摘要:
A fuel cell system operates under at least one of the conditions of no humidity or high temperature, and an operating method thereof, are characterized in that a fuel cell has a fuel gas flow path and an oxidant gas flow path arranged such that fuel gas and oxidant gas flow in opposite directions, a determining apparatus that determines the amount of water near the oxidant gas flow path inlet, and a fuel gas control apparatus which increases the amount of water near the oxidant gas flow path inlet by increasing the fuel gas flowrate and/or reducing the fuel gas pressure if it is determined in the determining apparatus that the amount of water near the oxidant gas flow path inlet is insufficient.
摘要:
A fuel cell system operates under at least one of the conditions of no humidity or high temperature, and an operating method thereof, are characterized in that a fuel cell has a fuel gas flow path and an oxidant gas flow path arranged such that fuel gas and oxidant gas flow in opposite directions, a determining apparatus that determines the amount of water near the oxidant gas flow path inlet, and a fuel gas control apparatus which increases the amount of water near the oxidant gas flow path inlet by increasing the fuel gas flowrate and/or reducing the fuel gas pressure if it is determined in the determining apparatus that the amount of water near the oxidant gas flow path inlet is insufficient.
摘要:
This electrode for fuel cell comprises: carbon nanotubes; a catalyst for fuel cell supported on the carbon nanotubes; and an ionomer provided to coat the carbon nanotubes and the catalyst for fuel cell, wherein when a length of the carbon nanotubes is represented by La [μm] and an inter-core pitch of the carbon nanotubes is represented by Pa [nm], the length La and the inter-core pitch Pa satisfy two expressions given below: 30≦La≦240; and 0.351×La+75≦Pa≦250.
摘要:
This electrode for fuel cell comprises: carbon nanotubes; a catalyst for fuel cell supported on the carbon nanotubes; and an ionomer provided to coat the carbon nanotubes and the catalyst for fuel cell, wherein when a length of the carbon nanotubes is represented by La [μm] and an inter-core pitch of the carbon nanotubes is represented by Pa [nm], the length La and the inter-core pitch Pa satisfy two expressions given below: 30≦La≦240; and 0.351×La+75≦Pa≦250.
摘要:
A method of manufacturing a fuel cell includes: growing carbon nanotubes substantially perpendicular to a substrate formed by loading a growth catalyst on a base material; arranging the substrate and a polymer electrolyte membrane so as to oppose to each other and combining the carbon nanotubes with the polymer electrolyte membrane; and dissolving and removing part of the substrate by immersing the substrate in a solution which dissolves the substrate, after the carbon nanotubes and the polymer electrolyte membrane are combined.
摘要:
The present invention relates a method for manufacturing a fuel cell. An object of the present invention is to provide a method for manufacturing a membrane electrode assembly capable of solving an electrical connection problem caused by uneven tube lengths and improving an output, and a solid polymer electrolyte fuel cell. The method for manufacturing the membrane electrode assembly of the present invention includes a seed catalyst layer forming process (1), a CNT growing process (2), a CNT entanglement promoting process (3), a catalyst carrying process (4), an ionomer arranging process (5), and a transferring (MEA conversion) process (6). According to the present invention, entanglement of adjacent CNTs can be promoted by the CNT entanglement promoting process (3) and therefore the electrical connection of the CNTs can be ensured. Thus, the output of the cell can be improved.
摘要:
A method of producing a fuel cell includes: preparing a plurality of carbon nanotubes that are aligned substantially vertically to a plane of a substrate; supporting an electrode catalyst on the carbon nanotubes; forming an electrode layer by disposing an ionomer formed of a first solid polymer electrolyte on a surface of the carbon nanotubes on which the electrode catalyst is supported; and placing the electrode layer to face an electrolyte membrane formed of a second solid polymer electrolyte, which has a glass-transition temperature lower than that of the first solid polymer electrolyte, and bonding the electrolyte membrane to the electrode layer by applying a pressure higher than 5 MPa between the electrolyte membrane and electrode layer at a temperature that is higher than the glass-transition temperature of the second solid polymer electrolyte and that is lower than the glass-transition temperature of the first solid polymer electrolyte.
摘要:
A cathode catalyst layer (16) includes electron conducting carbon nanotubes (CNTs) (161) having a hollow space formed at an interior. The CNTs (161) are, in a hollow space forming direction thereof, open at a first end and are closed at a second end. The open end (161a) is disposed so as to be in contact with a gas diffusion layer (22). On the other hand, the closed end (161b) is disposed so as to be in contact with a polymer electrolyte membrane (12). Defects are formed on a surface of the CNTs (161). The defects (161c) are formed so as to communicate between an outer surface of the CNTs (161) and the hollow space. Catalyst particles (162) are provided on the outer surface of the CNTs (161), and an ionomer (163) is provided so as to cover the catalyst particles (162).
摘要:
A fuel cell is disclosed comprising: a power generation layer including an electrolyte membrane, and an anode and a cathode provided on respective surfaces of the electrolyte membrane; a fuel gas flow path layer located on a side of the anode of the power generation layer to supply a fuel gas to the anode while flowing the fuel gas along a flow direction of the fuel gas approximately orthogonal to a stacking direction in which respective layers of the fuel cell are stacked; and an oxidizing gas flow path layer located on a side of the cathode of the power generation layer to supply an oxidizing gas to the cathode while flowing the oxidizing gas along a flow direction of the oxidizing gas opposed to the flow direction of the fuel gas. A power generation area of the fuel cell, in which electric power is generated, has an upstream region including a most upstream position along the flow direction of the fuel gas and a downstream region including a most downstream position along the flow direction of the fuel gas. A midstream region, which is a remaining region of the power generation area other than the upstream region and the downstream region, has higher water vapor transfer resistance between the anode side and the cathode side than the upstream region and the downstream region.
摘要:
A method for producing a catalyst supporting a metal or an alloy on a support, including: independently controlling a temperature of a first supercritical fluid to be first temperature, the first supercritical fluid containing a precursor of the metal or precursor of the alloy that is dissolved in a supercritical fluid; independently controlling a temperature of the support to be a second temperature higher than the temperature of the first supercritical fluid; and supplying the first supercritical fluid controlled to the first temperature to the support, to cause the metal or the alloy to be supported on the support.