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公开(公告)号:US06472105B2
公开(公告)日:2002-10-29
申请号:US09341668
申请日:1999-07-19
申请人: Michio Murai , Takayuki Inuzuka , Yasuhiro Yoshida , Shigeru Aihara , Daigo Takemura , Hisashi Shiota , Jun Aragane , Hiroaki Urushibata , Kouji Hamano
发明人: Michio Murai , Takayuki Inuzuka , Yasuhiro Yoshida , Shigeru Aihara , Daigo Takemura , Hisashi Shiota , Jun Aragane , Hiroaki Urushibata , Kouji Hamano
IPC分类号: H01M1040
CPC分类号: C09J127/16 , C09J129/04 , H01M2/1673 , H01M6/10 , H01M10/0431 , H01M10/052
摘要: An adhesive for batteries. The adhesive has improved wetting properties, improved adhesive strength and prevents deterioration of battery performance. Secondary batteries can be obtained having an arbitrary shape such as a thin shape with high reliability and high charge and discharge efficiency. The adhesive includes a thermoplastic resin, a solvent capable of dissolving the resin and a neutral and aprotic surfactant. The surfactant includes a polysiloxene skeleton. The adhesive is used in batteries for adhering an active material layer joined to a current collector to a separator.
摘要翻译: 电池用粘合剂 粘合剂具有改善的润湿性能,改进的粘合强度并防止电池性能的劣化。 可以获得具有任意形状的二次电池,例如具有高可靠性和高充电和放电效率的薄形状。 粘合剂包括热塑性树脂,能够溶解树脂的溶剂和中性和非质子表面活性剂。 表面活性剂包括聚硅氧烷骨架。 粘合剂用于将结合到集电器的活性材料层粘附到隔板上的电池中。
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公开(公告)号:US06387565B1
公开(公告)日:2002-05-14
申请号:US09381272
申请日:1999-09-20
申请人: Shigeru Aihara , Daigo Takemura , Hisashi Shiota , Jun Aragane , Hiroaki Urushibata , Yasuhiro Yoshida , Kouji Hamano , Michio Murai , Takayuki Inuzuka
发明人: Shigeru Aihara , Daigo Takemura , Hisashi Shiota , Jun Aragane , Hiroaki Urushibata , Yasuhiro Yoshida , Kouji Hamano , Michio Murai , Takayuki Inuzuka
IPC分类号: H01M618
CPC分类号: H01M2/1673 , H01M2/164 , H01M2/168 , H01M4/13 , H01M6/10 , H01M6/40 , H01M10/0436 , H01M10/052 , H01M10/0525 , H01M10/058
摘要: Conventional batteries are disadvantageous in that a firm outer case must be used to maintain an electrical connection between electrodes, which has been an obstacle to size reduction. Those in which each electrode and a separator are joined with an adhesive resin suffer from conflict between adhesive strength and battery characteristics. To solve these problems, it is an object of the invention to provide a battery which requires no outer case so as to realize reduction in thickness and weight and yet exhibits excellence in both battery characteristics and adhesive strength. A positive electrode, a negative electrode, and a separator are joined via an adhesive resin layer having at least one adhesive resin layer containing a filler. The adhesive resin layer has pores, which are filled with an electrolytic solution to exhibit sufficient ion conductivity thereby to improve battery characteristics and to retain adhesive strength.
