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    Polymer-supported metal complex catalyst
    1.
    发明授权
    Polymer-supported metal complex catalyst 有权
    聚合物负载金属络合物催化剂

    公开(公告)号：US08092720B2

    公开(公告)日：2012-01-10

    申请号：US12309660

    申请日：2007-06-20

    申请人： Shunichi Hashimoto ,  Masahiro Anada

    发明人： Shunichi Hashimoto ,  Masahiro Anada

    IPC分类号： H01B1/20 ,  B01J31/12

    CPC分类号： C07C67/317 ,  B01J31/1658 ,  B01J31/2239 ,  B01J31/2243 ,  B01J31/226 ,  B01J2231/321 ,  B01J2231/323 ,  B01J2231/325 ,  B01J2231/326 ,  B01J2231/327 ,  B01J2231/342 ,  B01J2231/348 ,  B01J2231/46 ,  B01J2231/645 ,  B01J2531/0219 ,  B01J2531/822 ,  C07B53/00 ,  C07D209/48 ,  C07D307/84 ,  C08F8/42 ,  C08F212/08 ,  C07C69/753 ,  C07C69/757 ,  C08F212/00 ,  C08F212/32 ,  C08F212/34

    摘要： Polymer supported metal complex catalysts and methods of their preparation and use are described. The polymer supported metal complex catalysts can be obtained via ligand exchange reactions between polymer ligands and a metal complex having catalytic activity. For example, a polymer supported rhodium (II) complex catalyst can be prepared via ligand exchange reaction between an insoluble polymer and a rhodium (II) carboxylate complex, wherein the insoluble polymer is prepared by a copolymerization reaction of (i) a styrene derivative with a substituted carboxylic acid, (ii) a styrene, and (iii) a linear alkane with both ends substituted by vinylbenzyloxy groups. The polymer supported catalysts can be used to catalyze asymmetric carbene reactions such as C—H insertion reactions and the like with high catalytic activity, chemical selectivity, diastereoselectivity, and enantioselectivity.

    摘要翻译： 描述了聚合物负载的金属络合物催化剂及其制备和用途的方法。 聚合物负载的金属络合物催化剂可以通过聚合物配体和具有催化活性的金属络合物之间的配体交换反应获得。 例如，可以通过不溶性聚合物和铑（II）羧酸络合物之间的配体交换反应来制备聚合物负载的铑（II）配合物催化剂，其中不溶性聚合物通过（i）苯乙烯衍生物与 取代的羧酸，（ii）苯乙烯，和（iii）两端被乙烯基苄氧基取代的直链烷烃。 聚合物负载的催化剂可用于催化具有高催化活性，化学选择性，非对映选择性和对映体选择性的不对称卡宾反应如C-H插入反应等。

    POLYMER-SUPPORTED METAL COMPLEX CATALYST
    2.
    发明申请
    POLYMER-SUPPORTED METAL COMPLEX CATALYST 有权
    聚合物支持的金属复合催化剂

    公开(公告)号：US20090227743A1

    公开(公告)日：2009-09-10

    申请号：US12309660

    申请日：2007-06-20

    申请人： Shunichi Hashimoto ,  Masahiro Anada

    发明人： Shunichi Hashimoto ,  Masahiro Anada

    IPC分类号： C08F8/42 ,  C07C69/74 ,  C07D307/87 ,  C07C69/76

    CPC分类号： C07C67/317 ,  B01J31/1658 ,  B01J31/2239 ,  B01J31/2243 ,  B01J31/226 ,  B01J2231/321 ,  B01J2231/323 ,  B01J2231/325 ,  B01J2231/326 ,  B01J2231/327 ,  B01J2231/342 ,  B01J2231/348 ,  B01J2231/46 ,  B01J2231/645 ,  B01J2531/0219 ,  B01J2531/822 ,  C07B53/00 ,  C07D209/48 ,  C07D307/84 ,  C08F8/42 ,  C08F212/08 ,  C07C69/753 ,  C07C69/757 ,  C08F212/00 ,  C08F212/32 ,  C08F212/34

