Production process of aminomethyl group-containing benzamide compound
    1.
    发明申请
    Production process of aminomethyl group-containing benzamide compound 失效
    含氨基甲基的苯甲酰胺化合物的生产工艺

    公开(公告)号:US20050203313A1

    公开(公告)日:2005-09-15

    申请号:US10515215

    申请日:2003-05-02

    CPC classification number: C07C231/06 C07C237/30

    Abstract: There is provided a process for producing an aminomethyl group-containing benzamide compound represented by the general formula (II): wherein —CONH2 and —X represent a substituent on the benzene ring and —CONH2 exists at the meta- or para-position of —CH2NH2, and X and n are as defined below, which comprises hydrating an aminomethyl group-containing benzonitrile compound represented by the general formula (I): wherein —CN and —X represent a substituent on the benzene ring and —CN exists at the meta- or para-position of —CH2NH2, X represents a chlorine atom or a fluorine atom, and n represents an integer of 0 to 4, provided that, when n is 2 or more, X may be the same or different.

    Abstract translation: 提供了用于制备由通式(II)表示的含氨基甲基的苯甲酰胺化合物的方法:其中-CONH 2和-X表示苯环上的取代基,-CONH 2存在于 - CH 2 NH 2,X和n定义如下,其包括水合由通式(I)表示的含氨基甲基的苄腈化合物:其中-CN和-X表示苯环上的取代基,-CN存在于元环 - 或-CH 2 NH 2的对位,X表示氯原子或氟原子,n表示0〜4的整数,条件是当n为2以上时,X可以相同或不同。

    Photooxidation catalyst and production process for aldehyde derivatives
    2.
    发明授权
    Photooxidation catalyst and production process for aldehyde derivatives 失效
    光氧化催化剂和醛衍生物的生产工艺

    公开(公告)号:US06720458B2

    公开(公告)日:2004-04-13

    申请号:US10235834

    申请日:2002-09-06

    Abstract: The present invention relates to a catalyst useful for a photooxidation reaction and also relates to a novel process for producing aldehydes, particularly aromatic aldehydes, which are useful as an intermediate for the production of agrochemical and medical preparations. The catalyst is particularly suitable for the oxidation of a methyl group difficult to oxidize. A photooxidation catalyst according to the invention is a halogenated aromatic nitrile represented by the following formula (1): (wherein X represents a chlorine atom or a fluorine atom, m represents an integer of 1 to 5, n represents an integer of 1 to 5, m+n≦6, and when n is 2 or more, Xs may be the same or different).

    Abstract translation: 本发明涉及可用于光氧化反应的催化剂,还涉及一种生产醛,特别是芳族醛的新方法,其可用作生产农药和医药制剂的中间体。 该催化剂特别适用于难以氧化的甲基的氧化。根据本发明的光氧化催化剂是由下式(1)表示的卤代芳族腈:(其中X表示氯原子或氟原子,m 表示1〜5的整数,n表示1〜5的整数,m + n <= 6,n为2以上时,X可以相同也可以不同。

    Fluoran compounds and color forming recording materials using same
    3.
    发明授权
    Fluoran compounds and color forming recording materials using same 失效
    氟类化合物和使用其的成色记录材料

