公开(公告)号：US20160075895A1

公开(公告)日：2016-03-17

申请号：US14853141

申请日：2015-09-14

申请人： Shizuka KOHZUKI ,  Teruki Kusahara ,  Hiroki Nakane

发明人： Shizuka KOHZUKI ,  Teruki Kusahara ,  Hiroki Nakane

IPC分类号： C09D11/30

CPC分类号： C09D11/10 ,  C09D11/101 ,  C09D11/322

摘要： An active energy ray curable composition includes a non-polymerizable resin; and polymerizable compounds comprising a mono-functional monomer having a single polymerizable unsaturated ethylene double bond, wherein the following relations are satisfied: ΔTg=|Tgp−Tgm}≧19 degrees C., where Tgp represents a glass transition temperature of the non-polymerizable resin and Tgm represents a glass transition temperature of a homopolymer of the mono-functional monomer, TgH≧10 degrees C., where TgH represents the higher of Tgp and Tgm, and TgL≦40 degrees C., where TgL represents the lower of Tgp and Tgm.

摘要翻译： 活性能量射线固化性组合物包含不可聚合树脂; 和包含具有单个可聚合不饱和乙烯双键的单官能单体的可聚合化合物，其中满足以下关系：＆Dgr; Tg = | Tgp-Tgm}≥19℃，其中Tgp表示非 - 可聚合树脂，Tgm表示单官能单体的均聚物的玻璃化转变温度TgH≥10℃，其中TgH表示Tgp和Tgm较高，TgL＆nlE; 40℃，其中TgL表示较低 的Tgp和Tgm。

公开(公告)号：US20170267881A1

公开(公告)日：2017-09-21

申请号：US15615570

申请日：2017-06-06

申请人： Shizuka KOHZUKI ,  Teruki KUSAHARA ,  Hiroki NAKANE

发明人： Shizuka KOHZUKI ,  Teruki KUSAHARA ,  Hiroki NAKANE

IPC分类号： C09D11/10 ,  C09D11/101 ,  C09D11/322

CPC分类号： C09D11/10 ,  C09D11/101 ,  C09D11/322

摘要： An active energy ray image forming apparatus containing a head, a heating mechanism disposed inside the head, and a storing part configured to accommodate a non-polymerizable synthetic resin and a mono-functional monomer containing a single unsaturated ethylene double bond. An active energy ray image forming apparatus, containing a head, a heating mechanism disposed inside the head, and a storing part configured to accommodate a non-polymerizable synthetic resin and a mono-functional monomer containing a single unsaturated ethylene double bond, where the heating mechanism is heated to 60° C. when ink is discharged.

公开(公告)号：US20170015850A1

公开(公告)日：2017-01-19

申请号：US15202858

申请日：2016-07-06

申请人： Mie YOSHINO ,  Manabu ARITA ,  Shizuka KOHZUKI ,  Hiroki KOBAYASHI

发明人： Mie YOSHINO ,  Manabu ARITA ,  Shizuka KOHZUKI ,  Hiroki KOBAYASHI

IPC分类号： C09D11/107 ,  C08F222/14 ,  B33Y70/00 ,  C09D11/101 ,  B41J11/00 ,  C08F222/38 ,  C09D11/30

CPC分类号： C09D11/107 ,  B33Y10/00 ,  B33Y30/00 ,  B33Y70/00 ,  B41J11/002 ,  C08F222/14 ,  C08F222/38 ,  C09D11/101 ,  C09D11/30 ,  C09D11/324

摘要： In accordance with sonic embodiments of the present invention, an active energy ray curable composition including a polymerizable compound composition is provided. When the active energy ray curable composition is formed into a film having an average thickness of 10 μm on a substrate and, after a lapse of 15 seconds, the film is irradiated with an active energy ray having a light quantity of 1,500 mJ/cm2 to become a cured product, the cured product satisfies the following conditions (1) and (2): (1) when the substrate is a polypropylene substrate, the cured product has a glass transition temperature of 60° C. or more; and (2) when the substrate is a polycarbonate substrate, an adhesion between the polycarbonate substrate and the cured product is 70 or more, the adhesion being measured according to a cross-cut adhesion test defined in Japanese industrial Standards K5400.

