公开(公告)号：US06916535B2

公开(公告)日：2005-07-12

申请号：US10133398

申请日：2002-04-29

申请人： Shinichi Okajima ,  Jinichiro Kato ,  Katsuhiro Fujimoto

发明人： Shinichi Okajima ,  Jinichiro Kato ,  Katsuhiro Fujimoto

IPC分类号： C08G63/183 ,  C08G63/672 ,  C08G63/80 ,  C08J3/12 ,  B32B15/02 ,  C08F20/00

CPC分类号： C08J3/12 ,  C08G63/183 ,  C08G63/672 ,  C08G63/80 ,  C08J2367/02 ,  Y10T428/2982

摘要： The present invention provides a poly(trimethylene terephthalate) pellet comprising 80 wt % or more of trimethylene terephthalate repeating units copolymerized with bis(3-hydroxypropyl) ether at a ratio in a range from 0.01 to 2 wt %, wherein an amount of terminal carboxyl groups is 25 milli-equivalent/kg or less and an intrinsic viscosity is in a range from 0.8 to 2 dl/g, which pellet has an L* value of 75 or more, a b* value in a range from −2 to 5, and a weight in a range from 1 to 50 mg/piece.

摘要翻译： 本发明提供一种聚对苯二甲酸丙二醇酯颗粒，其包含80重量％以上的以二（3-羟丙基）醚与二（3-羟丙基）醚共聚的三亚甲基对苯二甲酸酯重复单元，其比例为0.01〜2重量％，其中末端羧基 基团为25毫当量/ kg以下，特性粘度为0.8〜2dl / g，该颗粒的L *值为75以上，ab *值为-2〜5， 重量范围为1〜50mg /片。

公开(公告)号：US06645619B2

公开(公告)日：2003-11-11

申请号：US10149393

申请日：2002-06-12

申请人： Jinichiro Kato ,  Tetsuko Takahashi ,  Shinichi Okajima ,  Katsuhiro Fujimoto ,  Kenji Imura

发明人： Jinichiro Kato ,  Tetsuko Takahashi ,  Shinichi Okajima ,  Katsuhiro Fujimoto ,  Kenji Imura

IPC分类号： D02G300

CPC分类号： C08G63/6886 ,  C08G63/80 ,  D01F6/84 ,  Y10T428/2904 ,  Y10T428/2909 ,  Y10T428/2913

摘要： The present invention provides poly(trimethylene terephthalate) copolymerized with ester-forming sulfonate and a fiber thereof. The polymer of the present invention is high in melting point, small in loss of melting viscosity and has a high molecular weight. The fiber of the present invention is high in toughness, excellent in whiteness and dyeable with a cationic dye, whereby it is useful for clothing, carpets or non-woven sheets, etc.

摘要翻译： 本发明提供与酯形成磺酸酯共聚的聚（对苯二甲酸丙二醇酯）及其纤维。 本发明的聚合物熔点高，熔融粘度降低，分子量高。 本发明的纤维的韧性高，白度优异，可用阳离子染料染色，因此可用于服装，地毯或无纺布等。

公开(公告)号：US06652964B1

公开(公告)日：2003-11-25

申请号：US09485938

申请日：2000-02-18

申请人： Jinichiro Kato ,  Katsuhiro Fujimoto

发明人： Jinichiro Kato ,  Katsuhiro Fujimoto

IPC分类号： D02G302

CPC分类号： D01F6/84 ,  Y10T428/2913 ,  Y10T428/2915

摘要： A polyester fiber is disclosed, comprising a polyester obtained by copolymerizing a third component with poly(trimethylene terephthalate) wherein the third component is an ester-forming sulfonate compound in a copolymerizing ratio of from 0.5 to 5 mol %, the fiber has a peak temperature of loss tangent of from 85 to 115° C., and the relationship between modulus Q (g/d) and elastic recovery R (%) of the fiber satisfies the following formula (1): 0.18≦Q/R≦0.45. This fiber can be dyed into a dark shade under atmospheric pressure and enables fast dyeing of a fabric using the fiber in composite with a stretch fiber represented by polyurethane elastic fiber or a fiber material having low heat resistance such as wool silk and acetate fiber. The composite fabric can be dyed under atmospheric pressure, therefore, the physical properties of fiber having low heat resistance used in combination is not impaired during the dyeing process. The polyester fiber of the present invention can be treated for caustic reduction, therefore, a fiber having highly soft and dry touch and dyeability into brilliant color can be obtained.

