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    Process for producing an oligoester and producing unsaturated polyester resin by use thereof
    5.
    发明授权
    Process for producing an oligoester and producing unsaturated polyester resin by use thereof 失效
    制备低聚酯并通过其使用生产不饱和聚酯树脂的方法

    公开(公告)号：US4306056A

    公开(公告)日：1981-12-15

    申请号：US150691

    申请日：1980-05-16

    申请人： Akira Miyamoto ,  Senzo Shimizu ,  Fumitaka Satoh ,  Yasumitsu Higuchi ,  Toshiyuki Abe ,  Kohji Yamamoto

    发明人： Akira Miyamoto ,  Senzo Shimizu ,  Fumitaka Satoh ,  Yasumitsu Higuchi ,  Toshiyuki Abe ,  Kohji Yamamoto

    IPC分类号： C08G63/42

    CPC分类号： C08G63/42

    摘要： Processes for producing an oligoester and producing unsaturated polyester resin by use of the oligoester using unsaturated dibasic acid or its anhydride and isophthalic acid as dibasic acid components, and propylene oxide as a polyol component, characterized by (a) the step of reacting isophthalic acid with propylene oxide in the presence of an amine compound catalyst to form an oligoester, (b) the step of removing volatile components from the oligoester by heating it at a temperature range of 180.degree.-300.degree. C., (c) the step of treating the resulting oligoester with silica-alumina compound having adsorbing property, and (d) the step of reacting the oligoester so treated with the unsaturated dibasic acid or its anhydride.

    摘要翻译： 通过使用不饱和二元酸或其酸酐和间苯二甲酸作为二元酸组分的低聚酯和作为多元醇组分的环氧丙烷，通过使用低聚酯制备低聚酯并生产不饱和聚酯树脂的方法，其特征在于（a）使间苯二甲酸与 环氧丙烷在胺化合物催化剂的存在下反应形成低聚酯，（b）通过在180-300℃的温度范围加热从低聚酯中除去挥发性组分的步骤，（c） 所得到的具有吸附性的二氧化硅 - 氧化铝化合物的低聚酯，和（d）使如此处理的低聚酯与不饱和二元酸或其酸酐反应的步骤。

    Process for producing an aromatic polyester copolymer
    6.
    发明授权
    Process for producing an aromatic polyester copolymer 失效
    芳香族聚酯共聚物的制造方法

    公开(公告)号：US4362858A

    公开(公告)日：1982-12-07

    申请号：US327038

    申请日：1981-12-03

    申请人： Senzo Shimizu ,  Isao Nomura ,  Motohachi Usui ,  Mashahiro Harada

    发明人： Senzo Shimizu ,  Isao Nomura ,  Motohachi Usui ,  Mashahiro Harada

    IPC分类号： C08G63/00 ,  C08G63/19 ,  C08G63/40

    CPC分类号： C08G63/40 ,  C08G63/19

    摘要： A process for producing an aromatic polyester copolymer wherein the alternating configuration of the components making up the copolymer is highly regular, said process comprising a first step of reacting a dihydric phenolic compound with an aromatic dicarboxylic acid dichloride A in a reaction medium consisting of water and a water-immiscible solvent in the presence of a basic inorganic compound to give a phenolic hydroxyl-terminated aromatic oligoester containing predominantly an oligomer having a degree of polymerization of 1-2, and a second step of reacting the aromatic dihydroxy oligoester obtained in the first step with an aromatic dicarboxylic acid dichloride B in the presence of a basic inorganic compound in an amount at least sufficient to neutralize the free phenolic hydroxyl groups remaining in the reaction product mixture obtained in the first step.

    摘要翻译： 一种制备芳族聚酯共聚物的方法，其中构成共聚物的组分的交替配置是高度规则的，所述方法包括使二羟基酚化合物与芳族二羧酸二氯化物A在由水和 在碱性无机化合物的存在下，与水不混溶的溶剂，得到主要含有聚合度为1-2的低聚物的酚羟基封端的芳族低聚酯，第二步是使第一 在碱性无机化合物的存在下，用至少足以中和残留在第一步获得的反应产物混合物中的游离酚羟基的量与芳族二羧酸二氯B步骤。

    Process for preparing polyamide with molten dicarboxylic acid component
    7.
    发明授权
    Process for preparing polyamide with molten dicarboxylic acid component 失效
    用熔融二羧酸成分制备聚酰胺的方法

