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    Carbonaceous electrode material for non-aqueous secondary battery
    1.
    发明授权
    Carbonaceous electrode material for non-aqueous secondary battery 有权
    用于非水二次电池的碳质电极材料

    公开(公告)号：US06335122B1

    公开(公告)日：2002-01-01

    申请号：US09402122

    申请日：1999-12-16

    申请人： Shinichiro Yamada ,  Hiroshi Imoto ,  Hideto Azuma ,  Tadashi Senoo ,  Koji Sekai ,  Masayuki Nagamine ,  Atsuo Omaru ,  Naohiro Sonobe ,  Jiro Masuko ,  Minoru Ishikawa

    发明人： Shinichiro Yamada ,  Hiroshi Imoto ,  Hideto Azuma ,  Tadashi Senoo ,  Koji Sekai ,  Masayuki Nagamine ,  Atsuo Omaru ,  Naohiro Sonobe ,  Jiro Masuko ,  Minoru Ishikawa

    IPC分类号： H01M458

    CPC分类号： H01M4/587 ,  H01M4/133 ,  H01M4/505 ,  H01M4/525 ,  H01M10/0525 ,  H01M2004/021

    摘要： A carbonaceous electrode having improved capacities for doping and dedoping of a cell active substance, such as lithium, and suitable for a non-aqueous solvent secondary battery, is constituted by a carbonaceous material having a true density as measured by a butanol substitution method of at most 1.46 g/cm3, a true density as measured by a helium substitution method of at least 1.7 g/cm3, a hydrogen-to-carbon atomic ratio H/C of at most 0.15 as measured according to elementary analysis, a BET specific surface area of at most 50 m2/g as measured by nitrogen adsorption BET method, and a carbon dioxide adsorption capacity of at least 10 ml/g. The carbonaceous material is advantageously produced by carbonizing an organic material originated from bamboo genera of family Gramineae, particularly genus Pleioblastus or Bambusa, at 1000-1400° C. under a reduced pressure or under a flowing inert gas stream to provide an appropriate porous structure.

    摘要翻译： 具有改善的电池活性物质（例如锂）的掺杂和去掺杂的适用于非水溶剂二次电池的容量的碳质电极由具有真实密度的碳质材料构成，所述碳质材料通过丁醇取代方法 最大1.46g / cm 3，通过氦取代方法测定的至少1.7g / cm 3的真实密度，根据元素分析测定的氢/碳原子比H / C至多为0.15，BET比表面积 通过氮吸附BET法测定的面积为至多50m 2 / g，二氧化碳吸附容量至少为10ml / g。 碳质材料有利地通过在1000-1400℃下在减压下或在流动的惰性气流下碳化源自禾本科的竹属，特别是Pleioblastus或Bambusa的竹属的有机材料来产生，以提供合适的多孔结构。

    Anode material and method of manufacturing the same
    2.
    发明授权
    Anode material and method of manufacturing the same 失效
    阳极材料及其制造方法

    公开(公告)号：US5716732A

    公开(公告)日：1998-02-10

    申请号：US812734

    申请日：1997-03-06

    申请人： Hiroshi Imoto ,  Atsuo Omaru ,  Hideto Azuma ,  Yoshio Nishi ,  Yoshihisa Gonno ,  Masayuki Nagamine

    发明人： Hiroshi Imoto ,  Atsuo Omaru ,  Hideto Azuma ,  Yoshio Nishi ,  Yoshihisa Gonno ,  Masayuki Nagamine

