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公开(公告)号:US10676419B2
公开(公告)日:2020-06-09
申请号:US16141501
申请日:2018-09-25
IPC分类号: C07C51/225 , C07C51/215 , B01J23/889 , B01J27/051 , B01J37/03 , B01J27/057 , C07C51/25 , B01J27/187 , C07C1/04
摘要: The method disclosed herein relates to two stage catalytic processes for converting syngas to acetic acid, acrylic acid and/or propylene. More specifically, the method described and claimed herein relate to a method of producing acrylic acid and acetic acid comprising the steps of: a) providing a feedstream comprising syngas; b) contacting the feedstream with a first catalyst to produce a first product stream comprising C2-C3 olefins and/or C2-C3 paraffins; and c) contacting the first product stream with oxygen gas and a second catalyst, thereby producing a second product stream comprising acrylic acid and acetic acid, wherein there is no step for separating the components of the first product stream before the first product stream is contacted with the second catalyst.
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公开(公告)号:US20190023640A1
公开(公告)日:2019-01-24
申请号:US16141501
申请日:2018-09-25
IPC分类号: C07C51/225 , C07C51/215 , C07C51/25 , B01J37/03 , B01J27/051 , B01J27/057 , B01J23/889 , B01J27/187 , C07C1/04 , C07C57/04 , C07C53/08
CPC分类号: C07C51/225 , B01J23/8892 , B01J27/0515 , B01J27/0576 , B01J27/187 , B01J37/035 , C07C1/0435 , C07C1/0485 , C07C51/215 , C07C51/252 , C07C2523/889 , C07C2527/187 , C07C57/04 , C07C53/08
摘要: The method disclosed herein relates to two stage catalytic processes for converting syngas to acetic acid, acrylic acid and/or propylene. More specifically, the method described and claimed herein relate to a method of producing acrylic acid and acetic acid comprising the steps of: a) providing a feedstream comprising syngas; b) contacting the feedstream with a first catalyst to produce a first product stream comprising C2-C3 olefins and/or C2-C3 paraffins; and c) contacting the first product stream with oxygen gas and a second catalyst, thereby producing a second product stream comprising acrylic acid and acetic acid, wherein there is no step for separating the components of the first product stream before the first product stream is contacted with the second catalyst.
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公开(公告)号:US09695365B2
公开(公告)日:2017-07-04
申请号:US14907863
申请日:2014-07-28
CPC分类号: C10G2/332 , C01B3/34 , C01B3/36 , C01B2203/0205 , C01B2203/0216 , C01B2203/025 , C01B2203/062 , C01B2203/1241 , C01B2203/148 , C10G2/34 , C10G31/06 , C10G2300/1025 , C10G2400/20 , C10G2400/22 , C10K3/026 , C10K3/06
摘要: The present disclosures and inventions relate to a method comprising: a) introducing a natural gas; b) reforming the natural gas; wherein the reforming step comprises contacting the natural gas with steam to produce a syngas; c) converting the syngas to a product mixture comprising at least one olefin and a byproduct comprising a paraffin and a gasoline; wherein the converting step comprises contacting the syngas with a Co/Mn catalyst; and d) converting the byproduct to syngas.
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公开(公告)号:US20160186070A1
公开(公告)日:2016-06-30
申请号:US14907863
申请日:2014-07-28
CPC分类号: C10G2/332 , C01B3/34 , C01B3/36 , C01B2203/0205 , C01B2203/0216 , C01B2203/025 , C01B2203/062 , C01B2203/1241 , C01B2203/148 , C10G2/34 , C10G31/06 , C10G2300/1025 , C10G2400/20 , C10G2400/22 , C10K3/026 , C10K3/06
摘要: The present disclosures and inventions relate to a method comprising: a) introducing a natural gas; b) reforming the natural gas; wherein the reforming step comprises contacting the natural gas with steam to produce a syngas; c) converting the syngas to a product mixture comprising at least one olefin and a byproduct comprising a paraffin and a gasoline; wherein the converting step comprises contacting the syngas with a Co/Mn catalyst; and d) converting the byproduct to syngas.
