进料器，水平反应器和室 处于真空状态。 连续固态聚合装置防止预聚物停滞区的形成，并且允许固态聚合在真空状态下连续发生而没有任何惰性气体。

公开(公告)号：US20160090448A1

公开(公告)日：2016-03-31

申请号：US14583429

申请日：2014-12-26

申请人： Samsung SDI Co., Ltd.

发明人： So Young KWON ,  Jin Kyu KIM ,  Young Sub JIN ,  Joon Sung KIM ,  Ki Yon LEE ,  Suk Min JUN

IPC分类号： C08G69/26 ,  C08G69/30

CPC分类号： C08G69/265 ,  C08G69/30

摘要： A copolymerized polyamide resin includes a polymer of a monomer mixture comprising a dicarboxylic acid component comprising adipic acid and a dicarboxylic acid represented by Formula 1, wherein each R1 is independently a C1 to C5 alkyl group and a is an integer from 0 to 4, and a diamine component comprising m-xylene diamine and a diamine represented by Formula 2, wherein A is a single bond or a C1 to C10 hydrocarbon group, R2 and R3 are each independently a C1 to C5 alkyl group, and b and c are each independently an integer from 0 to 4, wherein the copolymerized polyamide resin has a difference between a melting temperature (Tm) and a crystallization temperature (Tc) of about 50° C. or more. The copolymerized polyamide resin may have excellent heat resistance and reduced or no gel generation and yellowing phenomenon in a molding process.

摘要翻译： 共聚聚酰胺树脂包括单体混合物的聚合物，其包含包含己二酸和由式1表示的二羧酸的二羧酸组分的单体混合物，其中每个R 1独立地为C 1至C 5烷基，a为0至4的整数，并且 包含间二甲苯二胺和由式2表示的二胺的二胺组分，其中A是单键或C1至C10烃基，R2和R3各自独立地为C1至C5烷基，b和c各自独立地为 0〜4的整数，其中共聚聚酰胺树脂的熔融温度（Tm）和结晶温度（Tc）之差在约50℃以上。 共聚聚酰胺树脂可以在成型工艺中具有优异的耐热性和减少的或没有凝胶产生和泛黄现象。

公开(公告)号：US20150065681A1

公开(公告)日：2015-03-05

申请号：US14465860

申请日：2014-08-22

申请人： Samsung SDI Co., Ltd

发明人： Jin Kyu KIM ,  So Young KWON ,  Sang Kyun IM ,  Ki Yon LEE ,  Suk Min JUN ,  Gook Geon BAE

IPC分类号： C08G69/28 ,  C07C231/02 ,  C07C69/96 ,  C07C67/00 ,  C07C69/78 ,  C07C68/00 ,  C08G69/26 ,  C07C233/76

CPC分类号： C08G69/28 ,  C07C231/02 ,  C08G69/265 ,  C08J3/12 ,  C07C233/78

摘要： Disclosed herein is a method of preparing prepolymer particles. The method includes injecting a prepolymer in a solution state by bottom-up type injection to form prepolymer particles by removing a solvent from the prepolymer in a solution state. The method can prepare prepolymer particles, which can be used in solid-state polymerization, using a bottom-up type flash process.

摘要翻译： 本文公开了制备预聚物颗粒的方法。 该方法包括以溶液状态从预聚物中除去溶剂，通过自下而上型注射将溶液状态的预聚物注入以形成预聚物颗粒。 该方法可以制备可用于固态聚合的预聚物颗粒，使用自底向上的闪蒸法。

公开(公告)号：US20160083509A1

公开(公告)日：2016-03-24

申请号：US14685927

申请日：2015-04-14

申请人： Samsung SDI Co., Ltd.

发明人： Sang Kyun IM ,  Shin Hyo BAE ,  Su Yeong SON ,  Ki Yon LEE ,  So Young KWON ,  Joon Sung KIM ,  Jin Kyu KIM ,  Tae Joon PARK ,  Young Sub JIN

IPC分类号： C08G63/60

CPC分类号： C08G69/44

摘要： A polyamide ester resin includes: a repeat unit derived from a dicarboxylic acid; a repeat unit derived from a diamine; and a repeat unit represented by the following Formula 1, wherein the polyamide ester resin has a melting temperature (Tm) of about 280° C. or more. The polyamide ester resin can exhibit excellent properties in terms of moisture absorption resistance, heat resistance, discoloration resistance, fluidity and the like by using a cyclic ester. wherein R1 is a C3 to C12 linear, branched or cyclic alkylene group.

摘要翻译： 聚酰胺酯树脂包括：衍生自二羧酸的重复单元; 衍生自二胺的重复单元; 和由下式1表示的重复单元，其中聚酰胺酯树脂的熔融温度（Tm）为约280℃以上。 通过使用环状酯，聚酰胺酯树脂在耐吸湿性，耐热性，耐变色性，流动性等方面表现出优异的性能。 其中R1是C3-C12直链，支链或环状的亚烷基。

公开(公告)号：US20160032051A1

公开(公告)日：2016-02-04

申请号：US14566813

申请日：2014-12-11

申请人： Samsung SDI Co., Ltd.

发明人： So Young KWON ,  Joon Sung KIM ,  Eun Ju LEE ,  Ki Yon LEE ,  Sung Chul CHOI

IPC分类号： C08G69/26 ,  C08G69/30

CPC分类号： C08G69/265 ,  C08G69/30 ,  C08L77/06

摘要： A copolymerized polyamide resin includes a polymer of a monomer mixture comprising a dicarboxylic acid component and a diamine component including about 4 mol % to about 20 mol % of an alicyclic diamine represented by the Formula 1, wherein the polyamide resin has a melting temperature (Tm) from about 280 to about 330° C. and a crystallization temperature (Tc) from about 250 to about 300° C.: wherein, R1 and R2 are the same or different and are each independently a C1 to C5 alkyl group or a C6 to C10 aryl group, X is a C1 to C10 hydrocarbon group, and m and n are the same or different and are each independently an integer from 0 to 4. The copolymerized polyamide resin can exhibit excellent properties, such as crystallinity, heat resistance, processability and discoloration resistance, and an excellent balance therebetween.

摘要翻译： 共聚聚酰胺树脂包括包含二羧酸组分和包含约4mol％至约20mol％由式1表示的脂环族二胺的二胺组分的单体混合物的聚合物，其中聚酰胺树脂具有熔融温度（Tm ），约280至约330℃的结晶温度（Tc）为约250至约300℃。其中，R 1和R 2相同或不同，并且各自独立地为C 1至C 5烷基或C 6 至C10芳基，X为C1〜C10烃基，m和n相同或不同，各自独立地为0〜4的整数。共聚聚酰胺树脂的结晶性，耐热性， 加工性和耐变色性，以及它们之间的良好平衡。