    IPC分类号： H01M4/1393 ,  H01M4/48 ,  H01M4/485 ,  H01M4/58 ,  H01M4/587 ,  H01M10/0525 ,  H01M10/36 ,  H01M6/00

    CPC分类号： H01M4/587 ,  H01M10/0525 ,  H01M4/583 ,  H01M4/1393 ,  H01M4/485

    摘要： An anode material consisting of non-graphitizable carbon material obtained by baking a carbon precursor is disclosed. In this non-graphitizable carbon material, a ratio by weight of carbon Ps in a stacking structure as determined from diffraction peak originating in a (002) crystal lattice plane and X-ray diffraction spectrum components on the lower angle side with respect to the diffraction peak originating in the (002) crystal lattice plane of X-ray diffraction spectrum is smaller than 0.59, or the stacking index SI thereof is smaller than 0.76. Moreover, an average number of carbon layers n.sub.ave in a stacking structure is smaller than 2.46. Alternatively, when the baking temperature is T.degree.C. and the half width at half maximum of the peak appearing in the vicinity of 1340 cm.sup.-1 in the Raman spectrum is HW, the condition expressed below is satisfied. HW>138-0.06.multidot.T This non-graphitizable carbon material is manufactured by allowing the carbon precursor which becomes non-graphitizable carbon by baking to undergo heat treatment at a temperature 600.degree. C. or more under an inactive gas atmosphere of flow rate of 0.1 ml/sec. or more per 1 g of carbon precursor, or to undergo heat treatment at a temperature 600.degree. C. or more under an atmosphere of pressure less than 50 kPa. At this time, carbon precursor is mounted in a layered form so that the area in contact with the atmosphere is 10 cm.sup.2 or more per 1 Kg.

    摘要翻译： 公开了一种由通过焙烧碳前体获得的不可石墨化碳材料构成的负极材料。 在该非石墨化碳材料中，由源于（002）晶格面的衍射峰确定的层叠结构中的碳Ps的重量比和相对于衍射的下角侧的X射线衍射光谱成分 源于X射线衍射光谱的（002）晶格面的峰值小于0.59，或者其堆积指数SI小于0.76。 此外，层叠结构中的碳层的平均数量小于2.46。 或者，当烘烤温度为T℃时，在拉曼光谱中出现在1340cm -1附近的峰的半值宽度为HW时，满足以下表达的条件.HW> 138-0.06xTThis 不可石墨化的碳材料是通过在惰性气体气氛下以0.1ml / sec的流动速率在600℃或更高的温度下进行焙烧，使成为不可石墨化碳的碳前体进行热处理来制造的。 或更多的碳前体，或者在低于50kPa的压力的气氛下，在600℃以上的温度下进行热处理。 此时，碳前驱体以层叠的形式安装，使得与大气接触的面积为每1Kg为10cm 2以上。

    Anode material and method of manufacturing the same
    3.
    发明授权
    Anode material and method of manufacturing the same 失效
    阳极材料及其制造方法

    公开(公告)号：US5643426A

    公开(公告)日：1997-07-01

    申请号：US507324

    申请日：1995-08-23

    申请人： Hiroshi Imoto ,  Atsuo Omaru ,  Hideto Azuma ,  Yoshio Nishi ,  Yoshihisa Gonno ,  Masayuki Nagamine

    发明人： Hiroshi Imoto ,  Atsuo Omaru ,  Hideto Azuma ,  Yoshio Nishi ,  Yoshihisa Gonno ,  Masayuki Nagamine

    IPC分类号： H01M4/02 ,  H01M4/38 ,  H01M4/58 ,  C25B11/12

    CPC分类号： H01M4/587 ,  H01M4/13 ,  H01M4/583 ,  H01M10/0525 ,  H01M2004/021 ,  H01M2004/027

    摘要： An anode material consisting of non-graphitizable carbon material obtained by baking carbon precursor is disclosed. In this non-graphitizable carbon material, ratio by weight of carbon Ps in stacking structure determined from diffraction peak originating in (002) crystal lattice plane and X-ray diffraction spectrum components on the lower angle side with respect to the diffraction peak originating in the (002) crystal lattice plane of X-ray diffraction spectrum is smaller than 0.59, or stacking index SI thereof is smaller than 0.76. Moreover, average number of carbon layers n.sub.ave in stacking structure is smaller than 2.46. Alternatively, when baking temperature is T.degree. C. and half width at half maximum of peak appearing in the vicinity of 1340 cm.sup.-1 in Raman spectrum is HW, the condition expressed below is satisfied.HW>138-0.06.multidot.TThis non-graphitizable carbon material is manufactured by allowing carbon precursor which becomes non-graphitizable carbon by baking to undergo heat treatment at temperature 600.degree. C. or more under inactive gas atmosphere of flow rate of 0.1 ml/sec. or more per carbon precursor 1 g, or to undergo heat treatment at temperature 600.degree. C. or more under the atmosphere of pressure less than 50 kPa. At this time, carbon precursor is mounted in a layered form so that the area in contact with the atmosphere is 10 cm.sup.2 or more per 1 Kg.