摘要翻译: 常规电池的缺点在于,必须使用坚固的外壳来维持电极之间的电连接,这是阻碍尺寸减小的障碍。 每个电极和隔板与粘合剂树脂接合的那些在粘合强度和电池特性之间存在冲突。 为了解决这些问题,本发明的目的是提供一种电池,其不需要外壳,以便实现厚度和重量的减小,并且在电池特性和粘合强度两方面都表现出优异的性能。 正极,负极和隔膜通过具有至少一层含有填料的粘合性树脂层的粘接性树脂层接合。 粘合树脂层具有孔,填充有电解溶液以显示足够的离子传导性,从而改善电池特性并保持粘合强度。
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公开(公告)号:US06352797B1
公开(公告)日:2002-03-05
申请号:US09423629
申请日:1999-11-16
申请人: Yasuhiro Yoshida , Michio Murai , Takayuki Inuzuka , Kouji Hamano , Hisashi Shiota , Shigeru Aihara , Daigo Takemura , Jun Aragane , Hiroaki Urushibata
发明人: Yasuhiro Yoshida , Michio Murai , Takayuki Inuzuka , Kouji Hamano , Hisashi Shiota , Shigeru Aihara , Daigo Takemura , Jun Aragane , Hiroaki Urushibata
IPC分类号: H01M1040
CPC分类号: H01M10/0525 , H01M2/1653 , H01M2/1673 , H01M2/168 , H01M6/188 , H01M6/40 , H01M10/058 , Y10T29/49108
摘要: The invention is a high-performance lithium ion secondary battery which needs no firm case so that it is possible to reduce the size and weight and to design the shape freely and yet which secures high structural strength and safety. The method of the invention for forming a lithium ion battery comprises the step of joining a positive electrode (3) having a positive electrode active material layer (32) joined to a positive electrode current collector (31) and a negative electrode (5) having a negative electrode active material layer (52) joined to a negative electrode current collector (51) with an adhesive resin (6) comprising at least partially a plastic resin being present in parts therebetween and the step of deforming the adhesive resin (6). The method achieves simplification and improvement of productivity in forming a lithium ion battery.
摘要翻译: 本发明是一种高性能的锂离子二次电池,其不需要牢固的壳体,从而可以自由地减小尺寸和重量,并且可以自由地设计形状,并且确保了高的结构强度和安全性。 本发明的用于形成锂离子电池的方法包括:将具有与正极集电体(31)接合的正极活性物质层(32)的正极(3)和负极(5)接合的工序, 接合到负极集电体(51)的负极活性物质层(52)与粘合剂树脂(6)接合,所述粘合树脂(6)至少部分地包括在其间的部分中的塑料树脂和使粘合剂树脂(6)变形的步骤。 该方法简化并提高了形成锂离子电池的生产率。
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公开(公告)号:US06692543B1
公开(公告)日:2004-02-17
申请号:US09581813
申请日:2000-06-19
申请人: Kouji Hamano , Yasuhiro Yoshida , Michio Murai , Takayuki Inuzuka , Hisashi Shiota , Jun Aragane , Hiroaki Urushibata , Shigeru Aihara , Daigo Takemura
发明人: Kouji Hamano , Yasuhiro Yoshida , Michio Murai , Takayuki Inuzuka , Hisashi Shiota , Jun Aragane , Hiroaki Urushibata , Shigeru Aihara , Daigo Takemura
IPC分类号: H01M214
CPC分类号: H01M10/058 , H01M2/1673 , H01M2/168 , H01M4/1391 , H01M4/1393 , H01M6/10 , H01M6/40 , H01M10/0525 , Y10T29/49114 , Y10T29/49115
摘要: A method for manufacturing a lithium ion secondary battery comprising preparing a positive electrode (3) where a positive electrode active material (7) is joined with a positive electrode collector (6), a negative electrode (5) where a negative electrode active material (9) is joined with a negative electrode collector (10), and a separator (4) for retaining the electrolytes including lithium ions, being arranged between the positive electrode (3) and the negative electrode (5), the process of supplying adhesive solution applied on the separator with a second solvent different from a first solvent after applying the adhesive resin solution, where adhesive resin (11) is dissolved in the above first solvent, to the separator (4), and the process of forming an electrode laminate by sticking the positive electrode (3) and the negative electrode (5) to the separator (4).