摘要翻译： 公开了一种聚酯纤维，其包含通过使第三组分与聚（对苯二甲酸丙二醇酯）共聚而获得的聚酯，其中第三组分为酯形成磺酸酯化合物，其共聚比为0.5至5mol％，所述纤维具有峰值温度 的损耗角正切为85〜115℃，模量Q（g / d）与弹性恢复率R（％）之间的关系满足下式（1）：0.18 <= Q / R <= 0.45 。 该纤维可以在大气压下染成暗色，并且可以使用由聚氨酯弹性纤维代表的弹性纤维或具有低耐热性的纤维材料如羊毛丝和醋酸纤维的复合材料使织物快速染色。 复合织物可以在大气压下染色，因此在染色过程中组合使用的耐热性低的纤维的物理性能不受损害。本发明的聚酯纤维可以进行苛性还原处理，因此，纤维 可以获得高度柔软和干燥的接触性和染色性，成为明亮的颜色。

公开(公告)号：US06423814B1

公开(公告)日：2002-07-23

申请号：US09463846

申请日：2000-04-26

申请人： Jinichiro Kato ,  Katsuhiro Fujimoto ,  Tetsuko Takahashi

发明人： Jinichiro Kato ,  Katsuhiro Fujimoto ,  Tetsuko Takahashi

IPC分类号： C08G6302

CPC分类号： D01F6/84 ,  C08G63/183 ,  C08G63/672 ,  C08K5/52 ,  D01F6/62 ,  Y10T428/2913 ,  Y10T428/294 ,  Y10T428/2969 ,  C08L67/02

摘要： A polyester resin composition is disclosed, comprising poly(trimethylene terephthalate) in a proportion of 90 wt % or more, wherein the resin composition has an intrinsic viscosity of from 0.4 to 2 and contains a phosphorus compound corresponding to from 10 to 250 ppm in terms of the amount of phosphorus element, a cyclic dimer in an amount of not exceeding 3 wt % and a bis(3-hydroxypropyl)ether in an amount of 2 wt % or less. This polyester resin composition has excellent spinning stability and high melt stability and is used for the production of a poly(trimethylene terephthalate)-based fiber having excellent whiteness and high tenacity.

摘要翻译： 公开了一种聚酯树脂组合物，其包含90重量％以上的聚（对苯二甲酸丙二醇酯），其中树脂组合物的特性粘度为0.4〜2，含有对应于10〜250ppm的磷化合物 的磷元素的量，不超过3重量％的环状二聚体和2重量％以下的双（3-羟丙基）醚。 该聚酯树脂组合物具有优异的纺丝稳定性和高熔体稳定性，并且用于生产具有优异的白度和高强度的聚（对苯二甲酸丙二醇酯）基纤维。

公开(公告)号：US06867322B1

公开(公告)日：2005-03-15

申请号：US10070740

申请日：2000-09-13

申请人： Jinichiro Kato ,  Katsuhiro Fujimoto

发明人： Jinichiro Kato ,  Katsuhiro Fujimoto

IPC分类号： C07C27/02 ,  C07C29/09 ,  C07C29/128 ,  C07C67/03 ,  C08G63/183 ,  C08J11/24 ,  D01F6/62 ,  C07C63/313 ,  B32B27/00 ,  C07C67/48 ,  C08F6/00 ,  C08J11/04

CPC分类号： C08J11/24 ,  C07C29/095 ,  C07C29/1285 ,  C07C67/03 ,  C08G63/183 ,  C08J2367/02 ,  D01F6/62 ,  Y02P20/582 ,  Y02W30/706 ,  C07C69/82 ,  C07C31/205

摘要： An ester-forming monomer obtained by depolymerization of polytrimethylene terephthalate and having an acrolein content of no greater than 0.5 wt %. Polymers obtained using the monomer and fibers, films and molded articles comprising the polymers. The ester-forming monomer is obtained by reacting polytrimethylene terephthalate with at least one compound selected from among monoalcohols, 1,3-propanediol and water in the presence of a basic substance. When the recovered ester-forming monomer is used as the starting material for production of a polymer, it is possible to produce a molding polymer for fibers, films and the like with quality equivalent to or higher than that obtained using virgin monomer.

