公开(公告)号：US06821675B1

公开(公告)日：2004-11-23

申请号：US09601234

申请日：2000-10-30

申请人： Kenichi Morigaki ,  Kazuya Iwamoto ,  Hizuru Koshina ,  Harunari Shimamura ,  Yoshiaki Nitta

发明人： Kenichi Morigaki ,  Kazuya Iwamoto ,  Hizuru Koshina ,  Harunari Shimamura ,  Yoshiaki Nitta

IPC分类号： H01M458

CPC分类号： H01M4/366 ,  H01M2/0275 ,  H01M4/38 ,  H01M4/386 ,  H01M4/387 ,  H01M6/181 ,  H01M10/052 ,  H01M10/0562 ,  H01M10/0565 ,  H01M2300/0085

摘要： A negative electrode of a non-aqueous electrolyte secondary battery contains, as main a component, composite particles constructed in such a manner that at least part of the surface of nuclear particles comprising at least one of tin, silicon and zinc as a constituent element, is coated with a solid solution or an inter-metallic compound composed of elements included in the nuclear particle and at least one element, exclusive of the element included in said nuclear particle, selected from a group of elements in a Periodic Table, comprising group 2 elements, transition elements, group 12 elements, group 13 elements and group 14 elements exclusive of carbon. The batteries of the present invention include non-aqueous electrolytic solution and solid electrolytes comprising polymer gel electrolytes. The construction of the present invention provides a non-aqueous electrolytic secondary battery with which a possibility of the generation of gas is extremely low when stored at high temperatures. It also provides a battery having higher capacity, and superior cycle properties, high-rate charge/discharge properties.

摘要翻译： 作为非水电解质二次电池的负极，以作为构成要素的锡，硅，锌中的至少一种的核粒子的至少一部分表面构成的复合粒子作为主要成分， 涂覆有固体溶液或由核颗粒中包含的元素组成的金属间化合物和至少一种元素，不包括所述核颗粒中包含的元素，其选自周期表中的元素组，其包含组2 元素，过渡元素，第12族元素，13族元素和不含碳的第14族元素。 本发明的电池包括非水电解液和包含聚合物凝胶电解质的固体电解质。 本发明的构造提供了一种非水电解二次电池，其在高温下储存时具有产生气体的可能性极低。 它还提供具有更高容量和优异的循环性能，高速率充电/放电性能的电池。

公开(公告)号：US20110027652A1

公开(公告)日：2011-02-03

申请号：US12922977

申请日：2009-03-19

申请人： Kenichi Morigaki

发明人： Kenichi Morigaki

IPC分类号： H01M4/505 ,  H01M4/40

CPC分类号： H01M4/505 ,  C01G45/02 ,  C01P2002/72 ,  C01P2002/74 ,  C01P2006/12 ,  C01P2006/40 ,  C01P2006/80 ,  H01M2/022 ,  H01M4/06 ,  H01M4/131 ,  H01M4/382 ,  H01M4/40 ,  H01M4/502 ,  H01M6/16 ,  H01M10/052 ,  H01M2004/021 ,  Y02E60/122

摘要： A lithium battery (1) including a positive electrode (10) containing low-crystallinity manganese dioxide having a specific surface area of 8 to 28 m2/g as a positive electrode active material, a negative electrode (11) containing metallic lithium or a lithium alloy as a negative electrode active material, and an organic electrolyte is provided. The lithium battery (1), due to said low-crystallinity manganese dioxide contained therein, has excellent storage characteristics at high temperatures of 100° C. or higher, large-current discharge characteristics, large-current pulse discharge characteristics, low-temperature discharge characteristics, and like characteristics, and in addition, is cost advantageous.

摘要翻译： 一种锂电池（1），包括含有比表面积为8〜28m 2 / g的低结晶性二氧化锰的正极（10）作为正极活性物质，负极（11）含有金属锂或锂 合金作为负极活性物质，提供有机电解质。 锂电池（1）由于其中包含的所述低结晶度二氧化锰，在100℃或更高的高温下具有优异的储存特性，大电流放电特性，大电流脉冲放电特性，低温放电 特性等特征，另外成本有利。

