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    Secondary battery having a non-aqueous electrolyte
    1.
    发明授权
    Secondary battery having a non-aqueous electrolyte 有权
    具有非水电解质的二次电池

    公开(公告)号：US06682856B1

    公开(公告)日：2004-01-27

    申请号：US09959099

    申请日：2001-10-18

    申请人： Shoichiro Watanabe ,  Kazuya Iwamoto ,  Atsushi Ueda ,  Jun Nunome ,  Hizuru Koshina

    发明人： Shoichiro Watanabe ,  Kazuya Iwamoto ,  Atsushi Ueda ,  Jun Nunome ,  Hizuru Koshina

    IPC分类号： H01M616

    CPC分类号： H01M10/0567 ,  H01M4/131 ,  H01M4/133 ,  H01M10/0525

    摘要： A non-aqueous electrolyte secondary battery which comprises a positive electrode containing a lithium-containing oxide; a negative electrode containing a material capable of absorbing and releasing lithium; and a non-aqueous electrolyte containing a non-aqueous solvent containing at least one non-cyclic ester and which is excellent in storage stability at high temperatures is provided by adding an oxidation resistance improving agent such as triphenylmethane, tetraphehylmethane or the like.

    摘要翻译： 一种非水电解质二次电池，其包含含有含锂氧化物的正极; 含有能够吸收和释放锂的材料的负极; 通过添加抗氧化性改善剂，例如三苯基甲烷，四苯甲烷等，可提供含有含有至少一种非环状酯的非水溶剂且非常高的储存稳定性优异的非水电解质。

    Secondary battery including an electrolytic solution with an organic additive
    2.
    发明授权
    Secondary battery including an electrolytic solution with an organic additive 失效
    二次电池包括具有有机添加剂的电解液

    公开(公告)号：US06303250B1

    公开(公告)日：2001-10-16

    申请号：US09289468

    申请日：1999-04-09

    申请人： Shoichiro Watanabe ,  Kazuya Iwamoto ,  Atsushi Ueda ,  Jun Nunome ,  Hizuru Koshina

    发明人： Shoichiro Watanabe ,  Kazuya Iwamoto ,  Atsushi Ueda ,  Jun Nunome ,  Hizuru Koshina

    IPC分类号： H01M624

    CPC分类号： H01M10/0567 ,  H01M4/131 ,  H01M4/133 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M10/0525 ,  H01M10/0569 ,  H01M10/0587 ,  H01M2300/004 ,  Y02T10/7011

    摘要： A battery excellent in high temperature storage characteristic is presented. It comprises a positive electrode containing a positive electrode active material, a negative electrode containing a negative electrode material, a nonaqueous solvent, and an electrolytic solution containing at least one of organic compounds expressed in formula 1 and formula 2. The positive electrode active material has an oxide compound containing a lithium atom, and the negative electrode material has a material capable of storing and releasing a lithium ion. Formula 1 where R1, R2, R3, R4 are individually at least one selected from the group consisting of H, aryl group, and aryl group having a functional group containing a substituent having an electron attracting property, and the number of H is three or less. Formula 2

    摘要翻译： 介绍了高温储存特性优良的电池。 它包括含有正极活性物质的正极，含有负极材料的负极，非水溶剂和含有式1和式2表示的至少一种有机化合物的电解液。正极活性物质具有 包含锂原子的氧化物，负极材料具有能够储存和释放锂离子的材料。其中R1，R2，R3，R4分别是选自H，芳基， 具有含有具有吸电子性的取代基的官能团的芳基，H的数量为3以下。式2

    Polymeric solid electrolyte and lithium secondary cell using the same
    5.
    发明授权
    Polymeric solid electrolyte and lithium secondary cell using the same 失效
    聚合物固体电解质和使用其的锂二次电池

    公开(公告)号：US06806004B1

    公开(公告)日：2004-10-19

    申请号：US09807124

    申请日：2001-07-31

    申请人： Kazuya Iwamoto ,  Takafumi Oura ,  Shinji Nakanishi ,  Atsushi Ueda ,  Hizuru Koshina

    发明人： Kazuya Iwamoto ,  Takafumi Oura ,  Shinji Nakanishi ,  Atsushi Ueda ,  Hizuru Koshina