摘要翻译： 通过聚对苯二甲酸丙二醇酯的解聚得到的丙烯醛含量不大于0.5重量％得到的酯形成单体。 使用单体和纤维获得的聚合物，包含聚合物的膜和模制品。 酯形成单体通过在碱性物质的存在下使聚对苯二甲酸丙二醇酯与选自一元醇，1,3-丙二醇和水中的至少一种化合物反应而获得。 当使用回收的酯形成单体作为聚合物的制备原料时，可以制造质量等于或高于使用原始单体的纤维，膜等的模塑聚合物。

公开(公告)号：US06692671B2

公开(公告)日：2004-02-17

申请号：US09899239

申请日：2001-07-06

申请人： Katsuhiro Fujimoto ,  Jinichiro Kato

发明人： Katsuhiro Fujimoto ,  Jinichiro Kato

IPC分类号： D01D516

CPC分类号： D06M15/53 ,  D01F6/62 ,  D06M7/00 ,  D06M13/02 ,  D06M13/224 ,  D06M2200/40 ,  Y10T428/2913 ,  Y10T428/2969

摘要： A process for producing a polyester fiber by melt spinning a polyester having at least 90% or more by weight of poly(trimethylene terphthalate), the process including rapidly cooling to solidify molten filaments extruded from a spinning nozzle, winding the solidified filaments around a first roll heated at from 30 to 80° C. and having a peripheral speed of from 300 to 3,500 in/mm without the filaments being wound thereon, delivering the filaments to a second roll heated at from 100 to 160° C. to be wound around its peripheral surface, whereby the filaments are drawn at a draw ratio of 1.3 to 4 between the first roll and the second roll having a peripheral speed higher than that of the first roll, and subsequently winding the filaments on a take-up winder having a peripheral speed lower than that of the second roll.

摘要翻译： 通过熔融纺丝具有至少90重量％以上聚（对苯二甲酸丙二醇酯）的聚酯的聚酯纤维来制造聚酯纤维的方法，该方法包括快速冷却以固化从纺丝喷嘴挤出的熔融长丝，将固化的纤维缠绕在第一 辊加热至30至80℃，圆周速度为300至3,500英寸/毫米，而不缠绕细丝，将细丝输送到加热至100至160℃的第二辊上以缠绕 其周边表面，其中长丝以第一辊和第二辊之间的拉伸比为1.3至4的圆周速度比第一辊的圆周速度拉伸，随后将长丝缠绕在具有 圆周速度比第二辊低。

公开(公告)号：US06468655B1

公开(公告)日：2002-10-22

申请号：US09601194

申请日：2000-07-28

申请人： Jinichiro Kato ,  Katsuhiro Fujimoto

发明人： Jinichiro Kato ,  Katsuhiro Fujimoto

IPC分类号： D02G300

CPC分类号： D06M15/53 ,  D01F6/62 ,  D06M7/00 ,  D06M13/02 ,  D06M13/165 ,  D06M13/17 ,  D06M13/224 ,  D06M13/256 ,  D06M13/292 ,  D06M2101/32 ,  D06M2200/00 ,  D06M2200/35 ,  D06M2200/40 ,  D06M2200/50 ,  Y10T428/2913 ,  Y10T428/2933 ,  Y10T428/2967 ,  Y10T428/2969

摘要： The present invention discloses a polyester fiber having a birefringence of 0.025 or more, comprising at least 90% by weight of a poly (trimethylene terephthalate), on which a finishing agent composed essentially of (1) an aliphatic hydrocarbon ester having a molecular weight of 300 to 800 and/or a mineral oil having a Redwood viscosity at 30° C. of 40 to 500 seconds, (2) a polyether having a structure containing an ethylene oxide unit and a propylene oxide unit, (3) a nonionic surfactant, and (4) an ionic surfactant in a specific proportion is applied.

