摘要:
The present invention provides a highly durable surface-conditioning agent for use in a pretreatment step for a phosphate coating treatment of metallic materials, which is an aqueous solution comprising 1 to 50 ppm of titanium ion, 50 to 1,000 ppm or phosphate ion, 50 to 400 ppm of tripolyphosphate ion and 20 to 1,500 ppm of carbonate ion, with a tripolyphosphate ion/titanium ion weight ratio of 10 to 100, and having a pH of 8.5 to 10.0.
摘要:
A solution which is stored in a treatment bath is stirred by vibration stirring means provided in the treatment bath in a range of receiving a metal molded article or around a substantially horizontal surface of the metal molded article so that mean acceleration a expressed in the following equation is at least 8 cm/sec.sup.2 : ##EQU1## where X, Y and Z, which are in units of cm/sec.sup.2, represent average acceleration values of flow rate changes within 60 seconds, measured simultaneously in three axial directions of X, Y and Z which are perpendicular to each other at a measuring position.
摘要:
An alkaline degreasing solution containing 0.01 to 3 g/l of alkali silicate calculated as Si concentration, and 0.01 to 10 g/l of a nonionic surfactant having an HLB value (=20.times.Mw/M, where Mw represents the weight of a hydrophilic group part and M represents the molecular weight of the surfactant) of 5 to 11 and a structure being expressed in the following general formula (I), with a pH value of at least 9.5:R--O--(EO).sub.m (AO).sub.n H (I)where R represents alkyl group, EO represents ethylene oxide group, AO represents alkylene oxide group (propylene oxide group and/or butylene oxide group), m represents an addition molar number of EO which is an integer of 3 to 7, n represents an addition molar number of AO which is an integer of 1 to 6, and m and n satisfy the relation of n
摘要:
An alkaline degreasing solution containing 0.01 to 3 g/l of alkali silicate calculated as Si concentration, and 0.01 to 10 g/l of a nonionic surfactant having an HLB value (=20.times.Mw/M, where Mw represents the weight of a hydrophilic group part and M represents the molecular weight of the surfactant) of 5 to 11 and a structure being expressed in the following general formula (I), with a pH value of at least 9.5:R--O--(EO).sub.m (AO).sub.n H (I)where R represents alkyl group, EO represents ethylene oxide group, AO represents alkylene oxide group (propylene oxide group and/or butylene oxide group), m represents an addition molar number of EO which is an integer of 3 to 7, n represents an addition molar number of AO which is an integer of 1 to 6, and m and n satisfy the relation of n
摘要:
Disclosed is a method for zinc phosphating a molded metal article wherein a treating bath composition comprises from 1.5 to 5.0 g/l of zinc ion, from 0.1 to 3.0 g/l of manganese ion, from 5 to 40 g/l of phosphate ion, from 0.05 to 3.0 g/l of a fluorine compound as HF and hydoxylamine as a chemical conversion accelerator. A concentration of hydroxylamine is maintained to satisfy the following relationship:0.5.ltoreq.�hydroxylamine!(g/l)-2.0.times.�Fe.sup.2+ !(g/l).ltoreq.3.0 The treating bath is agitated by a vibratory agitating means provided in the treating vessel so that a mean acceleration a of a treating solution present within a bath region in which the molded metal article is immersed to be treated under fluid agitation is at least 8 cm/sec.sup.2. The mean acceleration is calculated from the following equation: ##EQU1## wherein values of X, Y and Z, each in unit of cm/sec.sup.2, indicate average acceleration values of treating solution in three respective X, Y and Z axial directions which are perpendicular to each other. The velocity changes of the treating solution in a flow state in respective X, Y and Z directions are synchronously measured at measuring locations for 60 seconds to be averaged to obtain the respective average acceleration values in X, Y and Z directions.
摘要:
A method is provided for chemical conversion treatment by which a chemical conversion layer attaining satisfactory substrate-covering properties, adhesion to coating and corrosion resistance can be formed on any metal structure surface. More specifically, a method for chemical conversion treatment is provided by treating a metal structure with an agent for chemical conversion treatment, in which the agent contains zirconium, fluorine, an amino-containing alkoxysilane, and a hydroxyl-containing alkoxysilane with the contents of zirconium and the amino-containing alkoxysilane being 100 to 700 ppm in terms of metal and 50 to 500 ppm in terms of solid matter respectively at a fluorine/zirconium molar ratio of 3.5 to 7.0 and has a pH of 2.8 to 4.5.
摘要:
A method for surface treatment of aluminum alloy to form a uniform and dense zinc phosphate coating, which has excellent corrosion resistance properties on the surface of the aluminum alloy. The method includes steps of surface adjusting the surface of the aluminum alloy by a surface adjustor containing a predetermined volume of zinc phosphate particles, copolymer containing carboxylic acid group, and natural hectorite and/or synthetic hectorite respectively, and chemical conversion treating the surface of the resultant aluminum alloy by a zinc phosphate treating agent containing a predetermined volume of chelating agent that can chelate bond with iron ion.