    摘要： The present invention relates to a polymer-supported rhodium (II) catalyst and its application, which includes addition reaction to carbon-carbon multiple bond in α-diazocarbonyl compounds, insertion reaction to C—H and X—H (X═N, O, S, Se, Si and the like) bonds, or rearrangement and additional cyclization reaction thereofA novel insoluble polymer-supported rhodium (II) complex was prepared through a ligand exchange reaction between an insoluble polymer and a rhodium (II) carboxylato complex, wherein the insoluble polymer was prepared by a copolymerization reaction of (i) a styrene derivative with substituted carboxylic acid, (ii) a stylene, and (iii) a linear alkane with both ends substituted by vinylbenzyloxy groups,Namely, a polymer-supported metal complex catalyst having the following chemical formula 1: wherein M1 and M2 are rhodium, and the like; and X is an oxygen atom, etc; and R4 is an alkyl group, and the like; and k is 1 to 15%, m is 1 to 5% relative to k+l+m, and l is the remainder; and n is 4 and others; and R1 is alkyl-2-(4′-alkyloxy phthalimido methyl), etc, R2 is phenyl, etc; R3 is 4,4′-(1,3-propyrene-1,3-dioxymethyl)phenyl, etc.

    摘要翻译： 本发明涉及一种聚合物负载的铑（II）催化剂及其应用，其包括对α-二氮羰基化合物中碳 - 碳多键的加成反应，与CH和XH的插入反应（XN，O，S，Se，Si 等等）键，或重排和其他环化反应通过不溶性聚合物和铑（II）羧酸盐络合物之间的配体交换反应制备新的不溶性聚合物负载的铑（II）络合物，其中制备不溶性聚合物 通过（i）苯乙烯衍生物与取代羧酸的共聚反应，（ii）亚芳基和（iii）两端被乙烯基苄氧基取代的直链烷烃即具有以下化学式的聚合物负载的金属配合物催化剂 式1：其中M1和M2是铑等; X为氧原子等; 和R4是烷基等; k为1〜15％，m为1〜5％相对于k + 1 + m，l为余量; n为4等; R1是烷基-2-（4'-烷氧基苯二甲酰亚氨基甲基）等，R2是苯基等; R3是4,4' - （1,3-丙苯-1,3-二氧甲基）苯基等

    Image forming apparatus having support members with predetermined electric potentials
    3.
    发明授权
    Image forming apparatus having support members with predetermined electric potentials 有权
    具有具有预定电位的支撑构件的图像形成装置

    公开(公告)号：US08909112B2

    公开(公告)日：2014-12-09

    申请号：US12879585

    申请日：2010-09-10

    申请人： Tomoko Takahashi ,  Naoyuki Ozaki ,  Ryuji Yoshida ,  Nobuyuki Koinuma ,  Hiroaki Maeda ,  Shunichi Hashimoto ,  Mugijirou Uno ,  Yoshinori Nakagawa ,  Mikio Ishibashi ,  Hideki Zemba

    发明人： Tomoko Takahashi ,  Naoyuki Ozaki ,  Ryuji Yoshida ,  Nobuyuki Koinuma ,  Hiroaki Maeda ,  Shunichi Hashimoto ,  Mugijirou Uno ,  Yoshinori Nakagawa ,  Mikio Ishibashi ,  Hideki Zemba

    IPC分类号： G03G15/01 ,  G03G15/20 ,  G03G15/16

    CPC分类号： G03G15/0131 ,  G03G15/1605 ,  G03G15/161

    摘要： An image forming apparatus including a conveyance unit to convey a transfer medium, a first image forming unit to form a monochrome image transferred at a first transfer position onto the transfer medium, and a second image forming unit disposed downstream from the first image forming unit in a direction of conveyance of the transfer medium, including an intermediate transfer body to form a multi-colored toner image on the intermediate transfer body. The multi-colored toner image is transferred onto the transfer medium at a second transfer position. The conveyance unit is separated from the intermediate transfer body at the second transfer position in a monochrome mode to form the monochrome image using only the first image forming unit, and contacts the intermediate transfer body at the second transfer position in a full-color mode to form a full-color image using both the first and second image forming units.