公开(公告)号：US06689513B1

公开(公告)日：2004-02-10

申请号：US09622721

申请日：2001-03-05

申请人： Kenichi Morigaki ,  Masaya Okochi ,  Shinji Mino

发明人： Kenichi Morigaki ,  Masaya Okochi ,  Shinji Mino

IPC分类号： H01M1040

CPC分类号： H01M4/621 ,  H01M2/1673 ,  H01M4/13 ,  H01M6/164 ,  H01M10/0525 ,  H01M10/0565 ,  H01M10/0567 ,  H01M10/0569 ,  H01M2300/0037

摘要： A lithium secondary battery is disclosed. The battery comprises a positive electrode, a negative electrode, an electrolyte solution comprising an electrolyte, a separator, and a ligand. The ligand is oriented at the interface of the electrolyte solution and the positive electrode and at the interface of the electrolyte solution and the negative electrode. The ligand has a cyclic structure having a pore that has a diameter of about 1.7 angstroms or more and coordinates lithium ions more strongly than either the solvent or the electrolyte. Typical ligands are coronands (crown ethers), podanocoronands (lariat ethers), cryptands, and spherands. The battery maintains high reliability and energy density, even after storage at high temperature.

摘要翻译： 公开了一种锂二次电池。 电池包括正极，负极，包含电解质，隔膜和配体的电解质溶液。 配位体在电解质溶液与正极的界面和电解质溶液与负极的界面处取向。 配体具有直径约为1.7埃的孔的环状结构，并且比溶剂或电解质比锂离子更牢固。 典型的配体是冠状物（冠醚），podanocoronands（lariat ether），穴状物和小球。 即使在高温下储存后，电池仍保持高可靠性和能量密度。

公开(公告)号：US06670075B2

公开(公告)日：2003-12-30

申请号：US10019932

申请日：2002-01-07

申请人： Kenichi Morigaki ,  Kazuhiro Watanabe ,  Norishige Nanai ,  Masaya Ugaji

发明人： Kenichi Morigaki ,  Kazuhiro Watanabe ,  Norishige Nanai ,  Masaya Ugaji

IPC分类号： H01M462

CPC分类号： H01M10/0565 ,  H01M2/0207 ,  H01M2/1653 ,  H01M4/622 ,  H01M10/0525 ,  H01M2010/4292 ,  H01M2300/0082

摘要： In a lithium polymer secondary battery comprising: a positive electrode comprising a lithium-containing complex oxide; a negative electrode comprising a material capable of intercalating and deintercalating lithium ions; and a separator interposed between the positive electrode and the negative electrode, the weight Wp of the polymer material constituting the polymer electrolyte contained in the positive electrode, the weight Wn of the polymer material constituting the polymer electrolyte contained in the negative electrode, and the weight Ws of the polymer material constituting the polymer electrolyte contained in the separator satisfy all of the following: Ws

摘要翻译： 一种锂聚合物二次电池，包括：包含含锂复合氧化物的正极; 包含能够嵌入和脱嵌锂离子的材料的负极; 插入在正极和负极之间的隔膜，构成正极中所含的高分子电解质的高分子电解质的重量Wp，构成负极中的聚合物电解质的高分子电解质的重量Wn，重量 构成隔膜中所含聚合物电解质的聚合物材料的W满足以下所有条件：Ws

公开(公告)号：US5273843A

公开(公告)日：1993-12-28

申请号：US611116

申请日：1990-11-09

申请人： Hiroshi Fukuda ,  Shigeo Kobayashi ,  Kenichi Morigaki ,  Syuichi Nishino ,  Tomokazu Mitamura

发明人： Hiroshi Fukuda ,  Shigeo Kobayashi ,  Kenichi Morigaki ,  Syuichi Nishino ,  Tomokazu Mitamura

IPC分类号： H01M2/02 ,  H01M2/16 ,  H01M6/08 ,  H01M6/14 ,  H01M6/50 ,  H01M10/42 ,  H01M2/14

CPC分类号： H01M2/1613 ,  H01M6/14 ,  H01M10/4235 ,  H01M2/022 ,  H01M2/1653 ,  H01M2200/00 ,  H01M2200/10 ,  H01M2300/002 ,  H01M6/08

摘要： The present invention relates to a separator and spacer for use in non-aqueous inorganic electrolyte cells using oxyhalides as both a solvent and cathode active material, and an alkali metal as anode active material. There is provided a non-aqueous inorganic electrolyte cell which has a good discharge performance, preservability, and a safety to resist the charging at 5 V caused due to erroneous operations and accidents, by specifying a content of glass involved in the separator made of mainly glass fibers, specifying the type of synthetic resin of other components than glass fibers, or by specifying an oxyhalide absorbance of materials from which the separator and the spacer are produced.