    公开(公告)号:US4954631A

    公开(公告)日:1990-09-04

    申请号:US305554

    申请日:1989-02-02

    Abstract: Fluoran compounds are disclosed of formula (I) ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 independently represent hydrogen, halogen, lower alkoxy, C.sub.1 -C.sub.9 -alkyl, C.sub.5 or C.sub.6 -cycloalkyl, benzyl or phenyl, said benzyl or phenyl being optionally substituted by halogen, lower alkyl or lower alkoxy, and further R.sub.1 and R.sub.2 as well as R.sub.3 and R.sub.4 taken together with Ring A, may form a naphthalene ring optionally substituted by halogen, lower alkyl or lower alkoxy, R.sub.5, R.sub.6 and R.sub.7 independently represent halogen, lower alkyl or lower alkoxy, B.sub.1 and B.sub.2 independently represent hydrogen, C.sub.1 -C.sub.8 -alkyl, benzyl or phenyl, said benzyl or phenyl being optionally substituted by halogen, lower alkyl, lower alkoxy, or alkyl-substituted, X represents hydrogen atom or --NR.sub.8 R.sub.9 wherein R.sub.8 and R.sub.9 independently represent hydrogen, C.sub.1 -C.sub.8 -alkyl, C.sub.5 or C.sub.6 -cycloalkyl, or benzyl, said benzyl being optionally substituted by halogen, lower alkyl, lower alkoxy, or alkyl-substituted, and further R.sub.8 and R.sub.9 taken together with the adjacent nitrogen atom to which they are attached, may form a pyrrolidino, piperidino or morpholino ring, Ring B being optionally substituted by halogen, n, p and q independently represent 0, 1 or 2, and m represents 0, 1, 2 or 3, provided that when m is 0 or 1, X is not hydrogen atom. The compounds are used, together with a developer, in color forming recording materials such as pressure-sensitive copying papers, heat-sensitive recording papers and the like.

    Production process of aminomethyl group-containing benzamide compound
    4.
    发明授权
    Production process of aminomethyl group-containing benzamide compound 失效
    含氨基甲基的苯甲酰胺化合物的生产工艺

    公开(公告)号:US07227036B2

    公开(公告)日:2007-06-05

    申请号:US10515215

    申请日:2003-05-02

    CPC classification number: C07C231/06 C07C237/30

    Abstract: There is provided a process for producing an aminomethyl group-containing benzamide compound represented by the general formula (II): wherein —CONH2 and —X represent a substituent on the benzene ring and —CONH2 exists at the meta- or para-position of —CH2NH2, and X and n are as defined below, which comprises hydrating an aminomethyl group-containing benzonitrile compound represented by the general formula (I): wherein —CN and —X represent a substituent on the benzene ring and —CN exists at the meta- or para-position of —CH2NH2, X represents a chlorine atom or a fluorine atom, and n represents an integer of 0 to 4, provided that, when n is 2 or more, X may be the same or different

    Abstract translation: 提供了用于制备由通式(II)表示的含氨基甲基的苯甲酰胺化合物的方法:其中-CONH 2和-X表示苯环上的取代基,-CONH 2存在于 - CH 2 NH 2,X和n定义如下,其包括水合由通式(I)表示的含氨基甲基的苄腈化合物:其中-CN和-X表示苯环上的取代基,-CN存在于元环 - 或-CH 2 NH 2的对位,X表示氯原子或氟原子,n表示0〜4的整数,条件是当n为2以上时,X可以相同或不同

    Method for producing isocyanatoalkyl (meth)acrylate
    5.
    发明授权
    Method for producing isocyanatoalkyl (meth)acrylate 失效
    (甲基)丙烯酸异氰酸根合烷基酯的制备方法

    公开(公告)号:US06245935B1

    公开(公告)日:2001-06-12

    申请号:US09245707

    申请日:1999-02-08

    CPC classification number: C07C263/20 C07C265/04

    Abstract: A method for producing an isocyanatoalkyl (meth)acrylate substantially free of hydrolyzable chloride, comprising adding an amine and/or an imidazole and an epoxy group-containing compound and then purifying by distillation the isocyanatoalkyl (meth)acrylate until a 2-chloropropionic acid isocyanatoalkyl ester of an isocyanatoalkyl acrylate or a 2-methyl-2-chloropropionic acid isocyanatoalkyl ester of an isocyanatoalkyl methacrylate is substantially eliminated.

    Abstract translation: 一种制备基本上不含可水解氯化物的(甲基)丙烯酸异氰酸根合烷基酯的方法,包括加入胺和/或咪唑和含环氧基化合物,然后通过蒸馏纯化(甲基)丙烯酸异氰酸烷基酯直到2-氯丙酸异氰酸烷基酯 丙烯酸异氰酸根合烷基酯或甲基丙烯酸异氰酸根合烷基酯的2-甲基-2-氯丙酸异氰酸烷基酯的酯基本上被除去。

    Fluoran compounds and color forming recording materials using same
    6.
    发明授权
    Fluoran compounds and color forming recording materials using same 失效
    氟类化合物和使用其的成色记录材料