摘要翻译： 根据本发明的一些实施方案，提供了包含可聚合化合物组合物的活性能量射线固化性组合物。 当活性能量射线固化性组合物在基材上形成平均厚度为10μm的膜时，经过15秒后，用光量为1500mJ / cm 2的活性能量射线照射该膜 为了成为固化物，固化物满足以下条件（1）和（2）：（1）当基材为聚丙烯基板时，固化物的玻璃化转变温度为60℃以上; （2）当基材为聚碳酸酯基材时，聚碳酸酯基材与固化物的粘合力为70以上，根据日本工业标准K5400中规定的横切粘合试验测定粘合性。

公开(公告)号：US20150232675A1

公开(公告)日：2015-08-20

申请号：US14704205

申请日：2015-05-05

申请人： Mie YOSHINO ,  Takao HIRAOKA ,  Shizuka KOHZUKI

发明人： Mie YOSHINO ,  Takao HIRAOKA ,  Shizuka KOHZUKI

IPC分类号： C09D11/101 ,  C09D11/30

CPC分类号： C09D11/101 ,  B41J2/01 ,  C09D11/30 ,  C09D11/322 ,  C09D11/324

摘要： An active energy ray-curable ink which contains: polymerizable compounds containing a monofunctional polymerizable monomer a homopolymer of which has Tg of 90° C. or higher, wherein a cured product obtained by forming a coating film having an average thickness of 10 μm on a polycarbonate substrate using the ink, and 15 seconds later, and applying active energy rays having a light quantity of 1,500 mJ/cm2 to the coating film to cure satisfies the following (1) and (2):(1) a stretchability of the cured product represented by the following equation is 2 or greater, when the cured product is stretched by a tensile tester at a tensile speed of 20 mm/min, and temperature of 180° C., and Stretchability=(length after tensile test)/(length before tensile test) (2) adhesion between the substrate and the cured product as measured by a cross-cut test in accordance with JIS K5400 is 70 or greater.

公开(公告)号：US20150009265A1

公开(公告)日：2015-01-08

申请号：US14310452

申请日：2014-06-20

申请人： Shizuka KOHZUKI ,  Takao HIRAOKA

发明人： Shizuka KOHZUKI ,  Takao HIRAOKA

IPC分类号： C09D11/101 ,  C09D11/30

CPC分类号： C09D11/101 ,  C09D11/30 ,  C09D11/38

摘要： To provide a photopolymerizable inkjet ink including: diethylene glycol dimethacrylate; caprolactone-modified dipentaerythritol hexaacrylate; and a photopolymerization initiator represented by the following general formula (1): where X1 is represented by the following general formula (1-1), and X2 is represented by the following general formula (1-2): where R1 to R4 are each independently a C1-C6 alkyl group, and R1 and R2 may be linked to form a ring, and R3 and R4 may be linked to form a ring; Z1 and Z2 is —NR5R6 or OR7; R5 and R6 are each independently a C1-C6 alkyl group, and R5 and R6 may be linked to form a ring; and R7 is a hydrogen atom, a methyl group, or a trimethylsilyl group.

摘要翻译： 提供一种可光聚合喷墨油墨，其包含：二甘醇二甲基丙烯酸酯; 己内酯改性二季戊四醇六丙烯酸酯; 和由以下通式（1）表示的光聚合引发剂：其中X1由以下通式（1-1）表示，X2由以下通式（1-2）表示：其中R1至R4各自为 独立地为C1-C6烷基，R1和R2可以连接形成环，R3和R4可以连接形成环; Z 1和Z 2是-NR 5 R 6或OR 7; R5和R6各自独立地为C1-C6烷基，R5和R6可以连接形成环; 并且R 7是氢原子，甲基或三甲基甲硅烷基。

公开(公告)号：US20170183528A1

公开(公告)日：2017-06-29

申请号：US15385206

申请日：2016-12-20

申请人： Shizuka KOHZUKI ,  Akiko Bannai

发明人： Shizuka KOHZUKI ,  Akiko Bannai

IPC分类号： C09D11/54 ,  C11D3/30 ,  C11D3/24 ,  B41J2/165 ,  C09D11/30 ,  C09D11/322 ,  C09D11/107 ,  C09D11/102 ,  C11D3/43 ,  C11D1/00

CPC分类号： C09D11/54 ,  B41J2/16517 ,  B41J2/16552 ,  C09D11/102 ,  C09D11/107 ,  C09D11/30 ,  C09D11/322 ,  C11D1/004 ,  C11D3/245 ,  C11D3/30 ,  C11D3/43 ,  C11D7/5004 ,  C11D11/0047

摘要： Provided is a cleaning solution used for cleaning an ink containing a resin in an amount of 5 percent by mass or greater, the cleaning solution including a mixture solvent containing water and a solvent, wherein a hydrogen bond term of a Hansen solubility parameter of the mixture solvent is 7.0 (cal/cm3)1/2 or less.

公开(公告)号：US20190270903A1

公开(公告)日：2019-09-05

申请号：US16344279

申请日：2017-10-24

申请人： Shizuka KOHZUKI ,  Akiko BANNAI

发明人： Shizuka KOHZUKI ,  Akiko BANNAI

IPC分类号： C09D11/54 ,  C11D3/43 ,  C11D3/32 ,  C11D3/20 ,  C11D1/82 ,  C11D1/72 ,  C11D11/00 ,  C09D11/322 ,  C09D11/037 ,  C09D11/033 ,  B41J2/165

摘要： Provided is a cleaning solution including: water; a compound represented by general formula (1) below; a glycol ether solves in an amount of greater than 5 g in 100 g of water having a temperature of 25 degrees C., and a proportion of the glycol ether compound is 1 percent by mass or greater but 30 percent by mass or less, and wherein in general formula (1) below, R1 represents an alkyl group containing 1 or more but 4 or less carbon atoms.

