Pretreatment method for coating on molded metal article
    1.
    发明授权
    Pretreatment method for coating on molded metal article 失效
    用于在模制金属制品上涂覆的预处理方法

    公开(公告)号:US5780122A

    公开(公告)日:1998-07-14

    申请号:US760459

    申请日:1996-12-06

    CPC分类号: C23C22/73

    摘要: A solution which is stored in a treatment bath is stirred by vibration stirring means provided in the treatment bath in a range of receiving a metal molded article or around a substantially horizontal surface of the metal molded article so that mean acceleration a expressed in the following equation is at least 8 cm/sec.sup.2 : ##EQU1## where X, Y and Z, which are in units of cm/sec.sup.2, represent average acceleration values of flow rate changes within 60 seconds, measured simultaneously in three axial directions of X, Y and Z which are perpendicular to each other at a measuring position.

    摘要翻译: 将储存在处理槽中的溶液在接收金属模制品的范围内或处于金属模制品的基本水平的表面的范围内,通过设置在处理槽中的振动搅拌装置进行搅拌,使得以下述式 至少8cm / sec2:其中X,Y和Z以cm / sec2为单位,表示在X,Y的三个轴向上同时测量的60秒内的流量变化的平均加速度, Z在测量位置处彼此垂直。

    Highly durable surface-conditioning agent
    2.
    发明授权
    Highly durable surface-conditioning agent 失效
    高度耐用的表面处理剂

    公开(公告)号:US5908512A

    公开(公告)日:1999-06-01

    申请号:US955597

    申请日:1997-10-22

    IPC分类号: C23C22/80

    CPC分类号: C23C22/80

    摘要: The present invention provides a highly durable surface-conditioning agent for use in a pretreatment step for a phosphate coating treatment of metallic materials, which is an aqueous solution comprising 1 to 50 ppm of titanium ion, 50 to 1,000 ppm or phosphate ion, 50 to 400 ppm of tripolyphosphate ion and 20 to 1,500 ppm of carbonate ion, with a tripolyphosphate ion/titanium ion weight ratio of 10 to 100, and having a pH of 8.5 to 10.0.

    摘要翻译: 本发明提供了一种用于金属材料的磷酸盐涂层处理的预处理步骤中的高度耐用的表面调节剂,其是包含1至50ppm的钛离子,50至1,000ppm或磷酸根离子的水溶液,50至 400ppm的三聚磷酸根离子和20〜1500ppm的碳酸根离子,三聚磷酸盐离子/钛离子重量比为10〜100,pH为8.5〜10.0。

    Method for zinc phosphating molded metal articles
    3.
    发明授权
    Method for zinc phosphating molded metal articles 失效
    磷化锌成型金属制品的方法

    公开(公告)号:US5863357A

    公开(公告)日:1999-01-26

    申请号:US833008

    申请日:1997-04-04

    摘要: Disclosed is a method for zinc phosphating a molded metal article wherein a treating bath composition comprises from 1.5 to 5.0 g/l of zinc ion, from 0.1 to 3.0 g/l of manganese ion, from 5 to 40 g/l of phosphate ion, from 0.05 to 3.0 g/l of a fluorine compound as HF and hydoxylamine as a chemical conversion accelerator. A concentration of hydroxylamine is maintained to satisfy the following relationship:0.5.ltoreq.�hydroxylamine!(g/l)-2.0.times.�Fe.sup.2+ !(g/l).ltoreq.3.0 The treating bath is agitated by a vibratory agitating means provided in the treating vessel so that a mean acceleration a of a treating solution present within a bath region in which the molded metal article is immersed to be treated under fluid agitation is at least 8 cm/sec.sup.2. The mean acceleration is calculated from the following equation: ##EQU1## wherein values of X, Y and Z, each in unit of cm/sec.sup.2, indicate average acceleration values of treating solution in three respective X, Y and Z axial directions which are perpendicular to each other. The velocity changes of the treating solution in a flow state in respective X, Y and Z directions are synchronously measured at measuring locations for 60 seconds to be averaged to obtain the respective average acceleration values in X, Y and Z directions.