    公开(公告)号:US4826806A

    公开(公告)日:1989-05-02

    申请号:US79456

    申请日:1987-07-29

    Abstract: Fluoran compounds are disclosed of formula (I) ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 independently represent hydrogen, halogen, lower alkoxy, C.sub.1 -C.sub.9 -alkyl, C.sub.5 or C.sub.6 -cycloalkyl, benzyl or phenyl, said benzyl or phenyl being optionally substituted by halogen, lower alkyl or lower alkoxy, and further R.sub.1 and R.sub.2 as well as R.sub.3 and R.sub.4 taken together with Ring A, may form a naphthalene ring optionally substituted by halogen, lower alkyl or lower alkoxy, R.sub.5, R.sub.6 and R.sub.7 independently represent halogen, lower alkyl or lower alkoxy, B.sub.1 and B.sub.2 independently represent hydrogen, C.sub.1 -C.sub.8 -alkyl, benzyl or phenyl, said benzyl or phenyl being optionally substituted by halogen, lower alkyl, lower alkoxy, or alkyl-substituted amino, X represents hydrogen atom or --NR.sub.8 R.sub.9 wherein R.sub.8 and R.sub.9 independently represent hydrogen, C.sub.1 -C.sub.8 -alkyl, C.sub.5 or C.sub.6 -cycloalkyl, or benzyl, said benzyl being optionally substituted by halogen, lower alkyl, lower alkoxy, or alkyl-substituted amino, and further R.sub.8 and R.sub.9 taken together with the adjacent nitrogen atom to which they are attached, may form a pyrrolidino, piperidino or morpholino ring, Ring B being optionally substituted by halogen, n, p and q independently represent 0, 1 or 2, and m represents 0, 1, 2 or 3, provided that when m is 0 or 1, X is not hydrogen atom. The compounds are used, together with a developer, in color forming recording materials such as pressure-sensitive copying papers, heat-sensitive recording papers and the like.

    Abstract translation: 公开了式(I)的氟族化合物其中R 1,R 2,R 3和R 4独立地表示氢,卤素,低级烷氧基,C 1 -C 9 - 烷基,C 5或C 6 - 环烷基,苄基或苯基, 或任选被卤素,低级烷基或低级烷氧基取代的苯基,以及R 1和R 2以及R 3和R 4与环A一起可形成任选被卤素,低级烷基或低级烷氧基取代的萘环,R 5,R 6 并且R7独立地表示卤素,低级烷基或低级烷氧基,B1和B2独立地表示氢,C1-C8-烷基,苄基或苯基,所述苄基或苯基任选被卤素,低级烷基,低级烷氧基或烷基取代的氨基 ,X表示氢原子或-NR 8 R 9,其中R 8和R 9独立地表示氢,C 1 -C 8 - 烷基,C 5或C 6 - 环烷基或苄基,所述苄基任选被卤素,低级烷基,低级烷氧基或烷基取代的氨基 ,另外R8和R9结合在一起 h与它们相连的相邻氮原子可以形成吡咯烷基,哌啶子基或吗啉代环,环B任选被卤素取代,n,p和q独立地表示0,1或2,m表示0,1,2 或3,条件是当m为0或1时,X不为氢原子。 这些化合物与显影剂一起用于诸如压敏复印纸,热敏记录纸等的成色记录材料中。

    Hydraulic heat-resisting material and premold product made of such
hydraulic heat-resisting material
    7.
    发明授权
    Hydraulic heat-resisting material and premold product made of such hydraulic heat-resisting material 失效
    液压耐热材料和预制产品由这种液压耐热材料制成

    公开(公告)号:US4472201A

    公开(公告)日:1984-09-18

    申请号:US407343

    申请日:1982-08-12

    CPC classification number: C04B28/02

    Abstract: Hydraulic heat-resisting material of an improved thermal property which has high strength and high volume stability under high temperature is disclosed. The material substantially consists of 5 to 70 parts by weight of a mixture, the mixture consisting of 49.95 to 87.3% by weight of hydraulic cement, 49.95 to 9.7% by weight of amorphous silica and 0.1 to 3% by weight of a dispersing agent, and 95 to 30 parts by weight of a heat-resisting aggregate. Premold product made of the above material is also disclosed.