    公开(公告)号：US4438257A

    公开(公告)日：1984-03-20

    申请号：US451397

    申请日：1982-12-20

    申请人： Akira Miyamoto ,  Senzo Shimizu ,  Masahiro Harada ,  Tamotu Ajiro ,  Hideki Hara

    发明人： Akira Miyamoto ,  Senzo Shimizu ,  Masahiro Harada ,  Tamotu Ajiro ,  Hideki Hara

    IPC分类号： C08G69/00 ,  C08G69/26 ,  C08G69/28

    CPC分类号： C08G69/28 ,  C08G69/265

    摘要： A process for preparing a polyamide is provided. The polyamide is prepared by causing a dicarboxylic acid and a diamine to polycondensate directly under an atmosphere of an inert gas at atmospheric pressure. The polycondensation reaction is mainly carried out in two diamine component-adding steps, one step comprising adding part of the diamine to the molten dicarboxylic acid until the molar ratio of the diamine to the dicarboxylic acid is brought to within the range of from 0.900 to 0.990 while raising continuously the temperature of the reaction mixture to a temperature not exceeding about 5.degree. C. above the melting point of the object polyamide and the other step comprising adding the remainder of the diamine to the reaction mixture maintained at a temperature higher than about 10.degree. C., but not exceeding about 35.degree. C. above the melting point of the object polyamide until the overall molar ratio of the diamine to the dicarboxylic acid is brought to within the range of from 0.995 to 1.005.

    摘要翻译： 提供了制备聚酰胺的方法。 通过使二羧酸和二胺在大气压下在惰性气体气氛下直接缩聚制备聚酰胺。 缩聚反应主要在两个二胺组分添加步骤中进行，一步包括将一部分二胺加入到熔融二羧酸中直到二胺与二羧酸的摩尔比达到0.900-0.990 同时将反应混合物的温度持续升高至高于目标聚酰胺熔点以上约5℃的温度，另一步骤包括将剩余的二胺加入保持在高于约10℃的温度的反应混合物中 ℃，但不超过目标聚酰胺熔点的约35℃，直到二胺与二羧酸的总摩尔比达到0.995至1.005的范围。

    Method for isolating solid polyarylene ester from its organic solvent solution
    8.
    发明授权
    Method for isolating solid polyarylene ester from its organic solvent solution 失效
    从其有机溶剂溶液中分离固体聚亚芳基酯的方法

    公开(公告)号：US4202965A

    公开(公告)日：1980-05-13

    申请号：US945068

    申请日：1978-09-22

    申请人： Senzo Shimizu ,  Isao Nomura ,  Masahiro Harada

    发明人： Senzo Shimizu ,  Isao Nomura ,  Masahiro Harada

    IPC分类号： C08G63/00 ,  C08G63/19 ,  C08G63/195 ,  C08G63/81 ,  C08G63/89 ,  C08G63/72 ,  C08G63/74

    CPC分类号： C08G63/81 ,  C08G63/195 ,  C08G63/89

    摘要： A method for isolating a polyarylene ester from a solution of the polyarylene ester in tetrahydrofuran and/or dioxane which is prepared by polycondensing a dihydric phenol compound and an aromatic dicarboxylic acid or its derivative, which comprises adding water to the solvent solution to form a water-containing solution, the weight ratio of water to the solvent solution being from 0.01 to 0.5, subjecting the resulting water-containing solution to an aging treatment, then precipitating substantially all of the polyarylene ester as a particulate solid from the water-containing solution, and separating the precipitated polyarylene ester from the water-containing solution.

    摘要翻译： 从聚芳酯在四氢呋喃和/或二恶烷中的溶液中分离聚亚芳基酯的方法，其通过使二元酚化合物和芳族二羧酸或其衍生物缩聚而制备，其包括向溶剂溶液中加入水以形成水 水与溶剂溶液的重量比为0.01至0.5，对所得含水溶液进行时效处理，然后从含水溶液中基本上沉淀出所有作为颗粒状固体的聚亚芳基酯， 并将沉淀的聚亚芳基酯与含水溶液分离。

    Process for preparing polyamide in uniformly fluidized state
    9.
    发明授权
    Process for preparing polyamide in uniformly fluidized state 失效
    均匀流化状态制备聚酰胺的方法