摘要翻译: 本公开和发明涉及一种方法,包括:a)引入天然气; b)改造天然气; 其中所述重整步骤包括使天然气与蒸汽接触以产生合成气; c)将合成气转化成包含至少一种烯烃和包含石蜡和汽油的副产物的产物混合物; 其中所述转化步骤包括使所述合成气与Co / Mn催化剂接触; 和d)将副产物转化为合成气。
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公开(公告)号:US20160175819A1
公开(公告)日:2016-06-23
申请号:US14907854
申请日:2014-07-28
IPC分类号: B01J23/889 , C10G2/00
CPC分类号: B01J23/8892 , B01J37/04 , B01J2523/00 , C10G2/332 , C10G2/333 , C10G2400/22 , B01J2523/17 , B01J2523/22 , B01J2523/41 , B01J2523/72 , B01J2523/845 , B01J2523/847 , B01J2523/27
摘要: The present disclosures and inventions relate to a catalyst or catalyst composition and the methods of making and using the catalyst or catalyst composition. In one aspect, the present disclosure relates to a catalyst composition that includes a catalyst having the formula CA CB Ox and a catalyst support; a) CA is CoaMnbXd, wherein X comprises Si, Ti, Cu, Zns Pd, or La or a combination thereof; a ranges from 0.8 to 1.2; b ranges from 0.1 to 1; and d ranges from 0 to 0.5; and b) CB is NieCufMghSim, wherein e ranges from about 0.8 to 1.2; f ranges from 0 to 1; h ranges from 0 to 0.5; and m ranges from 0 to 0.5; wherein Ox is determined by the valence requirements of the other elements present, wherein in the catalyst support consists essentially of magnesia, alumina, silica, titanic, carbon, or zeolite, or a combination thereof; and wherein the catalyst composition converts synthesis gas to at least one olefin.
摘要翻译: 本公开和发明涉及催化剂或催化剂组合物以及制备和使用催化剂或催化剂组合物的方法。 一方面,本公开内容涉及一种催化剂组合物,其包含具有式CA CB Ox的催化剂和催化剂载体; a)CA是CoaMnbXd,其中X包括Si,Ti,Cu,Zns Pd或La或其组合; a范围为0.8〜1.2; b范围从0.1到1; d范围为0〜0.5; 和b)CB是NieCufMghSim,其中e在约0.8至1.2的范围内; f范围从0到1; h范围从0到0.5; m范围为0〜0.5; 其中Ox由存在的其它元素的化合价要求确定,其中在催化剂载体中主要由氧化镁,氧化铝,二氧化硅,钛,碳或沸石或其组合组成; 并且其中所述催化剂组合物将合成气转化为至少一种烯烃。
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公开(公告)号:US09856200B2
公开(公告)日:2018-01-02
申请号:US14786000
申请日:2014-04-22
发明人: Khalid Karim , Abdulaziz Al Jodai
IPC分类号: B01J27/057 , B01J37/04 , C07C51/215 , B01J23/652 , C07C5/48
CPC分类号: C07C51/215 , B01J23/6525 , B01J27/0576 , B01J37/04 , B01J2523/00 , C07C5/48 , C07C2527/057 , Y02P20/582 , B01J2523/32 , B01J2523/3706 , B01J2523/55 , B01J2523/56 , B01J2523/68 , B01J2523/824 , B01J2523/64 , B01J2523/42 , B01J2523/27 , B01J2523/41 , B01J2523/33 , B01J2523/69 , C07C57/04
摘要: The present disclosures and inventions relate to a supported catalyst composition for the catalytic oxidation of a hydrocarbon such as propane with oxygen or air, in the presence of a catalyst composition comprising a support material and a mixed metal composition comprising metals in the molar ratios described by the formula MoaVbGacPddNbeZf, wherein the support material is neutral or oxidative.
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公开(公告)号:US09486785B2
公开(公告)日:2016-11-08
申请号:US14907854
申请日:2014-07-28
IPC分类号: B01J23/889 , C10G2/00 , B01J37/04
CPC分类号: B01J23/8892 , B01J37/04 , B01J2523/00 , C10G2/332 , C10G2/333 , C10G2400/22 , B01J2523/17 , B01J2523/22 , B01J2523/41 , B01J2523/72 , B01J2523/845 , B01J2523/847 , B01J2523/27
摘要: The present disclosures and inventions relate to a catalyst or catalyst composition and the methods of making and using the catalyst or catalyst composition. In one aspect, the present disclosure relates to a catalyst composition that includes a catalyst having the formula CA CB Ox and a catalyst support; a) CA is CoaMnbXd, wherein X comprises Si, Ti, Cu, Zns Pd, or La or a combination thereof; a ranges from 0.8 to 1.2; b ranges from 0.1 to 1; and d ranges from 0 to 0.5; and b) CB is NieCufMghSim, wherein e ranges from about 0.8 to 1.2; f ranges from 0 to 1; h ranges from 0 to 0.5; and m ranges from 0 to 0.5; wherein Ox is determined by the valence requirements of the other elements present, wherein in the catalyst support consists essentially of magnesia, alumina, silica, titanic, carbon, or zeolite, or a combination thereof; and wherein the catalyst composition converts synthesis gas to at least one olefin.