    摘要翻译： 一种图像形成装置，包括：传送单元，用于传送转印介质;第一图像形成单元，形成在第一转印位置转印到转印介质上的单色图像;以及第二图像形成单元，设置在第一图像形成单元的下游 转印介质的输送方向，包括中间转印体，以在中间转印体上形成多色调色剂图像。 多色调色剂图像在第二转印位置转印到转印介质上。 输送单元在单色模式下在第二转印位置处与中间转印体分离，以仅使用第一图像形成单元形成单色图像，并且以全色模式在第二转印位置处接触中间转印体， 使用第一和第二图像形成单元形成全色图像。

    Image forming apparatus
    4.
    发明授权
    Image forming apparatus 失效
    图像形成装置

    公开(公告)号：US08761651B2

    公开(公告)日：2014-06-24

    申请号：US13137014

    申请日：2011-07-15

    申请人： Ryuji Yoshida ,  Nobuyuki Koinuma ,  Mugijirou Uno ,  Tomoko Takahashi ,  Mikio Ishibashi ,  Hideki Zemba ,  Yoshinori Nakagawa ,  Shunichi Hashimoto ,  Naoyuki Ozaki ,  Hideaki Kanaya

    发明人： Ryuji Yoshida ,  Nobuyuki Koinuma ,  Mugijirou Uno ,  Tomoko Takahashi ,  Mikio Ishibashi ,  Hideki Zemba ,  Yoshinori Nakagawa ,  Shunichi Hashimoto ,  Naoyuki Ozaki ,  Hideaki Kanaya

    IPC分类号： G03G15/20

    CPC分类号： G03G15/1695 ,  G03G15/2064 ,  G03G2215/1666

    摘要： An image forming apparatus, including a fixing liquid applicator applying a fixing liquid including a plasticizer swelling and softening a toner forming a toner image to fix on a recording medium thereto before bearing the toner image; a transferer transferring the toner image on a toner image bearer onto the recording medium while contacting the toner image to the fixing liquid thereon; and a fixing device heating the toner image and the fixing liquid to fix the toner image thereon, wherein the fixing liquid applicator comprises an application member bearing the fixing liquid on its surface and apply the liquid on a surface of the recording medium the toner image is transferred onto; a feeder feeding the fixing liquid to the application member; and an inducement mechanism inducing the fixing liquid pooling at a delivery point where the feeder feeds the fixing liquid to the application member out of the point.

    摘要翻译： 一种图像形成装置，包括施加包含增塑剂的定影液膨胀并固化形成调色剂图像的调色剂的定影液体施加器，以在承载调色剂图像之前固定在记录介质上; 转印器将调色剂图像载体转印到记录介质上，同时使调色剂图像与定影液体接触; 以及定影装置加热调色剂图像和定影液以将调色剂图像固定在其上，其中定影液施加器包括在其表面上承载定影液体的施加构件，并将该液体施加在记录介质的表面上，调色剂图像为 转移到 将定影液供给到施加部件的送料器; 以及诱导机构，其将所述定影液体汇集在所述输送点处，所述输送点将所述定影液供给到所述施加部件。

    Conductive member, and charging roller, process cartridge and image forming apparatus using same
    7.
    发明授权
    Conductive member, and charging roller, process cartridge and image forming apparatus using same 有权
    导电构件和充电辊，处理盒和使用其的成像装置