    公开(公告)号：US4433136A

    公开(公告)日：1984-02-21

    申请号：US383974

    申请日：1982-06-01

    申请人： Akira Miyamoto ,  Senzo Shimizu ,  Kazuo Yamamiya ,  Masahiro Harada

    发明人： Akira Miyamoto ,  Senzo Shimizu ,  Kazuo Yamamiya ,  Masahiro Harada

    IPC分类号： C08G69/00 ,  C08G69/04 ,  C08G69/28

    CPC分类号： C08G69/28

    摘要： A process for preparing a polyamide is provided. The polyamide is prepared by effecting direct polycondensation reaction of a dicarboxylic acid component containing at least 80 mole % of adipic acid and a diamine component containing at least 70 mole % of m-xylylene diamine under an atmosphere of an inert gas and at atmospheric pressure at a controlled temperature which is higher than the melting point of the dicarboxylic acid component and which can maintain the reaction mixture in a uniformly-fluidized state throughout the reaction.

    摘要翻译： 提供了制备聚酰胺的方法。 聚酰胺通过在惰性气体气氛下和大气压下进行包含至少80摩尔％己二酸的二羧酸组分和含有至少70摩尔间苯二甲胺的二胺组分的直接缩聚反应来制备 控制温度高于二羧酸组分的熔点，并且可以在整个反应过程中将反应混合物保持在均匀流化状态。

    Process for producing aromatic polyester carbonate resin
    10.
    发明授权
    Process for producing aromatic polyester carbonate resin 失效
    制备芳香族聚酯碳酸酯树脂的方法

    公开(公告)号：US4395534A

    公开(公告)日：1983-07-26

    申请号：US322244

    申请日：1981-11-17

    申请人： Senzo Shimizu ,  Isao Nomura ,  Masahiro Harada ,  Motohachi Usui ,  Susumu Taniyama ,  Shigeo Yanada

    发明人： Senzo Shimizu ,  Isao Nomura ,  Masahiro Harada ,  Motohachi Usui ,  Susumu Taniyama ,  Shigeo Yanada

    IPC分类号： C08G63/64

    CPC分类号： C08G63/64

    摘要： A process for producing an aromatic polyester carbonate resin in which the molar ratio of the dihydric phenolic compound residue to aromatic dicarboxylic acid residue to carbonate bond is in the range of 2:0.5:1.5-2:1.4:0.6 and these constituent components form an alternating configuration of high regularity, said process comprising a first step wherein in producing a hydroxyl-terminated aromatic oligocarbonate by reacting a dihydric phenolic compound with a halogenated carbonyl compound in a reaction medium consisting of water and a water-immiscible solvent in the presence of a basic inorganic compound, the reaction is carried out by using the basic inorganic compound in an amount of 0.6-1.6 moles per mole of the dihydric phenolic compound and the halogenated carbonyl compound in an amount of 0.3-0.8 mole per mole of the dihydric phenolic compound to form a reaction product mixture consisting predominantly of a phenolic hydroxyl-terminated oligocarbonate of a degree of polymerization of 1-3, and a second step in which an esterification reaction is carried out by reacting the reaction product mixture obtained in the first step with an aromatic dicarboxylic acid dichloride in the presence of a basic inorganic compound in an amount at least sufficient to neutralize the free phenolic hydroxyl groups that remain in the reaction product mixture.

    摘要翻译： 一种芳族聚酯碳酸酯树脂的制造方法，其中二羟基酚类化合物残基与芳族二羧酸残基与碳酸酯键的摩尔比在2:0.5:1.5-2:1.4:0.6的范围内，并且这些组成成分形成 所述方法包括第一步骤，其中通过在由水和水不混溶溶剂组成的反应介质中在二元酚化合物与卤代羰基化合物的反应介质中反应来制备羟基封​​端的芳族低聚碳酸酯 碱性无机化合物，通过使用每摩尔二元酚类化合物和卤代羰基化合物的0.6-1.6摩尔量的碱性无机化合物，其量为每摩尔二羟基酚化合物0.3-0.8摩尔 以形成主要由聚合度为酚羟基封端的低聚碳酸酯组成的反应产物混合物 为1-3，第二步是在碱性无机化合物存在下使至少足以中和的第一步获得的反应产物混合物与芳族二羧酸二氯化物反应进行酯化反应 保留在反应产物混合物中的游离酚羟基。