摘要翻译: 一种锂离子二次电池的制造方法,其特征在于,准备正极活性物质(7)与正极集电体(6)接合的正极(3),负极活性物质(5) 9)与负极集电体(10)连接,并且在正极(3)和负极(5)之间配置用于保持包含锂离子的电解质的隔板(4),提供粘合剂溶液 在将粘合树脂(11)溶解在上述第一溶剂中的粘合性树脂溶液施加到隔膜(4)之后,将第一溶剂与第一溶剂不同的第二溶剂施加到隔膜上,以及通过 将正极(3)和负极(5)粘贴到隔板(4)上。
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公开(公告)号:US06376125B2
公开(公告)日:2002-04-23
申请号:US09809076
申请日:2001-03-16
申请人: Hisashi Shiota , Shigeru Aihara , Daigo Takemura , Jun Aragane , Hiroaki Urushibata , Kouji Hamano , Yasuhiro Yoshida , Takayuki Inuzuka , Michio Murai
发明人: Hisashi Shiota , Shigeru Aihara , Daigo Takemura , Jun Aragane , Hiroaki Urushibata , Kouji Hamano , Yasuhiro Yoshida , Takayuki Inuzuka , Michio Murai
IPC分类号: H01M202
CPC分类号: H01M10/0431 , H01M4/62 , H01M10/0436 , H01M10/052
摘要: An object is to provide with good productivity a practical lithium ion secondary battery which secures lightness in weight and safety without using a firm battery case and has reduced internal resistivity. The lithium ion secondary battery comprises a tabular roll type laminated electrode body in which a band-formed positive electrode (3) comprising a positive electrode active material layer (7) and a positive electrode current collector (6) alternates with a band-formed negative electrode (5) comprising a negative electrode active material layer (9) and a negative electrode current collector (10), having therebetween a band-formed rolled separator (4) which holds a lithium ion-containing electrolytic solution, the positive electrode (3) or the negative electrode (5) being adhered with two separators (4) by an adhesive layer (11).
摘要翻译: 本发明的目的是提供一种实用的锂离子二次电池,其具有轻巧的重量和安全性,而不使用牢固的电池盒并具有降低的内部电阻率。 锂离子二次电池包括片状辊型层叠电极体,其中包含正极活性物质层(7)和正极集电体(6)的带状正极(3)与带状负极 包含负极活性物质层(9)和负极集电体(10)的电极(5),其间具有保持含锂离子的电解液的带状卷取分离体(4),所述正极(3) )或负极(5)通过粘合剂层(11)与两个隔板(4)粘合。
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公开(公告)号:US06811928B2
公开(公告)日:2004-11-02
申请号:US09381295
申请日:1999-09-22
申请人: Shigeru Aihara , Daigo Takemura , Hisashi Shiota , Jun Aragane , Hiroaki Urushibata , Yasuhiro Yoshida , Kouji Hamano , Michio Murai , Takayuki Inuzuka
发明人: Shigeru Aihara , Daigo Takemura , Hisashi Shiota , Jun Aragane , Hiroaki Urushibata , Yasuhiro Yoshida , Kouji Hamano , Michio Murai , Takayuki Inuzuka
IPC分类号: H01M618
CPC分类号: H01M10/0436 , H01M2/164 , H01M2/1646 , H01M2/1653 , H01M2/1673 , H01M2/168 , H01M4/13 , H01M6/10 , H01M6/40 , H01M10/052 , H01M10/0525 , H01M10/058 , Y10T29/49108
摘要: Conventional batteries are disadvantageous in that a firm outer case must be used to maintain an electrical connection between electrodes, which has been an obstacle to size reduction. Those in which each electrode and a separator are joined with an adhesive resin suffer from conflict between adhesive strength and battery characteristics, particularly ion conductivity and internal resistivity. To solve these problems, it is an object of the invention to reduce resistance between electrodes, i.e., internal resistance of a battery to improve battery characteristics while securing both insulation function against electron conduction and ion conductivity between electrodes and also to maintain adhesive strength enough to firmly join the electrodes thereby to provide a light, compact and thin battery. The internal resistivity can be diminished by joining a positive electrode and a negative electrode with an adhesive resin layer having at least one adhesive resin layer containing a filler. The adhesive resin layer has pores, which are filled with an electrolytic solution to exhibit sufficient ion conductivity thereby to improve battery characteristics and to retain adhesive strength.