    公开(公告)号：US07603062B2

    公开(公告)日：2009-10-13

    申请号：US11517390

    申请日：2006-09-08

    申请人： Eiji Shimojo ,  Masanori Kawasumi ,  Yoshiyuki Kimura ,  Masahiko Satoh ,  Takeshi Uchitani ,  Hideki Zemba ,  Yutaka Narita ,  Shunichi Hashimoto ,  Eisaku Murakami ,  Shin Kayahara

    发明人： Eiji Shimojo ,  Masanori Kawasumi ,  Yoshiyuki Kimura ,  Masahiko Satoh ,  Takeshi Uchitani ,  Hideki Zemba ,  Yutaka Narita ,  Shunichi Hashimoto ,  Eisaku Murakami ,  Shin Kayahara

    IPC分类号： G03G15/02

    CPC分类号： G03G15/0208 ,  G03G15/025 ,  G03G2215/025

    摘要： A conductive member, including a long conductive supporting body, an electrical resistance adjusting layer, disposed on the outer circumferential surface of the conductive supporting body and having a reduced diameter section at either end, and a pair of gap maintaining members which are respectively fitted onto said reduced diameter sections of the electrical resistance adjusting layer. The outer circumferential surfaces of the gap maintaining members have a height differential with respect to the outer circumferential surface of the electrical resistance adjusting layer, in such a manner that when abutted against an image carrier, a prescribed gap is formed between the outer circumferential surface of the image carrier and the outer circumferential surface of the electrical resistance adjusting layer. An interval between the end faces of the electrical resistance adjusting layer and the faces of the gap maintaining members opposing the end faces satisfies a predetermined relationship.

    摘要翻译： 导电构件，包括长导电支撑体，电阻调节层，设置在导电支撑体的外圆周表面上，并且在任一端具有减小的直径部分，以及一对间隙保持构件，其分别装配到 所述电阻调节层的直径减小部分。 间隙保持构件的外周面相对于电阻调节层的外周面具有高度差，使得当抵靠图像载体时，在外周面之间形成规定的间隙 图像载体和电阻调节层的外周面。 电阻调节层的端面与与端面相对的间隙保持构件的面之间的间隔满足规定的关系。

    DEVELOPMENT DEVICE, PROCESS CARTRIDGE, AND IMAGE FORMING APPARATUS USING THE DEVELOPMENT DEVICE
    8.
    发明申请
    DEVELOPMENT DEVICE, PROCESS CARTRIDGE, AND IMAGE FORMING APPARATUS USING THE DEVELOPMENT DEVICE 有权
    开发设备，过程盒和使用开发设备的图像形成设备

    公开(公告)号：US20080226311A1

    公开(公告)日：2008-09-18

    申请号：US12049838

    申请日：2008-03-17

    申请人： Tetsuya Senoh ,  Eisaku Murakami ,  Masahiko Satoh ,  Masanori Kawasumi ,  Hideki Zemba ,  Takeshi Uchitani ,  Kenichi Taguma ,  Shunichi Hashimoto

    发明人： Tetsuya Senoh ,  Eisaku Murakami ,  Masahiko Satoh ,  Masanori Kawasumi ,  Hideki Zemba ,  Takeshi Uchitani ,  Kenichi Taguma ,  Shunichi Hashimoto

    IPC分类号： G03G15/08

    CPC分类号： G03G15/0808 ,  G03G15/0877 ,  G03G15/0879 ,  G03G15/0893 ,  G03G2215/0838

    摘要： A novel development device includes a developer roller, a developer reservoir, a rotatable conveyor, and a replenisher unit. The developer roller is configured to supply toner particles to the electrostatic latent image. The developer reservoir is configured to hold the developer therewithin for application to the developer roller. The rotatable conveyor is configured to rotate within the developer reservoir to convey the developer toward the developer roller. The replenisher unit has a tubular member terminating at a port opening in the developer reservoir. The replenisher unit is configured to direct a particulate material through the tubular member into the developer reservoir via the port. The particulate material is toner particles, carrier particles, or a mixture of toner particles and a given amount of carrier particles. The port is submerged in the developer within the developer reservoir as the rotatable conveyor rotates.