摘要翻译： 本发明公开了一种双折射率为0.025以上的聚酯纤维，其含有至少90重量％的聚（对苯二甲酸丙二醇酯），其上整理剂基本上由（1）脂肪族烃酯组成，其分子量为 300至800和/或在30℃下具有红木粘度的矿物油为40至500秒，（2）具有包含环氧乙烷单元和环氧丙烷单元的结构的聚醚，（3）非离子表面活性剂， 和（4）应用特定比例的离子表面活性剂。

公开(公告)号：US06316101B2

公开(公告)日：2001-11-13

申请号：US09485581

申请日：2000-02-14

申请人： Jinichiro Kato ,  Katsuhiro Fujimoto ,  Tetsuko Takahashi

发明人： Jinichiro Kato ,  Katsuhiro Fujimoto ,  Tetsuko Takahashi

IPC分类号： D01F692

CPC分类号： D01F6/84 ,  C08G63/183 ,  C08G63/672 ,  C08K5/52 ,  D01F6/62 ,  Y10T428/2913 ,  Y10T428/294 ,  Y10T428/2969 ,  C08L67/02

摘要： There are disclosed polyester fibers that are composed of at least 90% by weight of poly(trimethylene terephthalate) and have a limiting viscosity of 0.4-2, being characterized by containing a phosphorus compound at 10-250 ppm in terms of weight of elemental phosphorus, containing no more than 3 wt % of cyclic dimers, containing no more than 2 wt % of bis(3-hydroxypropyl) ether copolymerized with the poly(trimethylene terephthalate), and having a birefringence of 0.03 or greater. The polyester fibers are poly(trimethylene terephthalate)-based fibers with excellent whiteness and tenacity, which are obtained by melt spinning of poly(trimethylene terephthalate) resin composition with improved whiteness, melt stability and spinning stability. The polyester fibers of the invention have satisfactory processability and can be mixed with stretch fibers and the like to provide fabrics having functions that cannot be obtained with commonly used polyester fibers and nylon fibers, for various types of clothing products and the like.

摘要翻译： 公开了由至少90重量％的聚（对苯二甲酸丙二醇酯）组成并且特性粘度为0.4-2的聚酯纤维，其特征在于以元素磷的重量计含有10-250ppm的磷化合物 ，含有不超过3重量％的环状二聚体，其含有不超过2重量％的与聚（对苯二甲酸丙二醇酯共聚）的双（3-羟丙基）醚，并且双折射率为0.03以上。聚酯纤维为聚 （三亚甲基对苯二甲酸酯）基纤维，其具有优异的白度和强度，其通过熔融纺丝具有改善的白度，熔体稳定性和纺丝稳定性的聚（对苯二甲酸丙二醇酯）树脂组合物而获得。 本发明的聚酯纤维具有令人满意的加工性，并且可以与拉伸纤维等混合，以提供具有通常使用的聚酯纤维和尼龙纤维不能获得的功能的织物，用于各种类型的服装产品等。