公开(公告)号：US20170267879A1

公开(公告)日：2017-09-21

申请号：US15454599

申请日：2017-03-09

申请人： Shizuka KOHZUKI ,  Akiko BANNAI

发明人： Shizuka KOHZUKI ,  Akiko BANNAI

IPC分类号： C09D9/00 ,  C09D9/04 ,  C09D11/54 ,  B41J2/165

CPC分类号： C09D9/005 ,  B41J2/16535 ,  B41J2/16552 ,  B41J2002/1655 ,  B41J2002/16558 ,  C09D9/00 ,  C09D9/04 ,  C09D11/10 ,  C09D11/107 ,  C09D11/322 ,  C09D11/54

摘要： Provided is cleaning solution used for cleaning ink containing water and resin, cleaning solution containing water and solvent. Solvent contains glycol ether compound represented by general formula 1. Ink film obtained by drying the ink has swelling ratio of 20 percent or higher but 150 percent or lower, where swelling ratio is calculated by mathematical formula 1 based on masses of ink film before/after immersed in cleaning solution at 25 degrees C. for 24 hours, R1(OR2)XOR3  General formula 1 In general formula 1, R1 and R3 represent hydrogen atom or alkyl group including from 1 through 4 carbon atoms, R2 represents alkyl group including from 2 through 3 carbon atoms, and X represents integer of from 1 through 4, Swelling ratio (%)=100×[(B−A)/A]  Mathematical formula 1 In mathematical formula 1, A represents mass of ink film before immersed, and B represents mass of ink film after immersed.

公开(公告)号：US20170058135A1

公开(公告)日：2017-03-02

申请号：US15233455

申请日：2016-08-10

申请人： Shizuka KOHZUKI ,  Mie YOSHINO ,  Manabu ARITA ,  Hiroki KOBAYASHI

发明人： Shizuka KOHZUKI ,  Mie YOSHINO ,  Manabu ARITA ,  Hiroki KOBAYASHI

IPC分类号： C09D11/101 ,  B41M5/50 ,  B41J2/01 ,  C09D11/30 ,  C09D11/107

CPC分类号： C09D11/101 ,  B41J2/01 ,  C09D11/30 ,  C09D11/322

摘要： An active energy ray curable composition including a polymerizable compound is provided. When a three-layer cured product of the active energy ray composition is obtained by a specific procedure, the three-layer cured product has (1) a stretchability of 1.1 or more and (2) a glass transition temperature of 50° C. or more. The stretchability is defined by a ratio L2/L1, wherein L1 represents a first length of the cured product before a tensile test and L2 represents a second length of the cured product after the tensile test. The tensile test includes stretching the cured product along with the substrate with a tensile tester at a stretching speed of 20 mm/min and a temperature of 180° C.

摘要翻译： 提供了包含可聚合化合物的活性能量射线固化性组合物。 当通过具体程序获得活性能量射线组合物的三层固化产物时，三层固化产物具有（1）1.1或更高的拉伸性和（2）50℃的玻璃化转变温度或 更多。 拉伸性由比率L2 / L1定义，其中L1表示拉伸试验前的固化物的第一长度，L2表示拉伸试验后的固化物的第二长度。 拉伸试验包括用拉伸试验机以20mm / min的拉伸速度和180℃的温度将固化产物与基材一起拉伸。

公开(公告)号：US20180016455A1

公开(公告)日：2018-01-18

申请号：US15717309

申请日：2017-09-27

申请人： Shizuka KOHZUKI ,  Mie YOSHINO ,  Manabu ARITA ,  Hiroki KOBAYASHI

发明人： Shizuka KOHZUKI ,  Mie YOSHINO ,  Manabu ARITA ,  Hiroki KOBAYASHI

IPC分类号： C09D11/101 ,  B41J2/01 ,  C09D11/30 ,  C09D11/322

摘要： An active energy ray curable composition including a polymerizable compound is provided. When a three-layer cured product of the active energy ray composition is obtained by a specific procedure, the three-layer cured product has (1) a stretchability of 1.1 or more and (2) a glass transition temperature of 50° C. or more. The stretchability is defined by a ratio L2/L1, wherein L1 represents a first length of the cured product before a tensile test and L2 represents a second length of the cured product after the tensile test. The tensile test includes stretching the cured product along with the substrate with a tensile tester at a stretching speed of 20 mm/min and a temperature of 180° C.