    摘要翻译： 一种新颖的显影装置包括显影辊，显影剂储存器，可旋转输送机和补充单元。 显影辊构造成将调色剂颗粒供应到静电潜像。 显影剂储存器构造成将显影剂保持在其中以供显影辊使用。 旋转输送机构造成在显影剂储存器内旋转以将显影剂输送到显影辊。 补充单元具有终止于显影剂储存器中的开口处的管状构件。 补充单元构造成经由端口将颗粒材料引导通过管状构件进入显影剂储存器。 颗粒材料是调色剂颗粒，载体颗粒或调色剂颗粒和给定量的载体颗粒的混合物。 当可旋转输送机旋转时，端口被浸没在显影剂储存器内的显影剂中。

    Conductive member, and charging roller, process cartridge and image forming apparatus using same
    10.
    发明申请
    Conductive member, and charging roller, process cartridge and image forming apparatus using same 有权
    导电构件和充电辊，处理盒和使用其的成像装置

    公开(公告)号：US20070065178A1

    公开(公告)日：2007-03-22

    申请号：US11517390

    申请日：2006-09-08

    申请人： Eiji Shimojo ,  Masanori Kawasumi ,  Yoshiyuki Kimura ,  Masahiko Satoh ,  Takeshi Uchitani ,  Hideki Zemba ,  Yutaka Narita ,  Shunichi Hashimoto ,  Eisaku Murakami ,  Shin Kayahara

    发明人： Eiji Shimojo ,  Masanori Kawasumi ,  Yoshiyuki Kimura ,  Masahiko Satoh ,  Takeshi Uchitani ,  Hideki Zemba ,  Yutaka Narita ,  Shunichi Hashimoto ,  Eisaku Murakami ,  Shin Kayahara

    IPC分类号： G03G15/02

    CPC分类号： G03G15/0208 ,  G03G15/025 ,  G03G2215/025

    摘要： A conductive member forming a charging roller having high durability which maintains a stable gap with respect to an abutting member, comprising a long conductive supporting body, an electrical resistance adjusting layer, and gap maintaining members, wherein, taking X2 to be the thickness of the portions of the gap maintaining members which oppose the end faces of the electrical resistance adjusting layer, the relationship 1 mm≦X2≦3 mm is satisfied, taking X3 to be the interval between the end faces of the electrical resistance adjusting layer and the gap maintaining members which oppose these end faces, the relationship 0.1≦X3≦1 mm is satisfied, and taking X4 to be the interval from the faces of the gap maintaining members opposing the end faces of the electrical resistance adjusting layer, to the step difference faces of the reduced diameter sections of the electrical resistance adjusting layer, then X4 is 5 mm or greater, and is shorter than the length from the faces of the gap maintaining members which oppose the end faces of the electrical resistance adjusting layer to the positions on the electrical resistance adjusting layer opposing the end sections which correspond to the image forming region of the photosensitive body.

    摘要翻译： 一种导电构件，其形成具有高耐久性的充电辊，其相对于邻接构件保持稳定的间隙，包括长导电支撑体，电阻调节层和间隙保持构件，其中，X 2， SUB>为与电阻调节层的端面相对的间隙保持构件的部分的厚度，满足关系1 mm <= X 2 <= 3 mm，取X 3 <3>为电阻调节层的端面与与这些端面相对的间隙保持构件之间的间隔，关系式0.1 <= X 3 <= 1 mm，并且将X 4从与电阻调节层的端面相对的间隙保持部件的表面的距离设定为与电阻调节层的端面相对的直径部分的台阶差面 电阻调节层，则X 4是5mm或 并且比从与电阻调节层的端面相对的间隙保持构件的面相对于与感光体的图像形成区域对应的端部的电阻调节层的位置的长度短 身体。