摘要翻译: 常规电池的缺点在于,必须使用坚固的外壳来维持电极之间的电连接,这是阻碍尺寸减小的障碍。 其中每个电极和隔板与粘合剂树脂接合的那些在粘合强度和电池特性,特别是离子传导性和内部电阻率之间存在冲突。 为了解决这些问题,本发明的目的是降低电极之间的电阻,即电池的内部电阻以改善电池特性,同时确保绝缘功能与电极之间的电子传导和离子传导性,同时保持足够的粘合强度 牢固地连接电极,从而提供轻巧,紧凑和薄的电池。 通过用具有至少一个含有填料的粘合剂树脂层的粘合剂树脂层连接正极和负极,可以减小内部电阻率。 粘合树脂层具有孔,填充有电解溶液以显示足够的离子传导性,从而改善电池特性并保持粘合强度。
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公开(公告)号:US06232014B1
公开(公告)日:2001-05-15
申请号:US09341665
申请日:1999-07-19
申请人: Hisashi Shiota , Shigeru Aihara , Daigo Takemura , Jun Aragane , Hiroaki Urushibata , Kouji Hamano , Yasuhiro Yoshida , Takayuki Inuzuka , Michio Murai
发明人: Hisashi Shiota , Shigeru Aihara , Daigo Takemura , Jun Aragane , Hiroaki Urushibata , Kouji Hamano , Yasuhiro Yoshida , Takayuki Inuzuka , Michio Murai
IPC分类号: H01M202
CPC分类号: H01M2/1673 , H01M2/14 , H01M2/16 , H01M2/168 , H01M4/62 , H01M10/0431 , H01M10/052 , H01M10/0525
摘要: A practical lithium ion secondary battery. The battery is light in weight and is safe without using a firm battery case. It also has reduced internal resistivity. The battery includes a tabular roll-type laminated electrode body in which a band-formed positive electrode alternates with a band-formed negative electrode, with a band-formed rolled separator being placed therebetween. The positive electrode includes a positive electrode active material layer and a positive electrode current collector. The negative electrode includes a negative electrode active material layer and a negative electrode current collector. The separator holds a lithium ion-containing electrolytic solution. The positive electrode or the negative electrode is adhered with two separators by an adhesive layer.
摘要翻译: 实用的锂离子二次电池。 电池重量轻,安全可靠,无需使用牢固的电池盒。 它也降低了内部电阻率。 电池包括带状的辊状层叠电极体,带状的正极与带状的负极交替,带状的卷绕的隔膜位于它们之间。 正极包括正极活性物质层和正极集电体。 负极包括负极活性物质层和负极集电体。 分离器容纳含锂离子的电解液。 正极或负极通过粘合剂层与两个隔板粘合。
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公开(公告)号:US06723467B2
公开(公告)日:2004-04-20
申请号:US09789554
申请日:2001-02-22
申请人: Yasuhiro Yoshida , Osamu Hiroi , Kouji Hamano , Daigo Takemura , Sigeru Aihara , Hisashi Shiota , Jun Aragane , Hiroaki Urushibata , Michio Murai , Takayuki Inuzuka
发明人: Yasuhiro Yoshida , Osamu Hiroi , Kouji Hamano , Daigo Takemura , Sigeru Aihara , Hisashi Shiota , Jun Aragane , Hiroaki Urushibata , Michio Murai , Takayuki Inuzuka
IPC分类号: H01M216
CPC分类号: H01M2/145 , H01M2/16 , H01M2/1686 , H01M8/0202 , H01M2200/10
摘要: Conventional separators had a function that their melting made minute holes inside the separator smaller, leading to cut off of ion conductivity in temperature increase due to unusual conditions such as short circuit. However, there was a problem that, at a temperature higher than a certain degree, not only the minute holes were closed but also the separator itself was melted to cause deformation of the separator such as shrink and generation of holes due to melting and insulation was broken. The present invention has been carried out in order to solve the above problems. The separator for batteries of the present invention comprises a first porous layer (3a) containing a thermoplastic resin as a main component and a second porous layer (3b) laminated on the first porous layer (3a), which has higher heat resistance than that of the first porous layer (3a).