    Abstract translation: 公开了在高温下具有高强度和高体积稳定性的改进的热性能的液压耐热材料。 该材料基本上由5至70重量份的混合物组成,该混合物由49.95至87.3重量%的水硬水泥,49.95至9.7重量%的无定形二氧化硅和0.1至3重量%的分散剂组成, 和95〜30重量份的耐热骨料。 还公开了由上述材料制成的Premold产品。

    Spirobenzanthracene phthalide compounds, processes for preparing same
and color forming recording materials containing said compounds
    9.
    发明授权
    Spirobenzanthracene phthalide compounds, processes for preparing same and color forming recording materials containing said compounds 失效
    螺吡蒽酞化合物,其制备方法和含有所述化合物的成色记录材料

    公开(公告)号:US4794069A

    公开(公告)日:1988-12-27

    申请号:US72911

    申请日:1987-07-14

    CPC classification number: C09B11/24 B41M5/145 B41M5/327 Y10S430/165

    Abstract: Spirobenzanthracene phthalide compounds are disclosed of the formula (I) ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 independently represent C.sub.1 -C.sub.8 alkyl optionally substituted by C.sub.1 -C.sub.5 alkoxy; C.sub.5 or C.sub.6 cycloalkyl; or aralkyl or aryl optionally substituted by C.sub.1 -C.sub.5 alkyl or C.sub.1 -C.sub.5 alkoxy, and R.sup.1 and R.sup.2, R.sup.3 and R.sup.4, and R.sup.5 and R.sup.6 taken together with the nitrogen atom to which they are attached, may form pyrrolidino, piperidino or morpholino ring, and R.sup.7, R.sup.8, R.sup.9 and R.sup.10 independently represent hydrogen, C.sub.1 -C.sub.5 alkyl, C.sub.1 -C.sub.5 alkoxy or trifluoromethyl. The compounds are used, together with a developer, in color for materials such as pressure-sensitive copying papers, heat-sensitive recording papers and the like.

    Abstract translation: 公开了式(I)的化合物(I)其中R 1,R 2,R 3,R 4,R 5和R 6独立地表示任选被C 1 -C 5烷氧基取代的C 1 -C 8烷基; C5或C6环烷基; 或任选被C 1 -C 5烷基或C 1 -C 5烷氧基取代的芳烷基或芳基,并且R 1和R 2,R 3和R 4以及R 5和R 6与它们所连接的氮原子一起可以形成吡咯烷子基,哌啶子基或吗啉环 ,R 7,R 8,R 9和R 10独立地表示氢,C 1 -C 5烷基,C 1 -C 5烷氧基或三氟甲基。 化合物与显影剂一起用于诸如压敏复印纸,热敏记录纸等的材料。

    Fillet-welding equipment for pipe materials
    10.
    发明授权
    Fillet-welding equipment for pipe materials 失效
    管材的角焊设备

    公开(公告)号:US4576323A

    公开(公告)日:1986-03-18

    申请号:US558529

    申请日:1983-12-06

    Applicant: Yutaka Ohnishi

    Inventor: Yutaka Ohnishi

    CPC classification number: B23K9/028

    Abstract: A new and improved fillet welding equipment is disclosed which can be used to butt a pipe member against a plate-like surface and then weld the entire periphery of the butted pipe member. In this fillet welding equipment, a pair of welding torches are arranged such that their respective nozzles are opposed to and spaced about 90 degrees from each other. This pair of welding torches can be rotationally moved simultaneously and continuously through their respective predetermined ranges of about 90 degrees to weld one half round section of the entire periphery to be welded, which results in the reduced welding time.

    Abstract translation: 公开了一种新型改进的角焊设备,其可以用于将管件对接在板状表面上,然后焊接对接管件的整个周边。 在这种角焊设备中,一对焊炬被布置成使它们各自的喷嘴彼此相对并隔开90度。 这对焊炬可以同时且连续地旋转移动其各自约90度的预定范围,以焊接待焊接的整个周边的半圆形部分,这导致减少的焊接时间。

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