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    QUINOLINIUM ION DERIVATIVES, PROCESS FOR THE PRODUCTION OF THE DERIVATIVES, PRODUCTS MADE BY USING THE SAME, AND REDUCTION AND OXIDATION METHODS WITH THE DERIVATIVES
    1.
    发明申请
    QUINOLINIUM ION DERIVATIVES, PROCESS FOR THE PRODUCTION OF THE DERIVATIVES, PRODUCTS MADE BY USING THE SAME, AND REDUCTION AND OXIDATION METHODS WITH THE DERIVATIVES 失效
    喹啉衍生物，生产衍生物的方法，使用该衍生物的产品，以及与衍生物的还原和氧化方法

    公开(公告)号：US20100004454A1

    公开(公告)日：2010-01-07

    申请号：US12440538

    申请日：2007-03-05

    申请人： Shunichi Fukuzumi ,  Hiroaki Kotani ,  Kei Ohkubo

    发明人： Shunichi Fukuzumi ,  Hiroaki Kotani ,  Kei Ohkubo

    IPC分类号： C07D215/04 ,  C07D213/22 ,  C07D213/56

    CPC分类号： C09B15/00 ,  C07D215/10 ,  C09B57/00 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1011 ,  C09K2211/1029

    摘要： An electron donor-acceptor dyad is provided that can provide a charge-separated state with longevity and not only high oxidizing power but also high reducing power. A compound of the present invention is a quinolinium ion derivative represented by the following formula (I), a stereoisomer or tautomer thereof, or a salt thereof: where R1 is a hydrogen atom or an alkyl group, and Ar1 to Ar3 each are a hydrogen atom or an electron-donating group. The compound of the present invention has the above-mentioned structure and therefore can provide a charge-separated state with longevity and not only high oxidizing power but also high reducing power and can be used for various products such as photocatalysts, photosensitizers, dyes, oxidants, reductants, dye-sensitized solar cells, and organic EL devices.

    摘要翻译： 提供电子给体 - 受体二元体，其可以提供长寿命的电荷分离状态，不仅具有高氧化能力，而且还具有高还原能力。 本发明化合物是下式（I）表示的喹啉鎓离子衍生物，其立体异构体或互变异构体或其盐：其中，R 1为氢原子或烷基，Ar 1〜Ar 3为氢 原子或给电子基团。 本发明的化合物具有上述结构，因此可以提供具有寿命的电荷分离状态，不仅具有高的氧化能力，而且还具有高的还原能力，并且可用于各种产物如光催化剂，光敏剂，染料，氧化剂 ，还原剂，染料敏化太阳能电池和有机EL器件。

    Quinolinium ion derivatives, process for the production of the derivatives, products made by using the same, and reduction and oxidation methods with the derivatives
    2.
    发明授权
    Quinolinium ion derivatives, process for the production of the derivatives, products made by using the same, and reduction and oxidation methods with the derivatives 失效
    喹啉离子衍生物，制备衍生物的方法，使用该衍生物的产物，以及衍生物的还原和氧化方法

    公开(公告)号：US07977486B2

    公开(公告)日：2011-07-12

    申请号：US12440538

    申请日：2007-03-05

    申请人： Shunichi Fukuzumi ,  Hiroaki Kotani ,  Kei Ohkubo

    发明人： Shunichi Fukuzumi ,  Hiroaki Kotani ,  Kei Ohkubo

    IPC分类号： C07D215/04 ,  C07D213/22 ,  C07D213/56

    CPC分类号： C09B15/00 ,  C07D215/10 ,  C09B57/00 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1011 ,  C09K2211/1029

    摘要： An electron donor-acceptor dyad is provided that can provide a charge-separated state with longevity and not only high oxidizing power but also high reducing power. A compound of the present invention is a quinolinium ion derivative represented by the following formula (I), a stereoisomer or tautomer thereof, or a salt thereof: where R1 is a hydrogen atom or an alkyl group, and Ar1 to Ar3 each are a hydrogen atom or an electron-donating group. The compound of the present invention has the above-mentioned structure and therefore can provide a charge-separated state with longevity and not only high oxidizing power but also high reducing power and can be used for various products such as photocatalysts, photosensitizers, dyes, oxidants, reductants, dye-sensitized solar cells, and organic EL devices.