    摘要翻译： PCT No.PCT / JP93 / 01929 Sec。 371日期1995年8月23日 102（e）日期1995年8月23日PCT 1993年12月28日PCT公布。 WO95 / 18467 PCT出版物 日期：1995年7月6日公开了通过焙烧碳前体得到的由不可石墨化的碳材料构成的负极材料。 在该不石墨化碳材料中，由源于（002）晶格面的衍射峰和下角侧的X射线衍射光谱成分相对于起源于（002）晶格面的衍射峰确定的层叠结构中的碳Ps的重量比 X射线衍射光谱的（002）晶格面小于0.59，或堆积指数SI小于0.76。 此外，层叠结构中的碳层平均数小于2.46。 或者，当烘烤温度为T℃时，在拉曼光谱中出现在1340cm -1附近的峰值半峰宽为HW，满足以下表达的条件：W> 138-0.06×T这种非石墨化碳 通过在0.1ml /秒的流动速率的惰性气体气氛下，在600℃以上的温度下进行焙烧，使成为不可石墨化碳的碳前体进行热处理，从而制造材料。 或更多的每碳前体1g，或在压力小于50kPa的气氛下在600℃或更高温度下进行热处理。 此时，碳前驱体以层叠的形式安装，使得与大气接触的面积为每1Kg为10cm 2以上。

    Non-acqueous electrolyte secondary cell
    8.
    发明授权
    Non-acqueous electrolyte secondary cell 失效
    非水电解质二次电池

    公开(公告)号：US06686094B2

    公开(公告)日：2004-02-03

    申请号：US09043634

    申请日：1998-07-24

    申请人： Atsuo Omaru ,  Naoyuki Nakajima ,  Masayuki Nagamine

    发明人： Atsuo Omaru ,  Naoyuki Nakajima ,  Masayuki Nagamine

    IPC分类号： H01M462

    CPC分类号： H01M10/0525 ,  H01M2/348 ,  H01M4/131 ,  H01M4/133 ,  H01M4/485 ,  H01M4/525 ,  H01M4/587 ,  H01M4/625 ,  H01M6/10 ,  H01M6/164 ,  H01M10/0587 ,  H01M2300/0025

    摘要： In a non-aqueous electrolyte secondary battery including an anode and a cathode consisting of material capable of doping/undoping of lithium, and non-aqueous electrolytic solution in which electrolyte is dissolved in a non-aqueous solvent, flaky graphite having high crystallinity and high electron conductivity is added as conductive agent into the anode and the cathode. Further, granulated carbon and carbon black having specific material property is added as conductive agent in addition to the flaky graphite. Thus, non-aqueous electrolyte secondary battery having long cycle life time and high reliability can be obtained.

    摘要翻译： 在包括由锂掺杂/脱掺杂的材料构成的阳极和阴极的非水电解质二次电池以及其中电解质溶解在非水溶剂中的非水电解液中，具有高结晶性和高结晶性的片状石墨 将电子传导性作为导电剂添加到阳极和阴极中。 此外，除了片状石墨之外，还加入具有特定材料特性的造粒碳和炭黑作为导电剂。 因此，可以获得具有长循环寿命和高可靠性的非水电解质二次电池。

    Material for positive electrode and secondary battery
    9.
    发明授权
    Material for positive electrode and secondary battery 有权
    正极和二次电池的材料

    公开(公告)号：US07045251B2

    公开(公告)日：2006-05-16

    申请号：US11113771

    申请日：2005-04-25

    申请人： Hisashi Tsujimoto ,  Yoshikatsu Yamamoto ,  Junji Kuyama ,  Masayuki Nagamine ,  Atsuo Omaru ,  Hiroaki Tanizaki

    发明人： Hisashi Tsujimoto ,  Yoshikatsu Yamamoto ,  Junji Kuyama ,  Masayuki Nagamine ,  Atsuo Omaru ,  Hiroaki Tanizaki

    IPC分类号： H01M4/50 ,  H01M4/52

    CPC分类号： H01M4/505 ,  H01M4/131 ,  H01M4/133 ,  H01M4/134 ,  H01M4/364 ,  H01M4/386 ,  H01M4/525 ,  H01M4/587 ,  H01M10/052 ,  H01M10/0525 ,  H01M10/0587 ,  H01M2004/028

    摘要： Disclosed is a non-aqueous electrolyte secondary battery having an excellent preservation characteristic at a high temperature and charging/discharging cycle characteristic.A rolled body in which a strip-shape positive electrode and negative electrode are rolled with a separator in-between is provided inside a battery can. The positive electrode contains LixMn2−yMayO4 (where, Ma is at least one element selected from the group consisting of metal elements other than Mn, and B) and LiNi1−zMbzO2 (where, Mb is at least one element selected from the group consisting of metal elements other than Ni, and B). By replacing part of Mn and Ni with other elements, the crystal structure can be stabilized. Thereby, the capacity retention ratio after preservation at a high temperature, and a heavy load discharging power under a high electric potential cutoff can be improved. The mean particle size of particles of the above-mentioned oxides are preferable to be 30 μm and below so that an excellent charging/discharging cycle characteristic can be obtained.