摘要翻译: 本公开和发明涉及催化剂或催化剂组合物以及制备和使用催化剂或催化剂组合物的方法。 一方面,本公开内容涉及一种催化剂组合物,其包含具有式CA CB Ox的催化剂和催化剂载体; a)CA是CoaMnbXd,其中X包括Si,Ti,Cu,Zns Pd或La或其组合; a范围为0.8〜1.2; b范围从0.1到1; d范围为0〜0.5; 和b)CB是NieCufMghSim,其中e在约0.8至1.2的范围内; f范围从0到1; h范围从0到0.5; m范围为0〜0.5; 其中Ox由存在的其它元素的化合价要求确定,其中在催化剂载体中主要由氧化镁,氧化铝,二氧化硅,钛,碳或沸石或其组合组成; 并且其中所述催化剂组合物将合成气转化为至少一种烯烃。
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公开(公告)号:US20160177187A1
公开(公告)日:2016-06-23
申请号:US14907859
申请日:2014-07-28
CPC分类号: C10G2/332 , C01B3/34 , C01B3/38 , C01B2203/0211 , C01B2203/0244 , C01B2203/04 , C01B2203/046 , C01B2203/0475 , C01B2203/062 , C01B2203/1241 , C01B2203/127 , C01B2203/148 , C10G2/34 , C10G31/06 , C10G45/02 , C10G2300/1025 , C10G2300/4081 , C10G2300/42 , C10G2400/20 , C10G2400/22 , C10L1/04 , C10L2290/10 , C10L2290/42 , C10L2290/54
摘要: The present disclosures and inventions relate to a method that includes the steps of: a) introducing a natural gas; b) reforming the natural gas; wherein the reforming step comprises contacting the natural gas with steam to produce a syngas; c) converting the syngas to a product mixture comprising an olefin; wherein the converting step comprises contacting the syngas with a Co/Mn catalyst; wherein waste water is produced prior to step d); and d) recovering the waste water; wherein some or all of the recovered waste water is added to the natural gas prior to being introduced.
摘要翻译: 本公开和发明涉及包括以下步骤的方法:a)引入天然气; b)改造天然气; 其中所述重整步骤包括使天然气与蒸汽接触以产生合成气; c)将合成气转化为包含烯烃的产物混合物; 其中所述转化步骤包括使所述合成气与Co / Mn催化剂接触; 其中在步骤d)之前产生废水; 和d)回收废水; 其中在引入之前将一部分或全部回收的废水加入到天然气中。
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公开(公告)号:US09827555B2
公开(公告)日:2017-11-28
申请号:US14907856
申请日:2014-07-28
CPC分类号: B01J23/8892 , B01J35/1019 , B01J35/1023 , B01J37/031 , B01J37/04 , B01J37/10 , B01J2523/00 , C10G2/332 , C10G2400/20 , C10G2400/22 , B01J2523/41 , B01J2523/72 , B01J2523/845 , B01J2523/17 , B01J2523/27
摘要: The disclosed subject matter presents a catalyst or catalyst composition as well as the methods of making and using the catalyst or catalyst composition. In one aspect, the disclosed subject matter relates to a catalyst comprising CoMnaSibXcYdOx wherein in X comprises an element from Group 11; Y comprises an element from Group 12; a ranges from 0.8 to 1.2; b ranges from 0.1 to 1; c ranges from 0.01 to 0.05; d ranges from 0.01 to 0.05; x is a number determined by the valency requirements of the other elements present; and wherein the catalyst converts synthesis gas to at least one olefin.
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公开(公告)号:US09701910B2
公开(公告)日:2017-07-11
申请号:US14907860
申请日:2014-07-28
CPC分类号: C10G2/332 , C01B3/34 , C01B3/38 , C01B2203/0216 , C01B2203/0244 , C01B2203/04 , C01B2203/062 , C01B2203/1241 , C01B2203/127 , C01B2203/148 , C10G2/34 , C10G45/02 , C10G2300/1025 , C10G2400/20 , C10G2400/22 , C10K3/026 , C10K3/06 , Y02P30/40
摘要: The present disclosures and inventions relate to a method including the steps of: a) introducing a natural gas; b) reforming the natural gas; wherein the reforming step comprises contacting the natural gas with steam to produce a syngas; c) converting the syngas to a product mixture comprising an olefin, carbon dioxide, and hydrogen; wherein the converting step comprises contacting the syngas with a Co/Mn catalyst; and d) converting at least some process hydrogen and at least some process and/or external carbon dioxide to syngas by a reverse water gas shift reaction, and recycling such reverse water gas shift reaction produced syngas to before step c).
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