    IPC分类号： H01M1040

    CPC分类号： H01M10/052 ,  C08F230/08 ,  H01B1/122 ,  H01M4/62 ,  H01M4/622 ,  H01M10/0565 ,  H01M2300/0082 ,  Y02T10/7011

    摘要： A polymeric solid electrolyte capable of conducting lithium ions which contains silylamide bonds in its polymer skeleton structure, for example, which is obtained by a method comprising subjecting a mixture of lithium silylamide and an organic compound having at least one carbon—carbon double bond to a polymerization in a dry atmosphere; and a lithium secondary cell using the polymeric solid electrolyte. The polymeric solid electrolyte is a “dry” polymeric solid electrolyte which contains counter ions forming lithium salts with lithium ions in its polymer skeleton structure and thus has a single ion electron conducting system wherein lithium ions alone are mobile ions, and hence has excellent conductivity, and further is easy to produce. The polymeric solid electrolyte can therefore be used for producing a novel lithium secondary cell which is an alternative for conventional lithium cells using an organic solvent and is safe and excellent in the capability of corresponding to a variety of shapes and has a high cell voltage.

    摘要翻译： 能够在其聚合物骨架结构中导电含有甲硅烷基酰胺键的锂离子的聚合物固体电解质，例如通过包括将具有至少一个碳 - 碳双键的锂甲硅烷基酰胺和有机化合物的混合物 在干燥气氛中聚合; 和使用聚合物固体电解质的锂二次电池。 聚合物固体电解质是一种“干”聚合物固体电解质，其包含在其聚合物骨架结构中与锂离子形成锂盐的反离子，因此具有单独的离子电子传导系统，其中单独的锂离子是移动离子，因此具有优异的导电性， 并且进一步易于生产。 因此，聚合物固体电解质可用于制造新的锂二次电池，其是使用有机溶剂的常规锂电池的替代方案，并且对于各种形状的能力安全且优异且具有高的电池电压。

    Non-aqueous electrochemical device
    8.
    发明授权
    Non-aqueous electrochemical device 失效
    非水电化学装置

    公开(公告)号：US06630272B1

    公开(公告)日：2003-10-07

    申请号：US09856242

    申请日：2001-05-18

    申请人： Kazuya Iwamoto ,  Takafumi Oura ,  Shinji Nakanishi ,  Atsushi Ueda ,  Hizuru Koshina

    发明人： Kazuya Iwamoto ,  Takafumi Oura ,  Shinji Nakanishi ,  Atsushi Ueda ,  Hizuru Koshina

    IPC分类号： H01M1040

    CPC分类号： H01M10/0567 ,  H01G11/58 ,  H01M6/168 ,  H01M10/052 ,  H01M10/054 ,  Y02E60/13

    摘要： The present invention relates to an electrolyte for non-aqueous electrochemical device containing at least one of 6-substituted-1,3,5-triazine-2,4-dithiol and derivatives thereof as an additive and a non-aqueous electrochemical device, particularly a lithium secondary battery by the use thereof. The additive of the present invention forms a stable and low resistance film on the positive electrode, inhibiting characteristics of the electrochemical device from deteriorating on account of gas generated due to the decomposition of electrolyte.

    摘要翻译： 本发明涉及含有6-取代-1,3,5-三嗪-2,4-二硫醇及其衍生物作为添加剂和非水电化学装置中的至少一种的非水电化学装置的电解质，特别是 锂二次电池。 本发明的添加剂在正极上形成稳定且低电阻的膜，由于电解质分解而产生的气体，电化学装置的特性受到抑制。

    Non-Aqueous electrolyte secondary battery comprising composite particles
    9.
    发明授权
    Non-Aqueous electrolyte secondary battery comprising composite particles 失效
    包含复合颗粒的非水电解质二次电池

    公开(公告)号：US06821675B1

    公开(公告)日：2004-11-23

    申请号：US09601234

    申请日：2000-10-30

    申请人： Kenichi Morigaki ,  Kazuya Iwamoto ,  Hizuru Koshina ,  Harunari Shimamura ,  Yoshiaki Nitta

    发明人： Kenichi Morigaki ,  Kazuya Iwamoto ,  Hizuru Koshina ,  Harunari Shimamura ,  Yoshiaki Nitta

