摘要:
The present invention provides a pressure-sensitive adhesive sheet minimizing the corrosion of metals not in contact with the PSA sheet. PSA sheet 54 has a pressure-sensitive adhesive layer formed from an aqueous pressure-sensitive adhesive composition comprising an adhesive ingredient and a preservative in an aqueous medium. In a metal corrosion test carried out by placing 1 g of the PSA sheet 54 and a silver plate 56 so as not to be in mutual contact in a 50 mL vessel 52 and then closing and holding the vessel 52 at 85° C. for one week, the PSA sheet 54 does not corrode the silver plate 56.
摘要:
There is provided a pressure-sensitive adhesive (PSA) sheet with the property of corroding a metal not in contact therewith suppressed. This PSA sheet is provided with a PSA layer formed from a water-dispersed PSA composition. The PSA composition contains a water-dispersed acrylic polymer synthesized using a sulfur-containing chain transfer agent. Moreover, in a gas generation test whereby the PSA sheet is heated at 85° C. for one hour, the emission of sulfur-containing gas is 0.043 μg or less per 1 cm2 surface area of the sheet, when converted to SO42−.
摘要:
The present invention provides a pressure-sensitive adhesive (PSA) sheet which is formed using a non-toluene solvent-based acrylic PSA composition, and which minimizes corrosion of metals not in contact with the PSA sheet. PSA sheet 1 has PSA layers 21, 22 formed from a solvent-based PSA composition. The PSA composition includes, within an organic solvent that is substantially free of toluene substances, an acrylic polymer synthesized in presence of a sulfur-containing chain transfer agent. Moreover, in a gas generation test whereby PSA sheet 1 is heated at 85° C. for one hour, the emission of sulfur-containing gas is 0.043 μg or less per 1 cm2 surface area of PSA sheet 1, when converted to SO42−.
摘要:
A double-sided pressure-sensitive adhesive (PSA) sheet having a plastic film as a substrate is provided, with the property of corroding a metal not in contact therewith being suppressed. This PSA sheet has a PSA layer that uses a water-dispersed acrylic PSA composition on each side of the plastic film substrate. The PSA composition contains a water-dispersed acrylic polymer synthesized using a sulfur-containing chain transfer agent. The PSA sheet has the emission of sulfur-containing gas of 0.043 μg or less per 1 cm2 surface area of the PSA sheet, when converted to SO42−, in a gas generation test under which the PSA sheet is heated at 85° C. for one hour.
摘要:
An adhesive sheet is provided in which properties that cause corrosion of a non-contacting metal are inhibited. The adhesive sheet is provided with a pressure-sensitive adhesive layer formed from an aqueous dispersion type adhesive composition. The pressure-sensitive adhesive composition contains an aqueous dispersion type acrylic polymer synthesized using a chain transfer agent that does not have sulfur as a composite element thereof. The amount of sulfur-containing gas (as SO42−) released from the pressure-sensitive adhesive sheet in the case of heating for 1 hour at 85° C. is 0.043 μg/1 cm2 or less, adhesive strength on an ABS sheet is 10 N/20 mm or more, and holding time as determined in an 80° C. cohesive strength test is 1 hour or more.
摘要翻译:提供了一种粘合片,其中抑制了导致非接触金属腐蚀的性质。 粘合片设置有由水分散型粘合剂组合物形成的压敏粘合剂层。 压敏粘合剂组合物含有使用不具有硫作为其复合元素的链转移剂合成的水分散型丙烯酸类聚合物。 在85℃下加热1小时的情况下,从压敏粘合片释放的含硫气体(SO42-)为0.043μg/ lcm2以下,ABS板上的粘合强度为10 N / 20mm以上,并且在80℃的内聚强度试验中测定的保持时间为1小时以上。
摘要:
The present invention provides a water-dispersed acrylic PSA composition suitable for forming a PSA sheet. The PSA composition contains 100 parts by weight of an acrylic copolymer with a Tg of −70° C. to −50° C. obtained by polymerization of a monomer starting material containing 60 wt % or more of an alkyl (meth)acrylate with a C8-12 alkyl group and 5 wt % or less of a radical polymerizable monomer with a carboxyl group. When an adhesive sheet is formed therefrom, it exhibits an average SUS adhesive strength of 11 N/20 mm or greater, PP adhesive strength of 8.5 N/20 mm or greater, 80° C. hold time of 1 hour or longer, and gap height of 10 mm or less in a curved surface adhesion test.
摘要:
A double-sided pressure-sensitive adhesive (PSA) sheet 11 has, on each side of a plastic film substrate 1, a PSA layer 3 provided through an undercoat layer 2 containing a compound having an oxazoline group. The PSA layer 3 is formed from a water-dispersed PSA composition. This PSA composition contains an acrylic polymer synthesized by emulsion polymerization of a monomer raw material containing an alkyl(meth)acrylate and a carboxyl group-containing monomer, and a water-dispersed tackifier at a mass ratio of 100:5 to 100 based on solid content. The toluene emission when this PSA sheet is kept at 80° C. for 30 minutes is 20 μg or less per gram of the sheet.
摘要:
The present invention provides a water-dispersed acrylic PSA composition suitable for forming a PSA sheet. The PSA composition contains 0.5 to 15 parts by weight of an acrylic copolymer (polymer H) with a Tg of 30° C. to 120° C. in relation to 100 parts by weight of an acrylic copolymer (polymer L) with a Tg of −70° C. to −50° C. The polymer L is obtained by polymerization of a monomer starting material comprising 60 wt % or more of an alkyl (meth)acrylate with a C8-C12 alkyl group; and 0.5 to 10 wt % of a radical polymerizable monomer with a carboxyl group.
摘要:
Provided is a double-sided pressure-sensitive adhesive (PSA) sheet that can be appropriately used in parts to be recycled. A PSA sheet has a hemp-containing nonwoven fabric substrate having a bulk density of 0.35 to 0.60 g/cm3; and PSA layers respectively provided on both faces of the substrate. The PSA layers are formed from an aqueous dispersion containing a polymer obtained through emulsion polymerization of a monomer starting material that contains an alkyl(meth)acrylate having a C4-12 alkyl group, in a proportion not less than 60 wt %. The SUS adhesive strength is not less than 11 N/20 mm, and the PP adhesive strength is not less than 8.5 N/20 mm.
摘要:
A water-dispersed pressure-sensitive adhesive (PSA) composition having a low perishability is provided. This PSA composition includes as a base polymer an acrylic polymer and, when held in a 30° C. atmosphere for 5 days, the number of viable microorganisms present per milliliter of the composition following such storage is less than 106 cells. Such a composition may be produced by employing viable cell-free water containing essentially no viable microorganisms as, of the water used in the course of production, at least the water used in a step subsequent to a final step in which the composition is held continuously at a temperature of at least 60° C. for at least 30 minutes.