    摘要翻译： 公开了一种在高温和充放电循环特性方面具有优异的保存特性的非水电解质二次电池。 在电池壳内部设置有带状正极和负极在其间分离的卷状卷绕体。 正极含有Li x Mn 2 O y O y O 4（其中，Ma是至少一个 选自除Mn以外的金属元素的元素，以及B）和LiNi 1-z Mb z O 2 N（其中，Mb 是选自Ni之外的金属元素和B）中的至少一种元素。 通过用其他元素代替Mn和Ni的一部分，可以稳定晶体结构。 由此，能够提高高电位保存后的容量保持率和高电位切断下的重负荷放电功率。 上述氧化物的粒子的平均粒径优选为30μm以下，因此可以得到良好的充放电循环特性。

    Anode material for non-aqueous electrolyte secondary battery and non-aqueous electrolyte secondary battery using such anode material
    10.
    发明授权
    Anode material for non-aqueous electrolyte secondary battery and non-aqueous electrolyte secondary battery using such anode material 失效
    用于非水电解质二次电池的阳极材料和使用这种阳极材料的非水电解质二次电池

    公开(公告)号：US06716557B2

    公开(公告)日：2004-04-06

    申请号：US09859060

    申请日：2001-05-16

    申请人： Atsuo Omaru ,  Naoyuki Nakajima ,  Masayuki Nagamine

    发明人： Atsuo Omaru ,  Naoyuki Nakajima ,  Masayuki Nagamine

    IPC分类号： H01M458

    CPC分类号： D01F11/12 ,  D01F9/15 ,  H01M4/0433 ,  H01M4/133 ,  H01M4/587 ,  H01M10/0525 ,  H01M2004/021 ,  H01M2004/022 ,  H01M2300/004

    摘要： Carbon fiber having cross sectional shape which satisfies area replenishment rate of 0.8 or more is used as anode material for non-aqueous electrolyte secondary battery. Alternatively, since value of fractal dimension of cross section high order structure of the random radial type carbon fiber can be utilized as material parameter for evaluating the cross sectional structure, carbon fiber in which the value of the fractal dimension is caused to fall within the range from 1.1 to 1.8 and the crystallinity has been controlled such that it falls within reasonable range is used as anode material for non-aqueous electrolyte secondary battery. Further, carbon fiber having cross section high order structure such that the central portion is radial type structure and the surface layer portion is random radial type structure is used as anode material for non-aqueous electrolyte secondary battery. Furthermore, it is also effective to use carbon fiber having notch structure at the cross section. In addition, graphitized carbon fiber having cross sectional portions different in the crystal structure at predetermined periods in the fiber length direction is made up. By crushing the graphitized carbon fiber thus obtained, carbon fiber crushed powder having less unevenness and predetermined aspect ratio can be easily made up.

    摘要翻译： 作为非水电解质二次电池的负极材料，使用满足0.8以上的区域补充率的截面形状的碳纤维。 或者，由于可以利用随机径向型碳纤维的横截面高阶结构的分形尺寸的值作为用于评价截面结构的材料参数，其中使分形维数的值落在范围内的碳纤维 1.1〜1.8，结晶度控制在合理范围内，用作非水电解质二次电池的负极材料。 此外，作为非水电解质二次电池的负极材料，使用具有横截面高阶结构的碳纤维，使得中心部分是径向型结构，表层部分是随机径向型结构。 此外，在截面上使用具有凹口结构的碳纤维也是有效的。 此外，在纤维长度方向上，在规定时间内，形成具有晶体结构不同的截面部分的石墨化碳纤维。 通过粉碎由此获得的石墨化碳纤维，可以容易地制成具有较小不均匀性和预定纵横比的碳纤维粉碎粉末。