    IPC分类号： H01M458

    CPC分类号： H01M4/366 ,  H01M2/0275 ,  H01M4/38 ,  H01M4/386 ,  H01M4/387 ,  H01M6/181 ,  H01M10/052 ,  H01M10/0562 ,  H01M10/0565 ,  H01M2300/0085

    摘要： A negative electrode of a non-aqueous electrolyte secondary battery contains, as main a component, composite particles constructed in such a manner that at least part of the surface of nuclear particles comprising at least one of tin, silicon and zinc as a constituent element, is coated with a solid solution or an inter-metallic compound composed of elements included in the nuclear particle and at least one element, exclusive of the element included in said nuclear particle, selected from a group of elements in a Periodic Table, comprising group 2 elements, transition elements, group 12 elements, group 13 elements and group 14 elements exclusive of carbon. The batteries of the present invention include non-aqueous electrolytic solution and solid electrolytes comprising polymer gel electrolytes. The construction of the present invention provides a non-aqueous electrolytic secondary battery with which a possibility of the generation of gas is extremely low when stored at high temperatures. It also provides a battery having higher capacity, and superior cycle properties, high-rate charge/discharge properties.

    摘要翻译： 作为非水电解质二次电池的负极，以作为构成要素的锡，硅，锌中的至少一种的核粒子的至少一部分表面构成的复合粒子作为主要成分， 涂覆有固体溶液或由核颗粒中包含的元素组成的金属间化合物和至少一种元素，不包括所述核颗粒中包含的元素，其选自周期表中的元素组，其包含组2 元素，过渡元素，第12族元素，13族元素和不含碳的第14族元素。 本发明的电池包括非水电解液和包含聚合物凝胶电解质的固体电解质。 本发明的构造提供了一种非水电解二次电池，其在高温下储存时具有产生气体的可能性极低。 它还提供具有更高容量和优异的循环性能，高速率充电/放电性能的电池。

    Non-aqueous electrolyte secondary battery comprising composite particles
    10.
    发明授权
    Non-aqueous electrolyte secondary battery comprising composite particles 失效
    包含复合颗粒的非水电解质二次电池

    公开(公告)号：US06824920B1

    公开(公告)日：2004-11-30

    申请号：US09601421

    申请日：2000-09-28

    申请人： Kazuya Iwamoto ,  Hizuru Koshina ,  Harunari Shimamura ,  Yoshiaki Nitta

    发明人： Kazuya Iwamoto ,  Hizuru Koshina ,  Harunari Shimamura ,  Yoshiaki Nitta

    IPC分类号： H01M438

    CPC分类号： H01M4/38 ,  H01M4/366 ,  H01M4/386 ,  H01M4/387 ,  H01M4/42 ,  H01M10/0525 ,  H01M10/0568 ,  H01M10/0569

    摘要： The present invention relates to a non-aqueous electrolyte secondary battery. The negative electrode of the present invention is characterized by its composite particles constructed in such a manner that at least part of the surrounding surface of nuclear particles containing at least one of tin, silicon and zinc as a constituent element, is coated with a solid solution or an intermetallic compound, which are composed of the element contained in the nuclear particles, and at least one other element except the elements contained in the nuclear particles selected from a group comprising group 2 elements, transition elements, group 12 elements, group 13 elements and group 14 elements except carbon of the Periodic Table. The electrolyte uses anion lithium salts of organic acid dissolved in organic solvent with high oxidation resistant characteristics. By adopting the above construction, a battery which generates only a small amount of gas during a high temperature storing can be obtained. Furthermore, the batteries enjoy high energy density and a lower reduction rate of discharge capacity when used repeatedly as well as high charge/discharge properties.

    摘要翻译： 本发明涉及一种非水电解质二次电池。 本发明的负极的特征在于，其复合颗粒的构成是将含有锡，硅和锌中的至少一种作为构成元素的至少一部分核粒子的周围表面涂布固溶体 或由包含在核粒子中的元素组成的金属间化合物，以及除了选自包含第2族元素，过渡元素，第12族元素，第13族元素的核粒子中的元素以外的至少一种其它元素 和除了周期表碳以外的第14组元素。 电解质使用溶解于有机溶剂中的有机酸的阴离子锂盐，具有高抗氧化特性。 通过采用上述结构，可以获得在高温保存期间仅产生少量气体的电池。 此外，当重复使用电池以及高充电/放电性能时，电池具有高的能量密度和较低的放电容量的减小率。