    摘要翻译： 提供电子给体 - 受体二元体，其可以提供长寿命的电荷分离状态，不仅具有高氧化能力，而且还具有高还原能力。 本发明化合物是下式（I）表示的喹啉鎓离子衍生物，其立体异构体或互变异构体或其盐：其中，R 1为氢原子或烷基，Ar 1〜Ar 3为氢 原子或给电子基团。 本发明的化合物具有上述结构，因此可以提供具有寿命的电荷分离状态，不仅具有高的氧化能力，而且还具有高的还原能力，并且可用于各种产物如光催化剂，光敏剂，染料，氧化剂 ，还原剂，染料敏化太阳能电池和有机EL器件。

    PROCESS FOR PRODUCTION OF OXIDATION REACTION PRODUCT OF AROMATIC COMPOUND
    3.
    发明申请
    PROCESS FOR PRODUCTION OF OXIDATION REACTION PRODUCT OF AROMATIC COMPOUND 审中-公开
    芳香化合物氧化反应产物的生产方法

    公开(公告)号：US20120171111A1

    公开(公告)日：2012-07-05

    申请号：US13496382

    申请日：2010-09-15

    申请人： Kei Ohkubo ,  Shunichi Fukuzumi ,  Kentaro Mizushima

    发明人： Kei Ohkubo ,  Shunichi Fukuzumi ,  Kentaro Mizushima

    IPC分类号： C07C41/22 ,  C07D409/14 ,  C07D333/28 ,  C07D409/04 ,  C01B15/029 ,  C07C209/74

    CPC分类号： C07D215/06 ,  C07C37/62 ,  C07C41/22 ,  C07C209/74 ,  C07C209/80 ,  C07D333/22 ,  C07D333/28 ,  C07C39/27 ,  C07C43/225 ,  C07C211/52 ,  C07C211/56

    摘要： The present invention provides a process for producing an oxidation reaction product of an aromatic compound, having excellent environmental load reduction performance, cost reduction performance, etc. Provided is a process for producing an oxidation reaction product of a raw material aromatic compound by reacting the raw material aromatic compound with an oxidizing agent. The process further uses an electron donor-acceptor linked molecule. The process includes the step of: reacting the electron donor-acceptor linked molecule in an electron-transfer state, the oxidizing agent, and the raw material aromatic compound, thereby generating an oxidation reaction product resulting from oxidation of the raw material aromatic compound.

    摘要翻译： 本发明提供了具有优异的环境负荷降低性能，成本降低性能等的芳香族化合物的氧化反应产物的制造方法。原料芳香族化合物的氧化反应生成物的制造方法是将原料芳香族化合物 物质芳族化合物与氧化剂。 该方法进一步使用电子给体 - 受体连接分子。 该方法包括以下步骤：使电子转移态的电子给体 - 受体连接分子，氧化剂和原料芳族化合物反应，由此产生由原料芳族化合物氧化产生的氧化反应产物。

    Photooxidation catalyst and production process for aldehyde derivatives
    4.
    发明授权
    Photooxidation catalyst and production process for aldehyde derivatives 失效
    光氧化催化剂和醛衍生物的生产工艺

    公开(公告)号：US06720458B2

    公开(公告)日：2004-04-13

    申请号：US10235834

    申请日：2002-09-06

    申请人： Kohei Morikawa ,  Shunichi Fukuzumi ,  Kei Ohkubo ,  Yutaka Ohnishi

    发明人： Kohei Morikawa ,  Shunichi Fukuzumi ,  Kei Ohkubo ,  Yutaka Ohnishi

    IPC分类号： C07C4536

    CPC分类号： B01J31/0231 ,  B01J31/006 ,  B01J31/0235 ,  B01J31/0271 ,  B01J35/004 ,  B01J2231/70 ,  C07C45/33 ,  C07C45/36 ,  C07C67/313 ,  C07C253/30 ,  C07C47/55 ,  C07C69/76 ,  C07C255/56

    摘要： The present invention relates to a catalyst useful for a photooxidation reaction and also relates to a novel process for producing aldehydes, particularly aromatic aldehydes, which are useful as an intermediate for the production of agrochemical and medical preparations. The catalyst is particularly suitable for the oxidation of a methyl group difficult to oxidize. A photooxidation catalyst according to the invention is a halogenated aromatic nitrile represented by the following formula (1): (wherein X represents a chlorine atom or a fluorine atom, m represents an integer of 1 to 5, n represents an integer of 1 to 5, m+n≦6, and when n is 2 or more, Xs may be the same or different).

    摘要翻译： 本发明涉及可用于光氧化反应的催化剂，还涉及一种生产醛，特别是芳族醛的新方法，其可用作生产农药和医药制剂的中间体。 该催化剂特别适用于难以氧化的甲基的氧化。根据本发明的光氧化催化剂是由下式（1）表示的卤代芳族腈:(其中X表示氯原子或氟原子，m 表示1〜5的整数，n表示1〜5的整数，m + n <= 6，n为2以上时，X可以相同也可以不同。