公开(公告)号：US08668999B2

公开(公告)日：2014-03-11

申请号：US13143602

申请日：2010-11-10

申请人： Jun Nunome ,  Fumio Kato ,  Kenichi Morigaki ,  Shinichiro Tahara

发明人： Jun Nunome ,  Fumio Kato ,  Kenichi Morigaki ,  Shinichiro Tahara

IPC分类号： H01M6/10 ,  H01M4/00

CPC分类号： H01M6/16 ,  H01M2/1626 ,  H01M4/06 ,  H01M4/38 ,  H01M4/382 ,  H01M4/581 ,  H01M4/5815 ,  H01M6/14 ,  H01M2006/5094

摘要： A lithium primary battery 10 includes an electrode group in which a positive electrode 1 having iron disulfide as a positive electrode active material and a negative electrode 2 having lithium as a negative electrode active material are wound, with a separator 3 interposed between the positive electrode 1 and the negative electrode, wherein a density of the iron disulfide in a positive electrode mixture containing the positive electrode active material is in a range of 2.2-2.9 g/cm3, and the separator 3 is made of a non-woven fabric whose tensile strength is in a range of 6-30 N/mm2.

摘要翻译： 锂一次电池10包括其中缠绕有具有二硫化铁作为正极活性材料的正极1和具有锂作为负极活性材料的负极2的电极组，隔板3夹在正电极1 和负极，其中含有正极活性物质的正极混合物中的二硫化铁的密度在2.2〜2.9g / cm 3的范围内，隔板3由抗拉强度 在6-30N / mm2的范围内。

公开(公告)号：US20120288885A1

公开(公告)日：2012-11-15

申请号：US13393706

申请日：2010-08-27

申请人： Hiromasa Imaishi ,  Kenichi Morigaki ,  Yoshiro Tatsu ,  Gang Chang

发明人： Hiromasa Imaishi ,  Kenichi Morigaki ,  Yoshiro Tatsu ,  Gang Chang

IPC分类号： C12Q1/26 ,  C12N11/10

CPC分类号： C12Q1/26 ,  G01N2333/90209

摘要： The present invention relates to a method, and a kit, for measuring the enzymatic activity of cytochrome P450 comprehensively and with high efficiency and accuracy, wherein an oxygen sensing layer and a cytochrome P450-supporting layer are vertically integrated on a chip, and cytochrome P450 is supported in a hydrophilic polymer matrix in the cytochrome P450-supporting layer, the cytochrome P450 generates NADPH by being irradiated with light in the presence of at least one caged compound selected from the group consisting of caged-NADP and caged-G6P, an enzyme utilizing NADPH as a coenzyme (i.e., cytochrome P450 reductase) and a substrate thereof to supply NADP and/or G6P from the caged compound to generate NADPH to start the reaction between the enzyme and a substrate.

摘要翻译： 本发明涉及一种全面，高效，准确地测定细胞色素P450的酶活性的方法和试剂盒，其中氧感应层和细胞色素P450支持层垂直整合在芯片上，细胞色素P450 在细胞色素P450支持层中的亲水性聚合物基质中负载，细胞色素P450在存在至少一种选自笼养NADP和笼状-G6P的笼状化合物的存在下，用光照射产生NADPH，酶 利用NADPH作为辅酶（即细胞色素P450还原酶）及其底物从笼养化合物中提供NADP和/或G6P以产生NADPH以开始酶和底物之间的反应。

公开(公告)号：US20100009268A1

公开(公告)日：2010-01-14

申请号：US12444542

申请日：2006-10-18

申请人： Tohru Hitomi ,  Susumu Yamanaka ,  Shinji Fujii ,  Kenichi Takata ,  Kenichi Morigaki

发明人： Tohru Hitomi ,  Susumu Yamanaka ,  Shinji Fujii ,  Kenichi Takata ,  Kenichi Morigaki

IPC分类号： H01M6/14 ,  H01M4/58 ,  H01M4/48

CPC分类号： H01M4/587 ,  H01M4/06 ,  H01M4/364 ,  H01M4/405 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M4/5835 ,  H01M6/164 ,  H01M6/166

摘要： The present invention intends to provide a lithium primary battery excellent in large-current discharge characteristics in a low temperature environment without sacrificing the high-temperature storage characteristics. The present invention relates to a lithium primary battery including a positive electrode including a fluoride as a positive electrode active material, a negative electrode including metallic lithium or a lithium alloy as a negative electrode active material, a separator interposed between the positive electrode and the negative electrode, and an electrolyte. The positive electrode further includes a metal oxide being capable of absorbing and desorbing lithium ions, having a spinel structure, and having a discharge potential versus lithium lower than that of the fluoride.