    摘要翻译: 公开了一种锌成型金属制品的磷化方法,其中处理浴组合物包含1.5-5.0g / l锌离子,0.1-3.0g / l锰离子,5-40g / l磷酸根离子, 作为HF的0.05〜3.0g / l的氟化合物和作为化学转化促进剂的羟胺。 维持羟胺的浓度以满足以下关系:0.5

    Method for phosphating metal surface with zinc phosphate
    4.
    发明授权
    Method for phosphating metal surface with zinc phosphate 失效
    用磷酸锌浸渍金属表面的方法

    公开(公告)号:US5211769A

    公开(公告)日:1993-05-18

    申请号:US629853

    申请日:1990-12-18

    IPC分类号: C23C22/36 C23C22/77

    CPC分类号: C23C22/77 C23C22/362

    摘要: To treat an iron-based, zinc-based, and an aluminum-based surfaces etc. with zinc phosphate using the same solution, a treating solution is adjusted in concentrations so as to contain a simple fluoride in a range of 200.about.500 mg/l upon converting into a HF concentration and to contain a fluoride complex in a range shown in the following formula; ##EQU1## and also, it is adjusted in an active fluorine concentration so as to be 15.about.130 .mu.A at a value indicated by a silicon electrode meter. Instead of such adjusting aluminum ions in the treating solution is precipitated in an outside of a treating bath to separate them from the treating solution and then, this treating solution may be returned into the treating bath.

    Method for phosphating metal surface with zinc phosphate
    5.
    发明授权
    Method for phosphating metal surface with zinc phosphate 失效
    用磷酸锌磷化金属表面的方法

    公开(公告)号:US5399208A

    公开(公告)日:1995-03-21

    申请号:US11923

    申请日:1993-02-01

    IPC分类号: C23C22/36 C23C22/77 C23C22/12

    CPC分类号: C23C22/77 C23C22/362

    摘要: To treat an iron-based, zinc-based, and an aluminumbased surfaces etc. with zinc phosphate using the same solution, a treating solution is adjusted in concentrations so as to contain a simple fluoride in a range of 200.about.500 mg/l upon converting into a HF concentration and to contain a fluoride complex in a range shown in the following formula; ##EQU1## and also, it is adjusted in an active fluorine concentration so as to be 15.about.130 .mu.A at a value indicated by a silicon electrode meter. Instead of such adjusting, aluminum ions in the treating solution is precipitated in an outside of a treating bath to separate them from the treating solution and then, this treating solution may be returned in to the treating bath.

    摘要翻译: 为了使用相同的溶液用磷酸锌处理铁基,锌基和铝基表面等,调节处理溶液的浓度,以便含有200-600mg / l范围内的简单氟化物 转化成HF浓度并含有下式所示的氟化物络合物; < IMAGE>并且以由硅电极计所指示的值调节为活性氟浓度以使得差异为130μA。 代替这种调整,处理溶液中的铝离子在处理浴的外部沉淀,以将它们与处理溶液分离,然后将该处理溶液返回到处理浴中。

    Alkaline degreasing solution and degreasing method employing the same
    6.
    发明授权
    Alkaline degreasing solution and degreasing method employing the same 失效
    碱性脱脂溶液及其脱脂方法

    公开(公告)号:US5925613A

    公开(公告)日:1999-07-20

    申请号:US645685

    申请日:1996-05-14

    摘要: An alkaline degreasing solution containing 0.01 to 3 g/l of alkali silicate calculated as Si concentration, and 0.01 to 10 g/l of a nonionic surfactant having an HLB value (=20.times.Mw/M, where Mw represents the weight of a hydrophilic group part and M represents the molecular weight of the surfactant) of 5 to 11 and a structure being expressed in the following general formula (I), with a pH value of at least 9.5:R--O--(EO).sub.m (AO).sub.n H (I)where R represents alkyl group, EO represents ethylene oxide group, AO represents alkylene oxide group (propylene oxide group and/or butylene oxide group), m represents an addition molar number of EO which is an integer of 3 to 7, n represents an addition molar number of AO which is an integer of 1 to 6, and m and n satisfy the relation of n

    摘要翻译: 以Si浓度计,含有0.01〜3g / l的碱性硅酸盐和0.01〜10g / L的HLB值(= 20×Mw / M,其中Mw表示亲水性基团部分的重量)的非离子表面活性剂的碱性脱脂溶液 和M表示表面活性剂的分子量)为5〜11的结构,其结构用以下通式(I)表示,pH值为9.5以上:RO-(EO)m(AO)nH(I) 其中R表示烷基,EO表示环氧乙烷基,AO表示环氧烷基(环氧丙烷基和/或环氧丁烷基),m表示EO的加成摩尔数,为3〜7的整数,n表示相加 作为1〜6的整数的AO的摩尔数,m和n满足n

    Alkaline degreasing solution and degreasing method employing the same
    7.
    发明授权
    Alkaline degreasing solution and degreasing method employing the same 失效
    碱性脱脂溶液及其脱脂方法