公开(公告)号：US06284370B1

公开(公告)日：2001-09-04

申请号：US09555118

申请日：2000-05-25

申请人： Katsuhiro Fujimoto ,  Jinichiro Kato

发明人： Katsuhiro Fujimoto ,  Jinichiro Kato

IPC分类号： D01F600

CPC分类号： D06M15/53 ,  D01F6/62 ,  D06M7/00 ,  D06M13/02 ,  D06M13/224 ,  D06M2200/40 ,  Y10T428/2913 ,  Y10T428/2969

摘要： A polyester fiber comprising 90% or more by weight of a poly(trimethylene terephthalate), and showing a peak value of a thermal stress of 0.1 to 0.35 g/d, a boil-off shrinkage of 5 to 16%, a tenacity of 3 g/d or more, an elongation of 20 to 60%, a relationship between an elastic modulus Q (g/d) and an elastic recovery R (%) satisfying the formula (1), and a peak temperature of a loss tangent of 90 to 120° C.: 0.18≦Q/R≦0.45  (1) The polyester fiber of the present invention is a poly(trimethylene terephthalate) fiber which has an elongation, a thermal stress and a boil-off shrinkage in appropriate ranges, and the woven or knitted fabric prepared therefrom shows inhibition of an excessive thermal shrinkage during processing and manifests a low elastic modulus and a soft hand touch. Accordingly, the polyester fiber of the present invention is suitable for use in innerwear, outerwear, sportswear, legwear, lining cloths, swimwear and the like. In addition, the polyester fiber can be stably manufactured in high productivity by a process in which spinning and drawing are consecutively conducted to prevent the undrawn yarn from aging.

摘要翻译： 包含90重量％以上的聚对苯二甲酸丙二醇酯的聚酯纤维，热应力的峰值为0.1〜0.35g / d，蒸发收缩率为5〜16％，强度为3 g / d以上，伸长率为20〜60％，弹性模量Q（g / d）与满足式（1）的弹性恢复率R（％）之间的关系，以及损耗角正切的峰值温度 90〜120℃。本发明的聚酯纤维是在适当范围内具有伸长率，热应力和沸腾收缩率的聚（对苯二甲酸丙二醇酯）纤维，由其制备的机织或针织织物显示出抑制作用 在处理过程中热收缩过大，表现出低的弹性模量和柔软的手感。 因此，本发明的聚酯纤维适用于内衣，外衣，运动服，运动服，衬里布，泳装等。 此外，通过连续进行纺丝和拉伸以防止未拉伸丝变老的方法，可以以高生产率稳定地制造聚酯纤维。

公开(公告)号：US06740400B2

公开(公告)日：2004-05-25

申请号：US10066712

申请日：2002-02-06

申请人： Jinichiro Kato ,  Yoichiro Azuma ,  Katsuhiro Fujimoto ,  Teruhiko Matsuo

发明人： Jinichiro Kato ,  Yoichiro Azuma ,  Katsuhiro Fujimoto ,  Teruhiko Matsuo

IPC分类号： D02G300

CPC分类号： D01F6/62 ,  C08G63/183 ,  C08G63/672 ,  C08G63/80 ,  Y10T428/2913

摘要： A poly(trimethylene terephthalate) comprising 80% by weight or more of trimethylene terephthalate units based on the entire repeating units, having an intrinsic viscosity of from 0.4 to 1.5 dl/g, and satisfying the following formula (1) [—OH]/([—OH]+[—COOH]+[—CH2CH═CH2])×100≧40  (1) wherein [—OH], [—COOH] and [—CH2CH═CH2] represent a terminal hydroxyl group content, a terminal carboxyl group content and a terminal allyl group content of the poly(trimethylene terephthalate), respectively. The poly(trimethylene terephthalate) can be produced by reacting terephthalic acid and/or its lower alcohol ester is reacted with 1,3-propanediol to form 1,3-propanediol ester of terephthalic acid and/or its oligomer, and then polycondensation reaction of the reactant is conducted at temperature of from 235 to 270° C. while the above formula (1) is being satisfied to give the above poly(trimethylene terephthalate).

摘要翻译： 基于全部重复单元的80重量％以上的对苯二甲酸丙二醇酯单元，特性粘度为0.4〜1.5dl / g，满足下式（1）的聚（对苯二甲酸丙二醇酯），其中[-OH] ，[-COOH]和[-CH 2 CH = CH 2]分别表示聚（对苯二甲酸丙二醇酯）的末端羟基含量，末端羧基含量和末端烯丙基含量。 聚对苯二甲酸丙二醇酯可以通过使对苯二甲酸和/或其低级醇酯与1,3-丙二醇反应形成对苯二甲酸和/或其低聚物的1,3-丙二醇酯，然后进行缩聚反应 反应物在235〜270℃的温度下进行，同时满足上述式（1），得到上述聚（对苯二甲酸丙二醇酯）。