摘要翻译: 传统的分离器具有使分离器内部的熔融细小孔更小的功能,导致由于诸如短路的异常情况导致的温度升高导致的离子传导率的切断。 然而,存在如下问题:在高于一定程度的温度下,不仅关闭了微孔,而且分离器本身也被熔化,从而导致隔板变形,例如熔化和绝缘产生孔 破碎。 为了解决上述问题,已经进行了本发明。 本发明的电池用隔膜包括以热塑性树脂为主要成分的第一多孔层(3a)和层叠在第一多孔层(3a)上的第二多孔层(3b),耐热性高于 第一多孔层(3a)。
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公开(公告)号:US06485862B1
公开(公告)日:2002-11-26
申请号:US09622847
申请日:2001-02-12
申请人: Shoji Yoshioka , Hiroaki Urushibata , Hisashi Shiota , Jun Aragane , Makiko Kise , Shigeru Aihara , Daigo Takemura , Takashi Nishimura , Yasuhiro Yoshida , Osamu Hiroi , Kouji Hamano , Hironori Ozaki , Hideo Ichimura , Kenji Kawaguchi , Masaharu Moriyasu , Shinji Nakadeguchi , Michio Murai , Hisashi Tsukamoto
发明人: Shoji Yoshioka , Hiroaki Urushibata , Hisashi Shiota , Jun Aragane , Makiko Kise , Shigeru Aihara , Daigo Takemura , Takashi Nishimura , Yasuhiro Yoshida , Osamu Hiroi , Kouji Hamano , Hironori Ozaki , Hideo Ichimura , Kenji Kawaguchi , Masaharu Moriyasu , Shinji Nakadeguchi , Michio Murai , Hisashi Tsukamoto
IPC分类号: H01M202
CPC分类号: H01M10/0436 , H01M2/0207 , H01M2/0275 , H01M2/36 , H01M6/10 , H01M6/5072 , H01M10/05 , Y10T29/4911
摘要: A battery body, which is composed of a laminated body obtained by laminating a cathode and an anode via a separator or a wound body obtained by winding them in a laminated structure and a plurality of leads connected to the cathode and the anode, is contained in a flexible package, and after an electrolyte solution is injected thereinto, an opening of the package is sealed at pressure which is lower than atmospheric pressure and is reduced to not less than vapor pressure of the electrolyte solution so that a thin battery is fabricated. A rise in pressure in the battery due to generation of gas in the battery and volume expansion of the gas can be restrained when the battery is maintained at high temperature.
摘要翻译: 一种电池体,其由通过将隔板或卷绕体层叠在阴极和阳极上而获得的层叠体,或者通过将它们卷绕在层叠结构体中而形成的多个引线,以及连接到阴极和阳极的多个引线 柔性包装,并且在电解液注入其中之后,封装的开口在比大气压低的压力下密封并且被降低至不低于电解质溶液的蒸气压,从而制造薄电池。 当电池保持在高温时,可以抑制由于电池中的气体的产生引起的电池中的压力升高和气体的体积膨胀。
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公开(公告)号:US06482544B1
公开(公告)日:2002-11-19
申请号:US09608007
申请日:2000-06-30
申请人: Hisashi Shiota , Shigeru Aihara , Daigo Takemura , Shoji Yoshioka , Makiko Kise , Jun Aragane , Hiroaki Urushibata , Yasuhiro Yoshida , Michio Murai , Kenji Kawaguchi , Hironori Ozaki , Hideo Ichimura , Masaharu Moriyasu , Shinji Nakadeguchi , Takashi Nishimura , Hisashi Tsukamoto
发明人: Hisashi Shiota , Shigeru Aihara , Daigo Takemura , Shoji Yoshioka , Makiko Kise , Jun Aragane , Hiroaki Urushibata , Yasuhiro Yoshida , Michio Murai , Kenji Kawaguchi , Hironori Ozaki , Hideo Ichimura , Masaharu Moriyasu , Shinji Nakadeguchi , Takashi Nishimura , Hisashi Tsukamoto
IPC分类号: H01M208
CPC分类号: H01M2/0277 , H01M2/0212 , H01M2/0275 , H01M2/0285 , H01M2/0287
摘要: A battery package including laminate sheets adhered each other along their peripheral to form a container portion for receiving an electrode assembly and a seal portion. The seal portion surrounds the container portion and protrudes outwardly from side faces of the container portion. The seal portion has enough width to maintain the container portion free from moisture for long periods of time. The laminate sheets include a heat-adhesive polymer layer and a metal layer which stops moisture and provides a shape-maintaining ability to the laminar sheets. The seal portion is folded or curled to reduce a projection area of the battery package.
摘要翻译: 一种电池组,包括层叠片沿着其周边彼此粘合以形成用于容纳电极组件和密封部分的容器部分。 密封部分围绕容器部分并从容器部分的侧面向外突出。 密封部分具有足够的宽度以使容器部分长时间不含水分。 层压片包括热粘合聚合物层和阻止水分并提供对层状片的形状保持能力的金属层。 密封部分被折叠或卷曲以减小电池组件的投影面积。
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