    公开(公告)号:US5935919A

    公开(公告)日:1999-08-10

    申请号:US213242

    申请日:1998-12-17

    摘要: An alkaline degreasing solution containing 0.01 to 3 g/l of alkali silicate calculated as Si concentration, and 0.01 to 10 g/l of a nonionic surfactant having an HLB value (=20.times.Mw/M, where Mw represents the weight of a hydrophilic group part and M represents the molecular weight of the surfactant) of 5 to 11 and a structure being expressed in the following general formula (I), with a pH value of at least 9.5:R--O--(EO).sub.m (AO).sub.n H (I)where R represents alkyl group, EO represents ethylene oxide group, AO represents alkylene oxide group (propylene oxide group and/or butylene oxide group), m represents an addition molar number of EO which is an integer of 3 to 7, n represents an addition molar number of AO which is an integer of 1 to 6, and m and n satisfy the relation of n

    摘要翻译: 以Si浓度计,含有0.01〜3g / l的碱性硅酸盐和0.01〜10g / L的HLB值(= 20×Mw / M,其中Mw表示亲水性基团部分的重量)的非离子表面活性剂的碱性脱脂溶液 和M表示表面活性剂的分子量)为5〜11的结构,其结构用以下通式(I)表示,pH值为9.5以上:RO-(EO)m(AO)nH(I) 其中R表示烷基,EO表示环氧乙烷基,AO表示环氧烷基(环氧丙烷基和/或环氧丁烷基),m表示EO的加成摩尔数,为3〜7的整数,n表示相加 作为1〜6的整数的AO的摩尔数,m和n满足n

    Method for zinc-phosphating metal surface
    8.
    发明授权
    Method for zinc-phosphating metal surface 失效
    锌磷化金属表面方法

    公开(公告)号:US5328526A

    公开(公告)日:1994-07-12

    申请号:US40964

    申请日:1993-03-31

    IPC分类号: C23C22/12 C23C22/18 C23C22/36

    摘要: A zinc phosphate coating film suitable for cationic electrodeposition coating and superior in both of coating film adhesion and corrosion resistance (especially, warm brine resistance and scab resistance) is formed by a conversion treatment of a metal surface using an acidic zinc-phosphating solution which does not contain a nickel ion as an essential component. The conversion treatment is carried out by bringing a metal surface into contact with a zinc-phosphating solution containing a zinc ion of 0.1 to 2.0 g/l, a phosphate ion of 5 to 40 g/l, a lanthanum compound of 0.001 to 3 g/l in terms of a lanthanum metal, and a phosphating accelerator, thereby the zinc phosphate coating film is formed on the metal surface.

    摘要翻译: 通过使用酸性磷酸锌溶液对金属表面进行转化处理,形成适用于阳离子电沉积涂层的磷酸锌涂膜,并且在涂膜粘附性和耐腐蚀性(特别是耐温盐渍性和耐刮擦性)方面均优异。 不含镍离子作为必需成分。 转化处理通过使金属表面与含有0.1〜2.0g / l的锌离子,5〜40g / l的磷酸根离子,0.001〜3g的镧化合物的锌 - 磷酸化溶液接触来进行 镧金属和磷化促进剂,由此在金属表面上形成磷酸锌被膜。

    Activity control apparatus for zinc phosphate treatment solution
    10.
    发明授权
    Activity control apparatus for zinc phosphate treatment solution 失效
    磷酸锌处理溶液活性控制装置

    公开(公告)号:US5478529A

    公开(公告)日:1995-12-26

    申请号:US231408

    申请日:1994-04-22

    CPC分类号: C23C22/77 Y10S423/05

    摘要: A treatment solution which is stored in a treatment vessel is supplied to a mixing vessel and a simple fluoride solution is supplied into the mixing vessel from a simple fluoride supply vessel to convert aluminum salt of complex hydrofluoric acid which is contained in the treatment solution to complex hydrofluoric acid. Concentration of HF remaining in the mixed solution is measured with a metal silicon electrode meter provided in an HF concentration measuring part, so that a control signal is transmitted from a control unit to a pump and a flow control part on the basis of the data as obtained. The simple fluoride solution is supplied from the simple fluoride supply vessel to the treatment solution which is stored in the treatment vessel to return the activity of the treatment solution stored in the treatment vessel and to control the same in a prescribed range.

    摘要翻译: 将储存在处理容器中的处理溶液供给到混合容器中,将简单的氟化物溶液从简单的氟化物供给容器供给到混合容器中,以将处理溶液中所含的复合氢氟酸的铝盐转化为络合物 氢氟酸。 通过设置在HF浓度测量部件中的金属硅电极计测量残留在混合溶液中的HF的浓度,从而控制信号基于数据作为控制单元发送到泵和流量控制部件 获得。 简单的氟化物溶液从简单的氟化物供应容器供应到储存在处理容器中的处理溶液,以返回存储在处理容器中的处理溶液的活性并将其控制在规定的范围内。