摘要翻译： 本发明旨在提供在低温环境下具有优异的大电流放电特性的锂一次电池，而不牺牲高温储存特性。 本发明涉及一种锂一次电池，其包括正极，其包括作为正极活性物质的氟化物，包含金属锂或锂合金的负极作为负极活性物质，插入在正极和负极之间的隔膜 电极和电解质。 该正极还包括能够吸收和解吸锂离子的金属氧化物，其具有尖晶石结构，并且具有与锂的放电电位相对于低于氟化物的放电电位。

公开(公告)号：US5597659A

公开(公告)日：1997-01-28

申请号：US319738

申请日：1994-10-07

申请人： Kenichi Morigaki ,  Noriko Kabuto ,  Kazunori Haraguchi

发明人： Kenichi Morigaki ,  Noriko Kabuto ,  Kazunori Haraguchi

IPC分类号： H01M2/16 ,  H01M10/052 ,  H01M10/0565 ,  H07M10/40

CPC分类号： H01M10/052 ,  H01M10/0565 ,  H01M2/1653 ,  H01M2300/0085 ,  Y02P70/54 ,  Y10T29/49115

摘要： An organic electrolyte lithium secondary battery wherein lithium is an active material. The battery comprises a negative electrode made of metallic lithium or a lithium alloy and a separator made of a microporous polyolefin separator matrix whose pores are filled with an ionic conductive gel electrolyte. The separator is in the form of a sheet with at least one face contacting the negative electrode having a gel electrolyte layer. The gel electrolyte is formed by ultraviolet irradiation of a solution having a major component being a mixture of an oligomer and a monomer added to an organic electrolyte. Using the separator in an organic electrolyte lithium secondary battery internal short circuiting of the battery due to dendridic lithium growing on a negative electrode during the charging cycle can be prevented and a longer cycle life achieved.

摘要翻译： 一种有机电解质锂二次电池，其中锂是活性材料。 电池包括由金属锂或锂合金制成的负极和由微孔聚烯烃隔板基体制成的隔板，其孔中填充有离子导电凝胶电解质。 分离器是具有与具有凝胶电解质层的负极接触的至少一个面的片材的形式。 凝胶电解质是通过紫外线照射主要成分是加成有机电解质的低聚物和单体的混合物的溶液形成的。 在有机电解质中使用分离器锂二次电池可以防止由于在充电循环期间在负极上生长的树枝状锂而导致的电池内部短路，并且实现更长的循环寿命。

公开(公告)号：US20120316815A1

公开(公告)日：2012-12-13

申请号：US13579221

申请日：2011-11-04

申请人： Kenichi Morigaki

发明人： Kenichi Morigaki

IPC分类号： G01R31/36 ,  G06F19/00 ,  G01N27/416

CPC分类号： G01R31/392 ,  G01R31/389

摘要： Disclosed is a method for evaluating deterioration of a lithium ion secondary battery, in which an impedance spectrum of a lithium ion secondary battery is measured using alternating current of a predetermined frequency range. In a diagram including an arc-like portion obtained when the impedance spectrum is represented on a complex plane defined by a resistive component axis and a capacitive component axis, the coordinates of a peak of the arc-like portion are determined. The deterioration state of the lithium ion secondary battery is evaluated on the basis of the determined coordinates of the peak.

摘要翻译： 公开了一种用于评估锂离子二次电池的劣化的方法，其中使用预定频率范围的交流电测量锂离子二次电池的阻抗谱。 在包含在由电阻分量轴和电容分量轴限定的复平面上表示阻抗谱时获得的弧状部分的图表中，确定了弧状部分的峰值坐标。 基于确定的峰的坐标来评价锂离子二次电池的劣化状态。